CN108102174A - A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component - Google Patents
A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component Download PDFInfo
- Publication number
- CN108102174A CN108102174A CN201810025976.2A CN201810025976A CN108102174A CN 108102174 A CN108102174 A CN 108102174A CN 201810025976 A CN201810025976 A CN 201810025976A CN 108102174 A CN108102174 A CN 108102174A
- Authority
- CN
- China
- Prior art keywords
- fixing sleeve
- flame retardant
- sleeve component
- environmental protection
- mixing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
- C08K5/03—Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/18—Amines; Quaternary ammonium compounds with aromatically bound amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Abstract
The invention discloses a kind of environmental protection flame retardant automobile gear shifting inhaul cable fixing sleeve component, the raw material of the drag-line fixing sleeve component include 100 parts of neoprenes, 20~30 parts of 550 carbon blacks of N, 10~20 parts of decabromodiphenylethane, 10~20 parts of antimony oxides (environment-friendly type), 10~20 parts of dioctyl sebacates, 2~3 parts of antioxidant 4010NAs according to parts by weight.The drag-line fixing sleeve component of the present invention is by optimizing flame-retardant system, Plasticising system；Substitute original chlorinated paraffin flame-retardant system so that there is excellent flame retardant property, cryogenic property, and meet environmental requirement.
Description
Technical field
The present invention relates to technical field of rubber material more particularly to a kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve groups
Part.
Background technology
An important component-drag-line as automobile shift system fixes protective case component, and fixation is played in running car
The effect of automobile gear shift harness, while drag-line fixes protective case and also needs to the isolation inside and outside storehouse environment of automobile, sound insulation, noise reduction improve
The function of riding comfort；There is excellent flame retardant property while above-mentioned performance is met.
Conventional flame retardant neoprene is at present to prohibit according to REACH environmental requirement chlorinated paraffins using addition chlorinated paraffin
.
The content of the invention
The defects of the object of the invention is exactly to make up prior art, provides a kind of environmental protection flame retardant automobile gear shift zipper and fixes
Cover component.
The present invention is achieved by the following technical solutions：
A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component, which is characterized in that the raw material for having following parts by weight is made：
Neoprene 100-105, N-550 carbon black 20-30, decabromodiphenylethane 10-20, antimony oxide (environment-friendly type) 10-20, plasticising
Agent 10-20, anti-aging agent 2-3.
A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component, the plasticizer are dioctyl sebacate.
A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component, the anti-aging agent are p-phenylene diamine derivative
4010NA。
A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component, the decabromodiphenylethane and antimony oxide (ring
Guarantor's type) flame-retardant system is collectively constituted, and two used in the present invention kind fire retardant is commercially available.
The raw material of fixing sleeve component in the present invention is in addition to comprising above-mentioned raw materials, other auxiliary agents commonly used in the art, example
Such as accelerating agent, processing aid can be added according to the performance requirement of actual product.
A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component, is prepared by step in detail below：
(1) by neoprene, N-550 carbon blacks, decabromodiphenylethane, antimony oxide (environment-friendly type), plasticizer, anti-aging agent
It inserts jointly and mixing is carried out in mixing equipment, 70-100 DEG C of temperature control, pressure control 100-110Kgf/cm2, mixing 4-7 minutes obtains close
Refine rubber；
(2) qualified product is picked out from the rubber after mixing continue to insert and mill, temperature control 50- are carried out in mill equipment
60 DEG C, mill 3-5 minutes obtains molded rubber；
(3) molded rubber is inserted in vulcanizing equipment and carries out vulcanizing treatment, pressure control 160-180Kgf/ successively after by elder generation
Cm2,165-175 DEG C of temperature control, vulcanizing treatment 300~420 seconds.
