CN108097521A - Steel wire and its production equipment, preparation method - Google Patents
Steel wire and its production equipment, preparation method Download PDFInfo
- Publication number
- CN108097521A CN108097521A CN201810018418.3A CN201810018418A CN108097521A CN 108097521 A CN108097521 A CN 108097521A CN 201810018418 A CN201810018418 A CN 201810018418A CN 108097521 A CN108097521 A CN 108097521A
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- Prior art keywords
- steel wire
- ultraviolet
- coating
- inner core
- tank
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C1/00—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
- B05C1/04—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
- B05C1/06—Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length by rubbing contact, e.g. by brushes, by pads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
- B05C11/1002—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/28—Processes for applying liquids or other fluent materials performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
- B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
- B05D3/065—After-treatment
- B05D3/067—Curing or cross-linking the coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/20—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to wires
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D171/00—Coating compositions based on polyethers obtained by reactions forming an ether link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/443—Protective covering
- G02B6/4432—Protective covering with fibre reinforcements
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4479—Manufacturing methods of optical cables
Abstract
The present invention relates to optical cable production technical fields, and more particularly, to a kind of steel wire and its production equipment, preparation method, which includes steel wire inner core and coat and cure in the rust-proof coating on steel wire inner core, and rust-proof coating is ultraviolet-curing paint.Acid can effectively be resisted, the corrosivity that alkali and moisture are brought is destroyed, the rust-proof coating is not chemically reacted with acid, alkalescence substance and water, influence processing, the hydrogen and oxide of final product quality will not be generated, and can effectively stop that erosion is internally spread.In addition, cure has higher boundary strength between the rust-proof coating of steel wire core surface and steel wire inner core, certain mechanical injuries can be kept out.
Description
Technical field
The present invention relates to fiber optic cable manufacture technical field, more particularly, to steel wire and its production equipment, preparation method.
Background technology
In optical cable production, metal reinforcement popular at present is phosphating steel wire.Steel wire is in wet air or water
In easily occur galvanic interaction, steel wire surface will soon corrosion, and phosphating coat is just played steel wire and outside air phase
Isolation is the effect of antirust.
General phosphatization layer thickness is more than or equal to 2.5g/m2To be optimal.To obtain the phosphating coat of compact and firm, key is
Processing and rational phosphating time to steel wire surface.Continuously acting production lines because being influenced by drawing speed, pickling, phosphatization when
Between it is very short.Pickling time is short, and surface impurity removal is not clean, is bound to cause phosphating coat and is adsorbed loosely in steel wire surface, so that
It comes off below in drawing process, along with the consumption with phosphating solution, phosphating time cannot change, and be bound to cause phosphating coat
It is excessively thin, the requirement of phosphating steel wire is not achieved.
The oxidation resistance of phosphating steel wire is limited, and experiment confirms that its acid and alkali resistance corrosive nature is very poor, therefore in its application aspect
It has some limitations.Phosphating steel wire is applied among the production of optical cable in most cases, and phosphating steel wire is by water or sour oxygen
During change, it is possible to create hydrogen produces serious influence to optical cable quality.
The information for being disclosed in the background section is merely intended to deepen understanding of the general background technology to the present invention, and
It is not construed as recognizing or implies the information structure prior art known to those skilled in the art in any form.
The content of the invention
It is an object of the invention to provide a kind of steel wire and its production equipment, preparation method, solves the phosphorus of the prior art
The acid and alkali resistance corrosive nature of change steel wire is poor, and oxidation resistance is limited, and optical cable quality may be generated in being produced applied to optical cable
The technical issues of seriously affecting.
In a first aspect, the present invention provides a kind of steel wire, including:Steel wire inner core and coating simultaneously cure on the steel wire inner core
Rust-proof coating, the rust-proof coating be using ultraviolet-curing paint.
As a kind of further technical solution, the thickness of the rust-proof coating is 25-35 μm.
As a kind of further technical solution, the ultraviolet-curing paint by solvent, poly(aryl ether ketone), photoinitiator,
Levelling agent, coupling agent and antifoaming agent mix, in terms of parts by weight, described solvent 75-80 parts, and the poly(aryl ether ketone) 8-12
Part, described photoinitiator 5-7 parts, described levelling agent 0.8-1.2 parts, described coupling agent 1.6-2.4 parts, the antifoaming agent 0.8-
1.2 part.
