CN108102523A - A kind of glass fungus-proof powder that can be recycled and preparation method thereof - Google Patents

A kind of glass fungus-proof powder that can be recycled and preparation method thereof Download PDF

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Publication number
CN108102523A
CN108102523A CN201711386698.5A CN201711386698A CN108102523A CN 108102523 A CN108102523 A CN 108102523A CN 201711386698 A CN201711386698 A CN 201711386698A CN 108102523 A CN108102523 A CN 108102523A
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powder
proof powder
acid
glass
recycled
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CN201711386698.5A
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CN108102523B (en
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马丽涛
崔岩
王硕
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Ward Xiao County Chemical Industry Science Co Ltd
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Ward Xiao County Chemical Industry Science Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C23/00Other surface treatment of glass not in the form of fibres or filaments
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/10Homopolymers or copolymers of propene
    • C09D123/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/03Powdery paints
    • C09D5/033Powdery paints characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to glass technology fields, and in particular to a kind of glass fungus-proof powder that can be recycled and preparation method thereof;Its ingredient includes:The basic powder of skeleton isolation, waterglass, hydrochloric acid, boric anhydride, sorbic acid, ethanedioic acid, reindeer moss, appropriate amount of water;The present invention is using silica gel as padded coaming and mould proof powder carrier, certain cushioning effect can be not only played when in use, it can also absorb water in the first stage for generation of going mouldy, the two or three stage gone mouldy sponges the alkaline matter of generation, largely avoids going mouldy for glass;In addition reindeer moss powder is contained in the mould proof powder, the state of the mould proof powder can be shown, so as to which staff is facilitated to understand whether mould proof powder fails, if be not used, and take this as a foundation and recycled and replaced mould proof powder, while improve anti-mold effect and economic benefit.

