CN108071180A - It is a kind of using foam cement as the insulated fire battenboard of core plate - Google Patents

It is a kind of using foam cement as the insulated fire battenboard of core plate Download PDF

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Publication number
CN108071180A
CN108071180A CN201711410943.1A CN201711410943A CN108071180A CN 108071180 A CN108071180 A CN 108071180A CN 201711410943 A CN201711410943 A CN 201711410943A CN 108071180 A CN108071180 A CN 108071180A
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Prior art keywords
foam cement
core plate
battenboard
accounts
parts
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Pending
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CN201711410943.1A
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Chinese (zh)
Inventor
章代红
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ANHUI GUODIAN ENERGY EQUIPMENT ENGINEERING Co Ltd
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ANHUI GUODIAN ENERGY EQUIPMENT ENGINEERING Co Ltd
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Priority to CN201711410943.1A priority Critical patent/CN108071180A/en
Publication of CN108071180A publication Critical patent/CN108071180A/en
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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/88Insulating elements for both heat and sound
    • E04B1/90Insulating elements for both heat and sound slab-shaped
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/92Protection against other undesired influences or dangers
    • E04B1/94Protection against other undesired influences or dangers against fire
    • E04B1/941Building elements specially adapted therefor
    • E04B1/942Building elements specially adapted therefor slab-shaped
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00612Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Acoustics & Sound (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Building Environments (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The present invention relates to the research and development manufacture technology fields of building thermal insulation material, disclose a kind of insulated fire battenboard using foam cement as core plate, using wood fiber as panel, foam cement is core plate, wooden face foam cement battenboard is pressed into using preparation process is cold-pressed, panel plays a very good protection to foam cement core plate, improve the resistance to fire intensity of foam cement core plate, it is low to solve foam cement intensity, it is easy to crack scaling-off, the shortcomings of decorating poor performance, significantly improve the side pressure strength of battenboard, bending strength, the mechanical strengths such as impact flexibility, not only have many advantages, such as that machining property is good, also there is inorganic heat insulation material thermal and insulating performance, sound insulation property, the advantages that flame retardant property is good, it can be applicable to industry and civil buildings inner trim panels, internal partition wall, fire-resistant door core, the fields such as fire-retardant wall plate.