Second aspect, the present invention provide a kind of production equipment, for producing any institute provided such as above-mentioned technical proposal
The steel wire stated, including storing component, compression assemblies and the applicator assembly being sequentially communicated;
The storing component is used to store the ultraviolet-curing paint;The compression assemblies will be in the storing component
The ultraviolet-curing paint is delivered to the applicator assembly, with the steel wire inner core coating to be placed in the applicator assembly
The ultraviolet-curing paint.
As a kind of further technical solution, the applicator assembly is included with the mold base through inner cavity, described
The first end of mold base inner cavity is disposed with into mouth mold and the first mold gland, the mold base inner cavity second end successively
It is provided with outlet mold and the second mold gland;It is connected in the middle part of the inner cavity of the mold base with the compression assemblies;
The steel wire inner core is entered by the first end of the mold base inner cavity and is worn by the second end of the mold base inner cavity
Go out.
As a kind of further technical solution, the compression assemblies include squeezing tank, stripper plate and compression gas tank;It is described
Stripper plate is movably disposed in the extruding tank, and the extruding tank is divided into upper tank body and lower tank;The lower tank leads to
It crosses extrusion pipe with the compression assemblies to be connected, be connected by feeding pipe with the storing component;The upper tank body leads to
Compression gas tank described in gas pipeline is crossed to be connected.
As a kind of further technical solution, control device is further included, the control device includes the first level sensing
Device, the second liquid level sensor, the first control valve, the first control valve and the second control valve;
First liquid level sensor and second liquid level sensor are arranged at the inner wall of the extruding tank, and described the
One liquid level sensor is higher than second liquid level sensor;
First control valve is arranged on the extrusion pipe, and first control valve is arranged at the feeding pipe
On, second control valve is arranged on the gas pipeline;
First liquid level sensor is connected respectively with first control valve and second control valve;Described second
Liquid level sensor is connected respectively with first control valve and second control valve.
The third aspect, the present invention provide a kind of preparation method, are used to prepare any steel provided such as above-mentioned technical proposal
Silk, comprises the following steps:
Batch mixing:Batch mixing prepares ultraviolet cured paint composition;
Coating:By the ultraviolet cured paint composition coated on the steel wire inner core;
Cure:Ultraviolet light makes the ultraviolet-curing paint cure to obtain the steel wire.
As a kind of further technical solution, further include the unwrapping wire step before being arranged at coating step and be arranged at
Take-up step after curing schedule, the unwrapping wire step will implement the painting after coiled steel wire inner core expansion, tensioning
Cover step;The take-up step is wound after the steel wire for coating and curing is tensioned.
As a kind of further technical solution, the batch mixing step includes mixing, preheating and defoaming, the preheating temperature
For 40 DEG C.
Compared with prior art, a kind of steel wire provided by the invention and its production equipment, preparation method can reach following
Advantageous effect:
The present invention provides a kind of steel wire, wherein, the steel wire core surface of the steel wire is provided with one layer of rust-proof coating, Neng Gouyou
Acid is resisted on effect ground, the corrosivity brought of alkali and moisture is destroyed, the rust-proof coating not with acid, alkaline substance and water
Reaction is learned, influence processing, the hydrogen and oxide of final product quality will not be generated, and can effectively stop erosion internally
Sprawling.In addition, cure has higher boundary strength between the rust-proof coating of steel wire core surface and steel wire inner core, can support
Keep off certain mechanical injuries.
A kind of production equipment provided by the invention, for producing above-mentioned steel wire, rust-proof coating therein is set by means of production
Standby to be coated on steel wire core surface, speed of production is high.
A kind of preparation method provided by the invention is used to prepare above-mentioned steel wire, and not generated in production process any has danger
The substance that harmful gas, powder, residue or liquid etc. pollute the environment, and expended in process of production except ultraviolet light cures
Less electric energy is outer (DC frequency-changing control UV lamp may be employed, direct current can more effectively control the brightness of lamp), other institutes
Air pressure, the energy consumption of mechanical tensioning for having process use are very low.On the whole, this production method is produced in each process of above-mentioned steel wire
Raw energy consumption belongs to energy saving and environment friendly infant industry production far below the energy consumption that production phosphating steel wire generates.
