CN103865185A - Inner liner sizing for tubeless truck tire and preparation method of inner liner sizing - Google Patents
Inner liner sizing for tubeless truck tire and preparation method of inner liner sizing Download PDFInfo
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- CN103865185A CN103865185A CN201410129457.2A CN201410129457A CN103865185A CN 103865185 A CN103865185 A CN 103865185A CN 201410129457 A CN201410129457 A CN 201410129457A CN 103865185 A CN103865185 A CN 103865185A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention belongs to the field of tires, and relates to an inner liner sizing for a tubeless truck tire and a preparation method of inner liner sizing. The inner liner sizing for the tubeless truck tire comprises the following raw materials in parts by weight: 70-80 parts of brominated butyl rubber; 20 parts of natural rubber, 0-10 parts of modified chlorosulfonated polyethylene, 0-20 parts of butyl reclaimed rubber, 40-60 parts of carbon black, 10-30 parts of YB-5 radial tire special material, 10-30 parts of Stron WiTM KTC, 5.0-10 parts of aromatic oil, 4.0-8.0 parts of rubber homogenizing agent, 1.0-2.0 parts of stearic acid, 2-4 parts of tackifying resin, 0-1.0 part of magnesium oxide, 3.0-4.0 parts of zinc oxide-80, 0.5-1.2 part of sulphur and 1.0-2.0 parts of accelerant DM. On the premise of guaranteeing the extreme low air and moisture transmittance of the inner liner sizing, the production cost is reduced, and the viscosity of the sizing is increased.
Description
Technical field
The invention belongs to tire field, be specifically related to a kind of tubeless truck tyre air retaining wall sizing material and preparation method thereof.
Background technology
The air retaining wall of radial is positioned at carcass and obtains innermost layer, and for tubeless tyre, air retaining wall sizing material requires to have extremely low air and moisture transmission, to guarantee the interior pressure of tire.In order to meet this requirement of air retaining wall, the rubbery systems of brominated butyl rubber as air retaining wall formula that use at present more, the price comparison costliness of brominated butyl rubber, and be mainly derived from external import.
Summary of the invention
The object of this invention is to provide a kind of tubeless truck tyre air retaining wall sizing material and preparation method thereof, under the prerequisite of the extremely low air of assurance air retaining wall sizing material and moisture transmission, reduce production costs, increase the viscosity of sizing material.
Tubeless truck tyre air retaining wall sizing material of the present invention, in parts by weight, mixing the preparing of raw material by following component:
Brominated butyl rubber: 70~80 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 0~20 part, carbon black: 40~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~30 parts, strong prestige powder: 10~30 parts, aromatic hydrocarbon oil: 5.0~10 parts, rubber leveler: 4.0~8.0 parts, stearic acid: 1.0~2.0 parts, tackifying resin: 2~4 parts, magnesium oxide: 0~1.0 part, zinc oxide-80:3.0~4.0 part, sulphur: 0.5~1.2 part, altax: 1.0~2.0 parts.
Tubeless truck tyre air retaining wall sizing material of the present invention, in parts by weight, the raw material of preferred following component is mixing to be prepared:
Brominated butyl rubber: 70~75 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 5~10 parts, butyl reclaimed rubber: 10~20 parts, carbon black: 50~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~20 parts, strong prestige powder: 15~25 parts, aromatic hydrocarbon oil: 8~10 parts, rubber leveler: 6.0~8.0 parts, stearic acid: 1.5~2.0 parts, tackifying resin: 2~3 parts, magnesium oxide: 0.5~1.0 part, zinc oxide-80:3.5~4.0 part, sulphur: 0.5~1.0 part, altax: 1.5~2.0 parts.
Tubeless truck tyre air retaining wall sizing material of the present invention, in parts by weight, more preferably the raw material of following component is mixing prepares:
Brominated butyl rubber: 70 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 15 parts, carbon black: 52 parts, YB-5 radial-ply tyre PP Pipe Compound: 15 parts, strong prestige powder: 20 parts, aromatic hydrocarbon oil: 10 parts, rubber leveler: 6 parts, stearic acid: 2.0 parts, tackifying resin: 3 parts, magnesium oxide: 1.0 parts, zinc oxide-80:3.7 part, sulphur: 0.95 part, altax: 1.5 parts.
The preferred octyl group phenolic tackifying resins of tackifying resin.
The manufacturer of modification chlorosulfonated polyethylene is the Huangyan East Sea, Taizhou plain Chemical Co., Ltd..
The manufacturer of radial-ply tyre PP Pipe Compound YB-5 is Qingdao Meng Li rubber filling company limited.
The manufacturer of strong prestige powder is Shanghai Qi Xiang Chemical Co., Ltd..
The present invention's product used is commercially available.
The preparation method of air retaining wall sizing material for tubeless truck tyre, comprises the following steps:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 40~60 revs/min of Banbury mixer rotating speeds, pressurization 15~18MPa, 30~50s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 15~18MPa rises floating weight in the time that temperature reaches 110~120 ℃, drops into aromatic hydrocarbon oil, pressurization 15~18MPa, binder removal while causing 135~145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20~40 revs/min of rotating speeds, pressurization 15~17MPa, rises floating weight for 20~40 seconds, and pressurization 15~17MPa, rises floating weight, binder removal for 30~50 seconds.
