CN108080038A - A kind of nanometer air purification catalyst material with lemonene and preparation method thereof - Google Patents
A kind of nanometer air purification catalyst material with lemonene and preparation method thereof Download PDFInfo
- Publication number
- CN108080038A CN108080038A CN201711411442.5A CN201711411442A CN108080038A CN 108080038 A CN108080038 A CN 108080038A CN 201711411442 A CN201711411442 A CN 201711411442A CN 108080038 A CN108080038 A CN 108080038A
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- CN
- China
- Prior art keywords
- parts
- lemonene
- nanometer
- air purification
- purification catalyst
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- 239000000463 material Substances 0.000 title claims abstract description 28
- 238000004887 air purification Methods 0.000 title claims abstract description 15
- 235000010290 biphenyl Nutrition 0.000 title claims abstract description 15
- 239000003054 catalyst Substances 0.000 title claims abstract description 15
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 238000002360 preparation method Methods 0.000 title claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical class [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 15
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 claims abstract description 11
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000001450 anions Chemical class 0.000 claims abstract description 11
- 239000012153 distilled water Substances 0.000 claims abstract description 11
- 235000019441 ethanol Nutrition 0.000 claims abstract description 11
- 229940041616 menthol Drugs 0.000 claims abstract description 11
- 239000000843 powder Substances 0.000 claims abstract description 11
- JUWGUJSXVOBPHP-UHFFFAOYSA-B titanium(4+);tetraphosphate Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O JUWGUJSXVOBPHP-UHFFFAOYSA-B 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000005979 Citrus limon Nutrition 0.000 claims abstract description 10
- 244000248349 Citrus limon Species 0.000 claims abstract description 10
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 8
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 230000008859 change Effects 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 3
- 238000010025 steaming Methods 0.000 claims 1
- 239000011941 photocatalyst Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 241000233866 Fungi Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- -1 polypropylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
Classifications
-
- B01J35/39—
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
- A61L9/18—Radiation
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
- A61L9/18—Radiation
- A61L9/20—Ultra-violet radiation
- A61L9/205—Ultra-violet radiation using a photocatalyst or photosensitiser
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/16—Disinfection, sterilisation or deodorisation of air using physical phenomena
- A61L9/22—Ionisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
Abstract
The invention discloses a kind of nanometer air purification catalyst materials with lemonene, by deal restatement, including by 0.7 19 parts of nano-titanium dioxide, 0.1 0.18 parts of titanium phosphate, 9 17 parts of ethyl alcohol, 0.5 0.8 parts of lemon extract, 0.2 0.3 parts of menthol, 0.05 ~ 0.17 part of silica, 1 1.6 parts of polyacrylate, 0.3 0.7 parts of nanometer anion powder, 0.5 0.9 parts of titanate esters, 10 15 parts of distilled water.
Description
Technical field
The present invention relates to the technical fields of photocatalyst material, refer in particular to a kind of nanometer air purification catalyst with lemonene
Material and preparation method thereof.
Background technology
In life, with increasing rapidly for living standard, the increase of the environmental consciousness of people, people increasingly pay attention to living
Environment, however, there are the pollutions of the organic matters such as formaldehyde, stupid in house decorative material.Many harm are brought to people’s lives.Light
The appearance of catalyst coating, successfully solves purifying problem.But photocatalyst material translucency currently on the market but needs to be carried
It is high.
Photocatalyst material is coated on substrate surface, under the action of ultraviolet light and visible ray, generates strong catalytic degradation work(
Energy:Can effectively be degraded toxic and harmful gas in air;Various bacteria can be effectively killed, and bacterium or fungi can be released
Toxin decomposes and harmless treatment;It is also equipped with simultaneously except functions such as formaldehyde, deodorization, anti-pollution, purification air.And existing photocatalyst
Material does not have taste simultaneously, and for the serious place of some foreign flavor indoors, generally requiring to expend the longer time carries out at purification
Reason.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of nanometer air purification catalyst with lemonene
Material and preparation method thereof.