Description of the drawings
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution of the prior art
Embodiment or attached drawing needed to be used in the description of the prior art are briefly described, it should be apparent that, in describing below
Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor
It puts, can also be obtained according to these attached drawings other attached drawings.
Fig. 1 is a kind of cross section view for steel wire that the embodiment of the present invention one provides;
Fig. 2 is a kind of production equipment structure diagram provided by Embodiment 2 of the present invention;
Fig. 3 is the enlarged drawing of A in Fig. 2;
Fig. 4 is the enlarged drawing of B in Fig. 2.
Icon:11- steel wire inner cores;12- rust-proof coatings;21- payoff reels;22- unwrapping wire tensioning apparatus;31- take-ups
Volume;32- take-up tensioning apparatus;41- mold bases;421- is into mouth mold;422- the first mold glands;431- outlet molds;
432- the second mold glands;51- squeezes tank;52- stripper plates;53- compression gas tanks;The first liquid level sensors of 61-;62-
Second liquid level sensor;71- extrusion pipes;72- feeding pipes;73- gas pipelines;The first control valves of 81-;82- second
Control valve;9- mixing tank for coating colors;The ultraviolet light generating apparatus of 10-.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with attached drawing, it is clear that described implementation
Example is part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill
Personnel's all other embodiments obtained without making creative work, belong to the scope of protection of the invention.
In the description of the present invention, it is necessary to explanation, term " " center ", " on ", " under ", "left", "right", " vertical ",
The orientation or position relationship of the instructions such as " level ", " interior ", " outer " be based on orientation shown in the drawings or position relationship, merely to
Convenient for the description present invention and simplify description rather than instruction or imply signified device or element must have specific orientation,
With specific azimuth configuration and operation, therefore it is not considered as limiting the invention.In addition, term " first ", " second ",
" the 3rd " is only used for description purpose, and it is not intended that instruction or hint relative importance.
In the description of the present invention, it is necessary to illustrate, unless otherwise clearly defined and limited, term " installation ", " phase
Even ", " connection " should be interpreted broadly, for example, it may be being fixedly connected or being detachably connected or be integrally connected;It can
To be mechanical connection or be electrically connected;It can be directly connected, can also be indirectly connected by intermediary, Ke Yishi
Connection inside two elements.For the ordinary skill in the art, with concrete condition above-mentioned term can be understood at this
Concrete meaning in invention.
The specific embodiment of the present invention is described in detail below in conjunction with attached drawing.It should be appreciated that this place is retouched
The specific embodiment stated is merely to illustrate and explain the present invention, and is not intended to limit the invention.
Embodiment one
With reference to Fig. 1, the embodiment of the present invention provides a kind of steel wire, which includes steel wire inner core 11 and coat and cure in steel
Rust-proof coating 12 on silk inner core 11, rust-proof coating 12 are ultraviolet-curing paint.
Wherein, the thickness of rust-proof coating 12 is 25-35 μm.
It is detected according to experiment, 12 hardness of rust-proof coating of steel wire provided in this embodiment can reach 3-5H;Steel wire resists
Ageing properties, under the conditions of 280-320 DEG C, rust-proof coating 12 keeps not cracking, not fall off after 30h.
The corrosivity that rust-proof coating 12 in steel wire provided in this embodiment can effectively resist acid, alkali and moisture are brought
It destroys.The rust-proof coating 12 is not chemically reacted with acid, alkalescence substance and water, thus cannot generate influence process, into
The hydrogen and oxide of quality, and can effectively stop that erosion is internally spread.Rust-proof coating 12 after curing with
Between steel wire inner core 11 there is higher boundary strength, certain mechanical injuries can be kept out.
Specifically, ultraviolet-curing paint is a kind of composition, by solvent, poly(aryl ether ketone), photoinitiator, levelling agent, idol
Connection agent and antifoaming agent mix, in terms of parts by weight, 75-80 parts of solvent, and 8-12 parts of poly(aryl ether ketone), 5-7 parts of photoinitiator, stream
Flat agent 0.8-1.2 parts, 1.6-2.4 parts of coupling agent, 0.8-1.2 parts of antifoaming agent.