Description

It is a kind of using foam cement as the insulated fire battenboard of core plate
Technical field
The invention belongs to building thermal insulation material manufacture technology fields, and in particular to a kind of using foam cement as the heat preservation of core plate Fire prevention battenboard.
Background technology
The rapid development of national economy has driven the persistently overheating of building material industry, the energy and environment as building
The problem of two mouth benefits of industry are attracted attention gradually is suggested the new requirement based on building energy conservation and environmental protection.It is but overall Architectural design is unreasonable, and energy-saving effect is poor, uncoordinated with a series of safety prevention measure such as environment, fire prevention, seriously affects The overall performance of building so that energy saving and environmental protection is performed practically no function, and then affects the big of entire construction industry Development.Currently with the continuous growth of world energy sources demand, China's energy demand has also welcome peak, particularly goes in building Industry, the benefit increase of energy demand proportion mouth, and with the beneficial improvement of living standard of the people mouthful, building energy consumption most surmounts at last Industry etc. become the industry of energy consumption maximum in all industries.Various circles of society will higher to the cry of building energy conservation.It is protected in China Warm heat-barrier material research starting is more early, and initial heat preserving and insulating material research is mainly concentrated on above building common used material, Such as concrete, mortar, glass, plastics.Battenboard, by two layers of forming metal panel (or other materials panel) and directly in panel Centre foaming cures molding macromolecule heat-insulated inner core composition, is easily installed, lightweight, efficiently.What fill system used is also to close Molecular structure is steeped, the condensation of steam can be prevented.
Metal decking easy processing, can make it is variously-shaped, foam battenboard based on metal covering, there are energy consumption it is big, return The shortcomings of astigmat, wooden face organic foam battenboard good heat insulating, but there are certain fire hazard, inorganic non-metallic face folders There is the shortcomings of decoration and poor machining property in core plate.
The content of the invention
The purpose of the present invention is being directed to the problem of existing, a kind of insulated fire sandwich using foam cement as core plate is provided Plate is developed and a kind of integrates decoration, heat preservation, sound insulation, fire-retardant novel wall material.
The present invention is achieved by the following technical solutions:
It is a kind of using foam cement as the insulated fire battenboard of core plate, in adhesive adding mass fraction accounts for the fire retardant of 6-8% The ammonium chloride of 3-5% is accounted for mass fraction, carries out hot pressing after being mixed evenly to wood fiber plate, resin added is fiberboard matter The 12-14% of amount, 170-180 DEG C of hot pressing temperature, hot pressing time 5-6 minutes, maximum hot pressing pressure 3.0-3.5 MPa are prepared Panel, using the foam cement that is prepared as core plate, using cold-press process, pressing panel thickness is 5-6 millimeters, core thickness For 40-50 millimeters, cold pressing pressure 1.0-1.2 MPa, time 25-30 minute is cold-pressed, using foam cement face as sizing face, is prepared into To insulated fire battenboard;
The preparation method of the foam cement comprises the following steps:It is according to mass ratio by sulphate aluminium cement, flyash, clay 10-12:3-4:The ratio mixing of 1.0-1.2, adds in the auxiliary material that mass fraction accounts for 0.6-0.7%, adds in 0.80-0.85 times of volume Water, quickly stir evenly, mass fraction is then added in into uniform cement slurry accounts for the flake asbestos of 0.20-0.25%, Bian Jia Side is stirred, and repeatedly a small amount of addition finally, pours into the hydrogen peroxide that mass fraction accounts for 0.012-0.015%, turn in 3000-3100/ Minute speed under stir 15-20 seconds, you can enter mould, foaming, when 20-24 is small after demould, at 170-180 DEG C, humidity 95- Until water content is 10-12%, it is spare to cut into required core plate specification size for 98% time maintenance 15-18 days.
It is further described as to said program, the adhesive is made in parts by weight of following component:Glass enamel 40-50 parts of powder, 20-30 parts of bassanite, 15-20 parts of brown iron oxide, 10-12 parts of sodium metasilicate, 8-10 parts of phosphoric acid, 3-5 parts of copper oxide, 90-100 parts of water.
