CN108083409A - A kind of waste water treating agent and preparation method thereof - Google Patents

A kind of waste water treating agent and preparation method thereof Download PDF

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Publication number
CN108083409A
CN108083409A CN201711448143.9A CN201711448143A CN108083409A CN 108083409 A CN108083409 A CN 108083409A CN 201711448143 A CN201711448143 A CN 201711448143A CN 108083409 A CN108083409 A CN 108083409A
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China
Prior art keywords
parts
waste water
treating agent
water treating
diopside
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CN201711448143.9A
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Chinese (zh)
Inventor
芮培智
李延波
李晓敏
吴雪莲
张婉蓉
吉曙平
钱宜旺
范海涛
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Yangcheng Institute of Technology
Yancheng Institute of Technology
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Yangcheng Institute of Technology
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Priority to CN201711448143.9A priority Critical patent/CN108083409A/en
Publication of CN108083409A publication Critical patent/CN108083409A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62Heavy metal compounds

Abstract

The invention discloses a kind of waste water treating agent, include the raw material of following parts by weight:11 25 parts of sepiolite powder, 59 parts of sodium metaaluminate, 10 16 parts of ginger extract, 4 10 parts of waterglass, 5 10 parts of ball strepaster ball algae, 25 parts of edible seaweed powder, 36 parts of animal skin glue, 48 parts of white fused alumina micro mist, 36 parts of the herb mixtures tea dregs of rice, 26 parts of multi-vitamins, 25 parts of borax, 36 parts of erythrina bark, 48 parts of diopside, 25 parts of carbon black.The waste water treating agent of the present invention is to the Zn in heavy metal wastewater thereby2+、Cu2+、Pd2+、Cd2+, chromium, manganese have good removal effect, and have the advantages that it is environmentally friendly, energy saving, non-toxic, on operator without influence, handle after water non-secondary pollution;Preparation method is simple simultaneously, and raw material is easy to get, and cost is lower.

