CN108070334A - A kind of composited aluminum and plastic decking adhering resin - Google Patents
A kind of composited aluminum and plastic decking adhering resin Download PDFInfo
- Publication number
- CN108070334A CN108070334A CN201711431492.XA CN201711431492A CN108070334A CN 108070334 A CN108070334 A CN 108070334A CN 201711431492 A CN201711431492 A CN 201711431492A CN 108070334 A CN108070334 A CN 108070334A
- Authority
- CN
- China
- Prior art keywords
- adhering resin
- parts
- plastic decking
- composited aluminum
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/08—Copolymers of ethene
- C09J123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09J123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Abstract
The invention discloses a kind of composited aluminum and plastic decking adhering resin, the adhering resin includes following raw material components and parts by weight：25~50 parts of adhering resin masterbatch, 10~30 parts of low density polyethylene (LDPE), 10~30 parts of ethylene-vinyl acetate copolymer, 10~30 parts of polystyrene, 0.5~3 part of antioxidant, thio-2 acid double 0.2~0.5 part of stearyl, 0.1~0.5 part of surface modified calcium carbonates.The adhering resin film forming that the present invention obtains is easy, good fluidity, surface non-crystal point.As the adhering resin of composited aluminum and plastic decking, there is well stable adhesive property, excellent bonding persistence；Bonding interface after stripping is uniform；Filming performance is good, and film thickness is easy to control, the uniform color of film, non-crystal point impurity；Not roll banding in process；Resistance to circumstance of temperature difference function admirable, water boiling resistance are good；Good heat aging property.
Description
Technical field
The invention belongs to adhering resin fields, and in particular to a kind of composited aluminum and plastic decking adhering resin.
Background technology
The concept of composite material is simple.When homogenous material cannot meet requirement it is necessary to two kinds or two kinds
Above Material cladding gets up to meet needs.It should be noted that here it is compound be not synthesis.Component in composite material
Material is not allow for chemical attack, and simply physical combination, also is intended on their interface some chemical reactions certainly to enhance
Bonding force.Composited aluminum and plastic decking just belongs to one kind of composite material.
Composited aluminum and plastic decking abbreviation aluminium-plastic panel is by by surface treatment and by the use of the aluminium sheet of coating baking vanish as surface, poly- second
Alkene, polypropylene plastics mixing is as sandwich layer, the new material being combined by series of process processing.
Aluminium-plastic panel be by A Luxingen companies (ALUDINGEN) development and production at first of Germany, after by Dutch rich gram
The improvement of airline (FORKEN) and Alcoa (ALOCA), after the nineties, the quality of production is progressively stablized, and reaches
Higher level, since aluminium-plastic panel is made of two kinds of completely different materials of property (metal and nonmetallic), it both remains original
The key property of composition material (metallic aluminium, nonmetallic vinyon), and the deficiency of former group material is overcome, and then obtain
Numerous excellent material characters, such as luxury, gorgeous colorful decorative, weather-proof, anti-corrosion, resistance to wound hit, prevent fires, moisture-proof, sound insulation,
Heat-insulated, shock resistance；The characteristics such as light, easy processing shaping, easy carrying and installation, these features are the open wide utilization of aluminium-plastic panel
Prospect.
The patent 201310722583.4 of our company provides a kind of composited aluminum and plastic decking adhering resin.Although bonding force
Improve many, but the performance of other aspects is short of, including the easiness that forms a film, mobility, surface non-crystal point, film thickness
Control etc. is not as good as existing technology maturation.
The content of the invention
The defects of it is an object of the invention to overcome the prior art, it is a certain that defect is that existing adhering resin is often satisfied with
The requirement of performance indicator, and other performance index are had ignored, it such as improves bonding force and has ignored polymeric membrane surface spherulite and ask
Difficulty or the difficulty of processing that topic either forms a film etc..The present invention provides one kind from the comprehensive performance of adhering resin
The defects of composited aluminum and plastic decking adhering resin is to overcome in the prior art.
In order to realize object above and other purposes, the present invention is realized by including following technical scheme：A kind of aluminium
Plastic clad plate adhering resin, the adhering resin include following raw material components and parts by weight：
25~50 parts of adhering resin masterbatch
10~30 parts of low density polyethylene (LDPE)
10~30 parts of ethylene-vinyl acetate copolymer
10~30 parts of polystyrene
0.5~3 part of antioxidant
Double 0.2~0.5 part of the stearyls of thio-2 acid
0.1~0.5 part of surface modified calcium carbonate.
The present invention is further arranged to, and the adhering resin masterbatch includes the following raw material component and parts by weight：
100 parts of high density polyethylene (HDPE)
0.5~2 part of unsaturated monomer
0.1~0.5 part of initiator.
