CN108068186A - A kind of antimildew and antibacterial agent for improving solid wood furniture performance - Google Patents
A kind of antimildew and antibacterial agent for improving solid wood furniture performance Download PDFInfo
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- CN108068186A CN108068186A CN201711393447.XA CN201711393447A CN108068186A CN 108068186 A CN108068186 A CN 108068186A CN 201711393447 A CN201711393447 A CN 201711393447A CN 108068186 A CN108068186 A CN 108068186A
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- antimildew
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/02—Processes; Apparatus
- B27K3/12—Impregnating by coating the surface of the wood with an impregnating paste
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/70—Hydrophobation treatment
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Plant Pathology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to solid wood furniture manufacture technology fields,Disclose a kind of antimildew and antibacterial agent for improving solid wood furniture performance,It is combined with montmorillonite with rare earth metal,The hydrophobicity of wood surface can be improved,Kill mould,Also bacterial activity can be reduced,It is compound with inorganic metal with carboxymethyl chitosan simultaneously,Antibacterial effect is optimal,Utilize the porosity characteristic of timber,Carrier is effectively adsorbed,Antiseptic can enter the inside of timber with gluing carrier,Realize anti-microbial property,Its principle is using laminated metal compound as parent,It is reacted using Intercalation reaction,Antiseptic is inserted into interlayer,In addition to being avoided that coloring is bad,It is also good with stability,Long lifespan,The features such as antimicrobial efficiency is high,The service life of solid wood furniture can be extended 10 15 years by the antimildew and antibacterial agent that the present invention is prepared,And improve the protective effect to human body.
Description
Technical field
The invention belongs to solid wood furniture manufacturing technology fields, and in particular to a kind of to improve the mould proof of solid wood furniture performance
Antiseptic.
Background technology
Solid wood furniture refers to the furniture made of natural timber, and furniture surface can generally see the texture of timber.At present
Solid wood furniture in the market substantially there are two types of, one kind is log furniture, and the useful material of institute of furniture is all pure solid wood, including desktop,
Door-plate, side plate of cabinet etc. are made of pure solid wood, and plate or density board paster situation are made without using all other men.It is another
It is imitating solid wood furniture, that is, from the appearance the natural texture of timber, feel and color and luster are all the same with solid wood furniture, but
Actually the inside is furniture that solid wood and wood-based plate are made by mixing, for example, side plate, shelf etc. using veneer overlay particieboard or
Medium density fibre board (MDF), door and drawer then use solid wood paster.Pure solid wood furniture has value preserving function.It can be brought simultaneously to domestic environment
Gentle " forest breath ", thus quite welcome by medium-to-high grade consumer.Its advantages of is to embody nature：Natural texture, it is changeable
Form, furniture surface can generally see the decorative pattern of timber beauty.It is good that China's solid wood furniture industry runs current development situation
Good, intelligence is ground data research center and is shown, as the continuous expansion in market, China's solid wood furniture are asked in solid wood furniture industry operation in China's
Industry operation will welcome a new opportunity to develop.
Solid wood furniture is unavoidable in use to be present with mildew problem, especially in moist rainy south, prevents
Mould problem becomes anti-and does not allow to delay, while is hidden in solid wood furniture there are substantial amounts of bacterium in home environment and public environment
In, to the great harm that health has, antibacterial and mouldproof is the two large problems that solid wood furniture needs solve.
The content of the invention
The purpose of the present invention is being directed to the problem of existing, a kind of antimildew and antibacterial for improving solid wood furniture performance is provided
Agent, antimildew and antibacterial significant effect.