Description

A kind of waste water treating agent and preparation method thereof
Technical field
The present invention relates to wastewater treating technology fields, are specifically a kind of waste water treating agent and preparation method thereof.
Background technology
Water is Source of life, water pollution and the shortage of water resource, and people is forced to focus more on the protection of water resource, with And the improvement to waste water.How waste water to be made to reach discharging standards, be current urgent problem to be solved.
What heavy metal wastewater thereby referred to discharge in the industrial processes such as mining and metallurgy, machine-building, chemical industry, electronics, instrument contains weight The waste water of metal, heavy metal (such as containing cadmium, nickel, mercury, zinc) waste water are to an environmental pollution most serious and the mankind are endangered maximum One of industrial wastewater, water quality and quantity is related with production technology, and the heavy metal in waste water cannot generally decompose destruction, Zhi Nengzhuan It moves its existence position and changes its Material Form.
The processing method of heavy metal wastewater thereby is to reform production technology first at this stage, uses no or little the big huge sum of money of toxicity Belong to, in production site, treatment in situ (if do not discharged workshop) is handled frequently with chemical precipitation method, ion-exchange etc., Heavy metal can discharge or reuse less than discharge standard in treated water, form new heavy metal enriched product and recycle profit as far as possible With or be subject to harmless treatment.But the huge sum of money wastewater processing technology hysteresis in China at present, use common technique and traditional Heavy metal containing wastewater treatment means can not effectively reduce the heavy metal ion content in waste water, and causing that treated, water cannot be sharp again With, and cost for wastewater treatment is high.Therefore, the present invention provides a kind of waste water treating agent and preparation method thereof.
The content of the invention
It is an object of the invention to provide a kind of waste water treating agent and preparation method thereof, to solve to carry in above-mentioned background technology The problem of going out.
To achieve the above object, the present invention provides following technical solution:
A kind of waste water treating agent includes the raw material of following parts by weight:11-25 parts of sepiolite powder, 5-9 parts of sodium metaaluminate, life 10-16 parts of ginger extracting solution, 4-10 parts of waterglass, 5-10 parts of ball strepaster ball algae, 2-5 parts of edible seaweed powder, 3-6 parts of animal skin glue, Bai Gang Beautiful micro mist 4-8 parts, 3-6 parts of the herb mixtures tea dregs of rice, 2-6 parts of multi-vitamins, 2-5 parts of borax, 3-6 parts of erythrina bark, 4-8 parts of diopside, charcoal It is 2-5 parts black.
As further embodiment of the present invention:Include the raw material of following parts by weight:21 parts of sepiolite powder, 7 parts of sodium metaaluminate, 13 parts of ginger extract, 8 parts of waterglass, 7 parts of ball strepaster ball algae, 4 parts of edible seaweed powder, 5 parts of animal skin glue, 6 parts of white fused alumina micro mist, hardship 5 parts of tea seed cake, 4 parts of multi-vitamins, 3 parts of borax, 4 parts of erythrina bark, 5 parts of diopside, 4 parts of carbon black.
As further embodiment of the present invention:Include the raw material of following parts by weight:14 parts of sepiolite powder, 8 parts of sodium metaaluminate, 11 parts of ginger extract, 9 parts of waterglass, 6 parts of ball strepaster ball algae, 3 parts of edible seaweed powder, 4 parts of animal skin glue, 5 parts of white fused alumina micro mist, hardship 4 parts of tea seed cake, 5 parts of multi-vitamins, 4 parts of borax, 5 parts of erythrina bark, 7 parts of diopside, 3 parts of carbon black.
As further embodiment of the present invention:The diopside, erythrina bark, carbon black, the grain size of borax are 100-250 Mesh.
A kind of preparation method of waste water treating agent, comprises the following steps:(1) according to parts by weight weigh sepiolite powder, partially Sodium aluminate, ginger extract, waterglass, ball strepaster ball algae, edible seaweed powder, animal skin glue, white fused alumina micro mist, the herb mixtures tea dregs of rice, compound dimension Raw element, borax, erythrina bark, diopside and carbon black, it is spare;(2) sepiolite powder, white fused alumina micro mist, diopside and carbon black are mixed, 15-35min is mixed at 100-200 DEG C;(3) multi-vitamins, ginger extract, waterglass and the herb mixtures tea dregs of rice are mixed, After being stirred 5-10min at 30-42 DEG C, 100-125 DEG C is warming up to, stirs 10-20min, dried at 100-150 DEG C, It is ground up, sieved 80-120 mesh;(4) sodium metaaluminate, animal skin glue, borax and step (1) gains and step (2) gains are mixed It closes, 25-45min is stirred under 200-350r/min rotating speeds, erythrina bark, ball strepaster ball algae and edible seaweed powder are then added in, in 200- 1-2h is stirred under 350r/min rotating speeds to get finished product.
