CN108102245A - A kind of environment-friendly PVC leaching modeling liquid - Google Patents

A kind of environment-friendly PVC leaching modeling liquid Download PDF

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Publication number
CN108102245A
CN108102245A CN201711222719.XA CN201711222719A CN108102245A CN 108102245 A CN108102245 A CN 108102245A CN 201711222719 A CN201711222719 A CN 201711222719A CN 108102245 A CN108102245 A CN 108102245A
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parts
environment
modeling liquid
leaching modeling
friendly pvc
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Chinese (zh)
Inventor
游梦玲
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Guangde Yuehua Plastic Products Co Ltd
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Guangde Yuehua Plastic Products Co Ltd
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Priority to CN201711222719.XA priority Critical patent/CN108102245A/en
Publication of CN108102245A publication Critical patent/CN108102245A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of environment-friendly PVCs to soak modeling liquid, and the environment-friendly PVC leaching modeling liquid includes following raw material:37~42 parts of PVC resin powder, 23~32 parts of PVC paste resin, 25~34 parts of pigment, 15~23 parts of butyl rubber powder, 12~18 parts of rubber oil, 11~15 parts of silicon virgin rubber, 9~13 parts of vinyl silica gel oil, 8~15 parts of lightweight nano-calcium carbonate, 5~9 parts of nano zine oxide, newborn 7~14 parts of virgin rubber, 7~18 parts of three palm ester of citric acid, 30~46 parts of 3~5 parts of organic stabilizer and ionic liquid, and add new material on this base-material, environment-friendly PVC leaching modeling liquid is obtained after scattered grinding, environment-friendly PVC leaching modeling liquid security of the present invention is good, environment-friendly and green is pollution-free, uniform coloring, it is easy to use, good economy performance, it manufactures at low cost, with good potentiality, leaching modeling effect is good, it is good to soak plasticity matter.

Description

A kind of environment-friendly PVC leaching modeling liquid
Technical field
The present invention relates to polyvinyl chloride environment-friendly materials technical fields, and in particular to a kind of environment-friendly PVC leaching modeling liquid.
Background technology
PVC (polyvinyl chloride) leaching modeling liquid can be widely used in physical fitness equipment, labour protection PVC glove, hardware tool handle, Handle, iron wire clothes hanger, hook, electrical insulating material, soft rubber cover glue beans, craftwork, valve handle, automobile (motorcycle) theftproof lock In the coating of the products such as sheath.
Existing PVC paste resin or PVC leaching modeling liquid production equipments are in whipping process is produced, because stirrer paddle and material Friction process can generate heat, and when material reaches certain temperature (being more than 60 DEG C), it is existing that PVC will generate caking due to plasticizing As processing is difficult, has seriously affected production efficiency;(it is less than 0 DEG C) when environment temperature is very low, one of raw material of PVC leaching modeling liquid Plasticizer viscosity becomes larger, and can increase motor load in whipping process, motor is even burnt when serious.In addition, the modeling liquid of PVC leachings at present Color matching kettle is generally a kettle polychrome or more kettle polychromes, the former can increase cleaning difficulty when switching color, time-consuming, laborious, useless Material, and the latter then needs to increase equipment investment, increases cost, human and material resources is caused to waste.
The content of the invention
To solve the above problems, a kind of the present invention is intended to provide environment-friendly PVC leaching modeling liquid.
Purpose to realize the present invention, the technical solution adopted is that:A kind of environment-friendly PVC leaching modeling liquid, the environment-friendly PVC leaching modeling liquid Include following raw material:37~42 parts of PVC resin powder, 23~32 parts of PVC paste resin, 25~34 parts of pigment, butyl rubber powder 15~23 parts, 12~18 parts of rubber oil, 11~15 parts of silicon virgin rubber, 9~13 parts of vinyl silica gel oil, lightweight nano-calcium carbonate 8~ 15 parts, 5~9 parts of nano zine oxide, newborn 7~14 parts of virgin rubber, 7~18 parts of three palm ester of citric acid, 3~5 parts of organic stabilizer and 30~46 parts of ionic liquid.
Preferably, 1~2 part of γ-FeO (OH), ZnCO are also added in the environment-friendly PVC leaching modeling liquid3And FeTiO3- MgTiO3Mixture, wherein, γ-FeO (OH), ZnCO3And FeTiO3-MgTiO3Adding proportion be 2~3:1~2:1~3.
