CN108069636A - A kind of non-photocatalyst-type is except formaldehyde diatom ooze and preparation method thereof - Google Patents

A kind of non-photocatalyst-type is except formaldehyde diatom ooze and preparation method thereof Download PDF

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Publication number
CN108069636A
CN108069636A CN201711375434.XA CN201711375434A CN108069636A CN 108069636 A CN108069636 A CN 108069636A CN 201711375434 A CN201711375434 A CN 201711375434A CN 108069636 A CN108069636 A CN 108069636A
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China
Prior art keywords
diatom ooze
photocatalyst
mesh
weight percent
granularity
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Pending
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CN201711375434.XA
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Chinese (zh)
Inventor
魏保利
杨卫东
程晓飞
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Shanghai Liuzhou Liang Jin Baoxin Mstar Technology Ltd
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Shanghai Liuzhou Liang Jin Baoxin Mstar Technology Ltd
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Priority to CN201711375434.XA priority Critical patent/CN108069636A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/38Polysaccharides or derivatives thereof
    • C04B24/383Cellulose or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

The invention belongs to diatom ooze field of material technology, more particularly to a kind of non-photocatalyst-type is except formaldehyde diatom ooze and preparation method thereof.The technical issues of mainly solving not continuing efficiently to carry out air purification in the case of visible ray is insufficient indoors existing for existing diatom ooze material.The technical scheme is that:A kind of non-photocatalyst-type removes formaldehyde diatom ooze, is formulated by the raw material of following weight percentage:Diatomite 35%~45%, kaolin 10%~15%, cellulose 1%~3%, plant gum powder 3%~5%, polyvinyl alcohol 1%~5%, compound palladium series catalyst 1%~2%, titanium dioxide 5%~10%, powdered whiting 30%~35%;The diatomaceous granularity is 200~500 mesh, and the kaolinic granularity is 800~1500 mesh, and the granularity of the powdered whiting is 600~1250 mesh.The present invention has many advantages, such as that safety and environmental protection, absorption property are good.