Description

A kind of glass fungus-proof powder that can be recycled and preparation method thereof
Technical field
The present invention relates to glass technology fields, and in particular to a kind of glass fungus-proof powder that can be recycled and its preparation side Method.
Background technology
Finished glass plate needs to be packaged before storing after shipping, impaired to prevent glass surface from scratching, adjacent during packing There is separation layer between two sheet glass, separation layer is also prevented from glass plate because of Electrostatic Absorption together;Glass product (such as tablet Glass and its fabricated product) it is as improper in stored transport, corrosion (mouldy) can be scratched or generated due to the friction between glass, influence The final use of glass, so as to cause serious economic loss;Glass " mouldy " in storage is moisture in air in glass Surface condensation triggers;It is mouldy that glass appearance is made seriously to be stained;To prevent weathering of glass, ordinary plate glass is often required to chemistry Interleaving agent;
It existing mould proof powder higher price and is difficult to recycle again mostly, cost is higher;And preparation section is cumbersome, Flow is complicated;It needs to additionally introduce isolated material.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of glass fungus-proof powder that can be recycled, not only have and pass It unites the antimildew function of mould proof powder, the mould proof powder partly not failed can also be recycled, the mould proof powder contains silica gel in addition, can To play the role of certain buffering and antiwear.
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of glass fungus-proof powder that can be recycled, ingredient is by weight:Basic 30~40 parts of the powder of skeleton isolation, water 20~30 parts of glass, 40~60 parts of hydrochloric acid, 10~25 parts of boric anhydride, 1~5 part of sorbic acid, 1~5 part of ethanedioic acid, copper chloride 1~3 Part, appropriate amount of water.
A kind of preparation method for the glass fungus-proof powder that can be recycled comprises the following steps:
A, crush:After weighing raw material by proportioning, skeleton is isolated into basic powder, boric anhydride, sorbic acid, benzoic acid, ethanedioic acid It is respectively put into copper chloride in ball mill and carries out ball milling, the rotating speed of ball milling is 1000~1100rpm;
B, dissolving, reaction:By hydrochloric acid and the basic powder of the skeleton obtained through step a isolation, boric anhydride, sorbic acid, benzoic acid, Ethanedioic acid and copper chloride are added in suitable quantity of water, and make solvent fully dispersed using ultrasonic vibration, it is to be mixed uniformly after can be by water Glass is poured into water, and solution is heated while waterglass is poured into, and sustained oscillation, and solid is obtained after moisture is evaporated Obtained solid component is denoted as component a by component;
C, crush:Step is obtained component a through b first to shred as several fritters, then is ground processing, is finally putting into ball milling Ball milling is carried out in machine, gained powder is mould proof powder finished product;
Preferably, the grain size of powder is 600~1000 mesh after ball milling in the step a,
Preferably, the grain size of powder is 400~500 mesh after ball milling in the step c.
Preferably, the rotating speed of the step c ball millings is 1000~1100rpm.
Preferably, the frequency of ultrasonic disperse is 50~100Hz in the step b, and heating temperature is 50~90 DEG C.
Preferably, the basic powder of skeleton isolation includes polyester resin, polyethylene, polypropylene and polymethyl methacrylate One or more therein.
Advantageous effect:
The present invention can not only play certain buffering and make when in use using silica gel as padded coaming and mould proof powder carrier With can also absorb water in the first stage for generation of going mouldy, absorb the alkaline matter of generation in the two or three stage gone mouldy Fall, largely avoid going mouldy for glass;In addition in the mould proof powder the mould proof powder can be shown containing chlorination copper powders State, after mould proof powder fails, copper chloride integrally becomes blue with the alkali reaction generation blue precipitate generated when going mouldy, mould proof powder Color, so as to which staff is facilitated to understand whether mould proof powder fails, if be not used, and take this as a foundation and carry out recycling and more It relieves a garrison mould powder, while improves anti-mold effect and economic benefit.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention, Technical solution in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making All other embodiments obtained under the premise of creative work, belong to the scope of protection of the invention.
Embodiment 1:
A kind of glass fungus-proof powder that can be recycled, ingredient is by weight:15 parts of polyester resin, 15 parts of polyethylene, 25 parts of waterglass, 50 parts of hydrochloric acid, 15 parts of boric anhydride, 1 part of sorbic acid, 3 parts of ethanedioic acid, 2 parts of copper chloride, appropriate amount of water.
A kind of preparation method for the glass fungus-proof powder that can be recycled comprises the following steps:
A, crush:After weighing raw material by proportioning, skeleton is isolated into basic powder, boric anhydride, sorbic acid, benzoic acid, ethanedioic acid It is respectively put into copper chloride in ball mill and carries out ball milling, the rotating speed of a ball millings is 1050rpm, and the mesh number of ball milling is 600 mesh;
B, dissolving, reaction:By hydrochloric acid and the basic powder of the skeleton obtained through step a isolation, boric anhydride, sorbic acid, benzoic acid, Ethanedioic acid is added to copper chloride in suitable quantity of water, and makes solvent fully dispersed using ultrasonic vibration, and the frequency of ultrasonic disperse is 75Hz;It is to be mixed uniformly after waterglass can be poured into water, solution is heated while waterglass is poured into, heating temperature For 50 DEG C;And sustained oscillation, solid constituent is obtained after moisture is evaporated, obtained solid component is denoted as component a;