Preferably, 2~4 parts of thinner is also added in the environment-friendly PVC leaching modeling liquid, wherein, thinner is Porous deproteinized bone Hydrocarbon thinner.
Preferably, 8~11 parts of pearly-lustre mill base is also added in the environment-friendly PVC leaching modeling liquid.
Preferably, the pigment that environment-friendly PVC leaching modeling liquid uses is phthalocyanine is red, phthalocyanine basket, phthalocyanine green, everbright fast red, big Molecule is red, macromolecular is yellow, the one or several kinds in permanent bordeaux and azophloxine.
Preferably, the organic stabilizer is the mixed of the organic calcium-zinc composite stabilizing agent of paste and organotin antimony compound stabilizer Close object.
Preferably, 2~5 parts of antifoaming agent is also added in the environment-friendly PVC leaching modeling liquid.
Preferably, 2~3 parts of fungicide is also added in the environment-friendly PVC leaching modeling liquid.
Preferably, the manufacturing process of the environment-friendly PVC leaching modeling liquid comprises the following steps:
1) is just mixed:By rubber oil, silicon virgin rubber, vinyl silica gel oil, newborn virgin rubber, three palm ester of citric acid, organic stabilizers Agent, ionic liquid and antifoaming agent are added in stirred tank together, with rotating speed 1~3h of high-speed stirred of 2000~3000r/min, until object Material all merges and is uniformly mixed completely, keep 0.01~0.1MPa vacuum degree continue 2~5h of stirring obtain leaching mould liquid it is white Material;
2) mixes colours:By the dissolving of pigment, 45~60% glycerine, PVC environmental protection mill base and pearl powder in deionized water, exist Material is stirred at a temperature of 120~150 DEG C to be uniformly mixed to thick, adds remaining glycerine, then with 1500~2500r/ Rotating speed moderate-speed mixer to the material of min is uniformly mixed;
3) bis- mixing of:Thinner, γ-FeO will be added in the dispersed material mixed in step 1 while stirring (OH)、ZnCO3、FeTiO3-MgTiO3The pigment that step 2 mixes up is added in after being uniformly dispersed with fungicide, then with 2500~3000r/ The rotating speed of min is stirred 3~6h, then is transferred in three-roll grinder;
4) is ground:Scattered material is transferred in three-roll grinder, is at the uniform velocity ground 2~3 times, into uniform cream Shape carries out 2~4 times sand millings to fine and smooth paste putting into sand mill, environmental protection is made after high-speed stirred is uniformly mixed and refilters PVC leaching modeling liquid.
Beneficial effects of the present invention are:Environment-friendly PVC leaching modeling liquid of the present invention is carried out scientific and reasonable using Novel environment-friendlymaterial material The raw material of conventional Environmental Safety is used in formula by proportioning, and environment-friendly PVC leaching modeling liquid security obtained is good, and uniform coloring uses Convenient, good economy performance manufactures at low cost, the potentiality having had, and environmentally protective few harm meets polycyclic aromatic hydrocarbons (PAH) inspection specification, Polycyclic aromatic hydrocarbons (PAH) is not detected, meets environmental requirement, and environment-friendly PVC leaching modeling liquid of the present invention can be widely used for medical treatment, health and food etc. Field.
Description of the drawings
Fig. 1 is the raw material proportioning table of environment-friendly PVC leaching modeling liquid of the present invention.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work Embodiment belongs to the scope of protection of the invention.
Embodiment 1
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of environment-friendly PVC leaching modeling liquid, the environment-friendly PVC leaching Modeling liquid includes following raw material:42 parts of PVC resin powder, 23 parts of PVC paste resin, 34 parts of pigment, 15 parts of butyl rubber powder, rubber 18 parts of oil, 11 parts of silicon virgin rubber, 13 parts of vinyl silica gel oil, 8 parts of lightweight nano-calcium carbonate, 9 parts of nano zine oxide, newborn 7 parts of virgin rubber, 46 parts of 18 parts of three palm ester of citric acid, 3 parts of organic stabilizer and ionic liquid.
Wherein, 1 part of γ-FeO (OH), ZnCO are also added in the environment-friendly PVC leaching modeling liquid3And FeTiO3-MgTiO3's Mixture, wherein, γ-FeO (OH), ZnCO3And FeTiO3-MgTiO3Adding proportion be 3:2:1.
