CN108102284A - A kind of glazed flame-retardant heat-resistant antifriction ABS plastic - Google Patents

A kind of glazed flame-retardant heat-resistant antifriction ABS plastic Download PDF

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Publication number
CN108102284A
CN108102284A CN201810103718.1A CN201810103718A CN108102284A CN 108102284 A CN108102284 A CN 108102284A CN 201810103718 A CN201810103718 A CN 201810103718A CN 108102284 A CN108102284 A CN 108102284A
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parts
powder
abs
abs plastic
resistant antifriction
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涂光权
戴振伟
刘坡
张辉毅
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Zhejiang Yima New Material Co Ltd
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Zhejiang Yima New Material Co Ltd
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Priority to CN201810103718.1A priority Critical patent/CN108102284A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0856Iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0893Zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • C08K2003/3054Ammonium sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • C08K2003/323Ammonium polyphosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, the formula of raw material by weight is as follows:60 80 parts of ABS high glue powders, 30 40 parts of ABS resin, 15 25 parts of epoxy resin, 15 25 parts of neoprene, 8 12 parts of thermoplastic polyester, 8 12 parts of Fypro powder, 8 12 parts of mixed metal powder, 35 parts of reinforcing agent, 35 parts of adhesive, 35 parts of plasticizer, 13 parts of anti-aging agent, 57 parts of fire retardant, 13 parts of antioxidant.The case hardness of the ABS plastic is high, do not allow it is easy to scratch, ensure the ABS plastic smoulder either it is incombustible simultaneously, additionally it is possible to improve its service life, adhesive and plasticizer can also further improve the ABS plastic hardness, its security performance used has been effectively ensured.