Description

A kind of non-photocatalyst-type is except formaldehyde diatom ooze and preparation method thereof
Technical field
The invention belongs to diatom ooze field of material technology, more particularly to a kind of non-photocatalyst-type removes formaldehyde diatom ooze and its system Preparation Method.
Background technology
Decoration wall material of the diatom ooze as prevalence currently on the market receives the green grass or young crops of people with its excellent environmental-protecting performance It looks at.City's interior decoration at present, formaldehyde is one of main persistent ailment for perplexing health of people, and diatom ooze has powerful absorption work(in itself Can, coordinate the photocatalyst material in diatom ooze, can effective adsorption-decomposition function formaldehyde, purification metropolitan environments.
But traditional photocatalyst material is higher to environmental requirement, and it is net need to could to carry out air under sufficient light condition Change.
The content of the invention
The shortcomings that it is an object of the invention to overcome the prior art, provide a kind of non-photocatalyst-type except formaldehyde diatom ooze and its Preparation method solves not continuing efficiently to carry out air in the case of visible ray is insufficient indoors existing for existing diatom ooze material The technical issues of purification.
The present invention is achieved by the following technical solutions:
A kind of non-photocatalyst-type removes formaldehyde diatom ooze, is formulated by the raw material of following weight percentage:Diatomite 35%~45%, kaolin 10%~15%, cellulose 1%~3%, plant gum powder 3%~5%, polyvinyl alcohol 1%~5%, Compound palladium series catalyst 1%~2%, titanium dioxide 5%~10%, powdered whiting 30%~35%.
Further, the diatomaceous granularity be 200~500 mesh, the kaolinic granularity be 800~1500 mesh, institute The granularity for stating powdered whiting is 600~1250 mesh.
Further, the compound palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or composite Nano Pd/Fe2O3In one kind.
A kind of non-photocatalyst-type removes the preparation method of formaldehyde diatom ooze, is:It is 35%~45% by weight percent Cellulose that kaolin that diatomite, weight percent are 10%~15%, weight percent are 1%~3%, weight percent Polyvinyl alcohol that plant gum powder, weight percent for 3%~5% are 1%~5%, weight percent are 1%~2% to answer Close palladium series catalyst, the heavy carbonic acid that the titanium dioxide that weight percent is 5%~10% and weight percent are 30%~35% Calcium is uniformly after mixing, you can non-photocatalyst-type is made and removes formaldehyde diatom ooze.
Further, the diatomaceous granularity be 200~500 mesh, the kaolinic granularity be 800~1500 mesh, institute The granularity for stating powdered whiting is 600~1250 mesh.
Further, the compound palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or composite Nano Pd/Fe2O3In one kind.
The diatom ooze of the present invention can directly construct on metope, and plasticity is strong, adsorption capacity and the energy for purifying air Power is strong, and breaches traditional photocatalyst type product the office of photocatalysis Decomposition formaldehyde must could be carried out under visible light conditions Limit round-the-clock can decompose removal formaldehyde, more longlasting except aldehyde is more thorough.Compared with prior art, the present invention has safety Environmental protection, the advantages that absorption property is good.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with embodiment.
Embodiment 1
A kind of non-photocatalyst-type in the present embodiment is except formaldehyde diatom ooze, by the raw material preparation of following weight percentage Into:Diatomite 45%, kaolin 10%, cellulose 1%, plant gum powder 5%, polyvinyl alcohol 1%, compound palladium series catalyst 2%, Titanium dioxide 6%, powdered whiting 30%.
A kind of non-photocatalyst-type removes the preparation method of formaldehyde diatom ooze, is:By weight percent be 45% diatomite, Plant gum powder that cellulose that kaolin that weight percent is 10%, weight percent are 1%, weight percent are 5%, again Measure percentage be 1% polyvinyl alcohol, weight percent be 2% compound palladium series catalyst, weight percent be 6% titanium white After powder and the powdered whiting that weight percent is 30% uniformly mix, you can non-photocatalyst-type is made and removes formaldehyde diatom ooze.
The diatomaceous granularity be 200 mesh, the kaolinic granularity be 800 mesh, the granularity of the powdered whiting For 600 mesh.
The compound palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or Composite Nano Pd/Fe2O3In one kind.
Embodiment 2
A kind of non-photocatalyst-type in the present embodiment is except formaldehyde diatom ooze, by the raw material preparation of following weight percentage Into:Diatomite 35%, kaolin 15%, cellulose 2%, plant gum powder 5%, polyvinyl alcohol 2%, compound palladium series catalyst 1%, Titanium dioxide 10%, powdered whiting 30%.
A kind of non-photocatalyst-type removes the preparation method of formaldehyde diatom ooze, is:By weight percent be 35% diatomite, Plant gum powder that cellulose that kaolin that weight percent is 15%, weight percent are 2%, weight percent are 5%, again Measure percentage be 2% polyvinyl alcohol, weight percent be 1% compound palladium series catalyst, weight percent be 10% titanium After white powder and the powdered whiting that weight percent is 30% uniformly mix, you can non-photocatalyst-type is made and removes formaldehyde diatom ooze.
The diatomaceous granularity be 500 mesh, the kaolinic granularity be 1500 mesh, the granularity of the powdered whiting For 1250 mesh.
The compound palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or Composite Nano Pd/Fe2O3In one kind.
Embodiment 3
A kind of non-photocatalyst-type in the present embodiment is except formaldehyde diatom ooze, by the raw material preparation of following weight percentage Into:Diatomite 40%, kaolin 12%, cellulose 2%, plant gum powder 3%, polyvinyl alcohol 2%, compound palladium series catalyst 1%, Titanium dioxide 5%, powdered whiting 35%.
A kind of non-photocatalyst-type removes the preparation method of formaldehyde diatom ooze, is:By weight percent be 40% diatomite, Plant gum powder that cellulose that kaolin that weight percent is 12%, weight percent are 2%, weight percent are 3%, again Measure percentage be 2% polyvinyl alcohol, weight percent be 1% compound palladium series catalyst, weight percent be 5% titanium white After powder and the powdered whiting that weight percent is 35% uniformly mix, you can non-photocatalyst-type is made and removes formaldehyde diatom ooze.
The diatomaceous granularity be 300 mesh, the kaolinic granularity be 1000 mesh, the granularity of the powdered whiting For 800 mesh.
The compound palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or Composite Nano Pd/Fe2O3In one kind.
Embodiment 4
A kind of non-photocatalyst-type in the present embodiment is except formaldehyde diatom ooze, by the raw material preparation of following weight percentage Into:Diatomite 38%, kaolin 10%, cellulose 3%, plant gum powder 4%, polyvinyl alcohol 5%, compound palladium series catalyst 1%, Titanium dioxide 7%, powdered whiting 32%.
A kind of non-photocatalyst-type removes the preparation method of formaldehyde diatom ooze, is:By weight percent be 38% diatomite, Plant gum powder that cellulose that kaolin that weight percent is 10%, weight percent are 3%, weight percent are 4%, again Measure percentage be 5% polyvinyl alcohol, weight percent be 1% compound palladium series catalyst, weight percent be 7% titanium white After powder and the powdered whiting that weight percent is 32% uniformly mix, you can non-photocatalyst-type is made and removes formaldehyde diatom ooze.
The diatomaceous granularity be 400 mesh, the kaolinic granularity be 1200 mesh, the granularity of the powdered whiting For 1000 mesh.
The compound palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or Composite Nano Pd/Fe2O3In one kind.
Embodiment 5
A kind of non-photocatalyst-type in the present embodiment is except formaldehyde diatom ooze, by the raw material preparation of following weight percentage Into:Diatomite 39%, kaolin 11%, cellulose 2%, plant gum powder 2%, polyvinyl alcohol 3%, compound palladium series catalyst 2%, Titanium dioxide 8%, powdered whiting 33%.
A kind of non-photocatalyst-type removes the preparation method of formaldehyde diatom ooze, is:By weight percent be 39% diatomite, Plant gum powder that cellulose that kaolin that weight percent is 11%, weight percent are 2%, weight percent are 2%, again Measure percentage be 3% polyvinyl alcohol, weight percent be 2% compound palladium series catalyst, weight percent be 8% titanium white After powder and the powdered whiting that weight percent is 33% uniformly mix, you can non-photocatalyst-type is made and removes formaldehyde diatom ooze.
The diatomaceous granularity be 325 mesh, the kaolinic granularity be 1250 mesh, the granularity of the powdered whiting For 800 mesh.
The compound palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or Composite Nano Pd/Fe2O3In one kind.
The present invention can be embodied in a variety of forms without departing from the spiritual or substantive of invention, it should therefore be appreciated that on It states embodiment and is not limited to foregoing details, and should widely be explained in the range of claim limits, therefore fall into right and want It asks or the variation in its equivalent scope and remodeling should be covered by the following claims.