It is further described as to said program, the fire retardant is by tricresyl phosphate, tetrachlorophthalic acid Acid anhydride, ammonium octamolybdate, magnesium hydroxide are 14-16 according to mass ratio:10-12:4-5:The ratio of 1-2 is mixed with to obtain.
It is further described as to said program, the auxiliary material is consisted of the following compositions according to mass percent meter:It is poly- Vinyl alcohol accounts for 20-25%, water-reducing agent accounts for 15-18%, sodium carboxymethylcellulose accounts for 12-14%, manganese dioxide accounts for 10-12%, activator Account for 8-10%, calcium chloride accounts for 6-8%, remaining as calcium hydroxide.
It is further described as to said program, the hot pressing heating rate is 8-10 DEG C/min.
The present invention has the following advantages compared with prior art:In order to solve the problem of that the expensive application scenario of battenboard cost is limited, this Invention provides a kind of insulated fire battenboard using foam cement as core plate, and using wood fiber as panel, foam cement is core Plate is pressed into wooden face foam cement battenboard using preparation process is cold-pressed, and panel plays good guarantor to foam cement core plate Shield acts on, and improves the resistance to fire intensity of foam cement core plate, solves that foam cement intensity is low, scaling-off, decoration performance easy to crack The shortcomings of poor, significantly improves the mechanical strengths such as side pressure strength, bending strength, the impact flexibility of battenboard, not only has machinery The advantages that processing performance is good also has many advantages, such as that inorganic heat insulation material thermal and insulating performance, sound insulation property, flame retardant property are good, can It applies in the fields such as industry and civil buildings inner trim panels, internal partition wall, fire-resistant door core, fire-retardant wall plate.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
It is a kind of using foam cement as the insulated fire battenboard of core plate, in adhesive add mass fraction account for 6% fire retardant and Mass fraction accounts for 3% ammonium chloride, carries out hot pressing after being mixed evenly to wood fiber plate, and resin added is fiberboard quality 12%, 170 DEG C of hot pressing temperature, hot pressing time 5 minutes, panel is prepared, with what is be prepared in maximum 3.0 MPa of hot pressing pressure Foam cement is as core plate, and using cold-press process, pressing panel thickness is 5 millimeters, and core thickness is 40 millimeters, cold pressing pressure 1.0MPa is cold-pressed 25 minutes time, using foam cement face as sizing face, insulated fire battenboard is prepared;
The preparation method of the foam cement comprises the following steps:It is according to mass ratio by sulphate aluminium cement, flyash, clay 10:3:1.0 ratio mixing, adds in the auxiliary material that mass fraction accounts for 0.6%, adds in the water of 0.80 times of volume, quickly stirs evenly, Then the flake asbestos that mass fraction accounts for 0.20% is added in into uniform cement slurry, stirring while adding, repeatedly a small amount of addition, Finally, the hydrogen peroxide that mass fraction accounts for 0.012% is poured into, is stirred 15 seconds under 3000 revs/min of speed, you can enters mould, sends out Bubble, 20 it is small when after demould, at 170 DEG C, humidity conserves 15 days for 95% time, until water content is 10%, cuts into required core plate specification Size is spare.
It is further described as to said program, the adhesive is made in parts by weight of following component:Glass enamel 40 parts of powder, 20 parts of bassanite, 15 parts of brown iron oxide, 10 parts of sodium metasilicate, 8 parts of phosphoric acid, 3 parts of copper oxide, 90 parts of water.
It is further described as to said program, the fire retardant is by tricresyl phosphate, tetrachlorophthalic acid Acid anhydride, ammonium octamolybdate, magnesium hydroxide are 14 according to mass ratio:10:4:1 ratio is mixed with to obtain.
It is further described as to said program, the auxiliary material is consisted of the following compositions according to mass percent meter:It is poly- Vinyl alcohol, which accounts for 20%, water-reducing agent and accounts for 15%, sodium carboxymethylcellulose and account for 12%, manganese dioxide and account for 10%, activator and account for 8%, calcium chloride, to be accounted for 6%th, remaining as calcium hydroxide.
It is further described as to said program, the hot pressing heating rate is 8 DEG C/min.
Embodiment 2