The present invention is achieved by the following technical solutions：
A kind of antimildew and antibacterial agent for improving solid wood furniture performance, is made in parts by weight of following component：Montmorillonite accounts for
50-60 parts, 25-35 parts of zeolite powder, 5.5-6.0 parts of nitric acid, 7.0-8.0 parts of neopelex, absolute ethyl alcohol 10-12
Part, 4-6 parts of boric acid, 3-5 parts of urea, 3.5-4.0 parts of carboxymethyl chitosan, 2.2-2.4 parts of zinc chloride, calcium monohydrogen phosphate 1.6-1.8
Part, 1.4-1.6 parts of silver nitrate, copper oxide 1.3-1.5,1.0-1.2 parts of europium oxide, 0.7-1.0 parts of erbium oxide, dilute hydrochloric acid 40-50
Part, 120-130 parts of deionized water；Its preparation method comprises the following steps：
（1）Montmorillonite is dissolved in deionized water, is heated to 50-60 DEG C, is stirred 40-50 minutes, by europium oxide and erbium oxide
It is added to stir 20-30 minutes in nitric acid and obtains clear solution, boric acid and urea are dissolved in absolute ethyl alcohol, are stirred continuously
30-40 minutes, the montmorillonite solution of preparation is heated to 80-90 DEG C under water bath with thermostatic control, adds in the clear solution, reacts 1-
2 it is small when after, the absolute ethyl alcohol mixed liquor of preparation is added in reaction system, reaction is to becoming faint yellow colloidal sol；
（2）Zeolite powder and calcium monohydrogen phosphate are added in dilute hydrochloric acid, stirred 15-20 minutes at 60-70 DEG C, addition silver nitrate,
Copper oxide, zinc chloride are stirred by ultrasonic 30-40 minutes, add in carboxymethyl chitosan, are uniformly mixed, with step（1）It is prepared into
The faint yellow colloidal sol mixing arrived, adds in neopelex, is stood admittedly at 60-70 DEG C after being dispersed with stirring 15-20 minutes
When change 3-4 is small；
（3）Mixture after curing is transferred in Muffle furnace, combustion reaction, entire combustion reaction are carried out at 500-550 DEG C
Process continues 3-5 minutes, and heat preservation is taken out after 10-12 minutes, cools down and is ground to particle size 400-500 mesh scope up to described
Antimildew and antibacterial agent.
It is further described as to said program, the concentration of nitric acid is 18-20 mol/Ls, and dilute hydrochloric acid concentration is
0.2-0.3 mol/Ls.
It is further described as to said program, the silver nitrate, copper oxide, zinc chloride particle size are at 1-10 microns
Between.
It is further described as to said program, step（3）The Muffle furnace preheating temperature is 280-300 DEG C, preheating
When time is 3-5 small, heat temperature raising speed is 40-50 DEG C/h.
It is further described as to said program, the antimildew and antibacterial agent, which can be added in solid wood furniture coating, to be used.
The present invention has the following advantages compared with prior art：In order to solve antimildew and antibacterial poor performance in existing solid wood furniture
Problem, the present invention provides a kind of antimildew and antibacterial agents for improving solid wood furniture performance, are combined with montmorillonite with rare earth metal,
Can improve the hydrophobicity of wood surface, kill mould, can also reduce bacterial activity, at the same with carboxymethyl chitosan with it is inorganic
Metal composite, antibacterial effect are optimal, and using the porosity characteristic of timber, carrier are effectively adsorbed, antiseptic
The inside of timber can be entered with gluing carrier, realizes anti-microbial property, principle is the profit using laminated metal compound as parent
It is reacted with Intercalation reaction, antiseptic is inserted into interlayer, in addition to being avoided that coloring is bad, also with stability is good, the service life
The service life of solid wood furniture can be extended 10- by the features such as length, antimicrobial efficiency is high, the antimildew and antibacterial agent that the present invention is prepared
15 years, and improve the protective effect to human body.
Specific embodiment
With reference to specific embodiment, the invention will be further described.
