CN108102159A - Tubeless tyre inner face glue containing halobutyl reclaimed rubber - Google Patents

Tubeless tyre inner face glue containing halobutyl reclaimed rubber Download PDF

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Publication number
CN108102159A
CN108102159A CN201711444544.7A CN201711444544A CN108102159A CN 108102159 A CN108102159 A CN 108102159A CN 201711444544 A CN201711444544 A CN 201711444544A CN 108102159 A CN108102159 A CN 108102159A
Authority
CN
China
Prior art keywords
parts
rubber
inner face
face glue
tubeless tyre
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711444544.7A
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Chinese (zh)
Inventor
郑昌福
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sichuan Yuanxing Rubber Co Ltd
Original Assignee
Sichuan Yuanxing Rubber Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sichuan Yuanxing Rubber Co Ltd filed Critical Sichuan Yuanxing Rubber Co Ltd
Priority to CN201711444544.7A priority Critical patent/CN108102159A/en
Publication of CN108102159A publication Critical patent/CN108102159A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/14Gas barrier composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic
    • C08L2207/24Recycled plastic recycling of old tyres and caoutchouc and addition of caoutchouc particles

Abstract

The invention discloses a kind of tubeless tyre inner face glue containing halobutyl reclaimed rubber, the component of the tubeless tyre inner face glue includes in parts by weight:Natural rubber:40~60 parts, styrene butadiene rubber sbr 1500:35~25 parts, halobutyl reclaimed rubber:25~15 parts, halogenated butyl rubber:25 15 parts, carbon black N660:40~55 parts, precipitated calcium carbonate:105 35 parts, aromatic naphtha:5~15 parts, tackifier:1~3 part, zinc oxide:3.5~4.5 parts, stearic acid:1.0~2.0 parts, antioxidant 4020:1.0 parts, anti-aging agent RD:0.5~1.5 part, protection wax:1.0 parts, accelerant CZ:0.1~0.6 part, altax:0.1~0.4 part and Cosan S:1~4 part.The present invention is not only at low cost, has high gas retaining, and improves processing dispersiveness, adherence, is also improved in physical property, while decreases the consumption to oil product, there is certain environment protecting.It can be widely applied to special purpose vehicle, motor vehicle, electric car, bicycle and Li Che.