It is a kind of using foam cement as the insulated fire battenboard of core plate, in adhesive add mass fraction account for 7% fire retardant and Mass fraction accounts for 4% ammonium chloride, carries out hot pressing after being mixed evenly to wood fiber plate, and resin added is fiberboard quality 13%, 175 DEG C of hot pressing temperature, hot pressing time 5.5 minutes, panel is prepared, to be prepared in maximum 3.3 MPa of hot pressing pressure Foam cement as core plate, using cold-press process, pressing panel thickness is 5.5 millimeters, and core thickness is 45 millimeters, cold pressing pressure 1.1 MPa of power is cold-pressed 28 minutes time, using foam cement face as sizing face, insulated fire battenboard is prepared;
The preparation method of the foam cement comprises the following steps:It is according to mass ratio by sulphate aluminium cement, flyash, clay 11:3.5:1.1 ratio mixing, adds in the auxiliary material that mass fraction accounts for 0.65%, adds in the water of 0.83 times of volume, and quick stirring is equal It is even, the flake asbestos that mass fraction accounts for 0.22% is then added in into uniform cement slurry, stirring while adding, multiple a small amount of adds Enter, finally, pour into the hydrogen peroxide that mass fraction accounts for 0.013%, stirred 18 seconds under 3050 revs/min of speed, you can enter mould, Foaming, 22 it is small when after demould, at 175 DEG C, humidity conserves 16 days for 96% time, until water content is 11%, cut into needed for core plate advise Lattice size is spare.
It is further described as to said program, the adhesive is made in parts by weight of following component:Glass enamel 45 parts of powder, 25 parts of bassanite, 18 parts of brown iron oxide, 11 parts of sodium metasilicate, phosphatase 79 part, 4 parts of copper oxide, 95 parts of water.
It is further described as to said program, the fire retardant is by tricresyl phosphate, tetrachlorophthalic acid Acid anhydride, ammonium octamolybdate, magnesium hydroxide are 15 according to mass ratio:11:4.5:1.5 ratio is mixed with to obtain.
It is further described as to said program, the auxiliary material is consisted of the following compositions according to mass percent meter:It is poly- Vinyl alcohol, which accounts for 22%, water-reducing agent and accounts for 16%, sodium carboxymethylcellulose and account for 13%, manganese dioxide and account for 11%, activator and account for 9%, calcium chloride, to be accounted for 7%th, remaining as calcium hydroxide.
It is further described as to said program, the hot pressing heating rate is 9 DEG C/min.
Embodiment 3
It is a kind of using foam cement as the insulated fire battenboard of core plate, in adhesive add mass fraction account for 8% fire retardant and Mass fraction accounts for 5% ammonium chloride, carries out hot pressing after being mixed evenly to wood fiber plate, and resin added is fiberboard quality 14%, 180 DEG C of hot pressing temperature, hot pressing time 6 minutes, panel is prepared, with what is be prepared in maximum hot pressing pressure 3.5MPa Foam cement is as core plate, and using cold-press process, pressing panel thickness is 6 millimeters, and core thickness is 50 millimeters, cold pressing pressure 1.2 MPa are cold-pressed 30 minutes time, using foam cement face as sizing face, insulated fire battenboard are prepared;
The preparation method of the foam cement comprises the following steps:It is according to mass ratio by sulphate aluminium cement, flyash, clay 12:4:1.2 ratio mixing, adds in the auxiliary material that mass fraction accounts for 0.7%, adds in the water of 0.85 times of volume, quickly stirs evenly, Then the flake asbestos that mass fraction accounts for 0.25% is added in into uniform cement slurry, stirring while adding, repeatedly a small amount of addition, Finally, the hydrogen peroxide that mass fraction accounts for 0.015% is poured into, is stirred 20 seconds under 3100 revs/min of speed, you can enters mould, sends out Bubble, 24 it is small when after demould, at 180 DEG C, humidity conserves 18 days for 98% time, until water content is 12%, cuts into required core plate specification Size is spare.
It is further described as to said program, the adhesive is made in parts by weight of following component:Glass enamel 50 parts of powder, 30 parts of bassanite, 20 parts of brown iron oxide, 12 parts of sodium metasilicate, 0 part of phosphatase 11,5 parts of copper oxide, 100 parts of water.
It is further described as to said program, the fire retardant is by tricresyl phosphate, tetrachlorophthalic acid Acid anhydride, ammonium octamolybdate, magnesium hydroxide are 16 according to mass ratio:12:5:2 ratio is mixed with to obtain.
It is further described as to said program, the auxiliary material is consisted of the following compositions according to mass percent meter:It is poly- Vinyl alcohol, which accounts for 25%, water-reducing agent and accounts for 18%, sodium carboxymethylcellulose, accounts for that 14%, manganese dioxide accounts for 10-12%, activator accounts for 10%, chlorination Calcium accounts for 8%, remaining as calcium hydroxide.
It is further described as to said program, the hot pressing heating rate is 10 DEG C/min.