Embodiment 1
A kind of antimildew and antibacterial agent for improving solid wood furniture performance, is made in parts by weight of following component：Montmorillonite accounts for
50 parts, 25 parts of zeolite powder, 5.5 parts of nitric acid, 7.0 parts of neopelex, 10 parts of absolute ethyl alcohol, 4 parts of boric acid, 3 parts of urea,
3.5 parts of carboxymethyl chitosan, 2.2 parts of zinc chloride, 1.6 parts of calcium monohydrogen phosphate, 1.4 parts of silver nitrate, 1.3 parts of copper oxide, europium oxide 1.0
Part, 0.7 part of erbium oxide, 40 parts of dilute hydrochloric acid, 120 parts of deionized water；Its preparation method comprises the following steps：
（1）Montmorillonite is dissolved in deionized water, is heated to 50 DEG C, stirs 40 minutes, europium oxide and erbium oxide is added to
It is stirred 20 minutes in nitric acid and obtains clear solution, boric acid and urea are dissolved in absolute ethyl alcohol, be stirred continuously 30 minutes, it will
The montmorillonite solution of preparation is heated to 80 DEG C under water bath with thermostatic control, adds in the clear solution, when reaction 1 is small after, by preparation
Absolute ethyl alcohol mixed liquor is added in reaction system, and reaction is to becoming faint yellow colloidal sol；
（2）Zeolite powder and calcium monohydrogen phosphate are added in dilute hydrochloric acid, stirred 15 minutes at 60 DEG C, add in silver nitrate, copper oxide,
Zinc chloride is stirred by ultrasonic 30 minutes, adds in carboxymethyl chitosan, is uniformly mixed, with step（1）What is be prepared is faint yellow
Colloidal sol mixes, and adds in neopelex, when standing curing 3 is small at 60 DEG C after being dispersed with stirring 15 minutes；
（3）Mixture after curing is transferred in Muffle furnace, combustion reaction, entire combustion reaction process are carried out at 500 DEG C
Continue 3 minutes, heat preservation is taken out after ten minutes, is cooled down and is ground to particle size 400-500 mesh scope up to the antimildew and antibacterial
Agent.
It is further described as to said program, the concentration of nitric acid is 18 mol/Ls, and dilute hydrochloric acid concentration is rubbed for 0.2
You/liter.
It is further described as to said program, the silver nitrate, copper oxide, zinc chloride particle size are at 1-10 microns
Between.
It is further described as to said program, step（3）The Muffle furnace preheating temperature is 280 DEG C, preheating time
For 3 it is small when, heat temperature raising speed be 40 DEG C/h.
It is further described as to said program, the antimildew and antibacterial agent, which can be added in solid wood furniture coating, to be used.
Embodiment 2
A kind of antimildew and antibacterial agent for improving solid wood furniture performance, is made in parts by weight of following component：Montmorillonite accounts for
55 parts, 30 parts of zeolite powder, 5.8 parts of nitric acid, 7.5 parts of neopelex, 11 parts of absolute ethyl alcohol, 5 parts of boric acid, 4 parts of urea,
3.8 parts of carboxymethyl chitosan, 2.3 parts of zinc chloride, 1.7 parts of calcium monohydrogen phosphate, 1.5 parts of silver nitrate, copper oxide 1.4, europium oxide 1.1
Part, 0.8 part of erbium oxide, 45 parts of dilute hydrochloric acid, 125 parts of deionized water；Its preparation method comprises the following steps：
（1）Montmorillonite is dissolved in deionized water, is heated to 55 DEG C, stirs 45 minutes, europium oxide and erbium oxide is added to
It is stirred 25 minutes in nitric acid and obtains clear solution, boric acid and urea are dissolved in absolute ethyl alcohol, be stirred continuously 35 minutes, it will
The montmorillonite solution of preparation is heated to 85 DEG C under water bath with thermostatic control, adds in the clear solution, when reaction 1.5 is small after, will prepare
Absolute ethyl alcohol mixed liquor be added in reaction system, reaction is to becoming faint yellow colloidal sol；
（2）Zeolite powder and calcium monohydrogen phosphate are added in dilute hydrochloric acid, stirred 18 minutes at 65 DEG C, add in silver nitrate, copper oxide,
Zinc chloride is stirred by ultrasonic 35 minutes, adds in carboxymethyl chitosan, is uniformly mixed, with step（1）What is be prepared is faint yellow
Colloidal sol mixes, and adds in neopelex, when standing curing 3.5 is small at 65 DEG C after being dispersed with stirring 18 minutes；
（3）Mixture after curing is transferred in Muffle furnace, combustion reaction, entire combustion reaction process are carried out at 530 DEG C
Continue 4 minutes, heat preservation is taken out after 11 minutes, is cooled down and is ground to particle size 400-500 mesh scope up to the antimildew and antibacterial
Agent.
It is further described as to said program, the concentration of nitric acid is 19 mol/Ls, and dilute hydrochloric acid concentration is rubbed for 0.25
You/liter.
It is further described as to said program, the silver nitrate, copper oxide, zinc chloride particle size are at 1-10 microns
Between.
It is further described as to said program, step（3）The Muffle furnace preheating temperature is 290 DEG C, preheating time
For 4 it is small when, heat temperature raising speed be 45 DEG C/h.