As further embodiment of the present invention:Step (2) mixes sepiolite powder, white fused alumina micro mist, diopside and carbon black, 22min is mixed at 160 DEG C.
As further embodiment of the present invention:Step (3) is by multi-vitamins, ginger extract, waterglass and the herb mixtures tea dregs of rice Mixing after being stirred 7min at 38 DEG C, is warming up to 112 DEG C, stirs 16min, dried at 135 DEG C, be ground up, sieved 100 Mesh.
As further embodiment of the present invention:Step (4) is by sodium metaaluminate, animal skin glue, borax and step (1) gains It is mixed with step (2) gains, 30min is stirred under 280r/min rotating speeds, then add in erythrina bark, ball strepaster ball algae and edible seaweed Powder stirs 1.4h to get finished product under 285r/min rotating speeds.
Compared with prior art, the beneficial effects of the invention are as follows:
The waste water treating agent of the present invention is to the Zn in heavy metal wastewater thereby2+、Cu2+、Pd2+、Cd2+, chromium, manganese has and good goes Except effect, and have the advantages that it is environmentally friendly, energy saving, non-toxic, on operator without influence, processing after water non-secondary pollution;Simultaneously Preparation method is simple, and raw material is easy to get, and cost is lower.
Specific embodiment
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of waste water treating agent includes the raw material of following parts by weight:11 parts of sepiolite powder, 5 parts of sodium metaaluminate, ginger extraction 10 parts of liquid, 4 parts of waterglass, 5 parts of ball strepaster ball algae, 2 parts of edible seaweed powder, 3 parts of animal skin glue, 4 parts of white fused alumina micro mist, 3 parts of the herb mixtures tea dregs of rice, 2 parts of multi-vitamins, 2 parts of borax, 3 parts of erythrina bark, 4 parts of diopside, 2 parts of carbon black.The diopside, erythrina bark, carbon black, borax Grain size be 100 mesh.
A kind of preparation method of waste water treating agent, comprises the following steps:(1) according to parts by weight weigh sepiolite powder, partially Sodium aluminate, ginger extract, waterglass, ball strepaster ball algae, edible seaweed powder, animal skin glue, white fused alumina micro mist, the herb mixtures tea dregs of rice, compound dimension Raw element, borax, erythrina bark, diopside and carbon black, it is spare;(2) sepiolite powder, white fused alumina micro mist, diopside and carbon black are mixed, 15min is mixed at 100 DEG C;(3) multi-vitamins, ginger extract, waterglass and the herb mixtures tea dregs of rice are mixed, at 30 DEG C After being stirred 5min, 100 DEG C are warming up to, 10min is stirred, is dried at 100 DEG C, is ground up, sieved 80 mesh;(4) by meta-aluminic acid Sodium, animal skin glue, borax are mixed with step (1) gains and step (2) gains, and 25min is stirred under 200r/min rotating speeds, Then erythrina bark, ball strepaster ball algae and edible seaweed powder are added in, 1h is stirred under 200r/min rotating speeds to get finished product.
Embodiment 2
A kind of waste water treating agent includes the raw material of following parts by weight:25 parts of sepiolite powder, 9 parts of sodium metaaluminate, ginger extraction 16 parts of liquid, 10 parts of waterglass, 10 parts of ball strepaster ball algae, 5 parts of edible seaweed powder, 6 parts of animal skin glue, 8 parts of white fused alumina micro mist, the herb mixtures tea dregs of rice 6 Part, 6 parts of multi-vitamins, 5 parts of borax, 6 parts of erythrina bark, 8 parts of diopside, 5 parts of carbon black.The diopside, erythrina bark, carbon black, The grain size of borax is 250 mesh.
A kind of preparation method of waste water treating agent, comprises the following steps:(1) according to parts by weight weigh sepiolite powder, partially Sodium aluminate, ginger extract, waterglass, ball strepaster ball algae, edible seaweed powder, animal skin glue, white fused alumina micro mist, the herb mixtures tea dregs of rice, compound dimension Raw element, borax, erythrina bark, diopside and carbon black, it is spare;(2) sepiolite powder, white fused alumina micro mist, diopside and carbon black are mixed, 35min is mixed at 200 DEG C;(3) multi-vitamins, ginger extract, waterglass and the herb mixtures tea dregs of rice are mixed, at 42 DEG C After being stirred 10min, 125 DEG C are warming up to, 20min is stirred, is dried at 150 DEG C, is ground up, sieved 120 mesh;(4) by meta-aluminic acid Sodium, animal skin glue, borax are mixed with step (1) gains and step (2) gains, and 45min is stirred under 350r/min rotating speeds, Then erythrina bark, ball strepaster ball algae and edible seaweed powder are added in, 2h is stirred under 350r/min rotating speeds to get finished product.