Claims (6)

1. a kind of non-photocatalyst-type removes formaldehyde diatom ooze, it is characterised in that:It is formulated by the raw material of following weight percentage: Diatomite 35%~45%, kaolin 10%~15%, cellulose 1%~3%, plant gum powder 3%~5%, polyvinyl alcohol 1% ~5%, compound palladium series catalyst 1%~2%, titanium dioxide 5%~10%, powdered whiting 30%~35%.
2. non-photocatalyst-type according to claim 1 removes formaldehyde diatom ooze, it is characterised in that:The diatomaceous granularity is 200~500 mesh, the kaolinic granularity are 800~1500 mesh, and the granularity of the powdered whiting is 600~1250 mesh.
3. non-photocatalyst-type according to claim 1 removes formaldehyde diatom ooze, it is characterised in that:The compound palladium series catalyst For composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or composite Nano Pd/Fe2O3In one kind.
4. a kind of preparation method that formaldehyde diatom ooze is removed such as non-photocatalyst-type according to claim 1, it is characterised in that:It will weight Kaolin that diatomite that amount percentage is 35%~45%, weight percent are 10%~15%, weight percent be 1%~ Polyvinyl alcohol that plant gum powder that 3% cellulose, weight percent are 3%~5%, weight percent are 1%~5%, again Measure percentage be 1%~2% compound palladium series catalyst, weight percent be 5%~10% titanium dioxide and weight percent After 30%~35% uniform mixing of powdered whiting, you can non-photocatalyst-type is made and removes formaldehyde diatom ooze.
5. non-photocatalyst-type according to claim 4 removes the preparation method of formaldehyde diatom ooze, it is characterised in that:The diatom The granularity of soil is 200~500 mesh, and the kaolinic granularity is 800~1500 mesh, and the granularity of the powdered whiting is 600 ~1250 mesh.
6. non-photocatalyst-type according to claim 4 removes the preparation method of formaldehyde diatom ooze, it is characterised in that:It is described compound Palladium series catalyst is composite Nano Pd/TiO2, composite Nano Pd/Al2O3, composite Nano Pd/Mn2O3Or composite Nano Pd/Fe2O3 In one kind.
CN201711375434.XA 2017-12-19 2017-12-19 A kind of non-photocatalyst-type is except formaldehyde diatom ooze and preparation method thereof Pending CN108069636A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020388A (en) * 2018-08-31 2018-12-18 广东太氧谷环保科技有限公司 A kind of diatom ooze material and preparation method thereof of non-photocatalyst-type purification air formaldehyde

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1714930A (en) * 2004-06-14 2006-01-04 中国科学院生态环境研究中心 Formaldehyde gas cyaniding catalyst under the room temperature condition
CN1795970A (en) * 2004-12-28 2006-07-05 中国科学院生态环境研究中心 High performance catalyst for catalyzing formaldehyde to complete oxidation under room temperature temperature
CN104475094A (en) * 2014-12-10 2015-04-01 哈尔滨澳宝硅藻新材料有限公司 Diatom ooze wall material applied to non-photo-catalysis purification of formaldehyde in air at room temperature

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1714930A (en) * 2004-06-14 2006-01-04 中国科学院生态环境研究中心 Formaldehyde gas cyaniding catalyst under the room temperature condition
CN1795970A (en) * 2004-12-28 2006-07-05 中国科学院生态环境研究中心 High performance catalyst for catalyzing formaldehyde to complete oxidation under room temperature temperature
CN104475094A (en) * 2014-12-10 2015-04-01 哈尔滨澳宝硅藻新材料有限公司 Diatom ooze wall material applied to non-photo-catalysis purification of formaldehyde in air at room temperature

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109020388A (en) * 2018-08-31 2018-12-18 广东太氧谷环保科技有限公司 A kind of diatom ooze material and preparation method thereof of non-photocatalyst-type purification air formaldehyde
CN109020388B (en) * 2018-08-31 2021-05-04 广东太氧谷环保科技有限公司 Non-photocatalytic diatom ooze material for purifying air formaldehyde and preparation method thereof

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