In order to realize above-mentioned purpose, a kind of nanometer air purification catalyst material with lemonene provided by the present invention,
By deal restatement, including by 0.7-19 parts of nano-titanium dioxide, 0.1-0.18 parts of titanium phosphate, 9-17 parts of ethyl alcohol, lemon extract
0.5-0.8 parts, 0.2-0.3 parts of menthol, 0.05 ~ 0.17 part of silica, 1-1.6 parts of polyacrylate, nanometer anion powder
0.3-0.7 parts, 0.5-0.9 parts of titanate esters, 10-15 parts of distilled water.
Further, by deal restatement, including by 12 parts of nano-titanium dioxide, 0.13 part of titanium phosphate, 8 parts of ethyl alcohol, lemonene
0.7 part of essence, 0.25 part of menthol, 0.09 part of silica, polyacrylate 1.4%, 0.56 part of nanometer anion powder, titanate esters
0.7 part, 12 parts of distilled water.
A kind of preparation method of the nanometer air purification catalyst material with lemonene, including having the following steps:
S1. weigh nano-titanium dioxide, titanium phosphate and distilled water be stirred it is uniformly mixed;
S2. ethyl alcohol, lemon extract, menthol, silica, polyacrylate, nanometer anion powder and titanate esters are weighed to add in
Magnetic agitation is carried out in the mixed materials of step S1, and is stirred 20-30 minutes, finally obtains required material.
The present invention uses above-mentioned scheme, and its advantage is:Photocatalyst material in the present invention is under light-illuminating
To carry out light-catalyzed reaction, so as to air purification and sterilizing;Meanwhile photocatalyst material can also send citris aromas, to allow interior
It is pure and fresh that air replaces smelling good.
Specific embodiment
With reference to specific embodiment, the present invention is further illustrated.
Embodiment one:
In the present embodiment, a kind of nanometer air purification catalyst material with lemonene, by deal restatement, including by nano-silica
Change 0.7 part of titanium, 0.1 part of titanium phosphate, 9 parts of ethyl alcohol, 0.5 part of lemon extract, 0.2 part of menthol, 0.05 part of silica, polypropylene
1 part of acid esters, 0.3 part of nanometer anion powder, 0.5 part of titanate esters, 10 parts of distilled water.
Embodiment two:
In the present embodiment, a kind of nanometer air purification catalyst material with lemonene, by deal restatement, including by nano-silica
Change 19 parts of titanium, 0.18 part of titanium phosphate, 17 parts of ethyl alcohol, 0.8 part of lemon extract, 0.3 part of menthol, 0.17 part of silica, poly- third
1.6 parts of olefin(e) acid ester, 0.7 part of nanometer anion powder, 0.9 part of titanate esters, 15 parts of distilled water.
Embodiment three:
In the present embodiment, a kind of nanometer air purification catalyst material with lemonene, by deal restatement, including by nano-silica
Change 12 parts of titanium, 0.13 part of titanium phosphate, 8 parts of ethyl alcohol, 0.7 part of lemon extract, 0.25 part of menthol, 0.09 part of silica, poly- third
Olefin(e) acid ester 1.4%, 0.56 part of nanometer anion powder, 0.7 part of titanate esters, 12 parts of distilled water.
The preparation method of the heat sink material of the present invention is described further in conjunction with specific embodiment.
A kind of preparation method of the nanometer air purification catalyst material with lemonene, including having the following steps:
S1. weigh nano-titanium dioxide, titanium phosphate and distilled water be stirred it is uniformly mixed;
S2. ethyl alcohol, lemon extract, menthol, silica, polyacrylate, nanometer anion powder and titanate esters are weighed to add in
Magnetic agitation is carried out in the mixed materials of step S1, and is stirred 20-30 minutes, finally obtains required material.