Wherein, solvent includes the first solvent and the second solvent.First solvent includes n,N-dimethylacetamide, N, N- bis-
Methylformamide, N, at least one of N- dimethyl sulfoxide (DMSO)s or dichloromethane;Second solvent includes tetrahydrofuran, 1,2- bis-
At least one of chloromethanes or 1,2- dichloroethanes.
Photoinitiator includes at least one in benzophenone, styrax ethers, acylphosphine oxide class or alkylbenzene ketone
Kind;Levelling agent includes at least one of acrylic acid, organosilicon or fluorocarbons;Coupling agent includes titanate coupling agent, silicon
One kind in alkane coupling agent, chromium network coupling agent or zirconium class coupling agent;Antifoaming agent includes polyesters antifoaming agent or silicon class antifoaming agent.
It should be noted that the solidification temperature of ultraviolet-curing paint is determined according to the proportioning of solvent, solidification temperature scope
For 200-350 DEG C.Also, the speed of production of steel wire is also determined by solvent.When the first solvent is preferably N, N- dimethyl formyls
Amine, at this point, the solidification temperature of ultraviolet-curing paint is 145-175 DEG C.Ultraviolet-curing paint after curing condenses in steel wire
The surface of inner core 11 forms above-mentioned rust-proof coating 12.
Embodiment two
With reference to Fig. 2-4, the embodiment of the present invention provides a kind of production equipment, for producing the steel provided such as embodiment one
Silk, the production equipment include the storing component, compression assemblies and the applicator assembly that are sequentially communicated;Storing component is used to store above-mentioned purple
Outer photocureable coating;Ultraviolet-curing paint in storing component is delivered to applicator assembly by compression assemblies, to be coated to be placed in
11 coating ultraviolet light curing coating of steel wire inner core in component.
The production equipment is used to coat above-mentioned ultraviolet-curing paint for 11 surface of steel wire inner core, and applicator assembly, which has, to be accommodated
Space in steel wire, in production, steel wire inner core 11 is placed in applicator assembly, and compression assemblies are by the ultraviolet optical coating in storing component
Conveying is filled in applicator assembly, and 11 surface of steel wire inner core will adhere to one layer of ultraviolet-curing paint, be obtained by cured later
Above-mentioned steel wire, which has good acid and alkali-resistance, the corrosion resistance of humidity, and can keep out certain mechanical injuries.
Wherein, applicator assembly is included with the mold base 41 through inner cavity, and the first end in 41 inner cavity of mold base is set successively
It is equipped with into 421 and first mold gland 422 of mouth mold, the second end in 41 inner cavity of mold base is disposed with outlet mold 431 and
Two molds gland 432;It is connected in the middle part of the inner cavity of mold base 41 with compression assemblies;Steel wire inner core 11 by mold base 41 first end
It is pierced by into and by the second end of mold base 41.
Applicator assembly is used to carry out coating operation for 11 surface of steel wire inner core, and entire applicator assembly is a coating die,
Mainly include mold base 41, which has perforative inner cavity, connected in the middle part of inner cavity with storing component, to facilitate storing group
Ultraviolet-curing paint in part enters interior intracavitary.
Perforative inner cavity has opposite both ends, is pierced into for steel wire inner core 11 by the first end of inner cavity, during by inner cavity
11 surface of steel wire inner core will adhere to the ultraviolet-curing paint for being filled in inner cavity, be then pierced by by the second end of inner cavity, through solid
The steel wire that embodiment one is provided is obtained after change.
First end in inner cavity, from-inner-to-outer are disposed with into 421 and first mold gland 422 of mouth mold, the first mold
Gland 422 will be installed on mold base 41 into mouth mold 421, have the passage passed through for steel wire inner core 11, the passage into mouth mold 421
For hourglass shape, both ends diameter is big, and mid diameter is small, convenient for steel wire inner core 11 into the inner cavity of mold base 41, and it is logical into mouth mold 421
The mid diameter in road matches with 11 diameter of steel wire inner core.
Second end in inner cavity, from-inner-to-outer are disposed with 431 and second mold gland 432 of outlet mold, the second mold
Outlet mold 431 is installed on mold base 41 by gland 432, and outlet mold 431 also has the passage passed through for steel wire inner core 11, this is logical
Road is hourglass shape, and both ends diameter is big, and mid diameter is small, is pierced by the inner cavity of mold base 41 convenient for steel wire, and 431 passage of outlet mold
Mid diameter determines the thickness of rust-proof coating 12.