C, crush:Step is obtained component a through b first to shred as several fritters, then is ground processing, is finally putting into ball milling Ball milling is carried out in machine, gained powder is mould proof powder finished product, and the rotating speed of a ball millings is 1100rpm, and the mesh number of ball milling is 450 mesh.
Embodiment 2:
A kind of glass fungus-proof powder that can be recycled, ingredient is by weight:20 parts of polyethylene, 15 parts of polypropylene, water 20 parts of glass, 40 parts of hydrochloric acid, 25 parts of boric anhydride, 3 parts of sorbic acid, 2 parts of ethanedioic acid, 3 parts of copper chloride, appropriate amount of water.
A kind of preparation method for the glass fungus-proof powder that can be recycled comprises the following steps:
A, crush:After weighing raw material by proportioning, skeleton is isolated into basic powder, boric anhydride, sorbic acid, benzoic acid, ethanedioic acid It is respectively put into copper chloride in ball mill and carries out ball milling, the rotating speed of a ball millings is 1000rpm, and the mesh number of ball milling is 750 mesh;
B, dissolving, reaction:By hydrochloric acid and the basic powder of the skeleton obtained through step a isolation, boric anhydride, sorbic acid, benzoic acid, Ethanedioic acid is added to copper chloride in suitable quantity of water, and makes solvent fully dispersed using ultrasonic vibration, and the frequency of ultrasonic disperse is 60Hz;It is to be mixed uniformly after waterglass can be poured into water, solution is heated while waterglass is poured into, heating temperature For 70 DEG C;And sustained oscillation, solid constituent is obtained after moisture is evaporated, obtained solid component is denoted as component a;
C, crush:Step is obtained component a through b first to shred as several fritters, then is ground processing, is finally putting into ball milling Ball milling is carried out in machine, gained powder is mould proof powder finished product, and the rotating speed of a ball millings is 1050rpm, and the mesh number of ball milling is 500 mesh.
Embodiment 3:
A kind of glass fungus-proof powder that can be recycled, ingredient is by weight:Polipropene 25 part, poly-methyl methacrylate 15 parts of ester, 25 parts of waterglass, 55 parts of hydrochloric acid, 10 parts of boric anhydride, 4 parts of sorbic acid, 5 parts of ethanedioic acid, 1 part of copper chloride, appropriate amount of water.
A kind of preparation method for the glass fungus-proof powder that can be recycled comprises the following steps:
A, crush:After weighing raw material by proportioning, skeleton is isolated into basic powder, boric anhydride, sorbic acid, benzoic acid, ethanedioic acid It is respectively put into copper chloride in ball mill and carries out ball milling, the rotating speed of a ball millings is 100rpm, and the mesh number of ball milling is 900 mesh;
B, dissolving, reaction:By hydrochloric acid and the basic powder of the skeleton obtained through step a isolation, boric anhydride, sorbic acid, benzoic acid, Ethanedioic acid is added to copper chloride in suitable quantity of water, and makes solvent fully dispersed using ultrasonic vibration, and the frequency of ultrasonic disperse is 50Hz;It is to be mixed uniformly after waterglass can be poured into water, solution is heated while waterglass is poured into, heating temperature For 80 DEG C;And sustained oscillation, solid constituent is obtained after moisture is evaporated, obtained solid component is denoted as component a;
C, crush:Step is obtained component a through b first to shred as several fritters, then is ground processing, is finally putting into ball milling Ball milling is carried out in machine, gained powder is mould proof powder finished product, and the rotating speed of a ball millings is 1000rpm, and the mesh number of ball milling is 400 mesh.
Embodiment 4:
A kind of glass fungus-proof powder that can be recycled, ingredient is by weight:15 parts of polyester resin, polymethylacrylic acid 20 parts of methyl esters, 30 parts of waterglass, 60 parts of hydrochloric acid, 20 parts of boric anhydride, 5 parts of sorbic acid, 1 part of ethanedioic acid, 3 parts of copper chloride, appropriate amount of water.
A kind of preparation method for the glass fungus-proof powder that can be recycled comprises the following steps:
A, crush:After weighing raw material by proportioning, skeleton is isolated into basic powder, boric anhydride, sorbic acid, benzoic acid, ethanedioic acid It is respectively put into copper chloride in ball mill and carries out ball milling, the rotating speed of a ball millings is 1050rpm, and the mesh number of ball milling is 1000 mesh;
B, dissolving, reaction:By hydrochloric acid and the basic powder of the skeleton obtained through step a isolation, boric anhydride, sorbic acid, benzoic acid, Ethanedioic acid is added to copper chloride in suitable quantity of water, and makes solvent fully dispersed using ultrasonic vibration, and the frequency of ultrasonic disperse is 100Hz;It is to be mixed uniformly after waterglass can be poured into water, solution is heated while waterglass is poured into, heating temperature It spends for 90 DEG C;And sustained oscillation, solid constituent is obtained after moisture is evaporated, obtained solid component is denoted as component a;
C, crush:Step is obtained component a through b first to shred as several fritters, then is ground processing, is finally putting into ball milling Ball milling is carried out in machine, gained powder is mould proof powder finished product, and the rotating speed of a ball millings is 1100rpm, and the mesh number of ball milling is 450 mesh.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to Non-exclusive inclusion, so that process, method, article or equipment including a series of elements not only will including those Element, but also including other elements that are not explicitly listed or further include as this process, method, article or equipment Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that Also there are other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments The present invention is described in detail, it will be understood by those of ordinary skill in the art that:It still can be to foregoing each implementation Technical solution recorded in example modifies or carries out equivalent substitution to which part technical characteristic;And these modification or It replaces, the essence of appropriate technical solution is not made to depart from the spirit and scope of various embodiments of the present invention technical solution.

