CN108070876A - A kind of hypochlorite generator bundlees electric pole type cooling system and its application method - Google Patents

A kind of hypochlorite generator bundlees electric pole type cooling system and its application method Download PDF

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Publication number
CN108070876A
CN108070876A CN201810162508.XA CN201810162508A CN108070876A CN 108070876 A CN108070876 A CN 108070876A CN 201810162508 A CN201810162508 A CN 201810162508A CN 108070876 A CN108070876 A CN 108070876A
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China
Prior art keywords
cooling
temperature
cooling water
electric pole
bundlees
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CN201810162508.XA
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Chinese (zh)
Inventor
赵志兴
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Beijing Zi Jing Chen Technology Co Ltd
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Beijing Zi Jing Chen Technology Co Ltd
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Priority to CN201810162508.XA priority Critical patent/CN108070876A/en
Publication of CN108070876A publication Critical patent/CN108070876A/en
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/34Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis

Abstract

The invention discloses a kind of hypochlorite generators to bundle electric pole type cooling system and its application method, cooling system includes cooling mechanism and temperature control mechanism, cooling mechanism includes cooling tube, cooling water inlet and cooling water outlet, uniform winding is on the electrode in the shape of a spiral for cooling tube, cooling tube one end is connected to cooling water outlet, the other end is connected to cooling water inlet, temperature control mechanism includes temperature sensor, solenoid valve and temperature controller, temperature sensor is arranged close to cooling water outlet side, solenoid valve is arranged on cooling water inlet side, temperature sensor is connected to the input terminal of temperature controller, solenoid valve is connected to the output terminal of temperature controller.A kind of hypochlorite generator of the present invention bundlees electric pole type cooling system by the way that polytetrafluoroethylene (PTFE) cooling tube is spirally wound on the electrode, the contact area of cooling tube and electrolyte is big, good cooling results, the break-make of temperature control mechanism intelligent control cooling water can simultaneously send heat alert, energy conservation and environmental protection, it is safe and efficient.