And the compression assemblies at least one embodiment of the present invention include squeezing tank 51, stripper plate 52 and compression gas tank 53;
Stripper plate 52, which is movably disposed in, to be squeezed in tank 51, will be squeezed tank 51 and is divided for upper tank body and lower tank;Lower tank passes through extruding
Pipeline 71 is connected with compression assemblies, is connected by feeding pipe 72 with storing component;Upper tank body is pressed by gas pipeline 73
Contracting gas tank 53 is connected.
Stripper plate 52, which is movably disposed in, to be squeezed in tank 51, and the ultraviolet light in the gas and lower tank in upper tank body cures
Coating separates.Upper tank body is connected with compression gas tank 53, and equipped with compressed gas in compression gas tank 53, stripper plate 52 can be in compressed gas
Ultraviolet-curing paint in lower tank is applied pressure and enters coated group by extrusion pipe 71 by activity downwards under the promotion of body
In the mold base 41 of part.
It should be noted that since stripper plate 52 can be moved up and down squeezing in tank 51, then stripper plate 52 is separated to form
Upper tank body and lower tank volume be capable of against stripper plate 52 movement it is changed.In addition, compression gas tank 53 is built-in
There is the nitrogen of high pressure.
Specifically, in order to accurately control coating procedure, at least one embodiment of the present invention further includes control device, the control
Device includes the first liquid level sensor 61, the second liquid level sensor 62, the first control valve 81 and the second control valve 82;First liquid level
61 and second liquid level sensor 62 of sensor is arranged at the inner wall for squeezing tank 51, and the first liquid level sensor 61 is higher than the second liquid level
Sensor 62;First control valve 81 is arranged on feeding pipe 72, and the second control valve 82 is arranged on gas pipeline 73;First liquid
Level sensor 61 is connected respectively with the first control valve 81 and the second control valve 82;Second liquid level sensor 62 is controlled respectively with first
Valve 81 processed is connected with the second control valve 82.
In work, when the first level sensing of fluid level contacts of the ultraviolet-curing paint in lower tank, the first level sensing
Device 61 detects liquid level information, sends out code to the first control valve 81, no longer conveys ultraviolet light into extruding tank 51 and cure
Coating, while enabled instruction is sent to the second control valve 82, the compressed gas in compression gas tank 53 enters the upper tank for squeezing tank 51
Body, which is acted on stripper plate 52, promotes stripper plate 52 to move downward the ultraviolet-curing paint squeezed in lower tank, makes UV light
Change coating, which is entered by extrusion pipe 71 in the mold base 41 of applicator assembly, carries out coating operation.
The first level sensing is contacted when the liquid level of the ultraviolet-curing paint in lower tank drops to, it is ultraviolet in lower tank
The capacity of photocureable coating is less, because of pressure in tank body is too small ultraviolet-curing paint discharging may be caused unfavorable, influenced
Coating.At this point, the second liquid level sensor 62 detects liquid level information, out code is sent to the second control valve 82, compression gas tank
The upper tank body that compressed gas in 53 does not enter back into extruding tank 51 promotes stripper plate 52 to move downward, while the second liquid level sensor
62 send enabled instruction to the first control valve 81, start to feed into lower tank.
Above procedure Xun Huan carries out, and realizes automation control, the coating operation to 11 surface of steel wire inner core.Need what is illustrated
It is, in the charging stage, ultraviolet-curing paint no longer to be squeezed in 52 short time of stripper plate and is fed to applicator assembly, applicator assembly
41 inner cavity of mold base also has a certain amount of ultraviolet-curing paint, does not interfere with the coating operation of steel wire inner core 11.
Wherein, storing component includes mixing tank for coating colors 9 and multiple storage tanks, and each storage tank cures for storing a kind of ultraviolet light
The composition of coating, each storage tank are connected with mixing tank for coating colors 9, and the composition of each ultraviolet-curing paint enters mixing tank for coating colors
It is mixed, pre- thermosetting ultraviolet-curing paint.
In addition, production equipment provided in this embodiment further includes payoff reel 21, take-up volume 31 and ultraviolet light generating apparatus 10.
