CN108048711A - A kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions and preparation method thereof - Google Patents

A kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions and preparation method thereof Download PDF

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Publication number
CN108048711A
CN108048711A CN201711466504.2A CN201711466504A CN108048711A CN 108048711 A CN108048711 A CN 108048711A CN 201711466504 A CN201711466504 A CN 201711466504A CN 108048711 A CN108048711 A CN 108048711A
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aluminium alloy
alloy extrusions
speed
warming
strength corrosion
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唐开健
陈未荣
王超
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Anhui Xin Platinum Aluminum Co Ltd
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Anhui Xin Platinum Aluminum Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Extrusion Of Metal (AREA)

Abstract

The invention discloses a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions and preparation method thereof, are related to technical field of aluminum alloy technology, and the aluminium alloy extrusions includes following component by weight percent:Cu 0.35 0.5%, Si 0.2 0.3%, Fe 0.15 0.3%, Cr 0.16 0.24%, Mg 0.5 0.8%, Mn 0.32 0.48%, Zn 0.2 0.5%, Ti 0.08 0.15%, Li 0.02 0.05%, Ni 0.03 0.08%, Nb 0.06 0.12%, Ca 0.05 0.1%, Sc 0.04 0.08%, surplus Al.Each element and its content in reasonably optimizing aluminium alloy extrusions of the present invention, and preparation process is optimized, the aluminium alloy extrusions mechanical performance of preparation is excellent, and intensity is high, good corrosion resistance, disclosure satisfy that the performance requirement of high ferro aluminium alloy extrusions.