Embodiment 3
A kind of waste water treating agent includes the raw material of following parts by weight:21 parts of sepiolite powder, 7 parts of sodium metaaluminate, ginger extraction 13 parts of liquid, 8 parts of waterglass, 7 parts of ball strepaster ball algae, 4 parts of edible seaweed powder, 5 parts of animal skin glue, 6 parts of white fused alumina micro mist, 5 parts of the herb mixtures tea dregs of rice, 4 parts of multi-vitamins, 3 parts of borax, 4 parts of erythrina bark, 5 parts of diopside, 4 parts of carbon black.The diopside, erythrina bark, carbon black, borax Grain size be 150 mesh.
A kind of preparation method of waste water treating agent, comprises the following steps:(1) according to parts by weight weigh sepiolite powder, partially Sodium aluminate, ginger extract, waterglass, ball strepaster ball algae, edible seaweed powder, animal skin glue, white fused alumina micro mist, the herb mixtures tea dregs of rice, compound dimension Raw element, borax, erythrina bark, diopside and carbon black, it is spare;(2) sepiolite powder, white fused alumina micro mist, diopside and carbon black are mixed, 22min is mixed at 160 DEG C.(3) multi-vitamins, ginger extract, waterglass and the herb mixtures tea dregs of rice are mixed, at 38 DEG C After being stirred 7min, 112 DEG C are warming up to, 16min is stirred, is dried at 135 DEG C, is ground up, sieved 100 mesh.(4) by meta-aluminic acid Sodium, animal skin glue, borax are mixed with step (1) gains and step (2) gains, and 30min is stirred under 280r/min rotating speeds, Then erythrina bark, ball strepaster ball algae and edible seaweed powder are added in, 1.4h is stirred under 285r/min rotating speeds to get finished product.
Embodiment 4
A kind of waste water treating agent includes the raw material of following parts by weight:14 parts of sepiolite powder, 8 parts of sodium metaaluminate, ginger extraction 11 parts of liquid, 9 parts of waterglass, 6 parts of ball strepaster ball algae, 3 parts of edible seaweed powder, 4 parts of animal skin glue, 5 parts of white fused alumina micro mist, 4 parts of the herb mixtures tea dregs of rice, 5 parts of multi-vitamins, 4 parts of borax, 5 parts of erythrina bark, 7 parts of diopside, 3 parts of carbon black.The diopside, erythrina bark, carbon black, borax Grain size be 220 mesh.
A kind of preparation method of waste water treating agent, comprises the following steps:(1) according to parts by weight weigh sepiolite powder, partially Sodium aluminate, ginger extract, waterglass, ball strepaster ball algae, edible seaweed powder, animal skin glue, white fused alumina micro mist, the herb mixtures tea dregs of rice, compound dimension Raw element, borax, erythrina bark, diopside and carbon black, it is spare;(2) sepiolite powder, white fused alumina micro mist, diopside and carbon black are mixed, 18min is mixed at 115 DEG C;(3) multi-vitamins, ginger extract, waterglass and the herb mixtures tea dregs of rice are mixed, at 32 DEG C After being stirred 7min, 120 DEG C are warming up to, 16min is stirred, is dried at 108 DEG C, is ground up, sieved 110 mesh;(4) by meta-aluminic acid Sodium, animal skin glue, borax are mixed with step (1) gains and step (2) gains, and 36min is stirred under 310r/min rotating speeds, Then erythrina bark, ball strepaster ball algae and edible seaweed powder are added in, 1.5h is stirred under 280r/min rotating speeds to get finished product.
Inorganic agent finished product 100mg/L prepared by Application Example 3 carries out heavy metal containing wastewater treatment, and treatment effect is as follows, single Position (mg/L):
Project COD SS Zn2+ Cu2+ Pd2+ Cd2+ Chromium Manganese pH
Water sample 285 201 76 95 7.2 58 13 8 5.5
Embodiment 3 36 15.8 1.59 2.2 1.8 6.58 1.35 1.002 6.5
As can be known from the above table, waste water treating agent of the invention is to the Zn in heavy metal wastewater thereby2+、Cu2+、Pd2+、Cd2+, chromium, manganese tool There is good removal effect;The present invention have it is environmentally friendly, energy saving, non-toxic, on operator without influence, handle after water without secondary dirt The advantages of dye;Preparation method is simple, and raw material is easy to get, and cost is lower.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, can also be on the premise of this patent objective not be departed from the knowledge that one skilled in the relevant art possesses It makes a variety of changes.