A kind of preparation method of environmental protection flame retardant automobile gear shift zipper fixing sleeve component, described in step (2) after mixing
Rubber in pick out qualified product, specifically selecting condition is：Hardness is filtered out from mixing rubber as 50-55 degree, intensity
More than or equal to the 350% mixing rubber that 10MPa and elongation are not less than original length.
The concrete operations for carrying out deburring, inspection, packaging and storage after vulcanizing treatment to fixing sleeve have been the technology of this field
Personnel are known that details are not described herein.
It is an advantage of the invention that：The fixing sleeve component of the present invention is by selecting halogenated flame retardant decabromodiphenylethane and inorganic
The addition of fire retardant antimony oxide (environment-friendly type), dioctyl sebacate DOS so that there is excellent resistance to flame retardant property, resistance to low
Warm nature energy, concrete numerical value are shown in below table：
Specific embodiment
The technical solution further illustrated the present invention with reference to embodiment.
Embodiment 1
First, according to parts by weight by 100 parts of neoprenes, 25 parts of N-550 carbon blacks, 20 parts of decabromodiphenylethane, 15 part three
Aoxidize two antimony, 18 parts of dioctyl sebacate raw material are inserted in mixer in the item that temperature is 95 DEG C, pressure is 110Kgf/cm2
Mixing 6min is carried out under part, obtains mixing rubber.
Then, above-mentioned mixing rubber is detected, it is 51 degree, intensity 13.1MPa therefrom to filter out hardness, elongation
For 450%, the mixing rubber of burning time 1.5S.By the mixing rubber filtered out insert in open mill temperature for 55 DEG C, it
Under the conditions of carry out mill 4min and extrusion molding, then the molded part after extrusion molding is inserted in the mold in vulcanizing equipment,
Pressurize 170Kgf/cm2, is warming up to 175 DEG C, carries out vulcanizing treatment 360 seconds.After the rubber deburring of vulcanizing treatment.
Finally, test, pack and be put in storage, be fixed set.
Embodiment 2
First, according to parts by weight by 100 parts of neoprenes, 30 parts of N-550 carbon blacks, 15 parts of decabromodiphenylethane, 20 part three
Aoxidize two antimony, 20 parts of sebacic acid dibutyl ester raw material are inserted in mixer in the item that temperature is 95 DEG C, pressure is 110Kgf/cm2
Mixing 6min is carried out under part, obtains mixing rubber.
Then, above-mentioned mixing rubber is detected, it is 52 degree, intensity 13.7MPa therefrom to filter out hardness, elongation
For 441%, the mixing rubber of burning time 2S.By the mixing rubber filtered out insert in open mill temperature for 55 DEG C, item
Mill 4min and extrusion molding are carried out under part, then the molded part after extrusion molding is inserted in the mold in vulcanizing equipment, is added
170Kgf/cm2 is pressed, is warming up to 175 DEG C, carries out vulcanizing treatment 360 seconds.After the rubber deburring of vulcanizing treatment.
Finally, test, pack and be put in storage, be fixed set.
Embodiment 3
First, according to parts by weight by 100 parts of neoprenes, 20 parts of N-550 carbon blacks, 20 parts of decabromodiphenylethane, 20 part three
Aoxidize two antimony, 15 parts of sebacic acid dibutyl ester raw material are inserted in mixer in the item that temperature is 95 DEG C, pressure is 110Kgf/cm2
Mixing 6min is carried out under part, obtains mixing rubber.
Then, above-mentioned mixing rubber is detected, it is 52 degree, intensity 12.6MPa therefrom to filter out hardness, elongation
For 433%, the mixing rubber of burning time 0S.By the mixing rubber filtered out insert in open mill temperature for 55 DEG C, item
Mill 4min and extrusion molding are carried out under part, then the molded part after extrusion molding is inserted in the mold in vulcanizing equipment, is added
170Kgf/cm2 is pressed, is warming up to 175 DEG C, carries out vulcanizing treatment 360 seconds.After the rubber deburring of vulcanizing treatment.
