CN108096984A - Knockdown volatile organic matter resource regeneration processing unit and method - Google Patents

Knockdown volatile organic matter resource regeneration processing unit and method Download PDF

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Publication number
CN108096984A
CN108096984A CN201711157595.1A CN201711157595A CN108096984A CN 108096984 A CN108096984 A CN 108096984A CN 201711157595 A CN201711157595 A CN 201711157595A CN 108096984 A CN108096984 A CN 108096984A
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unit
exhaust gas
parallel
absorbing
knockdown
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CN201711157595.1A
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马斌斌
王婧婷
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WUXI ZHONGTIAN SOLID WASTE DISPOSAL Co Ltd
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WUXI ZHONGTIAN SOLID WASTE DISPOSAL Co Ltd
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Priority to CN201711157595.1A priority Critical patent/CN108096984A/en
Publication of CN108096984A publication Critical patent/CN108096984A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40001Methods relating to additional, e.g. intermediate, treatment of process gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/402Further details for adsorption processes and devices using two beds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of knockdown volatile organic matter resource regeneration processing units, including collection system, centralized recovery system, the collection system includes the pretreatment unit being sequentially connected, absorbing unit in parallel, post-processing unit, the first on-line monitoring system, the pretreatment unit is connected with organic exhaust gas import, and the parallel connection absorbing unit is also connected with portable absorption delivery unit;The centralized recovery system includes the air accumulator, heater, desorption unit, condensing unit, separating-purifying device, the solvent recycler that are sequentially connected, further include the dehydrater being sequentially connected, fixed gas clean unit in parallel and the second on-line monitoring system, the dehydrater is connected with condensing unit, the input terminal of the output terminal of the dehydrater and fixed gas clean unit in parallel is connected with air blower, and the output terminal of second on-line monitoring system is connected with air accumulator.

Description

Knockdown volatile organic matter resource regeneration processing unit and method
Technical field
The present invention relates to environmental protection technical fields, are related to the processing method of organic exhaust gas more particularly to a kind of combined type Volatile organic matter resource regeneration processing unit and method.
Background technology
Volatile organic compounds is the most common dirt of the industries such as petrochemical industry, pharmacy, printing, shoemaking, spray painting discharge Contaminate object.As organic synthesis industry and the rapid development of petrochemical industry, the volatile organic compounds into air are more next It is more.The processing method of organic exhaust gas has tens of kinds, and principle mainly has the recovery technology for recycling valuable solvent and decomposition to have Two major class of destruction technology of machine exhaust gas.From the perspective of environmental protection and economy, solvent recovery technology more it is worth further research with It promotes.
The type selecting of adsorbent is the key that solvent recovery technology, and suitable adsorbent need to be selected according to different exhaust gas constituents Carry out solvent recovery.Activated carbon is a kind of agraphitic carbon with irregular microstructure, due to its larger specific surface area and Stronger adsorption capacity, is the adsorbent of usage amount maximum, but activated carbon is affected etc. by aqueous vapor there are flammable, absorption property and lacked Point limits its application.Large pore macromolecular resin also has organic exhaust gas excellent as a kind of very excellent adsorbent Characterization of adsorption.Organic exhaust gas is relatively low in the heat of adsorption of resin surface, and adsorption process heating is smaller, and belongs to be not easy fuel wood in itself Material, therefore its safety coefficient greatly improves, and is one of most potential sorbing material of organic exhaust gas.Hydrophobic molecule sieve can be Higher adsorptive selectivity is still maintained under very high relative humidity, it is very big to organic matter adsorbance to the adsorbance very little of water, And the material is non-combustible, it can be applied widely with high temperature regeneration.
Traditional VOCs treatment pattern:In the setting of organic exhaust gas emission source, cleaning system, this method are directed on the spot The pollution sources that disposal of pollutants load is larger, continuously discharges are highly effective.But also there are many enterprises, particularly middle-size and small-size enterprise at present Industry, productive prospecting are:Production process interval, emission point are scattered;The characteristics of discharge gas is:Air quantity is larger, concentration is less high. In this case, the investment of traditional treatment in situ pattern and operating cost are higher..