Description

A kind of hypochlorite generator bundlees electric pole type cooling system and its application method
Technical field
The present invention relates to sodium hypochlorite electrolysis tech fields, and in particular to it is cold that a kind of hypochlorite generator bundlees electric pole type But system and its application method.
Background technology
Sodium hypochlorite is a kind of strong oxidizer, has the function of preferable disinfection and bleach odor, usually passes through electricity Solution is made.Hypochlorite generator is generated secondary using saline solution, industrial brine or seawater weak solution as raw material by cell reaction Sodium chlorate solution, preparation process be, weak brine is metered in electrolytic cell, passes through silicon rectifier and connects anode and cathode direct current Power supply generates sodium hypochlorite by adjusting Faradaic current electrolysis, and under certain electric current, electrolyte solution is due to the movement of ion And electrode reaction, electric action occurs, at this moment Cl-、OH-The anions Ghandler motion that faces south is waited to move, Na+、H+Cations is waited to be moved to cathode It is dynamic, and discharge on corresponding electrode, generate corresponding substance so as to carry out redox reaction.Sodium hypochlorite electrolytic cell is just Heat often can be generated during work, when internal temperature is excessively high, accelerates reaction rate, causes sodium hypochlorite in a timing Interior output is uneven, influences the concentration of follow-up liquor natrii hypochloritis.And it is bad due to radiating, electrolytic cell can also occur to soften and become Shape, service life is shorter, simultaneously because being influenced by temperature, electrolytic cell operation is extremely unstable, hangs in the balance, and failure is more, production Raw thimerosal fluctuation of concentration is big, influences Disinfection Effect.
Hypochlorous acid generator electrolyzer is mainly in a manner that plastic conduit cools down or be not added with cooling at present, some time chlorine Sour sodium generator has added cooling provision, but since the cooling tube material of selection is unreasonable, is extremely difficult to cooling effect, hard modeling Expects pipe wall is too thick, and specific surface area is again small, causes cooling effect poor.
A kind of hypochlorite generator proposed by the present invention bundlees electric pole type cooling system and its application method by that will gather Tetrafluoroethene cooling tube spirally winds the cooling system for forming binding electric pole type on the electrode, cooling tube and electrolyte Contact area is larger, can rapidly pass to the heat of reaction solution on the cold water in cooling tube, and cooling effect is preferable, and intelligence is controlled Warm mechanism can adjust the break-make of cooling water according to the temperature of electrolyte, and energy conservation and environmental protection is safe and efficient.
The content of the invention
It is an object of the invention to provide a kind of hypochlorite generators to bundle electric pole type cooling system and its application method, To solve the problems, such as that the cooling system cooling effect of existing hypochlorite generator is poor.
To achieve the above object, the technical scheme is that:The cooling system includes cooling mechanism and temperature control mechanism, The cooling mechanism include cooling tube, cooling water inlet and cooling water outlet, the cooling tube in the shape of a spiral uniform winding secondary On the electrode of sodium chlorate generator, the cooling tube is immersed in below liquid level of electrolyte, and described cooling tube one end is connected to cooling Water out, the cooling tube other end are connected to cooling water inlet, and the cooling water inlet is arranged below electrolytic cell one end, institute It states cooling water outlet to be arranged on above the electrolytic cell other end, the temperature control mechanism includes temperature sensor, solenoid valve and temperature Controller, the temperature sensor are mounted in electrolytic cell close to cooling water outlet side, the detection probe of the temperature sensor It stretches to below liquid level of electrolyte, the solenoid valve is arranged on cooling water inlet side, and the temperature sensor is connected to temperature control The input terminal of device processed, the solenoid valve are connected to the output terminal of temperature controller.
Preferably, the cooling mechanism further includes cooling pipe fixing device, and the cooling pipe fixing device is consolidated including two groups Determine frame and at least one fixed plate, two groups of fixed frames in " mouth " font and are respectively sleeved at electrode both ends, the fixed frame Be equipped with vertical slot, the fixed plate both ends be inserted into respectively in the vertical slots of two groups of fixed frames and vertically stood with electrode to Electrode surface is arranged on, multiple locating slots are uniformly provided on the outer ledge of the fixed plate, the cooling tube passes through with determining Position slot is fixed winding on the electrode.
Preferably, the temperature controller includes processes temperature signal chip, temperature prompt panel and high temperature alarm, institute Temperature sensor, solenoid valve, temperature prompt panel and high temperature alarm is stated to be electrically connected with processes temperature signal chip.
Preferably, the cooling tube is teflon hose.
Preferably, the internal diameter of the teflon hose and outer diameter are respectively 5mm and 6mm.
Preferably, the external cooling water source of cooling water inlet connection.
Preferably, the quantity of the fixed plate is two and is symmetrically mounted on electrode both sides.
Preferably, the cooling water in the cooling tube and electrolyte reverse flow.
Preferably, the cooling tube is set to one or more layers in the vertical direction.
The invention also provides a kind of hypochlorite generator bundlees the application method of electric pole type cooling system, the use Method includes:
Intercept the teflon hose of predetermined length;
It is made to be gradually curved and spirally wind around outer diameter be with plastics grilled gun baking teflon hose On the straight tube of 50mm;
Teflon hose is cooled down, and teflon hose after cooling is removed from straight tube;
Cooling pipe fixing device is installed in electrode surface;
Teflon hose with locating slot is engaged and fixation is wrapped in electrode surface in the shape of a spiral;
Electrode is mounted in electrolytic cell;
Teflon hose both ends are connected respectively with cooling water inlet and cooling water outlet;
Solenoid valves connect cooling water;
The temperature signal collected is sent to processes temperature signal chip by temperature sensor, when temperature is more than in setting During limit value, the excessively high prompting message of processes temperature signal chip-controlled temperature prompting panel displays temperature, and control high temperature alarm Device sends high temperature alarm;
When temperature is less than preset lower limit, cooling water is closed in the power-off of processes temperature signal chip controls solenoid valve.
The invention has the advantages that:
A kind of hypochlorite generator proposed by the present invention bundlees electric pole type cooling system and its application method by will be cold But the cooling system for spirally winding and forming cluster on the electrode, simple installation, contact of the cooling tube with electrolyte are managed Area is larger, and cooling tube is fixed by cooling down pipe fixing device, and cooling tube Density Distribution is uniform, and distance is appropriate, can rapidly by The heat of reaction solution is passed on the cold water in cooling tube, and cooling effect is preferable, avoids reaction temperature excessively high;It is thin using polytetrafluoro Wall hose is cooling tube, and material is soft, tube wall is relatively thin, and heat conductivility is excellent, and heat exchange is very fast, and wear-resisting, corrosion-resistant, anti-oxidant, Good insulating;Temperature control mechanism can adjust the break-make of cooling water, energy conservation and environmental protection, and can be when temperature is higher according to the temperature of electrolyte Alarm signal is sent in time, it is safe and efficient.
