CN108084852A - A kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof - Google Patents

A kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof Download PDF

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Publication number
CN108084852A
CN108084852A CN201711404410.2A CN201711404410A CN108084852A CN 108084852 A CN108084852 A CN 108084852A CN 201711404410 A CN201711404410 A CN 201711404410A CN 108084852 A CN108084852 A CN 108084852A
Authority
CN
China
Prior art keywords
liquid titanium
agent
adhesive force
adhesion promoter
titanium soil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711404410.2A
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Chinese (zh)
Inventor
杨军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai One Tian Coating Co Ltd
Original Assignee
Shanghai One Tian Coating Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shanghai One Tian Coating Co Ltd filed Critical Shanghai One Tian Coating Co Ltd
Priority to CN201711404410.2A priority Critical patent/CN108084852A/en
Publication of CN108084852A publication Critical patent/CN108084852A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Road Paving Structures (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to liquid titanium soil fields, specifically a kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof.It is made of the material of following mass percent:Polyester modification resin 35 55%, adhesion promoter 2 5%, filler material 20 40%, auxiliary agent 3 8%, mixed solvent 15 25%, and each component mass percent summation is 100%, wherein adhesion promoter is polyesters adhesion promoter, filler material includes the one or more in titanium dioxide, talcum powder and barium sulfate, the mixed solvent includes aromatic hydrocarbons, esters, ketone mixture, and the auxiliary agent includes dispersant, levelling agent, antifoaming agent and anti-settling agent.The present invention compared with the existing technology, can be effectively increased the adhesive force of liquid titanium soil so that using the carbon of liquid titanium soil, glass base material because collide with or long-time use after will not there is a situation where pull-aways;Due to adding adhesive force, liquid titanium soil coating is made to greatly enhance the adaptability of finishing coat, is adapted to different finishing coat species.

Description

A kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof
Technical field
The present invention relates to liquid titanium soil field, specifically a kind of liquid titanium soil coating that can enhance adhesive force and its preparations Method.
Background technology
Liquid titanium soil is a kind of coating, is a kind of coating that can be directly sprayed in air for metal base.Current Liquid titanium soil coating be substantially for almag, can perfectly will be existing since the surface of almag is more coarse Liquid titanium soil adsorbs, and avoids because there is a situation where pull-aways after long-time use of colliding with.But for other surfaces more light Sliding base material, such as engineering plastics, after 1 year even half a year, it may occur that larger pull-away situation seriously affects It uses.
The content of the invention
The present invention is overcome the deficiencies in the prior art, designs a kind of liquid titanium soil coating that can enhance adhesive force and its preparation Method adds the substrate surface of glass for the carbon of engineering plastics, can be effectively increased the adhesive force of liquid titanium soil, avoid because colliding with or There is a situation where pull-aways after long-time use.
To achieve the above object, a kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof, feature are designed It is made of the material of following mass percent:Polyester modification resin 35-55%, adhesion promoter 2-5%, filler material 20- 40%th, auxiliary agent 3-8%, mixed solvent 15-25%, and each component mass percent summation is 100%, wherein adhesion promoter is poly- Esters adhesion promoter, filler material include the one or more in titanium dioxide, talcum powder and barium sulfate, the mixed solvent bag Aromatic hydrocarbons, esters, ketone mixture are included, the auxiliary agent includes dispersant, levelling agent, antifoaming agent and anti-settling agent;
Its preparation method includes the following steps:S1, by half mixed fillers of polyester modification resin content in formula, scattered Agent, the mixed solvent of additive amount half put into dispersion machine together, and progress high speed dispersion, which is placed into grinder, to be ground, and is obtained Filler slurries;S2 adds in remaining half polyester modification resin and antifoaming agent, anti-settling agent into filler slurry, is mixed equal It is even;S3 adds in adhesion promoter and levelling agent and remaining half mixed solvent in the material obtained into S2, mixes again Conjunction is uniformly mixing to obtain liquid titanium soil;S4 takes 10 parts of liquid titanium soil, 0.8-1.2 parts of curing agent, 3-5 parts of diluent, liquid is obtained after mixing Titanium soil coating.
In the step S1, the rotating speed of disperse mill is 800-1200r/min, and filler jitter time is 25-35min, It is then ground, the fineness of the filler slurry obtained after the grinding is less than or equal to 20 microns.
In the step S2, the speed of mixing is 600-800r/min, mixing time 15-25min.
The present invention compared with the existing technology, can be effectively increased the adhesive force of liquid titanium soil so that use the carbon of liquid titanium soil, glass Fine base material because collide with or long-time use after will not there is a situation where pull-aways;Using simple, required painting is painted on Carbon, the glass substrate surface covered, is greatly improved spray efficiency;Due to adding adhesive force, make liquid titanium soil coating pair The adaptability of finishing coat greatly enhances, and is adapted to different finishing coat species.
Specific embodiment
Embodiment one:
Step 1,20 parts of polyester modification resin is removed, 2 parts of dispersant takes each 10 parts of titanium dioxide, talcum powder, barium sulfate, after mixing Dispersion machine is sent into, high speed dispersion is carried out after adding 3 parts of mixed solvents, dispersing speed is arranged on 1000 rpms, disperses 30 minutes.Then it is ground again until fineness is less than or equal to 20 microns.
Step 2,20 parts of polyester modification resins and 1 part of antifoaming agent, 5 portions of anti-settling agents are added in, with 700 rpms of stirring speed Degree stirring is after twenty minutes.
Step 3,3 parts of polyesters adhesion promoters and 1 part of levelling agent, 3 parts of mixed solvents are added, are stirred after mixing equal Liquid titanium soil is obtained after even.
Step 4, liquid titanium soil made from 10 parts of steps 3 is taken, adds in 1 part of curing agent thereto, 3 parts of diluents are sufficiently mixed, Obtain liquid titanium soil coating.
After obtaining liquid titanium soil coating, directly the base material of engineering plastics ingredient can be sprayed, it is attached due to enhancing Put forth effort, significantly increase adaptability of the liquid titanium soil coating to finishing coat and base material.

