CN103865185A - Inner liner sizing for tubeless truck tire and preparation method of inner liner sizing - Google Patents

Inner liner sizing for tubeless truck tire and preparation method of inner liner sizing Download PDF

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Publication number
CN103865185A
CN103865185A CN201410129457.2A CN201410129457A CN103865185A CN 103865185 A CN103865185 A CN 103865185A CN 201410129457 A CN201410129457 A CN 201410129457A CN 103865185 A CN103865185 A CN 103865185A
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parts
rubber
pressurization
inner liner
retaining wall
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田晓亮
朱之锋
鲍士明
苏纪征
程术海
杨绿永
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SHANDONG WANSHINE TIRE CO Ltd
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SHANDONG WANSHINE TIRE CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention belongs to the field of tires, and relates to an inner liner sizing for a tubeless truck tire and a preparation method of inner liner sizing. The inner liner sizing for the tubeless truck tire comprises the following raw materials in parts by weight: 70-80 parts of brominated butyl rubber; 20 parts of natural rubber, 0-10 parts of modified chlorosulfonated polyethylene, 0-20 parts of butyl reclaimed rubber, 40-60 parts of carbon black, 10-30 parts of YB-5 radial tire special material, 10-30 parts of Stron WiTM KTC, 5.0-10 parts of aromatic oil, 4.0-8.0 parts of rubber homogenizing agent, 1.0-2.0 parts of stearic acid, 2-4 parts of tackifying resin, 0-1.0 part of magnesium oxide, 3.0-4.0 parts of zinc oxide-80, 0.5-1.2 part of sulphur and 1.0-2.0 parts of accelerant DM. On the premise of guaranteeing the extreme low air and moisture transmittance of the inner liner sizing, the production cost is reduced, and the viscosity of the sizing is increased.

Description

Air retaining wall sizing material and preparation method thereof for tubeless truck tyre
Technical field
The invention belongs to tire field, be specifically related to a kind of tubeless truck tyre air retaining wall sizing material and preparation method thereof.
Background technology
The air retaining wall of radial is positioned at carcass and obtains innermost layer, and for tubeless tyre, air retaining wall sizing material requires to have extremely low air and moisture transmission, to guarantee the interior pressure of tire.In order to meet this requirement of air retaining wall, the rubbery systems of brominated butyl rubber as air retaining wall formula that use at present more, the price comparison costliness of brominated butyl rubber, and be mainly derived from external import.
Summary of the invention
The object of this invention is to provide a kind of tubeless truck tyre air retaining wall sizing material and preparation method thereof, under the prerequisite of the extremely low air of assurance air retaining wall sizing material and moisture transmission, reduce production costs, increase the viscosity of sizing material.
Tubeless truck tyre air retaining wall sizing material of the present invention, in parts by weight, mixing the preparing of raw material by following component:
Brominated butyl rubber: 70~80 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 0~20 part, carbon black: 40~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~30 parts, strong prestige powder: 10~30 parts, aromatic hydrocarbon oil: 5.0~10 parts, rubber leveler: 4.0~8.0 parts, stearic acid: 1.0~2.0 parts, tackifying resin: 2~4 parts, magnesium oxide: 0~1.0 part, zinc oxide-80:3.0~4.0 part, sulphur: 0.5~1.2 part, altax: 1.0~2.0 parts.
Tubeless truck tyre air retaining wall sizing material of the present invention, in parts by weight, the raw material of preferred following component is mixing to be prepared:
Brominated butyl rubber: 70~75 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 5~10 parts, butyl reclaimed rubber: 10~20 parts, carbon black: 50~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~20 parts, strong prestige powder: 15~25 parts, aromatic hydrocarbon oil: 8~10 parts, rubber leveler: 6.0~8.0 parts, stearic acid: 1.5~2.0 parts, tackifying resin: 2~3 parts, magnesium oxide: 0.5~1.0 part, zinc oxide-80:3.5~4.0 part, sulphur: 0.5~1.0 part, altax: 1.5~2.0 parts.