Description

Tubeless tyre inner face glue containing halobutyl reclaimed rubber
Technical field
The present invention relates to tire inner face glue technical fields, and in particular to a kind of tubeless wheel containing halobutyl reclaimed rubber Tire inner face glue.
Background technology
High gas retaining is always the important directions of tire development, tire lack pressure traveling be cause one of damaged tyres it is main Factor, general tubeless tyre inner face glue are made of natural gum, halogenated butyl rubber, the poly- butadiene-styrene rubber of breast, do not add halogenation fourth Base reclaimed rubber causes product cost height less economical, and the actual competitiveness of product reduces.
The content of the invention
The present invention overcomes the deficiencies in the prior art, provide a kind of tubeless tyre inner face containing halobutyl reclaimed rubber Glue.
To solve the technical issues of above-mentioned, the present invention uses following technical scheme:
A kind of tubeless tyre inner face glue containing halobutyl reclaimed rubber, the component of the tubeless tyre inner face glue Include in parts by weight:Natural rubber:40~60 parts, styrene butadiene rubber sbr 1500:35~25 parts, halobutyl regeneration Glue:25~15 parts, halogenated butyl rubber:25-15 parts, carbon black N660:40~55 parts, precipitated calcium carbonate:105-35 parts, aromatic naphtha:5 ~15 parts, tackifier:1~3 part, zinc oxide:3.5~4.5 parts, stearic acid:1.0~2.0 parts, antioxidant 4020:1.0 parts, prevent Old agent RD:0.5~1.5 part, protection wax:1.0 parts, accelerant CZ:0.1~0.6 part, altax:0.1~0.4 part and sulphur Powder S:1~4 part.
Further technical solution is that the component of the tubeless tyre inner face glue includes in parts by weight:My god T PNR NR:40 parts, emulsion polymerized styrene butadiene rubber SBR1500:35 parts, halogenated butyl rubber:25 parts, halobutyl reclaimed rubber:25 parts, gently Matter calcium carbonate:15 parts, carbon black N660:45 parts, aromatic naphtha:10 parts, tackifier:3 parts, zinc oxide:3.5 parts, stearic acid:1.5 parts, Antioxidant 4020:1.0 parts, anti-aging agent RD:1.5 parts, accelerant CZ:0.6 part, altax:0.4 part and Cosan S:1.85 Part.
Compared with prior art, one of advantageous effect of the embodiment of the present invention is:Present invention is mainly used for the inner faces of tire In glue, cost is can obviously reduce using sizing material of the present invention, tire gas retaining is good made of sizing material of the present invention.Not only cost of the invention It is low, there is high gas retaining, and processing dispersiveness, adherence are improved, it is also improved in physical property, while also subtracts Lack the consumption to oil product, there is certain environment protecting.It can be widely applied to special purpose vehicle, motor vehicle, electric car, bicycle With power vehicle.
Specific embodiment
All features or disclosed all methods disclosed in this specification or in the process the step of, except mutually exclusive Feature and/or step beyond, can combine in any way.
Any feature disclosed in this specification (including any accessory claim, summary), unless specifically stated, It is replaced by other equivalent or with similar purpose alternative features.I.e., unless specifically stated, each feature is a series of An example in equivalent or similar characteristics.
The specific embodiment of the present invention is described in detail with reference to embodiment.
Embodiment 1:
According to one embodiment of present invention, in the tubeless tyre containing halobutyl reclaimed rubber disclosed in the present embodiment Face glue, the component of the tubeless tyre inner face glue include in parts by weight:Natural rubber:50 parts, rosin butylbenzene rubber Glue SBR1500:30 parts, halogenated butyl rubber:20 parts, halobutyl reclaimed rubber:25 parts, carbon black N660:45 parts, aromatic naphtha:10 parts, Tackifier:3 parts, zinc oxide:3.5 parts, stearic acid:1.5 parts, antioxidant 4020:1.0 parts, anti-aging agent RD:1.5 parts, accelerating agent CZ:0.6 part, altax:0.4 part and Cosan S:1.65 part.
Tubeless tyre inner face glue containing halobutyl reclaimed rubber disclosed in the present embodiment, production stage are:
Step 1. plasticates natural rubber, butadiene-styrene rubber, cis-butadiene cement 60 seconds in mixer, adds in four points of carbon black total amount Three and precipitated calcium carbonate, tackifier, zinc oxide, stearic acid, anti-aging agent, resin, be kneaded 120 seconds, add in surplus in mixer Remaining a quarter carbon black and aromatic naphtha are kneaded 400 seconds in mixer, rubber compound are made.
Step 2. by rubber compound made of step 1 park 4 it is small when more than after, on a mill add in accelerating agent, Cosan In rubber compound, you can used by the normal production technology of tire.
The processing method of above-mentioned material is plasticated in mixer, mixing etc. is Conventional processing methods in mixer.
The tubeless tyre inner face glue that the present embodiment contains halobutyl reclaimed rubber is inflated after producing finished product and parks 3 Atmospheric pressure lost 4% after month, the mainstream product in the market park 3 months atmospheric pressure losts in 4.5-5%, year-on-year mainstream product in the market air pressure damage Lose low 0.5-1%.
Embodiment 2:
According to another embodiment of the invention, the tubeless tyre containing halobutyl reclaimed rubber disclosed in the present embodiment Inner face glue, the component of the tubeless tyre inner face glue include in parts by weight:Each component raw material weight number ratio is:My god T PNR NR:40 parts, styrene butadiene rubber sbr 1500:35 parts, halogenated butyl rubber:25 parts, halobutyl reclaimed rubber:25 parts, carbon black N660:45 parts, aromatic naphtha:8 parts, tackifier:2.5 parts, zinc oxide:3.5 parts, stearic acid:0.5 part, antioxidant 4020:1.0 parts, Anti-aging agent RD:0.5 part, accelerant CZ:0.8 part, altax:0.1 part and Cosan S:1 part.
Tubeless tyre inner face glue containing halobutyl reclaimed rubber disclosed in the present embodiment, production stage and embodiment 1 is identical.
The tubeless tyre inner face glue that the present embodiment contains halobutyl reclaimed rubber is inflated after producing finished product and parks 3 Atmospheric pressure lost 3.0% after month, the mainstream product in the market park 3 months atmospheric pressure losts in 4.5-5%, year-on-year mainstream product in the market air pressure Lose low 1.5-2%.
" one embodiment " for being spoken of in the present specification, " another embodiment ", " embodiment " etc., refer to combining Specific features, structure or the feature of embodiment description are included at least one embodiment of the application generality description. It is not centainly to refer to same embodiment that statement of the same race, which occur, in multiple places in the description.Furthermore, it is understood that with reference to any When a embodiment describes a specific features, structure or feature, what is advocated is this to realize with reference to other embodiment Feature, structure or feature are also fallen within the scope of the present invention.
Although reference be made herein to invention has been described for the multiple explanatory embodiments invented, however, it is to be understood that this Field technology personnel can be designed that a lot of other modifications and embodiment, these modifications and embodiment will fall in the application Within disclosed spirit and spirit.It more specifically, can be to theme group in the range of disclosure claim The building block and/or layout for closing layout carry out a variety of variations and modifications.Except the modification carried out to building block and/or layout Outer with improving, to those skilled in the art, other purposes also will be apparent.