Claims (3)

1. a kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof, it is characterized in that the object by following mass percent Material composition:Polyester modification resin 35-55%, adhesion promoter 2-5%, filler material 20-40%, auxiliary agent 3-8%, mixed solvent 15- 25%, and each component mass percent summation be 100%, wherein adhesion promoter be polyesters adhesion promoter, filler material Including the one or more in titanium dioxide, talcum powder and barium sulfate, the mixed solvent includes aromatic hydrocarbons, esters, ketone mixing Object, the auxiliary agent include dispersant, levelling agent, antifoaming agent and anti-settling agent,
Its preparation method includes the following steps:S1, by half mixed fillers of polyester modification resin content in formula, scattered Agent, the mixed solvent of additive amount half put into dispersion machine together, and progress high speed dispersion, which is placed into grinder, to be ground, and is obtained Filler slurries;S2 adds in remaining half polyester modification resin and antifoaming agent, anti-settling agent into filler slurry, is mixed equal It is even;S3 adds in adhesion promoter and levelling agent and remaining half mixed solvent in the material obtained into S2, mixes again Conjunction is uniformly mixing to obtain liquid titanium soil;S4 takes 10 parts of liquid titanium soil, 0.8-1.2 parts of curing agent, 3-5 parts of diluent, liquid is obtained after mixing Titanium soil coating.
2. a kind of liquid titanium soil coating that can enhance adhesive force according to claim 1 and preparation method thereof, it is characterized in that: In the step S1, the rotating speed of disperse mill is 800-1200r/min, and filler jitter time is 25-35min, is then carried out Grinding, the fineness of the filler slurry obtained after the grinding are less than or equal to 20 microns.
3. a kind of liquid titanium soil coating that can enhance adhesive force according to claim 1 and preparation method thereof, it is characterized in that: In the step S2, the speed of mixing is 600-800r/min, mixing time 15-25min.
CN201711404410.2A 2017-12-22 2017-12-22 A kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof Withdrawn CN108084852A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711404410.2A CN108084852A (en) 2017-12-22 2017-12-22 A kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711404410.2A CN108084852A (en) 2017-12-22 2017-12-22 A kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108084852A true CN108084852A (en) 2018-05-29

Family

ID=62178574

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711404410.2A Withdrawn CN108084852A (en) 2017-12-22 2017-12-22 A kind of liquid titanium soil coating that can enhance adhesive force and preparation method thereof

Country Status (1)

Country Link
CN (1) CN108084852A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101070450A (en) * 2007-05-15 2007-11-14 恒丰涂料(太仓)有限公司 Functional liquid coating used for magnesium aluminium alloy base material
CN101173147A (en) * 2006-10-31 2008-05-07 佛山市顺德区汉达精密电子科技有限公司 Bi-component priming paint
CN102010648A (en) * 2010-11-29 2011-04-13 常州市武进晨光金属涂料有限公司 Floating coat-free shining base coat used for metal pieces and preparation method thereof
CN102181214A (en) * 2011-04-15 2011-09-14 肇庆千江高新材料科技有限公司 Baking varnish for magnesium aluminum alloy base material and preparation and using methods thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101173147A (en) * 2006-10-31 2008-05-07 佛山市顺德区汉达精密电子科技有限公司 Bi-component priming paint
CN101070450A (en) * 2007-05-15 2007-11-14 恒丰涂料(太仓)有限公司 Functional liquid coating used for magnesium aluminium alloy base material
CN102010648A (en) * 2010-11-29 2011-04-13 常州市武进晨光金属涂料有限公司 Floating coat-free shining base coat used for metal pieces and preparation method thereof
CN102181214A (en) * 2011-04-15 2011-09-14 肇庆千江高新材料科技有限公司 Baking varnish for magnesium aluminum alloy base material and preparation and using methods thereof

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Application publication date: 20180529