CN108102345A - A kind of polyurethane plastic - Google Patents

A kind of polyurethane plastic Download PDF

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Publication number
CN108102345A
CN108102345A CN201611054916.0A CN201611054916A CN108102345A CN 108102345 A CN108102345 A CN 108102345A CN 201611054916 A CN201611054916 A CN 201611054916A CN 108102345 A CN108102345 A CN 108102345A
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CN
China
Prior art keywords
parts
component
polyurethane plastic
polyurethane
grouped
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611054916.0A
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Chinese (zh)
Inventor
陈广炎
刘飏
刘福军
罗建华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Danyang Yaben Chemical Technology Co Ltd
Original Assignee
Danyang Yaben Chemical Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Danyang Yaben Chemical Technology Co Ltd filed Critical Danyang Yaben Chemical Technology Co Ltd
Priority to CN201611054916.0A priority Critical patent/CN108102345A/en
Publication of CN108102345A publication Critical patent/CN108102345A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/346Clay
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/05Alcohols; Metal alcoholates
    • C08K5/053Polyhydroxylic alcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)

Abstract

The present invention relates to a kind of polyurethane plastic, according to parts by weight, the B component including 30 50 parts of component As and 50 70 parts, the component A is by following weight parts into being grouped into:Toluene di-isocyanate(TDI), polyether polyol, the B component is by following weight parts into being grouped into:Crosslinking agent, filler, pigment, curing agent.The polyurethane plastic of the present invention has manufacture craft simple, makes raw material and is easy to buy, has the advantages that low manufacture cost, have broad application prospects.

Description

A kind of polyurethane plastic
Technical field
The present invention relates to plastic cement preparing technical field more particularly to a kind of polyurethane plastic and its synthetic methods.
Background technology
Polyurethane plastic has moderate, the bright in colour, anti-skid wearable of elasticity, place cleaning, easy maintenance, can effectively avoid Sportsman's damage significantly improves the features such as sports achievement, is generally used in the sports and training of countries in the world.At me State, with the development of sports cause, it is indispensable that laying plastic cement race track has become major small and medium-sized cities self-growth One of hardware.
Existing polyurethane plastic complex production process, production cost are high.It is therefore desirable to propose a kind of new poly- ammonia Ester plastic cement and synthetic method.
The content of the invention
The object of the present invention is to provide a kind of polyurethane plastic and synthetic methods.
Technical scheme is as follows:
A kind of polyurethane plastic, which is characterized in that according to parts by weight, the B groups including 30-50 parts of component As and 50-70 parts Point,
The component A is by following weight parts into being grouped into:
30-40 parts of toluene di-isocyanate(TDI),
40-50 parts of polyether polyol;
The B component is by following weight parts into being grouped into:
Further, the crosslinking agent is trimethylolpropane.
Further, the filler is talcum powder or kaolin.
Further, the pigment is iron oxide.
Further, the curing agent is trimethylhexamethylenediamine.
A kind of synthetic method of polyurethane plastic of the present invention, it is characterised in that:
S1:The preparation of component A:Polyether polyol is added in reaction kettle, stirring is warming up to 90~120 DEG C, is taken off under vacuum It is cooled to 50 DEG C after water, adds in toluene diisocyanate, slow reaction is to being down to room temperature after 85 DEG C;
S2:The preparation of B component:Crosslinking agent, filler, pigment, curing agent are put into reaction kettle after mixing, stirred It mixes and is warming up to 80 degree, and be dehydrated under vacuo;
S3:By A and B component according to certain proportioning, it is poured into plastic mould, cures at room temperature, gathered after the demoulding Urethane plastic cement.
According to the above aspect of the present invention, the present invention at least has the following advantages that:
The polyurethane plastic of the present invention has manufacture craft simple, makes raw material and is easy to buy, has low manufacture cost Advantage has broad application prospects.
Specific embodiment
It elaborates with reference to specific embodiment to technical scheme.
Embodiment 1
A kind of polyurethane plastic, according to parts by weight, the B component including 30-50 parts of component As and 50-70 parts,
The component A is by following weight parts into being grouped into:
40 parts of toluene di-isocyanate(TDI),
50 parts of polyether polyol;
The B component is by following weight parts into being grouped into:
Preparation method:
S1:The preparation of component A:Polyether polyol is added in reaction kettle, stirring is warming up to 90~120 DEG C, is taken off under vacuum It is cooled to 50 DEG C after water, adds in toluene diisocyanate, slow reaction is to being down to room temperature after 85 DEG C;
S2:The preparation of B component:Trimethylolpropane, talcum powder, iron oxide, trimethylhexamethylenediamine are mixed equal It is put into after even in reaction kettle, stirring is warming up to 80 degree, and is dehydrated under vacuo;
S3:By A and B component according to certain proportioning, it is poured into plastic mould, cures at room temperature, gathered after the demoulding Urethane plastic cement.
Embodiment 2
A kind of polyurethane plastic, according to parts by weight, the B component including 30-50 parts of component As and 50-70 parts,
The component A is by following weight parts into being grouped into:
30 parts of toluene di-isocyanate(TDI),
40 parts of polyether polyol;
The B component is by following weight parts into being grouped into:
Preparation method:
S1:The preparation of component A:Polyether polyol is added in reaction kettle, stirring is warming up to 90~120 DEG C, is taken off under vacuum It is cooled to 50 DEG C after water, adds in toluene diisocyanate, slow reaction is to being down to room temperature after 85 DEG C;
S2:The preparation of B component:Trimethylolpropane, talcum powder, iron oxide, trimethylhexamethylenediamine are mixed equal It is put into after even in reaction kettle, stirring is warming up to 80 degree, and is dehydrated under vacuo;
S3:By A and B component according to certain proportioning, it is poured into plastic mould, cures at room temperature, gathered after the demoulding Urethane plastic cement.
Embodiment 3
A kind of polyurethane plastic, according to parts by weight, the B component including 30-50 parts of component As and 50-70 parts,
The component A is by following weight parts into being grouped into:
35 parts of toluene di-isocyanate(TDI),
45 parts of polyether polyol;
The B component is by following weight parts into being grouped into:
Preparation method:
S1:The preparation of component A:Polyether polyol is added in reaction kettle, stirring is warming up to 90~120 DEG C, is taken off under vacuum It is cooled to 50 DEG C after water, adds in toluene diisocyanate, slow reaction is to being down to room temperature after 85 DEG C;
S2:The preparation of B component:Trimethylolpropane, talcum powder, iron oxide, trimethylhexamethylenediamine are mixed equal It is put into after even in reaction kettle, stirring is warming up to 80 degree, and is dehydrated under vacuo;
S3:By A and B component according to certain proportioning, it is poured into plastic mould, cures at room temperature, gathered after the demoulding Urethane plastic cement.
The above is only the preferred embodiment of the present invention, is not intended to limit the invention, it is noted that for this skill For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is several improvement and Modification, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (6)