Wherein, 2 parts of thinner is also added in the environment-friendly PVC leaching modeling liquid, wherein, thinner is the hydrocarbon drop of Porous deproteinized bone Stick.
Wherein, 11 parts of pearly-lustre mill base is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, the pigment that environment-friendly PVC leaching modeling liquid uses for phthalocyanine is red, phthalocyanine basket, phthalocyanine green, everbright fast red, big point Son is red, macromolecular is yellow, the one or several kinds in permanent bordeaux and azophloxine.
Wherein, the organic stabilizer is the mixing of the organic calcium-zinc composite stabilizing agent of paste and organotin antimony compound stabilizer Object.
Wherein, 2 parts of antifoaming agent is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, 3 parts of fungicide is also added in the environment-friendly PVC leaching modeling liquid.
Embodiment 2
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of environment-friendly PVC leaching modeling liquid, the environment-friendly PVC leaching Modeling liquid includes following raw material:37 parts of PVC resin powder, 32 parts of PVC paste resin, 25 parts of pigment, 23 parts of butyl rubber powder, rubber 12 parts of oil, 15 parts of silicon virgin rubber, 9 parts of vinyl silica gel oil, 15 parts of lightweight nano-calcium carbonate, 5 parts of nano zine oxide, newborn virgin rubber 14 Part, 7 parts of three palm ester of citric acid, 5 parts of organic stabilizer and 30 parts of ionic liquid.
Wherein, 2 parts of γ-FeO (OH), ZnCO are also added in the environment-friendly PVC leaching modeling liquid3And FeTiO3-MgTiO3's Mixture, wherein, γ-FeO (OH), ZnCO3And FeTiO3-MgTiO3Adding proportion be 2:2:1.
Wherein, 4 parts of thinner is also added in the environment-friendly PVC leaching modeling liquid, wherein, thinner is the hydrocarbon drop of Porous deproteinized bone Stick.
Wherein, 8 parts of pearly-lustre mill base is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, the pigment that environment-friendly PVC leaching modeling liquid uses for phthalocyanine is red, phthalocyanine basket, phthalocyanine green, everbright fast red, big point Son is red, macromolecular is yellow, the one or several kinds in permanent bordeaux and azophloxine.
Wherein, the organic stabilizer is the mixing of the organic calcium-zinc composite stabilizing agent of paste and organotin antimony compound stabilizer Object.
Wherein, 5 parts of antifoaming agent is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, 2 parts of fungicide is also added in the environment-friendly PVC leaching modeling liquid.
Embodiment 3
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of environment-friendly PVC leaching modeling liquid, the environment-friendly PVC leaching Modeling liquid includes following raw material:42 parts of PVC resin powder, 32 parts of PVC paste resin, 34 parts of pigment, 23 parts of butyl rubber powder, rubber 18 parts of oil, 5 parts of silicon virgin rubber, 13 parts of vinyl silica gel oil, 15 parts of lightweight nano-calcium carbonate, 9 parts of nano zine oxide, newborn virgin rubber 14 Part, 18 parts of three palm ester of citric acid, 5 parts of organic stabilizer and 46 parts of ionic liquid.
Wherein, 2 parts of γ-FeO (OH), ZnCO are also added in the environment-friendly PVC leaching modeling liquid3And FeTiO3-MgTiO3's Mixture, wherein, γ-FeO (OH), ZnCO3And FeTiO3-MgTiO3Adding proportion be 3:2:3.
Wherein, 4 parts of thinner is also added in the environment-friendly PVC leaching modeling liquid, wherein, thinner is the hydrocarbon drop of Porous deproteinized bone Stick.
Wherein, 11 parts of pearly-lustre mill base is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, the pigment that environment-friendly PVC leaching modeling liquid uses for phthalocyanine is red, phthalocyanine basket, phthalocyanine green, everbright fast red, big point Son is red, macromolecular is yellow, the one or several kinds in permanent bordeaux and azophloxine.
Wherein, the organic stabilizer is the mixing of the organic calcium-zinc composite stabilizing agent of paste and organotin antimony compound stabilizer Object.
Wherein, 5 parts of antifoaming agent is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, 3 parts of fungicide is also added in the environment-friendly PVC leaching modeling liquid.