Finally, test, pack and be put in storage, be fixed set.
Applicant states that the present invention illustrates the detailed process equipment of the present invention and technological process by above-described embodiment,
But the invention is not limited in above-mentioned detailed process equipment and technological processes, that is, it is above-mentioned detailed not mean that the present invention has to rely on
Process equipment and technological process could be implemented.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention,
The addition of equivalence replacement and auxiliary element to each raw material of product of the present invention, selection of concrete mode etc. all fall within the present invention's
Within protection domain and the open scope.
Claims (6)
1. a kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component, which is characterized in that the raw material for having following parts by weight is made：Chlorine
Buna 100-105, N-550 carbon black 20-30, decabromodiphenylethane 10-20, antimony oxide (environment-friendly type) 10-20, plasticising
Agent 10-20, anti-aging agent 2-3.
2. a kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component according to claim 1, which is characterized in that described
Plasticizer is dioctyl sebacate.
3. a kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component according to claim 1, which is characterized in that described
Anti-aging agent is p-phenylene diamine derivative 4010NA.
4. a kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component according to claim 1, which is characterized in that described
Decabromodiphenylethane collectively constitutes flame-retardant system with antimony oxide (environment-friendly type).
5. a kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component according to claim 1, which is characterized in that by following
Specific steps are prepared：
（1）Neoprene, N-550 carbon blacks, decabromodiphenylethane, antimony oxide (environment-friendly type), plasticizer, anti-aging agent is common
It inserts and mixing is carried out in mixing equipment, 70-100 DEG C of temperature control, pressure control 100-110Kgf/cm2, mixing 4-7 minutes obtains mixing rubber
Glue；
（2）Qualified product is picked out from the rubber after mixing continue to insert and mill, temperature control 50-60 are carried out in mill equipment
DEG C, mill 3-5 minutes obtains molded rubber；
（3）Molded rubber is inserted in vulcanizing equipment and carries out vulcanizing treatment, pressure control 160-180Kgf/cm2, control successively after by elder generation
Warm 165-175 DEG C, vulcanizing treatment 300~420 seconds.
6. a kind of preparation method of environmental protection flame retardant automobile gear shift zipper fixing sleeve component according to claim 5, feature
It is, step（2）Described in qualified product is picked out from the rubber after mixing, specifically selecting condition is：From mixing rubber
The 350% mixing rubber that hardness is not less than original length for 50-55 degree, intensity more than or equal to 10MPa and elongation is filtered out in glue
Glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810025976.2A CN108102174A (en) | 2018-01-11 | 2018-01-11 | A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810025976.2A CN108102174A (en) | 2018-01-11 | 2018-01-11 | A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108102174A true CN108102174A (en) | 2018-06-01 |
Family
ID=62219796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810025976.2A Pending CN108102174A (en) | 2018-01-11 | 2018-01-11 | A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108102174A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103113640A (en) * | 2013-01-28 | 2013-05-22 | 安徽龙庵电缆集团有限公司 | High-performance freezing-resistant and flame-retardant chloroprene rubber covering material |
| CN103497383A (en) * | 2013-10-25 | 2014-01-08 | 上海驰程化工工贸有限公司 | High-strength, tear-resisting and antiflaming sheath rubber for cable and preparation method thereof |
| CN103937058A (en) * | 2014-05-07 | 2014-07-23 | 上海蓝昊电气江苏有限公司 | High-flame-retardant oil-resistant low-temperature resistant neoprene cable material and preparation process thereof |