Tubeless truck tyre air retaining wall sizing material of the present invention, in parts by weight, more preferably the raw material of following component is mixing prepares:
Brominated butyl rubber: 70 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 15 parts, carbon black: 52 parts, YB-5 radial-ply tyre PP Pipe Compound: 15 parts, strong prestige powder: 20 parts, aromatic hydrocarbon oil: 10 parts, rubber leveler: 6 parts, stearic acid: 2.0 parts, tackifying resin: 3 parts, magnesium oxide: 1.0 parts, zinc oxide-80:3.7 part, sulphur: 0.95 part, altax: 1.5 parts.
The preferred octyl group phenolic tackifying resins of tackifying resin.
The manufacturer of modification chlorosulfonated polyethylene is the Huangyan East Sea, Taizhou plain Chemical Co., Ltd..
The manufacturer of radial-ply tyre PP Pipe Compound YB-5 is Qingdao Meng Li rubber filling company limited.
The manufacturer of strong prestige powder is Shanghai Qi Xiang Chemical Co., Ltd..
The present invention's product used is commercially available.
The preparation method of air retaining wall sizing material for tubeless truck tyre, comprises the following steps:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 40~60 revs/min of Banbury mixer rotating speeds, pressurization 15~18MPa, 30~50s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 15~18MPa rises floating weight in the time that temperature reaches 110~120 ℃, drops into aromatic hydrocarbon oil, pressurization 15~18MPa, binder removal while causing 135~145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20~40 revs/min of rotating speeds, pressurization 15~17MPa, rises floating weight for 20~40 seconds, and pressurization 15~17MPa, rises floating weight, binder removal for 30~50 seconds.
Compared with prior art, the present invention has following beneficial effect:
The present invention, under the prerequisite of the extremely low air of assurance air retaining wall sizing material and moisture transmission, uses natural gum and modification chlorosulfonated polyethylene part to substitute brominated butyl rubber, and adds butyl reclaimed rubber, has reduced the consumption of brominated butyl rubber, has reduced production cost.Add YB-5 radial-ply tyre PP Pipe Compound is also in order to reduce production costs with strong two kinds of fillers of prestige powder simultaneously, has increased the viscosity of sizing material.
Embodiment
Below in conjunction with embodiment, the present invention is described further.
The raw material of embodiment 1-5 and parts by weight thereof are as table 1.
Embodiment 1
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 50 revs/min of Banbury mixer rotating speeds, pressurization 17MPa, 30s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 17MPa rises floating weight in the time that temperature reaches 115 ℃, drops into aromatic hydrocarbon oil, pressurization 17MPa, binder removal while causing 140 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20 revs/min of rotating speeds, pressurization 16MPa, rises floating weight for 30 seconds, and pressurization 16MPa, rises floating weight, binder removal for 45 seconds.
Embodiment 2
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 40 revs/min of Banbury mixer rotating speeds, pressurization 15MPa, 50s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 15MPa rises floating weight in the time that temperature reaches 110 ℃, drops into aromatic hydrocarbon oil, pressurization 15MPa, binder removal while causing 135 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,40 revs/min of rotating speeds, pressurization 15MPa, rises floating weight for 20 seconds, and pressurization 15MPa, rises floating weight, binder removal for 30 seconds.
Embodiment 3
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 60 revs/min of Banbury mixer rotating speeds, pressurization 18MPa, 30s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 18MPa rises floating weight in the time that temperature reaches 120 ℃, drops into aromatic hydrocarbon oil, pressurization 18MPa, binder removal while causing 145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20 revs/min of rotating speeds, pressurization 17MPa, rises floating weight for 40 seconds, and pressurization 17MPa, rises floating weight, binder removal for 50 seconds.
Embodiment 4
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 50 revs/min of Banbury mixer rotating speeds, pressurization 18MPa, 35s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 18MPa rises floating weight in the time that temperature reaches 115 ℃, drops into aromatic hydrocarbon oil, pressurization 18MPa, binder removal while causing 140 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,30 revs/min of rotating speeds, pressurization 17MPa, rises floating weight for 30 seconds, and pressurization 17MPa, rises floating weight, binder removal for 40 seconds.