It is further described as to said program, the antimildew and antibacterial agent, which can be added in solid wood furniture coating, to be used.
Embodiment 3
A kind of antimildew and antibacterial agent for improving solid wood furniture performance, is made in parts by weight of following component：Montmorillonite accounts for
60 parts, 35 parts of zeolite powder, 6.0 parts of nitric acid, 8.0 parts of neopelex, 12 parts of absolute ethyl alcohol, 6 parts of boric acid, 5 parts of urea,
4.0 parts of carboxymethyl chitosan, 2.4 parts of zinc chloride, 1.8 parts of calcium monohydrogen phosphate, 1.6 parts of silver nitrate, copper oxide 1.5, europium oxide 1.2
Part, 1.0 parts of erbium oxide, 50 parts of dilute hydrochloric acid, 130 parts of deionized water；Its preparation method comprises the following steps：
（1）Montmorillonite is dissolved in deionized water, is heated to 60 DEG C, stirs 50 minutes, europium oxide and erbium oxide is added to
It is stirred 30 minutes in nitric acid and obtains clear solution, boric acid and urea are dissolved in absolute ethyl alcohol, be stirred continuously 40 minutes, it will
The montmorillonite solution of preparation is heated to 90 DEG C under water bath with thermostatic control, adds in the clear solution, when reaction 2 is small after, by preparation
Absolute ethyl alcohol mixed liquor is added in reaction system, and reaction is to becoming faint yellow colloidal sol；
（2）Zeolite powder and calcium monohydrogen phosphate are added in dilute hydrochloric acid, stirred 20 minutes at 70 DEG C, add in silver nitrate, copper oxide,
Zinc chloride is stirred by ultrasonic 40 minutes, adds in carboxymethyl chitosan, is uniformly mixed, with step（1）What is be prepared is faint yellow
Colloidal sol mix, add in neopelex, be dispersed with stirring after twenty minutes at 70 DEG C stand cure 4 it is small when；
（3）Mixture after curing is transferred in Muffle furnace, combustion reaction, entire combustion reaction process are carried out at 550 DEG C
Continue 5 minutes, heat preservation is taken out after 12 minutes, is cooled down and is ground to particle size 400-500 mesh scope up to the antimildew and antibacterial
Agent.
It is further described as to said program, the concentration of nitric acid is 20 mol/Ls, and dilute hydrochloric acid concentration is rubbed for 0.3
You/liter.
It is further described as to said program, the silver nitrate, copper oxide, zinc chloride particle size are at 1-10 microns
Between.
It is further described as to said program, step（3）The Muffle furnace preheating temperature is 300 DEG C, preheating time
For 5 it is small when, heat temperature raising speed be 50 DEG C/h.
It is further described as to said program, the antimildew and antibacterial agent, which can be added in solid wood furniture coating, to be used.
Claims (5)
1. a kind of antimildew and antibacterial agent for improving solid wood furniture performance, which is characterized in that in parts by weight by following component
It is made：Montmorillonite account for 50-60 parts, 25-35 parts of zeolite powder, 5.5-6.0 parts of nitric acid, 7.0-8.0 parts of neopelex, nothing
10-12 parts of water-ethanol, 4-6 parts of boric acid, 3-5 parts of urea, 3.5-4.0 parts of carboxymethyl chitosan, 2.2-2.4 parts of zinc chloride, phosphoric acid
1.6-1.8 parts of hydrogen calcium, 1.4-1.6 parts of silver nitrate, copper oxide 1.3-1.5,1.0-1.2 parts of europium oxide, 0.7-1.0 parts of erbium oxide,
40-50 parts of dilute hydrochloric acid, 120-130 parts of deionized water；Its preparation method comprises the following steps：
（1）Montmorillonite is dissolved in deionized water, is heated to 50-60 DEG C, is stirred 40-50 minutes, by europium oxide and erbium oxide
It is added to stir 20-30 minutes in nitric acid and obtains clear solution, boric acid and urea are dissolved in absolute ethyl alcohol, are stirred continuously
30-40 minutes, the montmorillonite solution of preparation is heated to 80-90 DEG C under water bath with thermostatic control, adds in the clear solution, reacts 1-
2 it is small when after, the absolute ethyl alcohol mixed liquor of preparation is added in reaction system, reaction is to becoming faint yellow colloidal sol；
（2）Zeolite powder and calcium monohydrogen phosphate are added in dilute hydrochloric acid, stirred 15-20 minutes at 60-70 DEG C, addition silver nitrate,
Copper oxide, zinc chloride are stirred by ultrasonic 30-40 minutes, add in carboxymethyl chitosan, are uniformly mixed, with step（1）It is prepared into
The faint yellow colloidal sol mixing arrived, adds in neopelex, is stood admittedly at 60-70 DEG C after being dispersed with stirring 15-20 minutes
When change 3-4 is small；
（3）Mixture after curing is transferred in Muffle furnace, combustion reaction, entire combustion reaction are carried out at 500-550 DEG C
Process continues 3-5 minutes, and heat preservation is taken out after 10-12 minutes, cools down and is ground to particle size 400-500 mesh scope up to described
Antimildew and antibacterial agent.