The content of the invention
The purpose of the present invention is to reduce the cost of above-mentioned discharge enterprise pollution treatment, overcome traditional VOCs treatment pattern Limitation, provide it is a kind of can dispose center in the organic exhaust gas that Construction of Industrial Park is concentrated, pass through and portable collect, concentrate The processing unit and method of organic exhaust gas resource regeneration are recycled, VOCs treatment Purifying service is provided, reduces each enterprise one Secondary property input and later stage operating cost, reduce each enterprise engineering construction and management cost, while are conducive to centralized supervisory, control Disposal of pollutants total amount, avoids the wasting of resources.
To solve the above-mentioned problems, the present invention uses following scheme:
A kind of knockdown volatile organic matter resource regeneration processing unit, including collection system, centralized recovery system, institute Stating collection system includes the pretreatment unit being sequentially connected, absorbing unit in parallel, post-processing unit, the first on-line monitoring system, The pretreatment unit is connected with organic exhaust gas import, and the parallel connection absorbing unit is also connected with portable absorption delivery unit;
The centralized recovery system includes the air accumulator being sequentially connected, heater, desorption unit, condensing unit, separation carry Pure device, solvent recycler further include the dehydrater being sequentially connected, fixed gas clean unit in parallel and the second on-line monitoring system System, the dehydrater are connected with condensing unit, and the input terminal of the output terminal of the dehydrater and fixed gas clean unit in parallel connects Air blower is connected to, the output terminal of second on-line monitoring system is connected with air accumulator.
In the present invention, there is inert gas in air accumulator, inert gas is there are two effect, when finished when vapor is desorbed, Residual gas in exchange system, cycle purge dry the adsorbent in absorbing unit, second is that making adsorbent cooling cold after dry But.Dehydrater is used to remove the moisture content in fixed gas and purge gas.Through on-line monitoring system qualified discharge after fixed gas purification, Fixed gas clean unit is also that can move integrally, for further removing the micro organic exhaust gas in fixed gas;On-line monitoring System shows that interlocking during saturation is switched to another fixed gas clean unit and continues with fixed gas by fixed gas clean unit In micro organic exhaust gas, the fixed gas clean unit of adsorption saturation is moved to desorption unit and regenerated.The indifferent gas Body recycles in regenerative system is concentrated, and dry purging temperature is 80~150 DEG C, and cooling purging temperature is 0~30 DEG C, purging Time is the 10%~50% of entire regeneration period.What indifferent gas purging can smoulder to avoid generation adsorbent in the drying process Phenomenon reduces security risk.
As being further improved for above-mentioned technical proposal:
It is described parallel connection absorbing unit in filling adsorption material be activated carbon, zeolite molecular sieve, absorption resin in one kind or Several combinations.
The parallel connection absorbing unit includes two first absorbing units and the second absorbing unit parallel with one another, and described first inhales 3~9 temperature points, 1~5 pressure-measuring-point are provided in coupon member and the second absorbing unit.
The parallel connection fixed gas clean unit includes two first fixed gas clean units and the second fixed gas parallel with one another Clean unit.
The pretreatment unit can be the combination of one or both of deduster, dehumidifier.
The post-processing unit can be the combination of one or more of pickling tower, caustic wash tower, water scrubber.
First on-line monitoring system and the second on-line monitoring system configure online FID monitoring systems or online PID prisons Control system, data feedback to centralized recovery system.
The centralized recovery system can correspond to 1~15 set of portable collector unit.
The present invention also provides the treatment process of the knockdown volatile organic matter resource regeneration processing unit, including: Organic exhaust gas enters absorbing unit and carries out adsorption treatment, organic exhaust gas after absorbing unit absorption after being pre-processed by pretreatment unit By post-processing qualified discharge;Whole Transporting, will using heat source to centralized recovery area after absorbing unit disassembled simply after saturation It is handled after organic exhaust gas desorption into condensing unit, product is through separating-purifying recycling design after condensation, the packaged type after regeneration Absorbing unit can collect organic exhaust gas again.
As being further improved for above-mentioned technical proposal:
The on-line monitoring shows that interlocking during saturation is switched to another absorbing unit and continued with by absorbing unit Machine exhaust gas;The heat source selects saturated vapor or inert gas, activated carbon and absorption resin according to different sorbing material types It is desorbed using saturated vapor, molecular sieve is desorbed using inert gas;The condensing unit select suitable cooling water, One kind or combination in chilled water, into condensing unit after organic exhaust gas desorption, according to the boiling point of recycling organic solvent, on demand into Enter level-one cooling, two level cooling.