Description

A kind of glazed flame-retardant heat-resistant antifriction ABS plastic
Technical field
The present invention relates to ABS plastic technical field more particularly to a kind of glazed flame-retardant heat-resistant antifriction ABS plastics.
Background technology
ABS plastic, chemical name are acrylonitrile-butadiene-styrene copolymer, suitable for making common mechanical part, are subtracted Grind wear part, driving parts and telecommunication part.With the increasingly raising of people's living standard, also entering for household electrical appliance is quick The epoch of development, with the lasting release of global safety specification, it is desirable that the shell of household electrical appliance burn in fire slowly or It is nonflammable, and the fire retardancy of ABS plastic of the prior art is general, and its hardness deficiency, easily easily it is damaged.For This, we have proposed a kind of glazed flame-retardant heat-resistant antifriction ABS plastics.
The content of the invention
The present invention proposes a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, mentioned above in the background art to solve Problem.
The present invention proposes a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, and the formula of raw material by weight is as follows:ABS 60-80 parts of high glue powder, 30-40 parts of ABS resin, 15-25 parts of epoxy resin, 15-25 parts of neoprene, thermoplastic polyester 8-12 Part, 8-12 parts of Fypro powder, 8-12 parts of mixed metal powder, 3-5 parts of reinforcing agent, 3-5 parts of adhesive, 3-5 parts of plasticizer are prevented Old agent 1-3 parts, 5-7 parts of fire retardant, 1-3 parts of antioxidant.
Preferably, ABS high glue powders, the weight ratio of ABS resin are 65-75:33-38.
Preferably, epoxy resin, the weight ratio of neoprene are 18-22:18-22.
Preferably, thermoplastic polyester, Fypro powder, the weight ratio of mixed metal powder are 9-11:9-11:9-11.
Preferably, reinforcing agent, adhesive, plasticizer, anti-aging agent, fire retardant, the weight ratio of antioxidant are 3.5-4.5: 3.5-4.5:3.5-4.5:1.5-2.5:5.5-6.5:1.5-2.5.
Preferably, the formula of raw material by weight is as follows:
65-75 parts of ABS high glue powders, 33-38 parts of ABS resin, 18-22 parts of epoxy resin, 18-22 parts of neoprene, thermoplastic poly 9-11 parts of ester, 9-11 parts of Fypro powder, 9-11 parts of mixed metal powder, 3.5-4.5 parts of reinforcing agent, 3.5-4.5 parts of adhesive, 3.5-4.5 parts of plasticizer, 1.5-2.5 parts of anti-aging agent, 5.5-6.5 parts of fire retardant, 1.5-2.5 parts of antioxidant.
Preferably, the optimization formula of raw material by weight is as follows:
70 parts of ABS high glue powders, 35 parts of ABS resin, 20 parts of epoxy resin, 20 parts of neoprene, 10 parts of thermoplastic polyester, polyamide 10 parts of fiber powder, 10 parts of mixed metal powder, 4 parts of reinforcing agent, 4 parts of adhesive, 4 parts of plasticizer, 2 parts of anti-aging agent, 6 parts of fire retardant, 2 parts of antioxidant.
Preferably, the mixed metal powder is alumina powder, diamond dust, ferro element powder, manganese element powder and zinc member The mixed material of plain powder, and alumina powder, diamond dust, ferro element powder, the molal weight ratio of manganese element powder and Zn-ef ficiency powder For 2:0.5:1:0.8:1.
Preferably, the fire retardant is melamine melamine salt, borax, ammonium polyphosphate, ammonium sulfate and sodium tungstate Mixture, and melamine melamine salt, borax, ammonium polyphosphate, the molal weight ratio of ammonium sulfate and sodium tungstate are 1: 0.5:1:0.5:0.1.
Preferably, the glazed flame-retardant heat-resistant antifriction ABS plastic after the completion of preparation, it is necessary to its surface carry out it is more Secondary polishing, to ensure the gloss on its surface.
Compared with prior art, the advantageous effect of present invention is that:The present invention is with ABS high glue powders and ABS resin For main material, and supplemented by Fypro powder, mixed metal powder and reinforcing agent, and optimize the distribution of the group between above-mentioned raw materials Than so as to the glazed flame-retardant heat-resistant antifriction ABS plastic obtained, making its case hardness high, it is not easy to scratch, also be hindered by adding Fire agent and anti-aging agent, ensure the ABS plastic smoulder either it is incombustible simultaneously, additionally it is possible to that improves it uses the longevity Life, adhesive and plasticizer can also further improve the ABS plastic hardness, its security used have been effectively ensured Energy.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
The present invention proposes a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, and the formula of raw material by weight is as follows:ABS high glue It is 60 parts of powder, 30 parts of ABS resin, 15 parts of epoxy resin, 15 parts of neoprene, 8 parts of thermoplastic polyester, 8 parts of Fypro powder, mixed Close 8 parts of metal powder, 3 parts of reinforcing agent, 3 parts of adhesive, 3 parts of plasticizer, 1 part of anti-aging agent, 5 parts of fire retardant, 1 part of antioxidant.