Steel wire inner core 11 to be coated is wound payoff reel 21,11 unwrapping wire of steel wire inner core of payoff reel 21 by coating,
Become steel wire winding after curing and form take-up volume 31.Unwrapping wire tensioning apparatus 22 is provided between 21 applicator assembly of payoff reel,
Take-up tensioning apparatus 32 is provided between take-up volume 31 and applicator assembly.Ultraviolet light generating apparatus 10 is arranged at applicator assembly with receiving
Between thread tensioner 32, the steel wire for being completed to coating carries out illumination curing, and ultraviolet-curing paint condensation cure is made to exist
Rust-proof coating 12 is formed on steel wire inner core 11.
Embodiment three
An embodiment of the present invention provides a kind of method for producing steel wire, for producing the steel wire of the offer of above-described embodiment one,
It mainly includes the following steps that:
Batch mixing:Batch mixing prepares ultraviolet cured paint composition;
Coating:By ultraviolet cured paint composition coated on steel wire inner core 11;
Cure:Ultraviolet light makes ultraviolet-curing paint cure to obtain above-mentioned steel wire.
At least one embodiment of the present invention further includes the unwrapping wire step before being arranged at coating step and is arranged at curing
Take-up step after step, unwrapping wire step implement coating step after coiled steel wire inner core 11 is unfolded, is tensioned;Take-up step
It is wound after the steel wire for coating and curing is tensioned.
Wherein, the production equipment degree steel wire inner core 11 that coating procedure is provided by embodiment two is implemented, and steel wire inner core 11 passes through
The mold base 41 of applicator assembly is implemented after realizing coating operation using the ultraviolet radiation-curable formation of ultraviolet light generating apparatus
The steel wire that example one provides.
Steel wire inner core 11 to be coated is wound payoff reel 21,11 unwrapping wire of steel wire inner core of payoff reel 21 by coating,
Become steel wire winding after curing and form take-up volume 31.Unwrapping wire tensioning apparatus 22 is provided between 21 applicator assembly of payoff reel,
Take-up tensioning apparatus 32 is provided between take-up volume 31 and ultraviolet light generating apparatus 10.
Batch mixing step at least one embodiment of the present invention includes mixing, preheating and defoaming, and wherein preheating temperature is 40
℃。
It should be noted that in batch mixing step, there is a mixer in mixing tank for coating colors 9, ceaselessly move, be on the one hand batch mixing,
On the other hand the bubble in material is blended and discharged.Meanwhile batch mixing step plays an important role of defoaming.
The production technology of steel wire is mainly coated and cured in the embodiment of the present invention, and rust-proof coating 12 is by applicator assembly
Made of coating, solidification temperature can adjust according to speed of production, therefore the factor that speed of production is restricted is smaller, substantially
On can reach solidification temperature can be promoted how much, speed of production can be promoted how much.And existing steel wire phosphorization process needs
Steel wire keeps the regular hour to ensure the thickness of phosphate coating in phosphating pond.Therefore, the production of steel wire provided in this embodiment
Speed is higher than phosphating steel wire
As can be seen that the method for production steel wire provided in an embodiment of the present invention, does not generate in production process any harmful
The substance that pollutes the environment such as gas, powder, residue or liquid, and in process of production except ultraviolet light cure expend compared with
Few electric energy is outer (DC frequency-changing control UV lamp may be employed, direct current can more effectively control the brightness of lamp), other are all
The air pressure of process use, the energy consumption of mechanical tensioning are very low.On the whole, the method for this production steel wire is in each process of above-mentioned steel wire
The energy consumption of middle generation belongs to energy saving and environment friendly infant industry production far below the energy consumption that production phosphating steel wire generates.
It should be noted that above-mentioned whole production process should be waterproof and dampproof, applied because the invasion of moisture will cure ultraviolet light
The substances such as the photoinitiator in material generate hydrolysis, so as to reduce solidification effect of the rust-proof coating 12 on steel wire inner core 11.Also,
Line speed can be promoted to 200-350m/min, but solidification temperature should be promoted with the promotion of speed of production.
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent
Pipe is described in detail the present invention with reference to foregoing embodiments, it will be understood by those of ordinary skill in the art that:Its according to
Can so modify to the technical solution recorded in foregoing embodiments either to which part or all technical characteristic into
Row equivalent substitution;And these modifications or replacement, the essence of appropriate technical solution is not made to depart from various embodiments of the present invention technology
The scope of scheme.