Claims (2)

1. a kind of tubeless tyre inner face glue containing halobutyl reclaimed rubber, it is characterised in that:In the tubeless tyre The component of face glue includes in parts by weight:Natural rubber:40~60 parts, styrene butadiene rubber sbr 1500:35~25 parts, halogen Change butyl reclaimed rubber:25~15 parts, halogenated butyl rubber:25-15 parts, carbon black N660:40~55 parts, precipitated calcium carbonate:105-35 Part, aromatic naphtha:5~15 parts, tackifier:1~3 part, zinc oxide:3.5~4.5 parts, stearic acid:1.0~2.0 parts, anti-aging agent 4020:1.0 parts, anti-aging agent RD:0.5~1.5 part, protection wax:1.0 parts, accelerant CZ:0.1~0.6 part, altax:0.1 ~0.4 part and Cosan S:1~4 part.
2. the tubeless tyre inner face glue according to claim 1 containing halobutyl reclaimed rubber, it is characterised in that described The component of tubeless tyre inner face glue include in parts by weight:Natural rubber:40 parts, emulsion polymerized styrene butadiene rubber SBR1500:35 parts, halogenated butyl rubber:25 parts, halobutyl reclaimed rubber:25 parts, precipitated calcium carbonate:15 parts, carbon black N660:45 Part, aromatic naphtha:10 parts, tackifier:3 parts, zinc oxide:3.5 parts, stearic acid:1.5 parts, antioxidant 4020:1.0 parts, anti-aging agent RD:1.5 parts, accelerant CZ:0.6 part, altax:0.4 part and Cosan S:1.85 part.
CN201711444544.7A 2017-12-27 2017-12-27 Tubeless tyre inner face glue containing halobutyl reclaimed rubber Pending CN108102159A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711444544.7A CN108102159A (en) 2017-12-27 2017-12-27 Tubeless tyre inner face glue containing halobutyl reclaimed rubber

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711444544.7A CN108102159A (en) 2017-12-27 2017-12-27 Tubeless tyre inner face glue containing halobutyl reclaimed rubber

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Publication Number Publication Date
CN108102159A true CN108102159A (en) 2018-06-01

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423634A (en) * 2020-05-20 2020-07-17 威海市润通橡胶有限公司 Engineering inner tube made of nano material and production method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675760A (en) * 2012-06-25 2012-09-19 腾森橡胶轮胎(威海)有限公司 Tire air-tight layer rubber composite containing nano filler StronWiNTC
CN102775651A (en) * 2012-08-16 2012-11-14 中橡集团曙光橡胶工业研究设计院 Sponge tire sponge rubber material containing butyl reclaimed rubber
CN103865185A (en) * 2014-04-01 2014-06-18 山东万鑫轮胎有限公司 Inner liner sizing for tubeless truck tire and preparation method of inner liner sizing
CN103865135A (en) * 2014-04-01 2014-06-18 山东万鑫轮胎有限公司 Air impervious liner sizing material for tube tires and preparation method thereof
CN105017582A (en) * 2014-04-25 2015-11-04 建大橡胶(中国)有限公司 High-gas-maintaining-performance inner surface rubber and synthesis method of high-gas-maintaining-performance inner surface rubber

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675760A (en) * 2012-06-25 2012-09-19 腾森橡胶轮胎(威海)有限公司 Tire air-tight layer rubber composite containing nano filler StronWiNTC
CN102775651A (en) * 2012-08-16 2012-11-14 中橡集团曙光橡胶工业研究设计院 Sponge tire sponge rubber material containing butyl reclaimed rubber
CN103865185A (en) * 2014-04-01 2014-06-18 山东万鑫轮胎有限公司 Inner liner sizing for tubeless truck tire and preparation method of inner liner sizing
CN103865135A (en) * 2014-04-01 2014-06-18 山东万鑫轮胎有限公司 Air impervious liner sizing material for tube tires and preparation method thereof
CN105017582A (en) * 2014-04-25 2015-11-04 建大橡胶(中国)有限公司 High-gas-maintaining-performance inner surface rubber and synthesis method of high-gas-maintaining-performance inner surface rubber

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Title
魏宝玉: "丁基再生胶在无内胎子午线轮胎气密层中的应用", 《橡塑资源利用》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111423634A (en) * 2020-05-20 2020-07-17 威海市润通橡胶有限公司 Engineering inner tube made of nano material and production method thereof

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Application publication date: 20180601