Description of the drawings
Fig. 1 is that a kind of hypochlorite generator of the embodiment of the present invention 1 bundlees the structure diagram of electric pole type cooling system.
Fig. 2 is that a kind of cooling tube of hypochlorite generator binding electric pole type cooling system of the embodiment of the present invention 1 is fixed The structure diagram of device.
Fig. 3 is that a kind of cooling tube of hypochlorite generator binding electric pole type cooling system of the embodiment of the present invention 1 is fixed The side structure schematic diagram of device.
Fig. 4 is that a kind of hypochlorite generator of the embodiment of the present invention 1 bundlees the temperature control mechanism of electric pole type cooling system Fundamental diagram.
Specific embodiment
Following embodiment is not limited to the scope of the present invention for illustrating the present invention.
Embodiment 1
As shown in Figure 1, a kind of hypochlorite generator proposed by the present invention, which bundlees electric pole type cooling system, includes cooler Structure 1 and temperature control mechanism 2.Cooling mechanism includes cooling tube 11, cooling water inlet 12 and cooling water outlet 13, and cooling tube 11 is helically Shape uniform winding is on the electrode 3 of hypochlorite generator, equipped with electrolyte 5, electrode in the electrolytic cell 4 of hypochlorite generator 3 are placed in electrolytic cell 4, and both ends connection power supply, cooling tube 11 is immersed in below 5 liquid level of electrolyte, the cooling water in cooling tube 11 With 5 reverse flow of electrolyte, counterflow heat transfer can reach better heat transfer effect, and cooling tube 11 can be set to one in the vertical direction Layer or multilayer, the setting of 11 multilayer of cooling tube can ensure that electrolyte 5 reaches and more fully cool down that cooling tube 11 is polytetrafluoroethylene (PTFE) Hose, the internal diameter and outer diameter of teflon hose are chosen as 5mm and 6mm respectively, and thinner thickness, heat exchange rate is fast, gather Tetrafluoroethene hose is always about 6m, and 11 one end of cooling tube is connected to cooling water outlet 12, and 11 other end of cooling tube is connected to cold But water inlet 13, cooling water inlet 12 are arranged below 4 one end of electrolytic cell, and cooling water inlet 12 connects external cooling water source, cold But about 10 DEG C of the water temperature at water source, cooling water outlet 13 are arranged on above 4 other end of electrolytic cell, the warm water that cooling water outlet 13 comes out Available for common salt aqueous solution is configured, recycling is carried out.
Cooling mechanism 1 further includes cooling pipe fixing device 14, and as shown in Figures 2 and 3, cooling pipe fixing device 14 includes two groups Fixed frame 141 and at least one fixed plate 142, two groups of fixed frames 141 in " mouth " font and are respectively sleeved at 3 liang of electrode End, fixed frame 141 are equipped with vertical slot, 142 both ends of fixed plate be inserted into respectively in the vertical slots of two groups of fixed frames 141 and with Electrode 3 is vertically stood to 3 surface of electrode is arranged on, and in the present embodiment, the quantity of fixed plate 142 for two and is symmetrically installed In 3 both sides of electrode, be uniformly provided with multiple locating slots 143 on the outer ledge of fixed plate 142, cooling tube 11 by with locating slot 143, which are fixed, is wrapped on electrode 3, and teflon hose material is softer, by cool down pipe fixing device 14 engaging and Support causes the distributed architecture of cooling tube 11 more to stablize, and is unlikely to deform, and can adjust twining for cooling tube 11 by locating slot 143 Around density, evenly, cooling effect is more preferable for cooling.
As shown in figure 4, temperature control mechanism 2 includes temperature sensor 21, solenoid valve 22 and temperature controller 23, temperature sensing Device 21 is mounted on close to 13 side of cooling water outlet in electrolytic cell 4, and polytetrafluoro protection dress PT100 temperature may be selected in temperature sensor 21 Sensor, the detection probe of temperature sensor 21 are stretched to below 5 liquid level of electrolyte, and solenoid valve 22 is arranged on cooling water inlet 12 Side, temperature sensor 21 are connected to the input terminal of temperature controller 23, and solenoid valve 22 is connected to the output terminal of temperature controller 23. Temperature controller 23 includes processes temperature signal chip 231, temperature prompt panel 232 and high temperature alarm 233, temperature sensor 21st, solenoid valve 22, temperature prompt panel 232 and high temperature alarm 233 are electrically connected with processes temperature signal chip 231, temperature The temperature signal collected is sent to processes temperature signal chip 231,231 basis of processes temperature signal chip by sensor 21 The break-make of temperature value control temperature prompt panel 232, high temperature alarm 233 and solenoid valve 22.
The application method that a kind of hypochlorite generator of the present invention bundlees electric pole type cooling system includes:Intercept about 6m long Teflon hose;With plastics grilled gun baking teflon hose it is made to be gradually curved and spirally be closely wound On the straight tube that outer diameter is 50mm;Teflon hose is cooled down, and it is removed from the straight tube that outer diameter is 50mm;In electrode Surface installation cooling pipe fixing device;Teflon hose, which is engaged with locating slot, to be made it fixation is wrapped in electrode in the shape of a spiral Surface;Electrode is mounted in electrolytic cell;Teflon hose both ends are connected respectively with cooling water inlet and cooling water outlet It is logical;Solenoid valves connect cooling water;The temperature signal collected is sent to processes temperature signal chip by temperature sensor, When temperature is more than setting upper limit value (30 DEG C), processes temperature signal chip-controlled temperature prompting panel displays temperature is excessively high to be carried Awake information, and high temperature alarm is controlled to send high temperature alarm;When temperature is less than preset lower limit (22 DEG C), processes temperature signal Chip controls solenoid valve powers off, and closes cooling water.
A kind of hypochlorite generator proposed by the present invention bundle electric pole type cooling system by by cooling tube in the shape of a spiral Ground winding forms the cooling system of binding electric pole type on the electrode, and the contact area of cooling tube and electrolyte is larger, passes through simultaneously It cools down pipe fixing device and fixes cooling tube, cooling tube Density Distribution is uniform, and distance is appropriate, stable structure, can be rapidly by reaction The heat of solution is passed on the cold water in cooling tube, and cooling effect is preferable, avoids reaction temperature excessively high, soft using polytetrafluoro thin-walled It manages as cooling tube, material is soft, tube wall is relatively thin, and heat conductivility is excellent, and heat exchange is very fast, and wear-resisting, corrosion-resistant, anti-oxidant, insulation Property it is good, temperature control mechanism can adjust the break-make of cooling water, energy conservation and environmental protection, and can be timely when temperature is higher according to the temperature of electrolyte Alarm signal is sent, it is safe and efficient.
Although above having used general explanation and specific embodiment, the present invention is described in detail, at this On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore, These modifications or improvements without departing from theon the basis of the spirit of the present invention belong to the scope of protection of present invention.