The mixed metal powder is the mixed of alumina powder, diamond dust, ferro element powder, manganese element powder and Zn-ef ficiency powder Material is closed, and alumina powder, diamond dust, ferro element powder, the molal weight ratio of manganese element powder and Zn-ef ficiency powder are 2:0.5: 1:0.8:1.
The fire retardant is the mixing of melamine melamine salt, borax, ammonium polyphosphate, ammonium sulfate and sodium tungstate Object, and melamine melamine salt, borax, ammonium polyphosphate, the molal weight ratio of ammonium sulfate and sodium tungstate are 1:0.5:1: 0.5:0.1.
The glazed flame-retardant heat-resistant antifriction ABS plastic after the completion of preparation, it is necessary to repeatedly polished to its surface, To ensure the gloss on its surface.
Embodiment 2
The present invention proposes a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, and the formula of raw material by weight is as follows:ABS high glue It is 65 parts of powder, 33 parts of ABS resin, 18 parts of epoxy resin, 18 parts of neoprene, 9 parts of thermoplastic polyester, 9 parts of Fypro powder, mixed Close 9 parts of metal powder, 3.5 parts of reinforcing agent, 3.5 parts of adhesive, 3.5 parts of plasticizer, 1.5 parts of anti-aging agent, 5.5 parts of fire retardant, antioxygen 1.5 parts of agent.
The mixed metal powder is the mixed of alumina powder, diamond dust, ferro element powder, manganese element powder and Zn-ef ficiency powder Material is closed, and alumina powder, diamond dust, ferro element powder, the molal weight ratio of manganese element powder and Zn-ef ficiency powder are 2:0.5: 1:0.8:1.
The fire retardant is the mixing of melamine melamine salt, borax, ammonium polyphosphate, ammonium sulfate and sodium tungstate Object, and melamine melamine salt, borax, ammonium polyphosphate, the molal weight ratio of ammonium sulfate and sodium tungstate are 1:0.5:1: 0.5:0.1.
The glazed flame-retardant heat-resistant antifriction ABS plastic after the completion of preparation, it is necessary to repeatedly polished to its surface, To ensure the gloss on its surface.
Embodiment 3
The present invention proposes a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, and the formula of raw material by weight is as follows:ABS high glue 70 parts of powder, 35 parts of ABS resin, 20 parts of epoxy resin, 20 parts of neoprene, 10 parts of thermoplastic polyester, 10 parts of Fypro powder, 10 parts of mixed metal powder, 4 parts of reinforcing agent, 4 parts of adhesive, 4 parts of plasticizer, 2 parts of anti-aging agent, 6 parts of fire retardant, 2 parts of antioxidant.
The mixed metal powder is the mixed of alumina powder, diamond dust, ferro element powder, manganese element powder and Zn-ef ficiency powder Material is closed, and alumina powder, diamond dust, ferro element powder, the molal weight ratio of manganese element powder and Zn-ef ficiency powder are 2:0.5: 1:0.8:1.
The fire retardant is the mixing of melamine melamine salt, borax, ammonium polyphosphate, ammonium sulfate and sodium tungstate Object, and melamine melamine salt, borax, ammonium polyphosphate, the molal weight ratio of ammonium sulfate and sodium tungstate are 1:0.5:1: 0.5:0.1.
The glazed flame-retardant heat-resistant antifriction ABS plastic after the completion of preparation, it is necessary to repeatedly polished to its surface, To ensure the gloss on its surface.
Embodiment 4
The present invention proposes a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, and the formula of raw material by weight is as follows:ABS high glue 75 parts of powder, 38 parts of ABS resin, 22 parts of epoxy resin, 22 parts of neoprene, 11 parts of thermoplastic polyester, 11 parts of Fypro powder, It is 11 parts of mixed metal powder, 4.5 parts of reinforcing agent, 4.5 parts of adhesive, 4.5 parts of plasticizer, 2.5 parts of anti-aging agent, 6.5 parts of fire retardant, anti- 2.5 parts of oxidant.
The mixed metal powder is the mixed of alumina powder, diamond dust, ferro element powder, manganese element powder and Zn-ef ficiency powder Material is closed, and alumina powder, diamond dust, ferro element powder, the molal weight ratio of manganese element powder and Zn-ef ficiency powder are 2:0.5: 1:0.8:1.
The fire retardant is the mixing of melamine melamine salt, borax, ammonium polyphosphate, ammonium sulfate and sodium tungstate Object, and melamine melamine salt, borax, ammonium polyphosphate, the molal weight ratio of ammonium sulfate and sodium tungstate are 1:0.5:1: 0.5:0.1.
The glazed flame-retardant heat-resistant antifriction ABS plastic after the completion of preparation, it is necessary to repeatedly polished to its surface, To ensure the gloss on its surface.
Embodiment 5
The present invention proposes a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, and the formula of raw material by weight is as follows:ABS high glue 80 parts of powder, 40 parts of ABS resin, 25 parts of epoxy resin, 25 parts of neoprene, 12 parts of thermoplastic polyester, 12 parts of Fypro powder, 12 parts of mixed metal powder, 5 parts of reinforcing agent, 5 parts of adhesive, 5 parts of plasticizer, 3 parts of anti-aging agent, 7 parts of fire retardant, 3 parts of antioxidant.