Claims (7)

1. a kind of glass fungus-proof powder that can be recycled, it is characterised in that:Its ingredient is by weight:The basic powder 30 of skeleton isolation ~40 parts, 20~30 parts of waterglass, 40~60 parts of hydrochloric acid, 10~25 parts of boric anhydride, 1~5 part of sorbic acid, 1~5 part of ethanedioic acid, 1~3 part of copper chloride, appropriate amount of water.
2. a kind of glass fungus-proof powder that can be recycled according to claim 1, it is characterised in that:Preparation method include with Lower step:
A, crush:After weighing raw material by proportioning, skeleton is isolated into basic powder, boric anhydride, sorbic acid, benzoic acid, ethanedioic acid and chlorine Change copper, which is respectively put into ball mill, carries out ball milling, and the rotating speed of ball milling is 1000~1100rpm;
B, dissolving, reaction:By hydrochloric acid and the basic powder of the skeleton obtained through step a isolation, boric anhydride, sorbic acid, benzoic acid, second two Acid is added in suitable quantity of water with copper chloride, and makes solvent fully dispersed using ultrasonic vibration, it is to be mixed uniformly after can be by waterglass It is poured into water, solution is heated while waterglass is poured into, and sustained oscillation, solid group is obtained after moisture is evaporated Point, obtained solid component is denoted as component a;
C, crush:Step is obtained component a through b first to shred as several fritters, then is ground processing, is finally putting into ball mill Ball milling is carried out, gained powder is mould proof powder finished product.
3. a kind of glass fungus-proof powder that can be recycled according to claim 2, it is characterised in that:Ball in the step a The grain size of powder is 600~1000 mesh after mill.
4. a kind of glass fungus-proof powder that can be recycled according to claim 2, it is characterised in that:Ball in the step c The grain size of powder is 400~500 mesh after mill.
5. a kind of glass fungus-proof powder that can be recycled according to claim 1, it is characterised in that:The step c ball millings Rotating speed be 1000~1100rpm.
6. a kind of glass fungus-proof powder that can be recycled according to claim 1, it is characterised in that:Surpass in the step b The frequency that sound disperses is 50~100Hz, and heating temperature is 50~90 DEG C.
7. a kind of glass fungus-proof powder that can be recycled according to claim 1, it is characterised in that:The skeleton isolates base Plinth powder includes polyester resin, polyethylene, polypropylene and polymethyl methacrylate one or more therein.
CN201711386698.5A 2017-12-20 2017-12-20 Recyclable glass mildew-proof powder and preparation method thereof Expired - Fee Related CN108102523B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116036963A (en) * 2023-01-15 2023-05-02 惠州市宝斯特实业有限公司 Production equipment and production process for glass mildew-proof isolation powder
CN116496670A (en) * 2023-05-16 2023-07-28 惠州市宝斯特实业有限公司 Long-acting glass mildew-proof powder and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1477204A (en) * 1974-04-25 1977-06-22 Pinlkington Bros Ltd Interleaving materials for glass sheets
GB8921230D0 (en) * 1988-09-30 1989-11-08 Pagano Carmine A Glass interleaving,anti-staining and black spot eliminating materials
CA2185159A1 (en) * 1995-09-15 1997-03-16 Helmut Franz Buffered Acid Interleaving for Glass Sheets
CN102070881A (en) * 2011-01-11 2011-05-25 常峰 Mildewproof insulation material for glass and preparation method thereof
CN102432194A (en) * 2011-09-23 2012-05-02 泰州远创新材料科技有限公司 Novel glass mildew remover
CN105994357A (en) * 2016-05-21 2016-10-12 杨勇 Compound mildew preventive

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1477204A (en) * 1974-04-25 1977-06-22 Pinlkington Bros Ltd Interleaving materials for glass sheets
GB8921230D0 (en) * 1988-09-30 1989-11-08 Pagano Carmine A Glass interleaving,anti-staining and black spot eliminating materials
CA2185159A1 (en) * 1995-09-15 1997-03-16 Helmut Franz Buffered Acid Interleaving for Glass Sheets
CN102070881A (en) * 2011-01-11 2011-05-25 常峰 Mildewproof insulation material for glass and preparation method thereof
CN102432194A (en) * 2011-09-23 2012-05-02 泰州远创新材料科技有限公司 Novel glass mildew remover
CN105994357A (en) * 2016-05-21 2016-10-12 杨勇 Compound mildew preventive

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116036963A (en) * 2023-01-15 2023-05-02 惠州市宝斯特实业有限公司 Production equipment and production process for glass mildew-proof isolation powder
CN116036963B (en) * 2023-01-15 2023-09-05 惠州市宝斯特实业有限公司 Production equipment and production process for glass mildew-proof isolation powder
CN116496670A (en) * 2023-05-16 2023-07-28 惠州市宝斯特实业有限公司 Long-acting glass mildew-proof powder and preparation method thereof

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