The present invention is further arranged to, and the unsaturated monomer is in maleic anhydride or glycidyl methacrylate
It is a kind of.Preferably, the unsaturated monomer is selected from maleic anhydride.
The present invention is further arranged to, the initiator for cumyl peroxide or one kind in benzoyl peroxide or
Two kinds.
The present invention is further arranged to, melt index of the high density polyethylene (HDPE) under 190 DEG C, 2.16Kg for 2.0~
6.8g/10min。
The present invention is further arranged to, in the ethylene-vinyl acetate copolymer content of vinyl acetate for 10~
30%.
The present invention is further arranged to, and the surface modified calcium carbonate is the carbonic acid that reaction treatment is carried out through vinyl monomer
Calcium, processing procedure be by polyethylene wax of the number-average molecular weight 1500~5000, with 800~1500 mesh calcium carbonate powders with
10：1 ratio add in appropriate glycerol stearate monoesters in mixer internally mix, be granulated to obtain the final product.
The present invention is further arranged to, and the antioxidant is antioxidant 1010, antioxidant 1076 or antioxidant
One or more of B215.
It is easy to invent obtained adhering resin film forming, good fluidity, surface non-crystal point.Bonding tree as composited aluminum and plastic decking
Fat has well stable adhesive property, excellent bonding persistence；Bonding interface after stripping is uniform；Filming performance is good, film
Thick easy to control, the uniform color of film, non-crystal point impurity；Not roll banding in process；Resistance to circumstance of temperature difference function admirable, water boiling resistance
It is good；Good heat aging property.
Specific embodiment
The technical solution in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel all other embodiments obtained without making creative work belong to the model that the present invention protects
It encloses.
Embodiment 1
The present embodiment is the embodiment for preparing adhering resin masterbatch.
Adhering resin masterbatch includes the following raw material component and parts by weight in the present embodiment：
100 parts of high density polyethylene (HDPE)
2 parts of unsaturated monomer glycidyl methacrylate
0.5 part of initiator cumyl peroxide
Polyethylene is high density polyethylene (HDPE), and the melt index of high density polyethylene (HDPE) is 5.2g/ at 190 DEG C, under 2.16Kg
10min。
50 parts of adhering resin masterbatch
20 parts of low density polyethylene (LDPE)
10 parts of ethylene-vinyl acetate copolymer
16 parts of polystyrene
3 parts of antioxidant 1010
Double 0.5 part of the stearyls of auxiliary antioxidant thio-2 acid
0.5 part of surface modified calcium carbonate
The preparation method of adhering resin masterbatch is to add in screw extruder melt instead after each raw material components are mixed
It should.Extrusion temperature is 200 DEG C.Double screw extruder diameter is more than 25mm, and L/D is more than 32/1.Using water cooling flour milling pelletizing mode
Obtain adhering resin masterbatch.
Embodiment 2
The present embodiment is the embodiment for preparing adhering resin masterbatch.
Adhering resin masterbatch includes the following raw material component and parts by weight in the present embodiment：
100 parts of high density polyethylene (HDPE)
0.5 part of unsaturated monomer glycidyl methacrylate
0.1 part of initiator benzoyl peroxide
Polyethylene is high density polyethylene (HDPE), and the melt index of high density polyethylene (HDPE) is 6.8g/ at 190 DEG C, under 2.16Kg
10min。
40 parts of adhering resin masterbatch
30 parts of low density polyethylene (LDPE)
10 parts of ethylene-vinyl acetate copolymer
17 parts of polystyrene
2.4 parts of antioxidant B215
Double 0.5 part of the stearyls of auxiliary antioxidant thio-2 acid
0.1 part of surface modified calcium carbonate
The preparation method of adhering resin masterbatch is to add in screw extruder melt instead after each raw material components are mixed
It should.Extrusion temperature is 200 DEG C.Double screw extruder diameter is more than 25mm, and L/D is more than 32/1.Using water cooling flour milling pelletizing mode
Obtain adhering resin masterbatch.
Embodiment 3
The present embodiment is the embodiment for preparing adhering resin masterbatch.
Adhering resin masterbatch includes the following raw material component and parts by weight in the present embodiment：
100 parts of high density polyethylene (HDPE)
0.5 part of unsaturated monomer maleic anhydride
0.3 part of initiator benzoyl peroxide
Polyethylene is high density polyethylene (HDPE), and the melt index of high density polyethylene (HDPE) is 6.0g/ at 190 DEG C, under 2.16Kg
10min。
25 parts of adhering resin masterbatch
30 parts of low density polyethylene (LDPE)
30 parts of ethylene-vinyl acetate copolymer
14 parts of polystyrene
1,076 0.5 parts of antioxidant
Double 0.3 part of the stearyls of auxiliary antioxidant thio-2 acid
0.2 part of surface modified calcium carbonate
The preparation method of adhering resin masterbatch is to add in screw extruder melt instead after each raw material components are mixed
It should.Extrusion temperature is 200 DEG C.Double screw extruder diameter is more than 25mm, and L/D is more than 32/1.Using water cooling flour milling pelletizing mode
Obtain adhering resin masterbatch.