Compared with prior art, the present invention has following beneficial effect:
The present invention, under the prerequisite of the extremely low air of assurance air retaining wall sizing material and moisture transmission, uses natural gum and modification chlorosulfonated polyethylene part to substitute brominated butyl rubber, and adds butyl reclaimed rubber, has reduced the consumption of brominated butyl rubber, has reduced production cost.Add YB-5 radial-ply tyre PP Pipe Compound is also in order to reduce production costs with strong two kinds of fillers of prestige powder simultaneously, has increased the viscosity of sizing material.
Embodiment
Below in conjunction with embodiment, the present invention is described further.
The raw material of embodiment 1-5 and parts by weight thereof are as table 1.
Embodiment 1
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 50 revs/min of Banbury mixer rotating speeds, pressurization 17MPa, 30s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 17MPa rises floating weight in the time that temperature reaches 115 ℃, drops into aromatic hydrocarbon oil, pressurization 17MPa, binder removal while causing 140 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20 revs/min of rotating speeds, pressurization 16MPa, rises floating weight for 30 seconds, and pressurization 16MPa, rises floating weight, binder removal for 45 seconds.
Embodiment 2
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 40 revs/min of Banbury mixer rotating speeds, pressurization 15MPa, 50s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 15MPa rises floating weight in the time that temperature reaches 110 ℃, drops into aromatic hydrocarbon oil, pressurization 15MPa, binder removal while causing 135 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,40 revs/min of rotating speeds, pressurization 15MPa, rises floating weight for 20 seconds, and pressurization 15MPa, rises floating weight, binder removal for 30 seconds.
Embodiment 3
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 60 revs/min of Banbury mixer rotating speeds, pressurization 18MPa, 30s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 18MPa rises floating weight in the time that temperature reaches 120 ℃, drops into aromatic hydrocarbon oil, pressurization 18MPa, binder removal while causing 145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20 revs/min of rotating speeds, pressurization 17MPa, rises floating weight for 40 seconds, and pressurization 17MPa, rises floating weight, binder removal for 50 seconds.
Embodiment 4
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 50 revs/min of Banbury mixer rotating speeds, pressurization 18MPa, 35s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 18MPa rises floating weight in the time that temperature reaches 115 ℃, drops into aromatic hydrocarbon oil, pressurization 18MPa, binder removal while causing 140 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,30 revs/min of rotating speeds, pressurization 17MPa, rises floating weight for 30 seconds, and pressurization 17MPa, rises floating weight, binder removal for 40 seconds.
Embodiment 5
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 50 revs/min of Banbury mixer rotating speeds, pressurization 17MPa, 40s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 17MPa rises floating weight in the time that temperature reaches 115 ℃, drops into aromatic hydrocarbon oil, pressurization 17MPa, binder removal while causing 145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20 revs/min of rotating speeds, pressurization 17MPa, rises floating weight for 35 seconds, and pressurization 17MPa, rises floating weight, binder removal for 40 seconds.
The product physical and mechanical properties of embodiment 1-5 is as table 2.
Raw material and the parts by weight thereof of table 1 embodiment 1-5
Synergist S-421 95 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
Brominated butyl rubber | 70 | 70 | 80 | 70 | 75 |
Natural rubber | 20 | 20 | 20 | 20 | 20 |
Modification chlorosulfonated polyethylene | 10 | 10 | 0 | 10 | 5 |
Butyl reclaimed rubber | 15 | 0 | 20 | 10 | 20 |
Carbon black | 52 | 40 | 60 | 55 | 50 |
YB-5 radial-ply tyre PP Pipe Compound | 15 | 10 | 30 | 20 | 25 |
Strong prestige powder | 20 | 30 | 10 | 15 | 10 |
Aromatic hydrocarbon oil | 10 | 5 | 10 | 10 | 8 |
Rubber leveler | 6 | 4 | 8 | 8 | 6 |
Stearic acid | 2 | 1 | 2 | 2 | 1.5 |
Octyl group phenolic tackifying resins | 3 | 2 | 4 | 2 | 3 |
Magnesium oxide | 1 | 0 | 1 | 1 | 0.5 |
Sulphur | 0.95 | 0.5 | 1.2 | 0.5 | 1.0 |
Zinc oxide-80 | 3.7 | 4 | 3 | 4 | 3.5 |
Altax | 1.5 | 2 | 1 | 2 | 1.5 |
Table 2 embodiment 1-5 and conventional products physical and mechanical properties
Claims (5)
1. a tubeless truck tyre air retaining wall sizing material, is characterized in that, in parts by weight, and mixing the preparing of raw material by following component:
Brominated butyl rubber: 70~80 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 0~20 part, carbon black: 40~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~30 parts, strong prestige powder: 10~30 parts, aromatic hydrocarbon oil: 5.0~10 parts, rubber leveler: 4.0~8.0 parts, stearic acid: 1.0~2.0 parts, tackifying resin: 2~4 parts, magnesium oxide: 0~1.0 part, zinc oxide-80:3.0~4.0 part, sulphur: 0.5~1.2 part, altax: 1.0~2.0 parts.