Embodiment 4
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of environment-friendly PVC leaching modeling liquid, the environment-friendly PVC leaching Modeling liquid includes following raw material:37 parts of PVC resin powder, 23 parts of PVC paste resin, 25 parts of pigment, 15 parts of butyl rubber powder, rubber 12 parts of oil, 11 parts of silicon virgin rubber, 9 parts of vinyl silica gel oil, 8 parts of lightweight nano-calcium carbonate, 5 parts of nano zine oxide, newborn 7 parts of virgin rubber, 30 parts of 7 parts of three palm ester of citric acid, 3 parts of organic stabilizer and ionic liquid.
Wherein, 1 part of γ-FeO (OH), ZnCO are also added in the environment-friendly PVC leaching modeling liquid3And FeTiO3-MgTiO3's Mixture, wherein, γ-FeO (OH), ZnCO3And FeTiO3-MgTiO3Adding proportion be 2:1:1.
Wherein, 2 parts of thinner is also added in the environment-friendly PVC leaching modeling liquid, wherein, thinner is the hydrocarbon drop of Porous deproteinized bone Stick.
Wherein, 8 parts of pearly-lustre mill base is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, the pigment that environment-friendly PVC leaching modeling liquid uses for phthalocyanine is red, phthalocyanine basket, phthalocyanine green, everbright fast red, big point Son is red, macromolecular is yellow, the one or several kinds in permanent bordeaux and azophloxine.
Wherein, the organic stabilizer is the mixing of the organic calcium-zinc composite stabilizing agent of paste and organotin antimony compound stabilizer Object.
Wherein, 2 parts of antifoaming agent is also added in the environment-friendly PVC leaching modeling liquid.
Wherein, 2 parts of fungicide is also added in the environment-friendly PVC leaching modeling liquid.
Refering to Figure 1, the technical solution adopted by the present invention is:A kind of environment-friendly PVC leaching modeling liquid, the environment-friendly PVC leaching The manufacturing process of modeling liquid comprises the following steps:
1) is just mixed:By rubber oil, silicon virgin rubber, vinyl silica gel oil, newborn virgin rubber, three palm ester of citric acid, organic stabilizers Agent, ionic liquid and antifoaming agent are added in stirred tank together, with the rotating speed high-speed stirred 3h of 3000r/min, until material is all complete Merge and be uniformly mixed entirely, keep 0.01MPa vacuum degree continue stir 5h obtain leaching mould liquid expect in vain;
2) mixes colours:By the dissolving of pigment, 60% glycerine, PVC environmental protection mill base and pearl powder in deionized water, at 150 DEG C At a temperature of stir material and be uniformly mixed to thick, add remaining glycerine, then the rotating speed moderate-speed mixer with 2500r/min It is uniformly mixed to material;
3) bis- mixing of:Thinner, γ-FeO will be added in the dispersed material mixed in step 1 while stirring (OH)、ZnCO3、FeTiO3-MgTiO3The pigment that step 2 mixes up is added in after being uniformly dispersed with fungicide, then with 3000r/min's Rotating speed is stirred 6h, then is transferred in three-roll grinder;
4) is ground:Scattered material is transferred in three-roll grinder, is at the uniform velocity ground 3 times, into uniform paste, 4 times sand millings are carried out to fine and smooth paste putting into sand mill, and environment-friendly PVC leaching modeling is made after high-speed stirred is uniformly mixed and refilters Liquid.
In the present invention, environment-friendly PVC leaching modeling liquid of the present invention carries out scientific and reasonable proportioning using Novel environment-friendlymaterial material, will be normal The raw material for advising Environmental Safety is used in formula, and environment-friendly PVC leaching modeling liquid security obtained is good, and uniform coloring is easy to use, economical Property it is good, manufacture at low cost, the potentiality having had, environmentally protective few harm meets polycyclic aromatic hydrocarbons (PAH) inspection specification, do not detect polycyclic Aromatic hydrocarbon, meets environmental requirement, and environment-friendly PVC leaching modeling liquid of the present invention can be widely used for the fields such as medical treatment, health and food.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (9)

1. a kind of environment-friendly PVC leaching modeling liquid, it is characterised in that:The environment-friendly PVC leaching modeling liquid includes following raw material:Polyvinyl chloride resin 37~42 parts of powder, 23~32 parts of PVC paste resin, 25~34 parts of pigment, 15~23 parts of butyl rubber powder, 12~18 parts of rubber oil, 11~15 parts of silicon virgin rubber, 9~13 parts of vinyl silica gel oil, 8~15 parts of lightweight nano-calcium carbonate, 5~9 parts of nano zine oxide, breast 30~46 parts of 7~14 parts of virgin rubber, 7~18 parts of three palm ester of citric acid, 3~5 parts of organic stabilizer and ionic liquid.
2. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:Also add in the environment-friendly PVC leaching modeling liquid Added with 1~2 part of γ-FeO (OH), ZnCO3And FeTiO3-MgTiO3Mixture, wherein, γ-FeO (OH), ZnCO3With FeTiO3-MgTiO3Adding proportion be 2~3:1~2:1~3.
3. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:Also add in the environment-friendly PVC leaching modeling liquid Added with 2~4 parts of thinner, wherein, thinner is the hydrocarbon thinner of Porous deproteinized bone.
4. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:Also add in the environment-friendly PVC leaching modeling liquid Added with 8~11 parts of pearly-lustre mill base.
5. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:What the environment-friendly PVC leaching modeling liquid used Pigment is phthalocyanine is red, phthalocyanine basket, phthalocyanine green, everbright fast red, macromolecular is red, macromolecular is yellow, one kind in permanent bordeaux and azophloxine It is or several.
6. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:The organic stabilizer has for paste The mixture of machine calcium-zinc composite stabilizing agent and organotin antimony compound stabilizer.
7. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:Also add in the environment-friendly PVC leaching modeling liquid Added with 2~5 parts of antifoaming agent.
8. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:Also add in the environment-friendly PVC leaching modeling liquid Added with 2~3 parts of fungicide.
9. a kind of environment-friendly PVC leaching modeling liquid according to claim 1, it is characterised in that:The manufacture of the environment-friendly PVC leaching modeling liquid Technique comprises the following steps:
1) is just mixed:By rubber oil, silicon virgin rubber, vinyl silica gel oil, newborn virgin rubber, three palm ester of citric acid, organic stabilizer, from Sub- liquid and antifoaming agent are added in stirred tank together, with rotating speed 1~3h of high-speed stirred of 2000~3000r/min, until material is complete Portion merges and is uniformly mixed completely, keep 0.01~0.1MPa vacuum degree continue 2~5h of stirring obtain leaching mould liquid expect in vain;
2) mixes colours:By the dissolving of pigment, 45~60% glycerine, PVC environmental protection mill base and pearl powder in deionized water, 120~ Material is stirred at a temperature of 150 DEG C to be uniformly mixed to thick, adds remaining glycerine, then with 1500~2500r/min's Rotating speed moderate-speed mixer to material is uniformly mixed;
3) bis- mixing of:To while stirring be added in the dispersed material mixed in step 1 thinner, γ-FeO (OH), ZnCO3、FeTiO3-MgTiO3The pigment that step 2 mixes up is added in after being uniformly dispersed with fungicide, then with 2500~3000r/min's Rotating speed is stirred 3~6h, then is transferred in three-roll grinder;
4) is ground:Scattered material is transferred in three-roll grinder, is at the uniform velocity ground 2~3 times, into uniform paste, It puts into sand mill and carries out 2~4 times sand millings to fine and smooth paste, environment-friendly PVC leaching is made after high-speed stirred is uniformly mixed and refilters Mould liquid.
CN201711222719.XA 2017-11-29 2017-11-29 A kind of environment-friendly PVC leaching modeling liquid Withdrawn CN108102245A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861398A (en) * 2015-06-04 2015-08-26 山东万图高分子材料有限公司 Glazing PVC plastic soaking liquid and preparation method thereof
CN104910553A (en) * 2015-06-04 2015-09-16 山东万图高分子材料有限公司 Pitted polyvinyl chloride dipping plastic fluid and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104861398A (en) * 2015-06-04 2015-08-26 山东万图高分子材料有限公司 Glazing PVC plastic soaking liquid and preparation method thereof
CN104910553A (en) * 2015-06-04 2015-09-16 山东万图高分子材料有限公司 Pitted polyvinyl chloride dipping plastic fluid and preparation method thereof

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Application publication date: 20180601