In the present invention, on-line monitoring system visually manages the online FID monitorings of requirement configuration or online PID monitoring, data are anti- Centralized recovery area is fed to, reminds administrative staff's timely processing.After absorbing unit disassembled simply after saturation whole Transporting to concentrate Recovery area is handled into condensing unit after organic exhaust gas is desorbed using vapor, selected in suitable cooling water, chilled water A kind of or combination according to the boiling point of recycling organic solvent, sequentially enters level-one cooling, two level cooling.Product is through separation after condensation Recycling design is purified, the packaged type absorbing unit after regeneration can collect organic exhaust gas again.There is inert gas in air accumulator, it is lazy Property gas there are two effect, first, when vapor desorption finishes, residual gas in exchange system, cycle purge, dry absorption is single Adsorbent in member, second is that making adsorbent cooling down after dry.Dehydrater is used to remove the water in fixed gas and purge gas Part.Through on-line monitoring system qualified discharge after fixed gas purification, fixed gas clean unit is also that can move integrally, for into one Step removes the micro organic exhaust gas in fixed gas;On-line monitoring system shows that fixed gas clean unit will interlock during saturation and switches The micro organic exhaust gas in fixed gas, the fixed gas clean unit of adsorption saturation are continued with to another fixed gas clean unit Desorption unit is moved to be regenerated.
The technical effects of the invention are that:
The present invention is reduced every by portable collection, the processing unit and method of centralized recovery organic exhaust gas resource regeneration A enterprise disposably puts into and later stage operating cost, reduces each enterprise engineering construction and management cost, while is conducive to concentrate Supervision controls disposal of pollutants total amount, avoids the wasting of resources.
Description of the drawings
Fig. 1 is the process flow diagram of the method for the present invention.
In figure:1st, import organic exhaust gas;2nd, pretreatment unit;3rd, the first absorbing unit;4th, the second absorbing unit;5th, rear place Manage unit;6th, the first on-line monitoring system;7th, exhaust emissions;8th, portable absorbing unit transport;9th, vapor;10th, desorption is single Member;11st, condensing unit;12nd, separating-purifying;13rd, solvent recovery;14th, dehydrater;15th, air blower;16th, the first fixed gas purifies Unit;17th, the second fixed gas clean unit;18th, the second on-line monitoring system;19th, exhaust emissions;20th, inert gas;21st, store up Gas tank;22nd, heater.
Specific embodiment
The specific embodiment of the present invention is described further below in conjunction with the accompanying drawings, how skill is applied to the present invention whereby Art means solve technical problem, and the realization process for reaching technique effect can fully understand and implement according to this.Need what is illustrated It is that, as long as not forming conflict, each embodiment in the present invention and each feature in each embodiment can be combined with each other, institute The technical solution of formation is within protection scope of the present invention.
As shown in Figure 1, the knockdown volatile organic matter resource regeneration processing unit of the present embodiment, is including collecting System, centralized recovery system, collection system include the pretreatment unit 2 being sequentially connected, absorbing unit in parallel, post-processing unit 5, the One on-line monitoring system 6, pretreatment unit 2 are connected with organic exhaust gas import 1, and absorbing unit in parallel is also connected with portable absorption fortune Defeated unit 8;
Centralized recovery system include be sequentially connected air accumulator 21, heater 22, desorption unit 10, condensing unit 11, point From purifying plant 12, solvent recycler 13, further include the dehydrater 14 being sequentially connected, fixed gas clean unit in parallel and second Line monitoring system 18, dehydrater 14 are connected with condensing unit 11, the output terminal of dehydrater 14 and fixed gas clean unit in parallel Input terminal is connected with air blower 15, and the output terminal of the second on-line monitoring system 18 is connected with air accumulator 21.
In the present invention, heater 22 is used for heated inert gas, and water removal 14 is used to remove the moisture content in fixed gas;Indifferent gas Body recycles in regenerative system is concentrated, and the inert gas for cycling is stored in air accumulator 21.Effect that there are two inert gases, First, as the purge gass after saturated vapor thermal desorption, second is that the thermal desorption source of the gas for molecular sieve.Tolerance is regenerated according to absorption Unit size carries out frequency conversion adjustment, and the temperature of regeneration gas is adjusted according to the organic solvent property of recycling;Air blower is used for The fixed gas of generation when saturated vapor is desorbed is diluted, the air capacity of supplement carries out frequency conversion adjustment according to the tolerance of fixed gas.It is dilute Through on-line monitoring system qualified discharge after fixed gas purification after releasing;Fixed gas clean unit is also that can move integrally, and is used for Further remove the micro organic exhaust gas in fixed gas;On-line monitoring shows that fixed gas clean unit will interlock during saturation and switches The micro organic exhaust gas in fixed gas, the fixed gas clean unit of adsorption saturation are continued with to another fixed gas clean unit Desorption unit is moved to be regenerated.