The mixed metal powder is the mixed of alumina powder, diamond dust, ferro element powder, manganese element powder and Zn-ef ficiency powder Material is closed, and alumina powder, diamond dust, ferro element powder, the molal weight ratio of manganese element powder and Zn-ef ficiency powder are 2:0.5: 1:0.8:1.
The fire retardant is the mixing of melamine melamine salt, borax, ammonium polyphosphate, ammonium sulfate and sodium tungstate Object, and melamine melamine salt, borax, ammonium polyphosphate, the molal weight ratio of ammonium sulfate and sodium tungstate are 1:0.5:1: 0.5:0.1.
The glazed flame-retardant heat-resistant antifriction ABS plastic after the completion of preparation, it is necessary to repeatedly polished to its surface, To ensure the gloss on its surface.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of glazed flame-retardant heat-resistant antifriction ABS plastic, which is characterized in that the formula of its raw material by weight is as follows:ABS high glue It is 60-80 parts of powder, 30-40 parts of ABS resin, 15-25 parts of epoxy resin, 15-25 parts of neoprene, 8-12 parts of thermoplastic polyester, poly- 8-12 parts of nylon powder, 8-12 parts of mixed metal powder, 3-5 parts of reinforcing agent, 3-5 parts of adhesive, 3-5 parts of plasticizer, anti-aging agent 1-3 parts, 5-7 parts of fire retardant, 1-3 parts of antioxidant.
2. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that ABS high glue powders, ABS trees The weight ratio of fat is 65-75:33-38.
3. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that epoxy resin, neoprene rubber The weight ratio of glue is 18-22:18-22.
4. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that thermoplastic polyester, polyamides Amine fiber powder, the weight ratio of mixed metal powder are 9-11:9-11:9-11.
5. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that reinforcing agent, adhesive, Plasticizer, anti-aging agent, fire retardant, the weight ratio of antioxidant are 3.5-4.5:3.5-4.5:3.5-4.5:1.5-2.5:5.5- 6.5:1.5-2.5.
6. the glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 2-5, which is characterized in that its raw material is by weight Formula it is as follows:
65-75 parts of ABS high glue powders, 33-38 parts of ABS resin, 18-22 parts of epoxy resin, 18-22 parts of neoprene, thermoplastic poly 9-11 parts of ester, 9-11 parts of Fypro powder, 9-11 parts of mixed metal powder, 3.5-4.5 parts of reinforcing agent, 3.5-4.5 parts of adhesive, 3.5-4.5 parts of plasticizer, 1.5-2.5 parts of anti-aging agent, 5.5-6.5 parts of fire retardant, 1.5-2.5 parts of antioxidant.
7. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that its raw material is by weight Optimization formula is as follows:
70 parts of ABS high glue powders, 35 parts of ABS resin, 20 parts of epoxy resin, 20 parts of neoprene, 10 parts of thermoplastic polyester, polyamide 10 parts of fiber powder, 10 parts of mixed metal powder, 4 parts of reinforcing agent, 4 parts of adhesive, 4 parts of plasticizer, 2 parts of anti-aging agent, 6 parts of fire retardant, 2 parts of antioxidant.
8. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that the hybrid metal Powder is alumina powder, diamond dust, ferro element powder, the mixed material of manganese element powder and Zn-ef ficiency powder, and alumina powder, gold Emery, ferro element powder, the molal weight ratio of manganese element powder and Zn-ef ficiency powder are 2:0.5:1:0.8:1.
9. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that the fire retardant is Melamine melamine salt, borax, ammonium polyphosphate, the mixture of ammonium sulfate and sodium tungstate, and melamine melamine salt, boron Sand, ammonium polyphosphate, the molal weight ratio of ammonium sulfate and sodium tungstate are 1:0.5:1:0.5:0.1.
10. glazed flame-retardant heat-resistant antifriction ABS plastic according to claim 1, which is characterized in that the high glaze resistance Heat-resistant antifriction ABS plastic is fired after the completion of preparation, it is necessary to repeatedly be polished to its surface, to ensure the gloss on its surface.
CN201810103718.1A 2018-02-01 2018-02-01 A kind of glazed flame-retardant heat-resistant antifriction ABS plastic Pending CN108102284A (en)

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CN201810103718.1A CN108102284A (en) 2018-02-01 2018-02-01 A kind of glazed flame-retardant heat-resistant antifriction ABS plastic

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111171395A (en) * 2020-02-17 2020-05-19 褚乃博 Composite material made of recycled rubber, forming method and application thereof
CN112552637A (en) * 2020-12-10 2021-03-26 汕头市麦氧环保科技有限公司 Composite high polymer material and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104371253A (en) * 2013-08-12 2015-02-25 青岛博研达工业技术研究所(普通合伙) High performance flame retardant material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104371253A (en) * 2013-08-12 2015-02-25 青岛博研达工业技术研究所(普通合伙) High performance flame retardant material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111171395A (en) * 2020-02-17 2020-05-19 褚乃博 Composite material made of recycled rubber, forming method and application thereof
CN112552637A (en) * 2020-12-10 2021-03-26 汕头市麦氧环保科技有限公司 Composite high polymer material and preparation method thereof

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