Claims (10)

1. a kind of hypochlorite generator bundlees electric pole type cooling system, which is characterized in that the cooling system includes cooler Structure and temperature control mechanism, the cooling mechanism include cooling tube, cooling water inlet and cooling water outlet, and the cooling tube is in the shape of a spiral On the electrode of hypochlorite generator, the cooling tube is immersed in below liquid level of electrolyte uniform winding, the cooling tube one End is connected to cooling water outlet, and the cooling tube other end is connected to cooling water inlet, and the cooling water inlet is arranged on electrolysis Below slot one end, the cooling water outlet is arranged on above the electrolytic cell other end, and the temperature control mechanism includes temperature sensor, electricity Magnet valve and temperature controller, the temperature sensor are mounted in electrolytic cell close to cooling water outlet side, the temperature sensing The detection probe of device is stretched to below liquid level of electrolyte, and the solenoid valve is arranged on cooling water inlet side, the temperature sensor The input terminal of temperature controller is connected to, the solenoid valve is connected to the output terminal of temperature controller.
2. a kind of hypochlorite generator according to claim 1 bundlees electric pole type cooling system, which is characterized in that described Cooling mechanism further includes cooling pipe fixing device, and the cooling pipe fixing device includes two groups of fixed frames and at least one fixation Plate, two groups of fixed frames in " mouth " font and are respectively sleeved at electrode both ends, and the fixed frame is equipped with vertical slot, described solid Fixed board both ends are inserted into the vertical slots of two groups of fixed frames and are vertically stood with electrode to being arranged on electrode surface respectively, described solid Multiple locating slots are uniformly provided on the outer ledge of fixed board, the cooling tube is wrapped in electrode by being fixed with locating slot On.
3. a kind of hypochlorite generator according to claim 1 bundlees electric pole type cooling system, which is characterized in that described Temperature controller includes processes temperature signal chip, temperature prompt panel and high temperature alarm, the temperature sensor, electromagnetism Valve, temperature prompt panel and high temperature alarm are electrically connected with processes temperature signal chip.
4. a kind of hypochlorite generator according to claim 1 bundlees electric pole type cooling system, which is characterized in that described Cooling tube is teflon hose.
5. a kind of hypochlorite generator according to claim 4 bundlees electric pole type cooling system, which is characterized in that described The internal diameter and outer diameter of teflon hose are respectively 5mm and 6mm.
6. a kind of hypochlorite generator according to claim 1 bundlees electric pole type cooling system, which is characterized in that described The external cooling water source of cooling water inlet connection.
7. a kind of hypochlorite generator according to claim 1 bundlees electric pole type cooling system, which is characterized in that described The quantity of fixed plate is two and is symmetrically mounted on electrode both sides.
8. a kind of hypochlorite generator according to claim 1 bundlees electric pole type cooling system, which is characterized in that described Cooling water and electrolyte reverse flow in cooling tube.
9. a kind of hypochlorite generator according to claim 1 bundlees electric pole type cooling system, which is characterized in that described Cooling tube is set to one or more layers in the vertical direction.
10. a kind of hypochlorite generator according to claim 1-9 bundlees the application method of electric pole type cooling system, It is characterized in that, the application method includes:
Intercept the teflon hose of predetermined length;
It is 50mm to be gradually curved it with plastics grilled gun baking teflon hose and spirally wound around outer diameter Straight tube on;
Teflon hose is cooled down, and teflon hose after cooling is removed from straight tube;
Cooling pipe fixing device is installed in electrode surface;
Teflon hose with locating slot is engaged and fixation is wrapped in electrode surface in the shape of a spiral;
Electrode is mounted in electrolytic cell;
Teflon hose both ends are connected respectively with cooling water inlet and cooling water outlet;
Solenoid valves connect cooling water;
The temperature signal collected is sent to processes temperature signal chip by temperature sensor, when temperature is more than setting upper limit value When, the excessively high prompting message of processes temperature signal chip-controlled temperature prompting panel displays temperature, and high temperature alarm is controlled to send out Go out high temperature alarm;
When temperature is less than preset lower limit, cooling water is closed in the power-off of processes temperature signal chip controls solenoid valve.
CN201810162508.XA 2018-02-27 2018-02-27 A kind of hypochlorite generator bundlees electric pole type cooling system and its application method Pending CN108070876A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110230075A (en) * 2019-07-31 2019-09-13 贵州成黔科技开发有限公司 A kind of electrolytic cell heat-dissipation device
CN113186551A (en) * 2021-05-08 2021-07-30 潍坊思源环保设备有限公司 Sodium hypochlorite generator and production method thereof
CN114941146A (en) * 2022-06-15 2022-08-26 湖南凯旭新材料科技有限公司 Full-automatic efficient electrolytic cell
CN116321563A (en) * 2023-05-15 2023-06-23 山西丹源新材料科技股份有限公司 Furnace end electrode cooler with constant pressure water supply function