Embodiment 4
The present embodiment is the embodiment for preparing adhering resin masterbatch.
Adhering resin masterbatch includes the following raw material component and parts by weight in the present embodiment：
100 parts of high density polyethylene (HDPE)
1 part of unsaturated monomer maleic anhydride
0.3 part of initiator cumyl peroxide
Polyethylene is high density polyethylene (HDPE), and the melt index of high density polyethylene (HDPE) is 2g/ at 190 DEG C, under 2.16Kg
10min。
30 parts of adhering resin masterbatch
20 parts of low density polyethylene (LDPE)
30 parts of ethylene-vinyl acetate copolymer
17 parts of polystyrene
2.4 parts of antioxidant 1010
Double 0.5 part of the stearyls of auxiliary antioxidant thio-2 acid
0.1 part of surface modified calcium carbonate
The preparation method of adhering resin masterbatch is to add in screw extruder melt instead after each raw material components are mixed
It should.Extrusion temperature is 200 DEG C.Double screw extruder diameter is more than 25mm, and L/D is more than 32/1.Using water cooling flour milling pelletizing mode
Obtain adhering resin masterbatch.
Embodiment performance indicator is as follows：
The foregoing is merely a prefered embodiment of the invention, is not intended to limit the invention, all in the spirit and principles in the present invention
Within, any modifications, equivalent replacements and improvements are made should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of composited aluminum and plastic decking adhering resin, which is characterized in that the adhering resin includes following raw material components and weight
Part：
25~50 parts of adhering resin masterbatch
10~30 parts of low density polyethylene (LDPE)
10~30 parts of ethylene-vinyl acetate copolymer
10~30 parts of polystyrene
0.5~3 part of antioxidant
Double 0.2~0.5 part of the stearyls of thio-2 acid
0.1~0.5 part of surface modified calcium carbonate.
2. composited aluminum and plastic decking adhering resin according to claim 1, which is characterized in that the adhering resin masterbatch includes
The following raw material component and parts by weight：
100 parts of high density polyethylene (HDPE)
0.5~2 part of unsaturated monomer
0.1~0.5 part of initiator.
3. composited aluminum and plastic decking adhering resin according to claim 2, which is characterized in that the unsaturated monomer is Malaysia
One kind in acid anhydrides or glycidyl methacrylate.
4. composited aluminum and plastic decking adhering resin according to claim 2, which is characterized in that the initiator is peroxidating two
One or both of isopropylbenzene or benzoyl peroxide.
5. composited aluminum and plastic decking adhering resin according to claim 2, which is characterized in that the high density polyethylene (HDPE) exists
190 DEG C, the melt index under 2.16Kg is 2.0~6.8g/10min.
6. composited aluminum and plastic decking adhering resin according to claim 1, which is characterized in that the ethene-vinyl acetate is total to
The content of vinyl acetate is 10~30% in polymers.
7. composited aluminum and plastic decking adhering resin according to claim 1, which is characterized in that the surface modified calcium carbonate is
The calcium carbonate of reaction treatment is carried out through vinyl monomer, processing procedure is by polyethylene of the number-average molecular weight 1500~5000
Wax, with 800~1500 mesh calcium carbonate powders with 10：1 ratio add in appropriate glycerol stearate monoesters in mixer internally mix, make
Grain to obtain the final product.