Embodiment 5
The preparation method of air retaining wall sizing material for tubeless truck tyre, step is as follows:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 50 revs/min of Banbury mixer rotating speeds, pressurization 17MPa, 40s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 17MPa rises floating weight in the time that temperature reaches 115 ℃, drops into aromatic hydrocarbon oil, pressurization 17MPa, binder removal while causing 145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20 revs/min of rotating speeds, pressurization 17MPa, rises floating weight for 35 seconds, and pressurization 17MPa, rises floating weight, binder removal for 40 seconds.
The product physical and mechanical properties of embodiment 1-5 is as table 2.
Raw material and the parts by weight thereof of table 1 embodiment 1-5
Synergist S-421 95 Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
Brominated butyl rubber 70 70 80 70 75
Natural rubber 20 20 20 20 20
Modification chlorosulfonated polyethylene 10 10 0 10 5
Butyl reclaimed rubber 15 0 20 10 20
Carbon black 52 40 60 55 50
YB-5 radial-ply tyre PP Pipe Compound 15 10 30 20 25
Strong prestige powder 20 30 10 15 10
Aromatic hydrocarbon oil 10 5 10 10 8
Rubber leveler 6 4 8 8 6
Stearic acid 2 1 2 2 1.5
Octyl group phenolic tackifying resins 3 2 4 2 3
Magnesium oxide 1 0 1 1 0.5
Sulphur 0.95 0.5 1.2 0.5 1.0
Zinc oxide-80 3.7 4 3 4 3.5
Altax 1.5 2 1 2 1.5
Table 2 embodiment 1-5 and conventional products physical and mechanical properties
Figure BDA0000485661840000041
Figure BDA0000485661840000051

Claims (5)

1. a tubeless truck tyre air retaining wall sizing material, is characterized in that, in parts by weight, and mixing the preparing of raw material by following component:
Brominated butyl rubber: 70~80 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 0~20 part, carbon black: 40~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~30 parts, strong prestige powder: 10~30 parts, aromatic hydrocarbon oil: 5.0~10 parts, rubber leveler: 4.0~8.0 parts, stearic acid: 1.0~2.0 parts, tackifying resin: 2~4 parts, magnesium oxide: 0~1.0 part, zinc oxide-80:3.0~4.0 part, sulphur: 0.5~1.2 part, altax: 1.0~2.0 parts.
2. tubeless truck tyre air retaining wall sizing material according to claim 1, is characterized in that, in parts by weight, and mixing the preparing of raw material by following component:
Brominated butyl rubber: 70~75 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 5~10 parts, butyl reclaimed rubber: 10~20 parts, carbon black: 50~60 parts, YB-5 radial-ply tyre PP Pipe Compound: 10~20 parts, strong prestige powder: 15~25 parts, aromatic hydrocarbon oil: 8~10 parts, rubber leveler: 6.0~8.0 parts, stearic acid: 1.5~2.0 parts, tackifying resin: 2~3 parts, magnesium oxide: 0.5~1.0 part, zinc oxide-80:3.5~4.0 part, sulphur: 0.5~1.0 part, altax: 1.5~2.0 parts.
3. tubeless truck tyre air retaining wall sizing material according to claim 1, is characterized in that, in parts by weight, and mixing the preparing of raw material by following component:
Brominated butyl rubber: 70 parts, natural rubber: 20 parts, modification chlorosulfonated polyethylene: 0~10 part, butyl reclaimed rubber: 15 parts, carbon black: 52 parts, YB-5 radial-ply tyre PP Pipe Compound: 15 parts, strong prestige powder: 20 parts, aromatic hydrocarbon oil: 10 parts, rubber leveler: 6 parts, stearic acid: 2.0 parts, tackifying resin: 3 parts, magnesium oxide: 1.0 parts, zinc oxide-80:3.7 part, sulphur: 0.95 part, altax: 1.5 parts.
4. according to the tubeless truck tyre air retaining wall sizing material described in claim 1,2 or 3, it is characterized in that the preferred octyl group phenolic tackifying resins of tackifying resin.