Claims (8)

1. a kind of waste water treating agent, which is characterized in that include the raw material of following parts by weight:11-25 parts of sepiolite powder, sodium metaaluminate 5-9 parts, 10-16 parts of ginger extract, 4-10 parts of waterglass, 5-10 parts of ball strepaster ball algae, 2-5 parts of edible seaweed powder, animal skin glue 3-6 Part, 4-8 parts of white fused alumina micro mist, 3-6 parts of the herb mixtures tea dregs of rice, 2-6 parts of multi-vitamins, 2-5 parts of borax, 3-6 parts of erythrina bark, diopside 4- 8 parts, 2-5 parts of carbon black.
2. waste water treating agent according to claim 1, which is characterized in that include the raw material of following parts by weight:Sepiolite powder 21 parts, 7 parts of sodium metaaluminate, 13 parts of ginger extract, 8 parts of waterglass, 7 parts of ball strepaster ball algae, 4 parts of edible seaweed powder, animal skin glue 5 Part, 6 parts of white fused alumina micro mist, 5 parts of the herb mixtures tea dregs of rice, 4 parts of multi-vitamins, 3 parts of borax, 4 parts of erythrina bark, 5 parts of diopside, 4 parts of carbon black.
3. waste water treating agent according to claim 1, which is characterized in that include the raw material of following parts by weight:Sepiolite powder 14 parts, 8 parts of sodium metaaluminate, 11 parts of ginger extract, 9 parts of waterglass, 6 parts of ball strepaster ball algae, 3 parts of edible seaweed powder, animal skin glue 4 Part, 5 parts of white fused alumina micro mist, 4 parts of the herb mixtures tea dregs of rice, 5 parts of multi-vitamins, 4 parts of borax, 5 parts of erythrina bark, 7 parts of diopside, 3 parts of carbon black.
4. waste water treating agent according to claim 1, which is characterized in that the diopside, erythrina bark, carbon black, borax Grain size is 100-250 mesh.
5. the preparation method of a kind of waste water treating agent as described in claim 1-4 is any, which is characterized in that including following step Suddenly:(1)According to parts by weight weigh sepiolite powder, sodium metaaluminate, ginger extract, waterglass, ball strepaster ball algae, edible seaweed powder, Animal skin glue, white fused alumina micro mist, the herb mixtures tea dregs of rice, multi-vitamins, borax, erythrina bark, diopside and carbon black, it is spare;(2)By Hai Pao Mountain flour, white fused alumina micro mist, diopside and carbon black mixing, 15-35min is mixed at 100-200 DEG C;(3)Compound dimension is given birth to Element, ginger extract, waterglass and the mixing of the herb mixtures tea dregs of rice, after being stirred 5-10min at 30-42 DEG C, are warming up to 100-125 DEG C, 10-20min is stirred, dried at 100-150 DEG C, be ground up, sieved 80-120 mesh;(4)By sodium metaaluminate, animal skin glue, boron Sand and step(1)Gains and step(2)Gains mix, and 25-45min, Ran Houjia are stirred under 200-350r/min rotating speeds Enter erythrina bark, ball strepaster ball algae and edible seaweed powder, 1-2h is stirred under 200-350r/min rotating speeds to get finished product.
6. the preparation method of waste water treating agent according to claim 5, which is characterized in that step(2)By sepiolite powder, in vain Corundum powder, diopside and carbon black mixing, 22min is mixed at 160 DEG C.
7. the preparation method of waste water treating agent according to claim 5, which is characterized in that step(3)By multi-vitamins, Ginger extract, waterglass and the mixing of the herb mixtures tea dregs of rice, after being stirred 7min at 38 DEG C, are warming up to 112 DEG C, stir 16min, It dried at 135 DEG C, be ground up, sieved 100 mesh.
8. the preparation method of waste water treating agent according to claim 5, which is characterized in that step(4)By sodium metaaluminate, move Object hide glue, borax and step(1)Gains and step(2)Gains mix, and 30min are stirred under 280r/min rotating speeds, then Erythrina bark, ball strepaster ball algae and edible seaweed powder are added in, 1.4h is stirred under 285r/min rotating speeds to get finished product.
CN201711448143.9A 2017-12-27 2017-12-27 A kind of waste water treating agent and preparation method thereof Pending CN108083409A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112059645A (en) * 2020-09-15 2020-12-11 盐城工学院 Panel cutting device for construction

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Publication number Priority date Publication date Assignee Title
WO2005009610A1 (en) * 2003-07-25 2005-02-03 Japan Envirochemicals, Ltd. Heavy metal ion adsorbing agent
CN101538074A (en) * 2008-03-19 2009-09-23 广西大学 Method for removing heavy metallic salt in industrial wastewater by utilizing cuttlefish swim bladders
CN106007308A (en) * 2016-06-30 2016-10-12 山东胜伟园林科技有限公司 Short-cut nitrifying bacteria pseudomonas containing desilting agent and application thereof in salt eliminating underground pipe
CN106669590A (en) * 2016-12-30 2017-05-17 华南农业大学 Heavy metal mesoporous adsorbent material with molybdenum ore tailings as raw material as well as preparation method and application thereof
CN107285446A (en) * 2017-08-28 2017-10-24 湖南奇思环保有限公司 A kind of flocculant and its synthetic method and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005009610A1 (en) * 2003-07-25 2005-02-03 Japan Envirochemicals, Ltd. Heavy metal ion adsorbing agent
CN101538074A (en) * 2008-03-19 2009-09-23 广西大学 Method for removing heavy metallic salt in industrial wastewater by utilizing cuttlefish swim bladders
CN106007308A (en) * 2016-06-30 2016-10-12 山东胜伟园林科技有限公司 Short-cut nitrifying bacteria pseudomonas containing desilting agent and application thereof in salt eliminating underground pipe
CN106669590A (en) * 2016-12-30 2017-05-17 华南农业大学 Heavy metal mesoporous adsorbent material with molybdenum ore tailings as raw material as well as preparation method and application thereof
CN107285446A (en) * 2017-08-28 2017-10-24 湖南奇思环保有限公司 A kind of flocculant and its synthetic method and application

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112059645A (en) * 2020-09-15 2020-12-11 盐城工学院 Panel cutting device for construction

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