Preferably, in absorbing unit in parallel filling adsorption material be in activated carbon, zeolite molecular sieve, absorption resin one Kind or several combinations.
Preferably, absorbing unit in parallel includes two first absorbing units 3 and the second absorbing unit 4 parallel with one another, the 3~9 temperature points, 1~5 pressure-measuring-point are provided in one absorbing unit 3 and the second absorbing unit 4.
Preferably, fixed gas clean unit in parallel includes two first fixed gas clean units 16 and second parallel with one another Fixed gas clean unit 17.
Preferably, pretreatment unit 2 can be the combination of one or both of deduster, dehumidifier.
Preferably, post-processing unit 5 can be the combination of one or more of pickling tower, caustic wash tower, water scrubber.
Preferably, the first on-line monitoring system 6 and the second on-line monitoring system 18 configure online FID monitoring system or Line PID monitoring systems, data feedback to centralized recovery system.
Preferably, centralized recovery system can correspond to 1~15 set of portable collector unit.It is 7~30 days to collect the cycle, is taken off The attached cycle is 0.5~2 day
The treatment process of the knockdown volatile organic matter resource regeneration processing unit of the present embodiment, including:Organic waste Gas enters absorbing unit and carries out adsorption treatment after being pre-processed by pretreatment unit 2, organic exhaust gas passes through after absorbing unit absorption Post-process qualified discharge;Whole Transporting, will be organic using heat source to centralized recovery area after absorbing unit disassembled simply after saturation It is handled after exhaust gas desorption into condensing unit 11, product through separating-purifying recycling design, inhale by the packaged type after regeneration after condensation Coupon member can collect organic exhaust gas again.
Preferred embodiment as treatment process:On-line monitoring shows that interlocking during saturation is switched to another by absorbing unit Absorbing unit continues with organic exhaust gas (switching between the one the second absorbing units), is more than 80 DEG C, inlet and outlet in temperature point Triggering interlocking, automatically switches to another absorbing unit and continues with organic exhaust gas when pressure difference is more than 2kPa;Heat source is according to difference Sorbing material type select saturated vapor or inert gas, activated carbon and absorption resin are desorbed using saturated vapor, are divided Son sieve is desorbed using inert gas;Condensing unit 11 selects one kind or combination in suitable cooling water, chilled water, organic Into condensing unit 11 after exhaust gas desorption, according to the boiling point of recycling organic solvent, on demand into level-one cooling, two level cooling.
Embodiment 1
Idiographic flow is as shown in Figure 1.The emission point of ethyl acetate disperses, intermittent discharge more in certain department's production process, in 3 Portable 1, molecular sieve purification vehicle is respectively arranged in a Waste gas outlet, spare 1, sets 4 altogether, every processing air quantity 25000m3/ H, entrance concentration 300mg/m3, air exit configuration PID online monitoring systems real time monitoring, data feedback is to concentrating renewing zone. Organic exhaust gas carries out adsorption treatment, organic exhaust gas qualified discharge after absorption by entering absorbing unit after dehumidifier.Each absorption Unit box grows 6 meters, and on-line checking shows that absorbing unit will switch to another absorbing unit online and continue with during saturation Organic exhaust gas, whole Transporting is to centralized recovery area after the absorbing unit disassembled simply after saturation.Using vapor by organic exhaust gas It is handled after desorption into condensing unit, 130 DEG C of regeneration gas temperature, inert gas recycles in centralized recovery system, adds Hot device is used for heated inert gas, and the inert gas for cycling is stored in air accumulator, dry 110 DEG C of temperature of purging, cooling purging 20 DEG C of temperature.Fixed gas clean unit is also that can move integrally, for further removing the micro organic exhaust gas in fixed gas; On-line monitoring shows that interlocking during saturation is switched to another fixed gas clean unit and continued in fixed gas by absorbing unit Micro organic exhaust gas, the fixed gas clean unit of adsorption saturation is moved to desorption unit and regenerated.Cooling water cooling is selected, The gas of desorption enters level-one cooling.Product is through separating-purifying recycling design after condensation, the packaged type absorbing unit after regeneration Organic exhaust gas can be collected again.Centralized recovery system can correspond to 3 sets of movable type collector units, and it is 7 days to collect the cycle, desorption week Phase is 0.5 day.