Claims (10)
1. a kind of steel wire, which is characterized in that including:Steel wire inner core and coating simultaneously cure in the antirust painting on the steel wire inner core
Layer, the rust-proof coating are using ultraviolet-curing paint.
2. steel wire according to claim 1, which is characterized in that the thickness of the rust-proof coating is 25-35 μm.
3. steel wire according to claim 1, which is characterized in that the ultraviolet-curing paint is by solvent, poly(aryl ether ketone), light
Initiator, levelling agent, coupling agent and antifoaming agent mix, in terms of parts by weight, described solvent 75-80 parts, and the polyarylether
8-12 parts of ketone, described photoinitiator 5-7 parts, described levelling agent 0.8-1.2 parts, described coupling agent 1.6-2.4 parts, the antifoaming agent
0.8-1.2 parts.
4. a kind of production equipment, for producing the steel wire as any one of claim 1-3, which is characterized in that including according to
Storing component, compression assemblies and the applicator assembly of secondary connection;
The storing component is used to store the ultraviolet-curing paint;The compression assemblies will be described in the storing component
Ultraviolet-curing paint is delivered to the applicator assembly, with for be placed in the applicator assembly the steel wire inner core coating described in
Ultraviolet-curing paint.
5. production equipment according to claim 4, which is characterized in that the applicator assembly is included with the mould through inner cavity
Has seat, the first end in the mold base inner cavity is disposed with into mouth mold and the first mold gland, in the mold base inner cavity
Second end be disposed with outlet mold and the second mold gland;It is connected in the middle part of the inner cavity of the mold base with the compression assemblies
It is logical;
The steel wire inner core is entered by the first end of the mold base inner cavity and is pierced by by the second end of the mold base inner cavity.
6. production equipment according to claim 4, which is characterized in that the compression assemblies include squeeze tank, stripper plate and
Compression gas tank;The stripper plate is movably disposed in the extruding tank, and the extruding tank is divided into upper tank body and lower tank;
The lower tank is connected by extrusion pipe with the compression assemblies, is connected by feeding pipe with the storing component;
The upper tank body is connected by compression gas tank described in gas pipeline.
7. production equipment according to claim 6, which is characterized in that further include control device, the control device includes
First liquid level sensor, the second liquid level sensor, the first control valve and the second control valve;
First liquid level sensor and second liquid level sensor are arranged at the inner wall of the extruding tank, and first liquid
Level sensor is higher than second liquid level sensor;
First control valve is arranged on the feeding pipe, and second control valve is arranged on the gas pipeline;
First liquid level sensor is connected respectively with first control valve and second control valve;Second liquid level
Sensor is connected respectively with first control valve and second control valve.
8. a kind of preparation method is used to prepare such as the steel wire any one of claim 1-3, which is characterized in that including with
Lower step:
Batch mixing:Batch mixing prepares ultraviolet cured paint composition;
Coating:By the ultraviolet cured paint composition coated on the steel wire inner core;
Cure:Ultraviolet light makes the ultraviolet-curing paint cure to obtain the steel wire.
9. preparation method according to claim 8, which is characterized in that further include the unwrapping wire step before being arranged at coating step
Take-up step that is rapid and being arranged at after curing schedule, the coiled steel wire inner core is unfolded the unwrapping wire step, tensioning
After implement the coating step;The take-up step is wound after the steel wire for coating and curing is tensioned.
10. preparation method according to claim 8, which is characterized in that the batch mixing step includes mixing, preheats and disappear
Bubble, the preheating temperature are 40 DEG C.
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CN110548617A (en) * | 2019-10-09 | 2019-12-10 | 鲁普耐特集团有限公司 | Rope coating equipment and using method thereof |
CN113058818A (en) * | 2021-03-12 | 2021-07-02 | 河南科技大学 | Green nano coating device and method for continuous coating of micron-sized bonding wire |
CN114178148A (en) * | 2021-12-07 | 2022-03-15 | 安徽纯源镀膜科技有限公司 | Tire steel wire extrusion line slot plate and manufacturing process thereof |
CN115318582A (en) * | 2022-09-19 | 2022-11-11 | 安徽铂优新材料有限公司 | Copper line photocuring automatic coating production line equipment |
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