8. composited aluminum and plastic decking adhering resin according to claim 1, which is characterized in that the antioxidant is anti-oxidant
One or more of agent 1010, antioxidant 1076 or antioxidant B215.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711431492.XA CN108070334A (en) | 2017-12-26 | 2017-12-26 | A kind of composited aluminum and plastic decking adhering resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711431492.XA CN108070334A (en) | 2017-12-26 | 2017-12-26 | A kind of composited aluminum and plastic decking adhering resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108070334A true CN108070334A (en) | 2018-05-25 |
Family
ID=62155554
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711431492.XA Pending CN108070334A (en) | 2017-12-26 | 2017-12-26 | A kind of composited aluminum and plastic decking adhering resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108070334A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117524A (en) * | 2019-12-30 | 2020-05-08 | 河源市普立隆新材料科技有限公司 | Adhesive resin for aluminum ceiling |
| CN111394026A (en) * | 2019-12-31 | 2020-07-10 | 宁波能之光新材料科技股份有限公司 | Adhesive resin for high-adhesion wood-plastic aluminum plate and one-step preparation method thereof |
| CN111634084A (en) * | 2020-05-28 | 2020-09-08 | 广东中晨电子科技有限公司 | PCB back drilling cover plate and manufacturing method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1401721A (en) * | 2002-09-06 | 2003-03-12 | 广州市鹿山化工材料有限公司 | Hot-melt polyolefin adhesive and composite structure film using same |
| CN1401722A (en) * | 2002-08-29 | 2003-03-12 | 广州市鹿山化工材料有限公司 | Adhering resin for aluminium-plastic board |
| CN102585729A (en) * | 2011-12-15 | 2012-07-18 | 广州市合诚化学有限公司 | Low-melting-point adhesive resin as well as preparation method and application thereof |
| CN105349073A (en) * | 2015-12-08 | 2016-02-24 | 河北金天塑胶新材料有限公司 | Hot melt adhesive used for winding plastic steel around water drain pipe and preparing method thereof |
| CN106893524A (en) * | 2015-12-21 | 2017-06-27 | 上海邦中新材料有限公司 | A kind of plastic-aluminum pipe adhering resin |
-
2017
- 2017-12-26 CN CN201711431492.XA patent/CN108070334A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1401722A (en) * | 2002-08-29 | 2003-03-12 | 广州市鹿山化工材料有限公司 | Adhering resin for aluminium-plastic board |
| CN1401721A (en) * | 2002-09-06 | 2003-03-12 | 广州市鹿山化工材料有限公司 | Hot-melt polyolefin adhesive and composite structure film using same |
| CN102585729A (en) * | 2011-12-15 | 2012-07-18 | 广州市合诚化学有限公司 | Low-melting-point adhesive resin as well as preparation method and application thereof |
| CN105349073A (en) * | 2015-12-08 | 2016-02-24 | 河北金天塑胶新材料有限公司 | Hot melt adhesive used for winding plastic steel around water drain pipe and preparing method thereof |
| CN106893524A (en) * | 2015-12-21 | 2017-06-27 | 上海邦中新材料有限公司 | A kind of plastic-aluminum pipe adhering resin |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111117524A (en) * | 2019-12-30 | 2020-05-08 | 河源市普立隆新材料科技有限公司 | Adhesive resin for aluminum ceiling |
| CN111394026A (en) * | 2019-12-31 | 2020-07-10 | 宁波能之光新材料科技股份有限公司 | Adhesive resin for high-adhesion wood-plastic aluminum plate and one-step preparation method thereof |
| CN111634084A (en) * | 2020-05-28 | 2020-09-08 | 广东中晨电子科技有限公司 | PCB back drilling cover plate and manufacturing method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102994025B (en) | Hot melt glue for aluminum-plastic composite panel and preparation method of hot melt glue | |
| CN102229790B (en) | Preparation method for bonding material for plastic-aluminum composite product | |
| CN103173146B (en) | Ultra-low temperature composite hot melt adhesive membrane for aluminum board and fireproof board and preparation method of composite hot melt adhesive membrane | |
| CN108070334A (en) | A kind of composited aluminum and plastic decking adhering resin | |
| CN111154427B (en) | Aluminum ceiling glue film structure and aluminum ceiling structure thereof | |
| CN107868630B (en) | Adhesive resin with barrier function and preparation method thereof | |
| CN111117524B (en) | Adhesive resin for aluminum ceiling | |
| CN109837040B (en) | Adhesive, preparation method and application thereof, and plywood | |
| CN104497929A (en) | Aluminum-plastic plate dedicated bonding resin and preparation method thereof | |
| CN101705063A (en) | High molecular bonding resin for aluminum composite panel and preparation method thereof | |
| CN109321172A (en) | Adhering resin for aluminium-plastic board, preparation method and aluminium-plastic panel | |
| CN108178995B (en) | Adhesive resin for high-barrier bottle and preparation method thereof | |
| CN109732830A (en) | A kind of FEP film, the preparation method and the usage of punching | |
| CN103497423A (en) | High melt strength polypropylene (PP) composition and preparation method thereof | |
| CN109608837A (en) | A kind of polyester-polyolefin film and preparation method thereof | |
| CN112778938A (en) | Adhesive resin for pesticide barrier bottle and preparation method thereof | |
| CN1752121A (en) | Production method of polyethylene modified material capable of cladding aluminium | |
| CA3139602C (en) | Polypropylene board and method for preparing same | |
| CN105670524A (en) | Preparation method of high-quality breathable hot melt adhesive film | |
| CN110194862A (en) | One kind being based on the fire-retardant PE CABLE MATERIALS of draft flowing deformation technology and its continuous preparation method | |
| CN112480845B (en) | Adhesive for heat insulation tile and preparation method thereof | |
| CN104119636A (en) | High gloss glass fiber reinforced ABS/PC material for extrusion process and preparation method thereof | |
| JP2013221084A (en) | Film | |
| CN105885227A (en) | Polypropylene thin film modified master batch and preparation method thereof | |
| CN112519345A (en) | Composite heat insulation tile |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180525 |