Embodiment 2
Idiographic flow is as shown in Figure 1.The emission point of toluene disperses, intermittent discharge more in certain department's production process, useless in 5 Portable 1, active carbon purifying vehicle is respectively arranged in gas floss hole, spare 2, sets 7 altogether, every processing air quantity 25000m3/ h, enters Mouth concentration 220mg/m3, air exit configuration PID online monitoring systems real time monitoring, data feedback is to concentrating renewing zone.It is organic Exhaust gas carries out adsorption treatment, organic exhaust gas qualified discharge after absorption by entering absorbing unit after dehumidifier.Each absorbing unit Babinet grows 4.8 meters, and on-line checking shows that absorbing unit will switch to another absorbing unit online and continue with during saturation Machine exhaust gas, whole Transporting is to centralized recovery area after the absorbing unit disassembled simply after saturation.Using vapor by organic waste qi exhaustion It is attached to be handled into condensing unit, 140 DEG C of regeneration gas temperature, using inert gas as purge gass after vapor thermal desorption, Inert gas recycles in centralized recovery system, and the inert gas for cycling is stored in air accumulator, dry purging temperature 130 DEG C, cooling purging 25 DEG C of temperature.Dehydrater is used to remove the moisture content in fixed gas, purge gass.Fixed gas clean unit is also can It moves integrally, for further removing the micro organic exhaust gas in fixed gas;On-line monitoring shows absorbing unit i.e. by saturation Shi Liansuo switches to another fixed gas clean unit and continues with micro organic exhaust gas in fixed gas, and adsorption saturation is not coagulated Gas clean unit is moved to desorption unit and is regenerated.Through on-line monitoring system qualified discharge after fixed gas purification after dilution. Cooling water cooling is selected, the gas of desorption enters level-one cooling.Product is through separating-purifying recycling design after condensation, after regeneration can Portable absorbing unit can collect organic exhaust gas again.Centralized recovery system can correspond to 5 sets of movable type collector units, collect week Phase is 10 days, and desorption cycles are 1 day.
Embodiment 3
Idiographic flow is as shown in Figure 1.Dimethylbenzene, the emission point of butanol disperse, intermittent discharge more in certain department's production process, Portable 1, active carbon purifying vehicle is respectively arranged in 4 Waste gas outlets, spare 1, sets 5 altogether, every processing air quantity 50000m3/ h, entrance concentration 260mg/m3, 9 meters of babinet length.Air exit configuration PID online monitoring system real time monitorings, data It feeds back to and concentrates renewing zone.Organic exhaust gas carries out adsorption treatment, organic exhaust gas after absorption by entering absorbing unit after dehumidifier Qualified discharge.Absorbing unit on-line checking in parallel show absorbing unit will online be switched to during saturation another absorbing unit after Continuous processing organic exhaust gas, whole Transporting is to centralized recovery area after the absorbing unit disassembled simply after saturation.To have using vapor It is handled after machine exhaust gas desorption into condensing unit, 150 DEG C of regeneration gas temperature, inert gas conduct is used after vapor thermal desorption Purge gass, inert gas recycle in centralized recovery system, and the inert gas for cycling is stored in air accumulator, dry purging 140 DEG C of temperature, cooling 25 DEG C of temperature of purging.Dehydrater is used to remove the moisture content in fixed gas, purge gass.Fixed gas clean unit And can move integrally, for further removing the micro organic exhaust gas in fixed gas;On-line monitoring shows that absorbing unit is Interlocking during saturation is switched into another fixed gas clean unit and continues with micro organic exhaust gas in fixed gas, adsorption saturation Fixed gas clean unit be moved to desorption unit and regenerated.It is up to standard through on-line monitoring system after fixed gas purification after dilution Discharge.The combination of cooling water, chilled water is selected, the gas of desorption sequentially enters level-one cooling, two level cooling.Product passes through after condensation Separating-purifying recycling design, the packaged type absorbing unit after regeneration can collect organic exhaust gas again.Centralized recovery system, can be right 4 sets of movable type collector units are answered, it is 10 days to collect the cycle, and desorption cycles are 1.5 days.