1. a kind of polyurethane plastic, which is characterized in that according to parts by weight, the B groups including 30-50 parts of component As and 50-70 parts Point,
The component A is by following weight parts into being grouped into:
30-40 parts of toluene di-isocyanate(TDI),
40-50 parts of polyether polyol;
The B component is by following weight parts into being grouped into:
2. a kind of polyurethane plastic according to claim 1, it is characterised in that:The crosslinking agent is trimethylolpropane.
3. a kind of polyurethane plastic according to claim 1, it is characterised in that:The filler is talcum powder or kaolinite Soil.
4. a kind of polyurethane plastic according to claim 1, it is characterised in that:The pigment is iron oxide.
5. a kind of polyurethane plastic according to claim 1, it is characterised in that:The curing agent is tri-methyl hexamethylene Diamines.
6. a kind of synthetic method of polyurethane plastic according to claim 1, it is characterised in that:
S1:The preparation of component A:Polyether polyol is added in reaction kettle, stirring is warming up to 90~120 DEG C, after dehydrated under vacuum It is cooled to 50 DEG C, adds in toluene diisocyanate, slow reaction is to being down to room temperature after 85 DEG C;
S2:The preparation of B component:Crosslinking agent, filler, pigment, curing agent are put into reaction kettle after mixing, stirring rises Temperature is dehydrated under vacuo to 80 degree;
S3:By A and B component according to certain proportioning, it is poured into plastic mould, cures at room temperature, polyurethane is obtained after the demoulding Plastic cement.
CN201611054916.0A 2016-11-25 2016-11-25 A kind of polyurethane plastic Pending CN108102345A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611054916.0A CN108102345A (en) 2016-11-25 2016-11-25 A kind of polyurethane plastic

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611054916.0A CN108102345A (en) 2016-11-25 2016-11-25 A kind of polyurethane plastic

Publications (1)

Publication Number Publication Date
CN108102345A true CN108102345A (en) 2018-06-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201611054916.0A Pending CN108102345A (en) 2016-11-25 2016-11-25 A kind of polyurethane plastic

Country Status (1)

Country Link
CN (1) CN108102345A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104163905A (en) * 2014-06-09 2014-11-26 江苏欣润塑胶有限公司 Preparationmethod for anti-skid polyurethane plastic particles
CN105131819A (en) * 2015-09-16 2015-12-09 江苏长诺运动场地新材料有限公司 Water-based polyurethane track material and preparation method thereof
CN105367741A (en) * 2015-11-13 2016-03-02 淄博正大聚氨酯有限公司 Polyurethane sealing strip and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104163905A (en) * 2014-06-09 2014-11-26 江苏欣润塑胶有限公司 Preparationmethod for anti-skid polyurethane plastic particles
CN105131819A (en) * 2015-09-16 2015-12-09 江苏长诺运动场地新材料有限公司 Water-based polyurethane track material and preparation method thereof
CN105367741A (en) * 2015-11-13 2016-03-02 淄博正大聚氨酯有限公司 Polyurethane sealing strip and preparation method thereof

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Application publication date: 20180601

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