A kind of 2. antimildew and antibacterial agent for improving solid wood furniture performance as described in claim 1, which is characterized in that the nitric acid
Concentration is 18-20 mol/Ls, and dilute hydrochloric acid concentration is 0.2-0.3 mol/Ls.
A kind of 3. antimildew and antibacterial agent for improving solid wood furniture performance as described in claim 1, which is characterized in that the nitric acid
Silver, copper oxide, zinc chloride particle size are between 1-10 microns.
A kind of 4. antimildew and antibacterial agent for improving solid wood furniture performance as described in claim 1, which is characterized in that step（3）
The Muffle furnace preheating temperature is 280-300 DEG C, and when preheating time is 3-5 small, heat temperature raising speed is 40-50 DEG C/h.
5. a kind of antimildew and antibacterial agent for improving solid wood furniture performance as described in claim 1, which is characterized in that described mould proof
Antiseptic, which can be added in solid wood furniture coating, to be used.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711393447.XA CN108068186A (en) | 2017-12-21 | 2017-12-21 | A kind of antimildew and antibacterial agent for improving solid wood furniture performance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711393447.XA CN108068186A (en) | 2017-12-21 | 2017-12-21 | A kind of antimildew and antibacterial agent for improving solid wood furniture performance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108068186A true CN108068186A (en) | 2018-05-25 |
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| CN201711393447.XA Pending CN108068186A (en) | 2017-12-21 | 2017-12-21 | A kind of antimildew and antibacterial agent for improving solid wood furniture performance |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109169706A (en) * | 2018-07-19 | 2019-01-11 | 大美泰康（天津）生态科技有限公司 | Complex antimicrobials and antibacterial bacteriostatic type multifunctional inorganic ecologic coating obtained |
| CN110477522A (en) * | 2019-08-27 | 2019-11-22 | 广东溢达纺织有限公司 | Shellfish material and preparation method thereof and shell button |
| CN116212088A (en) * | 2023-05-09 | 2023-06-06 | 天津包钢稀土研究院有限责任公司 | Rare earth metal-based antibacterial bandage and preparation method thereof |
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| CN105176124A (en) * | 2015-09-17 | 2015-12-23 | 安徽温禾新材料科技股份有限公司 | Mouldproof additive used for processing wood-plastic floors |
| CN106188653A (en) * | 2016-08-29 | 2016-12-07 | 桂林舒康建材有限公司 | A kind of Novel wood-plastic composite material antibacterial and preparation method thereof |
| CN106280797A (en) * | 2016-08-17 | 2017-01-04 | 瑞安市智造科技有限公司 | A kind of antibiotic fungus-resisting paint |
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| CN1974151A (en) * | 2005-11-25 | 2007-06-06 | 北京林业大学 | Nanometer intercalated timber/montmorillonite composite material and its production process |
| CN101524635A (en) * | 2009-03-28 | 2009-09-09 | 大连理工大学 | Method for preparing chitosan/organo montmorillonite nanometer composite material |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109169706A (en) * | 2018-07-19 | 2019-01-11 | 大美泰康（天津）生态科技有限公司 | Complex antimicrobials and antibacterial bacteriostatic type multifunctional inorganic ecologic coating obtained |
| CN110477522A (en) * | 2019-08-27 | 2019-11-22 | 广东溢达纺织有限公司 | Shellfish material and preparation method thereof and shell button |
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Application publication date: 20180525 |