Embodiment provided above is the better embodiment of the present invention, only is used for facilitating illustrating the present invention, not to this hair The limitation of bright work in any form, any those of ordinary skill in the art, if putting forward skill not departing from the present invention In the range of art feature, using the equivalent embodiment locally changed or modified made by disclosed technology contents, and Without departing from the technical feature content of the present invention, in the range of still falling within the technology of the present invention feature.

Claims (10)

1. a kind of knockdown volatile organic matter resource regeneration processing unit, special including collection system, centralized recovery system Sign is:The collection system includes the pretreatment unit (2) being sequentially connected, absorbing unit in parallel, post-processing unit (5), the One on-line monitoring system (6), the pretreatment unit (2) are connected with organic exhaust gas import (1), and the parallel connection absorbing unit also connects Connect portable absorption delivery unit (8);
The centralized recovery system includes the air accumulator (21), heater (22), desorption unit (10), the condensing unit that are sequentially connected (11), it is net to further include the dehydrater (14) being sequentially connected, fixed gas in parallel for separating-purifying device (12), solvent recycler (13) Change unit and the second on-line monitoring system (18), the dehydrater (14) are connected with condensing unit (11), the dehydrater (14) Output terminal and the input terminal of fixed gas clean unit in parallel be connected with air blower (15), second on-line monitoring system (18) Output terminal be connected with air accumulator (21).
2. knockdown volatile organic matter resource regeneration processing unit according to claim 1, it is characterised in that:It is described Filling adsorption material is the combination of one or more of activated carbon, zeolite molecular sieve, absorption resin in absorbing unit in parallel.
3. knockdown volatile organic matter resource regeneration processing unit according to claim 1, it is characterised in that:It is described Absorbing unit in parallel includes two first absorbing units (3) and the second absorbing unit (4) parallel with one another, first absorbing unit (3) and in the second absorbing unit (4) 3~9 temperature points, 1~5 pressure-measuring-point are provided with.
4. knockdown volatile organic matter resource regeneration processing unit according to claim 1, it is characterised in that:It is described Fixed gas clean unit in parallel includes two first fixed gas clean units (16) and the second fixed gas clean unit parallel with one another (17)。
5. knockdown volatile organic matter resource regeneration processing unit according to claim 1, it is characterised in that:It is described Pretreatment unit (2) can be the combination of one or both of deduster, dehumidifier.
6. knockdown volatile organic matter resource regeneration processing unit according to claim 1, it is characterised in that:It is described Post-processing unit (5) can be the combination of one or more of pickling tower, caustic wash tower, water scrubber.
7. knockdown volatile organic matter resource regeneration processing unit according to claim 1, it is characterised in that:It is described First on-line monitoring system (6) and the second on-line monitoring system (18) configure online FID monitoring systems or online PID monitoring system System, data feedback to centralized recovery system.
8. knockdown volatile organic matter resource regeneration processing unit according to claim 1, it is characterised in that:It is described Centralized recovery system can correspond to 1~15 set of portable collector unit.
9. a kind for the treatment of process using knockdown volatile organic matter resource regeneration processing unit described in claim 1, It is characterized by comprising:Organic exhaust gas enters absorbing unit and carries out adsorption treatment, absorption after being pre-processed by pretreatment unit (2) Organic exhaust gas is by post-processing qualified discharge after unit absorption;After absorbing unit disassembled simply after saturation whole Transporting to concentrate Recovery area is handled after using heat source, organic exhaust gas is desorbed into condensing unit (11), and product is recycled through separating-purifying after condensation Solvent, the packaged type absorbing unit after regeneration can collect organic exhaust gas again.
10. treatment process according to claim 9, it is characterised in that:The on-line monitoring shows that absorbing unit will satisfy With when interlocking switch to another absorbing unit and continue with organic exhaust gas;The heat source is selected according to different sorbing material types With saturated vapor or inert gas, activated carbon and absorption resin are desorbed using saturated vapor, and molecular sieve uses inert gas It is desorbed;After the condensing unit (11) selects suitable cooling water, one kind in chilled water or combination, organic exhaust gas to be desorbed Into condensing unit (11), according to the boiling point of recycling organic solvent, on demand into level-one cooling, two level cooling.
CN201711157595.1A 2017-11-20 2017-11-20 Knockdown volatile organic matter resource regeneration processing unit and method Pending CN108096984A (en)

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Application publication date: 20180601