5. a preparation method for air retaining wall sizing material for tubeless truck tyre claimed in claim 1, is characterized in that, comprises the following steps:
A) one section mixing: in Banbury mixer, add brominated butyl rubber, natural rubber, modification chlorosulfonated polyethylene and butyl reclaimed rubber, 40~60 revs/min of Banbury mixer rotating speeds, pressurization 15~18MPa, 30~50s rises floating weight, now, each component high polymer material has all been viscous state, then, drop into carbon black, YB-5 radial-ply tyre PP Pipe Compound, strong prestige powder, rubber leveler, magnesium oxide, stearic acid, tackifying resin, pressurization 15~18MPa rises floating weight in the time that temperature reaches 110~120 ℃, drops into aromatic hydrocarbon oil, pressurization 15~18MPa, binder removal while causing 135~145 ℃;
B) add sulphur technique: in Banbury mixer, drop into one section of rubber unvulcanizate, add sulphur, altax, zinc oxide-80,20~40 revs/min of rotating speeds, pressurization 15~17MPa, rises floating weight for 20~40 seconds, and pressurization 15~17MPa, rises floating weight, binder removal for 30~50 seconds.
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CN104292511B (en) * 2014-08-26 2016-08-24 赛轮金宇集团股份有限公司 Tire sidewall and the methods for making and using same of the ageing-resistant protective rubber of bead
CN105949633A (en) * 2016-05-25 2016-09-21 德州玲珑轮胎有限公司 Tire inner liner rubber and preparation method thereof
CN105968437A (en) * 2016-06-27 2016-09-28 宁海建新减震系统有限公司 High-aging-resistance rubber material and preparation method thereof
CN106280043A (en) * 2016-08-24 2017-01-04 山东新大陆橡胶科技股份有限公司 Tire air-tight layer rubber composition and preparation method thereof
CN106543575A (en) * 2016-11-25 2017-03-29 青岛双星轮胎工业有限公司 Heavy load radial tire inner liner rubber composition
CN108084576A (en) * 2017-10-24 2018-05-29 固比斯特科技(宁波)有限公司 A kind of inner tube of a tyre rubber composition and the pricking-proof explosion-proof tire with the inner tube of a tyre
CN108102159A (en) * 2017-12-27 2018-06-01 四川远星橡胶有限责任公司 Tubeless tyre inner face glue containing halobutyl reclaimed rubber
CN108727656A (en) * 2018-05-24 2018-11-02 中策橡胶集团有限公司 A kind of truck tyre inner liner rubber composition and preparation method thereof
CN108864583A (en) * 2018-08-08 2018-11-23 江苏通用科技股份有限公司 Full-steel radial ply air/tight layer rubber and preparation method thereof
CN109517284A (en) * 2018-10-23 2019-03-26 山东日科化学股份有限公司 A kind of tire air-tight layer rubber material, as application of tyre airtight layer glue and preparation method thereof
CN109776975A (en) * 2017-11-10 2019-05-21 江苏润昌橡胶科技有限公司 A kind of tubeless high-capacity tyre inner liner sizing material and preparation method thereof
CN110423414A (en) * 2019-08-01 2019-11-08 江苏通用科技股份有限公司 A kind of inner liner film and preparation method thereof
CN111040322A (en) * 2019-12-30 2020-04-21 四川轮胎橡胶(集团)股份有限公司 Airtight layer adhesive and preparation method thereof
CN111732792A (en) * 2020-07-14 2020-10-02 四川远星橡胶有限责任公司 Sizing material for airtight layer of explosion-proof tire and preparation method thereof
CN111875892A (en) * 2020-06-30 2020-11-03 赛轮(沈阳)轮胎有限公司 Method for improving production stability of airtight layer rubber material
CN111961290A (en) * 2020-07-31 2020-11-20 赛轮集团股份有限公司 Low-zinc tire inner liner rubber and preparation method thereof
CN114031862A (en) * 2021-12-17 2022-02-11 青岛沃瑞轮胎有限公司 Novel low-carbon energy-saving environment-friendly tire air-tight layer for automobile and preparation method thereof