2. tubeless truck tyre air retaining wall sizing material according to claim 1, is characterized in that, in parts by weight, and mixing the preparing of raw material by following component:
Brominated butyl rubber: 70~75 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 5~10 parts, butyl reclaimed rubber: 10~20 parts, carbon black: 50~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~20 parts, strong prestige powder: 15~25 parts, aromatic hydrocarbon oil: 8~10 parts, rubber leveler: 6.0~8.0 parts, stearic acid: 1.5~2.0 parts, tackifying resin: 2~3 parts, magnesium oxide: 0.5~1.0 part, zinc oxide-80:3.5~4.0 part, sulphur: 0.5~1.0 part, altax: 1.5~2.0 parts.
3. tubeless truck tyre air retaining wall sizing material according to claim 1, is characterized in that, in parts by weight, and mixing the preparing of raw material by following component:
Brominated butyl rubber: 70 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 15 parts, carbon black: 52 parts, YB-5 radial-ply tyre PP Pipe Compound: 15 parts, strong prestige powder: 20 parts, aromatic hydrocarbon oil: 10 parts, rubber leveler: 6 parts, stearic acid: 2.0 parts, tackifying resin: 3 parts, magnesium oxide: 1.0 parts, zinc oxide-80:3.7 part, sulphur: 0.95 part, altax: 1.5 parts.
4. according to the tubeless truck tyre air retaining wall sizing material described in claim 1,2 or 3, it is characterized in that the preferred octyl group phenolic tackifying resins of tackifying resin.
5. a preparation method for air retaining wall sizing material for tubeless truck tyre claimed in claim 1, is characterized in that, comprises the following steps:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 40~60 revs/min of Banbury mixer rotating speeds, pressurization 15~18MPa, 30~50s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 15~18MPa rises floating weight in the time that temperature reaches 110~120 ℃, drops into aromatic hydrocarbon oil, pressurization 15~18MPa, binder removal while causing 135~145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20~40 revs/min of rotating speeds, pressurization 15~17MPa, rises floating weight for 20~40 seconds, and pressurization 15~17MPa, rises floating weight, binder removal for 30~50 seconds.
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Cited By (18)
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CN104292511B (en) * | 2014-08-26 | 2016-08-24 | 赛轮金宇集团股份有限公司 | Tire sidewall and the methods for making and using same of the ageing-resistant protective rubber of bead |
CN105949633A (en) * | 2016-05-25 | 2016-09-21 | 德州玲珑轮胎有限公司 | Tire inner liner rubber and preparation method thereof |
CN105968437A (en) * | 2016-06-27 | 2016-09-28 | 宁海建新减震系统有限公司 | High-aging-resistance rubber material and preparation method thereof |
CN106280043A (en) * | 2016-08-24 | 2017-01-04 | 山东新大陆橡胶科技股份有限公司 | Tire air-tight layer rubber composition and preparation method thereof |
CN106543575A (en) * | 2016-11-25 | 2017-03-29 | 青岛双星轮胎工业有限公司 | Heavy load radial tire inner liner rubber composition |
CN108084576A (en) * | 2017-10-24 | 2018-05-29 | 固比斯特科技(宁波)有限公司 | A kind of inner tube of a tyre rubber composition and the pricking-proof explosion-proof tire with the inner tube of a tyre |
CN108102159A (en) * | 2017-12-27 | 2018-06-01 | 四川远星橡胶有限责任公司 | Tubeless tyre inner face glue containing halobutyl reclaimed rubber |
CN108727656A (en) * | 2018-05-24 | 2018-11-02 | 中策橡胶集团有限公司 | A kind of truck tyre inner liner rubber composition and preparation method thereof |
CN108864583A (en) * | 2018-08-08 | 2018-11-23 | 江苏通用科技股份有限公司 | Full-steel radial ply air/tight layer rubber and preparation method thereof |
CN109517284A (en) * | 2018-10-23 | 2019-03-26 | 山东日科化学股份有限公司 | A kind of tire air-tight layer rubber material, as application of tyre airtight layer glue and preparation method thereof |
CN109776975A (en) * | 2017-11-10 | 2019-05-21 | 江苏润昌橡胶科技有限公司 | A kind of tubeless high-capacity tyre inner liner sizing material and preparation method thereof |
CN110423414A (en) * | 2019-08-01 | 2019-11-08 | 江苏通用科技股份有限公司 | A kind of inner liner film and preparation method thereof |
CN111040322A (en) * | 2019-12-30 | 2020-04-21 | 四川轮胎橡胶(集团)股份有限公司 | Airtight layer adhesive and preparation method thereof |
CN111732792A (en) * | 2020-07-14 | 2020-10-02 | 四川远星橡胶有限责任公司 | Sizing material for airtight layer of explosion-proof tire and preparation method thereof |
CN111875892A (en) * | 2020-06-30 | 2020-11-03 | 赛轮(沈阳)轮胎有限公司 | Method for improving production stability of airtight layer rubber material |
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Application publication date: 20140618 |