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JPH09308183A (en) * 1996-05-16 1997-11-28 Matsushita Electric Ind Co Ltd Liquid-cooled motor frame
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KR20110109398A (en) * 2010-03-31 2011-10-06 주식회사 동우워터텍 Highly efficient sodium hypochlorite generator with heat exchanger
CN107043945A (en) * 2017-06-15 2017-08-15 安徽唯达水处理技术装备有限公司 A kind of cooling type hypochlorite generator
CN208121213U (en) * 2018-02-27 2018-11-20 北京资顺晨化科技有限公司 A kind of hypochlorite generator's binding electric pole type cooling system

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2097209U (en) * 1991-08-19 1992-02-26 郑州市华中环保科技开发研究所 Electrolytic tube of generator for sodium hypochlorite
JPH09308183A (en) * 1996-05-16 1997-11-28 Matsushita Electric Ind Co Ltd Liquid-cooled motor frame
KR100964878B1 (en) * 2009-09-30 2010-06-23 주식회사 동우워터텍 Highly efficient sodium hypochlorite generator with water cooling heat exchanger
KR20110109398A (en) * 2010-03-31 2011-10-06 주식회사 동우워터텍 Highly efficient sodium hypochlorite generator with heat exchanger
CN107043945A (en) * 2017-06-15 2017-08-15 安徽唯达水处理技术装备有限公司 A kind of cooling type hypochlorite generator
CN208121213U (en) * 2018-02-27 2018-11-20 北京资顺晨化科技有限公司 A kind of hypochlorite generator's binding electric pole type cooling system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110230075A (en) * 2019-07-31 2019-09-13 贵州成黔科技开发有限公司 A kind of electrolytic cell heat-dissipation device
CN113186551A (en) * 2021-05-08 2021-07-30 潍坊思源环保设备有限公司 Sodium hypochlorite generator and production method thereof
CN114941146A (en) * 2022-06-15 2022-08-26 湖南凯旭新材料科技有限公司 Full-automatic efficient electrolytic cell
CN116321563A (en) * 2023-05-15 2023-06-23 山西丹源新材料科技股份有限公司 Furnace end electrode cooler with constant pressure water supply function

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