CN114230934A (en) * 2021-12-29 2022-03-25 中国化工集团曙光橡胶工业研究设计院有限公司 Aircraft tire inner liner rubber and preparation method thereof

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CN104292511B (en) * 2014-08-26 2016-08-24 赛轮金宇集团股份有限公司 Tire sidewall and the methods for making and using same of the ageing-resistant protective rubber of bead
CN105949633A (en) * 2016-05-25 2016-09-21 德州玲珑轮胎有限公司 Tire inner liner rubber and preparation method thereof
CN105968437A (en) * 2016-06-27 2016-09-28 宁海建新减震系统有限公司 High-aging-resistance rubber material and preparation method thereof
CN105968437B (en) * 2016-06-27 2018-07-24 宁海建新减震系统有限公司 The high rubber material and preparation method thereof of ageing-resistant performance
CN106280043A (en) * 2016-08-24 2017-01-04 山东新大陆橡胶科技股份有限公司 Tire air-tight layer rubber composition and preparation method thereof
CN106543575B (en) * 2016-11-25 2019-01-22 青岛双星轮胎工业有限公司 Heavy load radial tire inner liner rubber composition
CN106543575A (en) * 2016-11-25 2017-03-29 青岛双星轮胎工业有限公司 Heavy load radial tire inner liner rubber composition
CN108084576A (en) * 2017-10-24 2018-05-29 固比斯特科技(宁波)有限公司 A kind of inner tube of a tyre rubber composition and the pricking-proof explosion-proof tire with the inner tube of a tyre
CN109776975A (en) * 2017-11-10 2019-05-21 江苏润昌橡胶科技有限公司 A kind of tubeless high-capacity tyre inner liner sizing material and preparation method thereof
CN108102159A (en) * 2017-12-27 2018-06-01 四川远星橡胶有限责任公司 Tubeless tyre inner face glue containing halobutyl reclaimed rubber
CN108727656B (en) * 2018-05-24 2020-10-02 中策橡胶集团有限公司 Truck tire inner liner rubber composition and preparation method thereof
CN108727656A (en) * 2018-05-24 2018-11-02 中策橡胶集团有限公司 A kind of truck tyre inner liner rubber composition and preparation method thereof
CN108864583A (en) * 2018-08-08 2018-11-23 江苏通用科技股份有限公司 Full-steel radial ply air/tight layer rubber and preparation method thereof
CN109517284A (en) * 2018-10-23 2019-03-26 山东日科化学股份有限公司 A kind of tire air-tight layer rubber material, as application of tyre airtight layer glue and preparation method thereof
CN110423414A (en) * 2019-08-01 2019-11-08 江苏通用科技股份有限公司 A kind of inner liner film and preparation method thereof
CN111040322A (en) * 2019-12-30 2020-04-21 四川轮胎橡胶(集团)股份有限公司 Airtight layer adhesive and preparation method thereof
CN111875892A (en) * 2020-06-30 2020-11-03 赛轮(沈阳)轮胎有限公司 Method for improving production stability of airtight layer rubber material
CN111732792A (en) * 2020-07-14 2020-10-02 四川远星橡胶有限责任公司 Sizing material for airtight layer of explosion-proof tire and preparation method thereof
CN111732792B (en) * 2020-07-14 2023-01-31 四川远星橡胶有限责任公司 Sizing material for airtight layer of run-flat tire and preparation method thereof
CN111961290A (en) * 2020-07-31 2020-11-20 赛轮集团股份有限公司 Low-zinc tire inner liner rubber and preparation method thereof
CN111961290B (en) * 2020-07-31 2023-01-13 赛轮集团股份有限公司 Low-zinc tire inner liner rubber and preparation method thereof
CN114031862A (en) * 2021-12-17 2022-02-11 青岛沃瑞轮胎有限公司 Novel low-carbon energy-saving environment-friendly tire air-tight layer for automobile and preparation method thereof
CN114031862B (en) * 2021-12-17 2023-10-27 青岛沃瑞轮胎有限公司 Novel low-carbon energy-saving environment-friendly tire inner liner for automobile and preparation method thereof
CN114230934A (en) * 2021-12-29 2022-03-25 中国化工集团曙光橡胶工业研究设计院有限公司 Aircraft tire inner liner rubber and preparation method thereof

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Application publication date: 20140618