The embodiment of the above is only presently preferred embodiments of the present invention, and limit in any form is not done to the present invention
System.Any those skilled in the art without departing from the scope of the technical proposal of the invention, utilize the skill of the disclosure above
Art content makes technical solution of the present invention more possible variations and retouching or modification is the equivalent embodiment of the present invention.
Therefore all contents without departing from technical solution of the present invention, the equivalent equivalence changes that the thinking according to the present invention is made should all be covered by
In protection scope of the present invention.
Claims (3)
1. a kind of nanometer air purification catalyst material with lemonene, it is characterised in that:By deal restatement, including by nano-silica
Change 0.7-19 parts of titanium, 0.1-0.18 parts of titanium phosphate, 9-17 parts of ethyl alcohol, 0.5-0.8 parts of lemon extract, 0.2-0.3 parts of menthol, two
0.05 ~ 0.17 part of silica, 1-1.6 parts of polyacrylate, 0.3-0.7 parts of nanometer anion powder, 0.5-0.9 parts of titanate esters, steaming
10-15 parts of distilled water.
2. a kind of nanometer air purification catalyst material with lemonene according to claim 1, it is characterised in that:By deal
Restatement, including by 12 parts of nano-titanium dioxide, 0.13 part of titanium phosphate, 8 parts of ethyl alcohol, 0.7 part of lemon extract, 0.25 part of menthol,
0.09 part of silica, polyacrylate 1.4%, 0.56 part of nanometer anion powder, 0.7 part of titanate esters, 12 parts of distilled water.
3. a kind of a kind of system of nanometer air purification catalyst material with lemonene as described in 1 and 2 any one of claim
Preparation Method, it is characterised in that:Including having the following steps:
S1. weigh nano-titanium dioxide, titanium phosphate and distilled water be stirred it is uniformly mixed;
S2. ethyl alcohol, lemon extract, menthol, silica, polyacrylate, nanometer anion powder and titanate esters are weighed to add in
Magnetic agitation is carried out in the mixed materials of step S1, and is stirred 20-30 minutes, finally obtains required material.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711411442.5A CN108080038A (en) | 2017-12-23 | 2017-12-23 | A kind of nanometer air purification catalyst material with lemonene and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711411442.5A CN108080038A (en) | 2017-12-23 | 2017-12-23 | A kind of nanometer air purification catalyst material with lemonene and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN108080038A true CN108080038A (en) | 2018-05-29 |
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CN201711411442.5A Pending CN108080038A (en) | 2017-12-23 | 2017-12-23 | A kind of nanometer air purification catalyst material with lemonene and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN108080038A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112121612A (en) * | 2020-09-23 | 2020-12-25 | 佛山绿森林环保科技有限公司 | Automobile essence capable of removing formaldehyde and releasing negative ions and preparation method thereof |
CN112915779A (en) * | 2021-01-12 | 2021-06-08 | 港华(广州)生物科技有限公司 | Photocatalyst formaldehyde removal freshener and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
CN104722297A (en) * | 2015-02-06 | 2015-06-24 | 广州星帮尼环保科技有限公司 | Nano air purifying catalytic agent and preparation method thereof |
-
2017
- 2017-12-23 CN CN201711411442.5A patent/CN108080038A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101486867A (en) * | 2009-02-12 | 2009-07-22 | 张文磊 | Photo-catalytic coating |
CN104722297A (en) * | 2015-02-06 | 2015-06-24 | 广州星帮尼环保科技有限公司 | Nano air purifying catalytic agent and preparation method thereof |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112121612A (en) * | 2020-09-23 | 2020-12-25 | 佛山绿森林环保科技有限公司 | Automobile essence capable of removing formaldehyde and releasing negative ions and preparation method thereof |
CN112915779A (en) * | 2021-01-12 | 2021-06-08 | 港华(广州)生物科技有限公司 | Photocatalyst formaldehyde removal freshener and preparation method thereof |
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WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180529 |
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WD01 | Invention patent application deemed withdrawn after publication |