Claims (5)

  1. It is 1. a kind of using foam cement as the insulated fire battenboard of core plate, which is characterized in that mass fraction is added in adhesive It accounts for the fire retardant of 6-8% and mass fraction accounts for the ammonium chloride of 3-5%, hot pressing is carried out to wood fiber plate after being mixed evenly, is applied Glue amount be fiberboard quality 12-14%, 170-180 DEG C of hot pressing temperature, hot pressing time 5-6 minutes, maximum hot pressing pressure 3.0- 3.5 MPa, are prepared panel, and using the foam cement that is prepared as core plate, using cold-press process, pressing panel thickness is 5-6 millimeters, core thickness is 40-50 millimeters, cold pressing pressure 1.0-1.2 MPa, time 25-30 minute is cold-pressed, with foam cement Face is sizing face, and insulated fire battenboard is prepared;
    The preparation method of the foam cement comprises the following steps:It is according to mass ratio by sulphate aluminium cement, flyash, clay 10-12:3-4:The ratio mixing of 1.0-1.2, adds in the auxiliary material that mass fraction accounts for 0.6-0.7%, adds in 0.80-0.85 times of volume Water, quickly stir evenly, mass fraction is then added in into uniform cement slurry accounts for the flake asbestos of 0.20-0.25%, Bian Jia Side is stirred, and repeatedly a small amount of addition finally, pours into the hydrogen peroxide that mass fraction accounts for 0.012-0.015%, turn in 3000-3100/ Minute speed under stir 15-20 seconds, you can enter mould, foaming, when 20-24 is small after demould, at 170-180 DEG C, humidity 95- Until water content is 10-12%, it is spare to cut into required core plate specification size for 98% time maintenance 15-18 days.
  2. It is 2. a kind of using foam cement as the insulated fire battenboard of core plate as described in claim 1, which is characterized in that the gluing Agent is made in parts by weight of following component:40-50 parts of glass enamel powder, 20-30 parts of bassanite, 15-20 parts of brown iron oxide, 10-12 parts of sodium metasilicate, 8-10 parts of phosphoric acid, 3-5 parts of copper oxide, 90-100 parts of water.
  3. It is 3. a kind of using foam cement as the insulated fire battenboard of core plate as described in claim 1, which is characterized in that described fire-retardant Agent be by tricresyl phosphate, tetrachlorophthalic tetrachlorophthalic anhydrid, ammonium octamolybdate, magnesium hydroxide according to mass ratio be 14-16:10-12: 4-5:The ratio of 1-2 is mixed with to obtain.
  4. It is 4. a kind of using foam cement as the insulated fire battenboard of core plate as described in claim 1, which is characterized in that the auxiliary material It is consisted of the following compositions according to mass percent meter:Polyvinyl alcohol accounts for 20-25%, water-reducing agent accounts for 15-18%, sodium carboxymethylcellulose Account for 12-14%, manganese dioxide accounts for 10-12%, activator accounts for 8-10%, calcium chloride accounts for 6-8%, remaining as calcium hydroxide.
  5. It is 5. a kind of using foam cement as the insulated fire battenboard of core plate as described in claim 1, which is characterized in that the hot pressing Heating rate is 8-10 DEG C/min.
CN201711410943.1A 2017-12-23 2017-12-23 It is a kind of using foam cement as the insulated fire battenboard of core plate Pending CN108071180A (en)

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Publication number Priority date Publication date Assignee Title
CN1063886A (en) * 1991-02-07 1992-08-26 四川师范学院 Novel inorganic adhesive
CN101716793A (en) * 2009-11-27 2010-06-02 北京化工大学 Aluminium hydroxide composite anti-flaming density fiber board and preparation method thereof
CN204163218U (en) * 2014-10-27 2015-02-18 王铁石 A kind of Novel sandwich insulating board
CN104723629A (en) * 2015-02-17 2015-06-24 中国林业科学研究院林产化学工业研究所 Preparation method for phenolic foam sandwich board
CN105201085A (en) * 2015-08-26 2015-12-30 中国林业科学研究院木材工业研究所 Composite board and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1063886A (en) * 1991-02-07 1992-08-26 四川师范学院 Novel inorganic adhesive
CN101716793A (en) * 2009-11-27 2010-06-02 北京化工大学 Aluminium hydroxide composite anti-flaming density fiber board and preparation method thereof
CN204163218U (en) * 2014-10-27 2015-02-18 王铁石 A kind of Novel sandwich insulating board
CN104723629A (en) * 2015-02-17 2015-06-24 中国林业科学研究院林产化学工业研究所 Preparation method for phenolic foam sandwich board
CN104723629B (en) * 2015-02-17 2017-03-01 中国林业科学研究院林产化学工业研究所 A kind of preparation method of Phonelic foam sandwich board
CN105201085A (en) * 2015-08-26 2015-12-30 中国林业科学研究院木材工业研究所 Composite board and preparation method thereof

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张玉龙: "《塑料、橡胶助剂速查手册》", 31 August 2012, 中国纺织出版社 *
李江华,等: "《建筑材料》", 31 July 2016, 华中科技大学出版社 *
童佳民,等: "《高效建筑消防(上卷)》", 31 January 2012, 青岛出版社 *
翟海潮: "《实用胶黏剂配方及生产技术》", 30 April 2000, 化学工业出版社 *

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