| CN106188706A (en) * | 2015-04-30 | 2016-12-07 | 南京金三力高分子科技有限公司 | A kind of flame-retardant chloroprene rubber material and preparation method thereof |
| CN205877159U (en) * | 2016-07-27 | 2017-01-11 | 安徽中鼎密封件股份有限公司 | Car is fixed protective sheath subassembly of cable for shift system |
-
2018
- 2018-01-11 CN CN201810025976.2A patent/CN108102174A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103113640A (en) * | 2013-01-28 | 2013-05-22 | 安徽龙庵电缆集团有限公司 | High-performance freezing-resistant and flame-retardant chloroprene rubber covering material |
| CN103497383A (en) * | 2013-10-25 | 2014-01-08 | 上海驰程化工工贸有限公司 | High-strength, tear-resisting and antiflaming sheath rubber for cable and preparation method thereof |
| CN103937058A (en) * | 2014-05-07 | 2014-07-23 | 上海蓝昊电气江苏有限公司 | High-flame-retardant oil-resistant low-temperature resistant neoprene cable material and preparation process thereof |
| CN106188706A (en) * | 2015-04-30 | 2016-12-07 | 南京金三力高分子科技有限公司 | A kind of flame-retardant chloroprene rubber material and preparation method thereof |
| CN205877159U (en) * | 2016-07-27 | 2017-01-11 | 安徽中鼎密封件股份有限公司 | Car is fixed protective sheath subassembly of cable for shift system |
Non-Patent Citations (1)
| Title |
|---|
| 温辉梁 主编: "《化工助剂》", 31 December 2009, 江西科学技术出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101955603A (en) | Heat cold and oil-resistant sizing material | |
| CN104177695A (en) | Crosslinked halogen-free flame-retardant cable material | |
| CN103709539B (en) | A kind of oil resistant fire-retardant chlorinated polyethylene heat-shrinkable T bush and preparation method and application | |
| CN103113640B (en) | High-performance freezing-resistant and flame-retardant chloroprene rubber covering material | |
| CN102746589A (en) | Sheath rubber for longitudinal water-tight demagnetization cable used for ship, and manufacture method for sheath rubber | |
| CN103540065A (en) | Modified oilproof aging-resistant polyvinyl chloride cable sheath material | |
| CN103965537A (en) | Method for producing self-crosslinking composite polyethylene cable material | |
| CN103102544A (en) | Low-smoke zero-halogen flame-retardant cable material and preparation method thereof | |
| CN103804882A (en) | High-performance chlorohydrin rubber and preparation method thereof | |
| CN102352066A (en) | Low-smoke halogen-free environment-friendly flame-retardant material and preparation method thereof | |
| CN105504465A (en) | High-temperature-resistant insulation sheath material used for cables | |
| CN102751020A (en) | Longitudinal watertight degaussing cable for warship and manufacturing method thereof | |
| CN103788510A (en) | High-performance cable sheath material | |
| CN103289415B (en) | A kind of cable jacket material containing modified methyl vinylsiloxane rubber and preparation method thereof | |
| CN102746588B (en) | Sheath rubber for middle and high voltage cable used for petrochemical apparatus motion, and manufacture method for sheath rubber | |
| CN102751017B (en) | Strengthening tensile type longitudinal watertight degaussing cable for ships and warships and manufacturing method thereof | |
| CN105254995A (en) | Mud-resistant cable sheath rubber material and preparation method thereof | |
| CN108102174A (en) | A kind of environmental protection flame retardant automobile gear shift zipper fixing sleeve component | |
| CN105367918B (en) | A kind of halogen-free refractory conductor shielding material and preparation method thereof | |
| CN104194160A (en) | Polypropylene film covering material and preparation method thereof | |
| CN103788579A (en) | High-temperature resistant urban rail cable sheath material | |
| CN106609003A (en) | Low-smoke zero-halogen high-flame-retardant rat-ant-water-proof cable sheathing material and preparation method | |
| CN103524883A (en) | Modified polypropylene insulation material for communication equipment wire harness | |
| CN101955601A (en) | Chloroprene rubber improved by employing ionomer | |
| CN103554777A (en) | Polyvinyl chloride insulating material for wire harness of communication equipment |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180601 |
|
| RJ01 | Rejection of invention patent application after publication |