Description

A kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions and preparation method thereof
Technical field
The present invention relates to technical field of aluminum alloy technology more particularly to a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions and its preparations Method.
Background technology
In recent years, high ferro technology has very extensive application in China.Since the density of aluminium alloy is relatively low, and with compared with High intensity, therefore, aluminium alloy are that high ferro realizes the best material of lightweight, and mitigation high ferro that can be very big using aluminium alloy arranges The dead weight of vehicle.Since high ferro locomotive is chronically exposed in air, and travel speed is very fast, it is necessary to work long hours, this is just to height Tensile strength, fatigue strength, elongation percentage, corrosion resistance and welding performance of iron aluminum alloy materials etc. have higher want It asks.The prior art mainly using 5083 aluminium alloy extrusions manufacture high ferro, but there are fatigue strength is low, tensile strength is uneven, Elongation percentage is low, corrosion resistance is low, the problems such as, cannot still fully meet the performance requirement of high ferro plate.
The content of the invention
Technical problems based on background technology, the present invention propose a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions and Its preparation method.
A kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions proposed by the present invention, the aluminium alloy extrusions wrap by weight percent Include following component:Cu 0.35-0.5%, Si 0.2-0.3%, Fe 0.15-0.3%, Cr 0.16-0.24%, Mg 0.5- 0.8%th, Mn 0.32-0.48%, Zn 0.2-0.5%, Ti 0.08-0.15%, Li 0.02-0.05%, Ni 0.03- 0.08%th, Nb 0.06-0.12%, Ca 0.05-0.1%, Sc 0.04-0.08%, surplus Al.
Preferably, the aluminium alloy extrusions includes following component by weight percent:Cu 0.42-0.46%, Si 0.23- 0.27%th, Fe 0.24-0.28%, Cr 0.18-0.22%, Mg 0.68-0.74%, Mn 0.37-0.42%, Zn 0.34- 0.39%th, Ti 0.1-0.12%, Li 0.03-0.05%, Ni 0.04-0.06%, Nb 0.08-0.1%, Ca 0.07- 0.09%th, Sc 0.05-0.07%, surplus Al.
Preferably, Ti, Nb, Sc meet relational expression:0.7≤Ti/(Nb+Sc)≤0.8.
The present invention also proposes the preparation method of above-mentioned high ferro high-strength corrosion-resistant aluminium alloy extrusions, comprises the following steps:
S1, commercial-purity aluminium, various intermediate alloys are subjected to dispensing, melting, ingot casting of casting to obtain;
S2, ingot casting is placed in heating furnace, carries out Homogenization Treatments, 300-320 is first warming up to the speed of 110 DEG C/h DEG C, 1-2h is kept the temperature, then 440-460 DEG C is warming up to the speed of 90 DEG C/h, 1-2h is kept the temperature, then is warming up to the speed of 70 DEG C/h 540-560 DEG C, 2-3h is kept the temperature, is taken out, water spray is chilled to room temperature;
S3, the ingot casting after Homogenization Treatments is warming up to 480-500 DEG C with the speed of 80 DEG C/h, extrusion forming;
Then S4, the section bar blank air-blast quenching by extrusion forming carry out ageing treatment, first with the speed of 50-70 DEG C/h 140-160 DEG C is warming up to, keeps the temperature 1-2h, then 190-200 DEG C is warming up to 90-100 DEG C of speed, keeps the temperature 4-6h, furnace cooling To 170-180 DEG C, then come out of the stove and be air-cooled to room temperature.
Preferably, in the S2, cooling rate is 40-50 DEG C/min.
Preferably, in the S3, extrusion speed 50-60m/min.
Advantageous effect:The present invention is formed by controlling the content of Zn, Mg, Cu, Si in aluminium alloy in aluminium alloy Al2Cu、Al2CuMg、Mg2Si、MgZn2Hardening constituents, each hardening constituent synergistic effect are waited, crystallization of refinement plays aluminium alloy apparent strong Change acts on, and improves the mechanical properties such as tensile strength, yield strength, hardness, the toughness of aluminium alloy extrusions;Ca, Si, Ti, Nb, Sc are thin Change crystal grain, refine the effect of cast sturcture and seam organization, improve recrystallization temperature, the thermal stability of reinforcing material avoids crystalline substance Between corrode, improve its corrosive nature, reduce cracking sensitivity Fe, Li, Cr, Mn, Ni cooperation, further improve aluminium alloy extrusions Hardness, intensity and fatigue performance;In preparation process, Homogenization Treatments are carried out to aluminium alloy cast ingot, are first rapidly heated, gradual Heating rate is reduced, improves diffusion, thinning microstructure prevents burning, improves its homogenization of composition degree, then through being squeezed into After type, ageing treatment, further improve the interior tissue uniformity of aluminium alloy extrusions, crystal grain thinning, and then improve aluminium alloy type The comprehensive mechanical property of material, the aluminium alloy extrusions mechanical performance of preparation is excellent, has good intensity, hardness and corrosion resistance, And good processing performance, it disclosure satisfy that the performance requirement of high ferro aluminium alloy extrusions.
Specific embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
The present invention proposes a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions, and the aluminium alloy extrusions includes by weight percent Following component:Cu 0.35%, Si 0.2%, Fe 0.15%, Cr 0.16%, Mg 0.5%, Mn 0.32%, Zn 0.2%, Ti 0.08%, Li 0.02%, Ni 0.03%, Nb 0.06%, Ca 0.05%, Sc 0.04%, surplus Al.
The present invention also proposes the preparation method of above-mentioned high ferro high-strength corrosion-resistant aluminium alloy extrusions, comprises the following steps:
S1, commercial-purity aluminium, various intermediate alloys are subjected to dispensing, melting, ingot casting of casting to obtain;
S2, ingot casting is placed in heating furnace, carries out Homogenization Treatments, be first warming up to 300 DEG C with the speed of 110 DEG C/h, protect Warm 1h, then 440 DEG C are warming up to the speed of 90 DEG C/h, 1h is kept the temperature, then 540 DEG C are warming up to the speed of 70 DEG C/h, 2h is kept the temperature, is taken Go out, water spray is chilled to room temperature;
S3, the ingot casting after Homogenization Treatments is warming up to 480 DEG C with the speed of 80 DEG C/h, extrusion forming;
Then S4, the section bar blank air-blast quenching by extrusion forming are carried out ageing treatment, are first heated up with the speed of 50 DEG C/h To 140 DEG C, 1h is kept the temperature, then 190 DEG C are warming up to 90 DEG C of speed, 4h is kept the temperature, cools to 170 DEG C with the furnace, then come out of the stove and be air-cooled to Room temperature.
Embodiment 2
The present invention proposes a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions, and the aluminium alloy extrusions includes by weight percent Following component:Cu 0.42%, Si 0.23%, Fe 0.24%, Cr 0.18%, Mg 0.68%, Mn 0.37%, Zn 0.34%th, Ti 0.1%, Li 0.03%, Ni 0.04%, Nb 0.08%, Ca 0.07%, Sc 0.05%, surplus Al.
The present invention also proposes the preparation method of above-mentioned high ferro high-strength corrosion-resistant aluminium alloy extrusions, comprises the following steps:
S1, commercial-purity aluminium, various intermediate alloys are subjected to dispensing, melting, ingot casting of casting to obtain;
S2, ingot casting is placed in heating furnace, carries out Homogenization Treatments, be first warming up to 305 DEG C with the speed of 110 DEG C/h, protect Warm 1h, then 445 DEG C are warming up to the speed of 90 DEG C/h, 1h is kept the temperature, then 545 DEG C are warming up to the speed of 70 DEG C/h, 2h is kept the temperature, is taken Go out, water spray is chilled to room temperature, and cooling rate is 40 DEG C/min;
S3, the ingot casting after Homogenization Treatments is warming up to 485 DEG C with the speed of 80 DEG C/h, extrusion forming, extrusion speed is 50m/min;
Then S4, the section bar blank air-blast quenching by extrusion forming are carried out ageing treatment, are first heated up with the speed of 55 DEG C/h To 145 DEG C, 1h is kept the temperature, then 195 DEG C are warming up to 95 DEG C of speed, 4h is kept the temperature, cools to 170 DEG C with the furnace, then come out of the stove and be air-cooled to Room temperature.
Embodiment 3
The present invention proposes a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions, and the aluminium alloy extrusions includes by weight percent Following component:Cu 0.4%, Si 0.25%, Fe 0.22%, Cr 0.2%, Mg 0.65%, Mn 0.42%, Zn 0.38%, Ti 0.12%, Li 0.04%, Ni 0.06%, Nb 0.09%, Ca 0.08%, Sc 0.06%, surplus Al.
The present invention also proposes the preparation method of above-mentioned high ferro high-strength corrosion-resistant aluminium alloy extrusions, comprises the following steps:
S1, commercial-purity aluminium, various intermediate alloys are subjected to dispensing, melting, ingot casting of casting to obtain;
S2, ingot casting is placed in heating furnace, carries out Homogenization Treatments, be first warming up to 310 DEG C with the speed of 110 DEG C/h, protect Warm 1.5h, then 450 DEG C are warming up to the speed of 90 DEG C/h, 1.5h is kept the temperature, then 550 DEG C are warming up to the speed of 70 DEG C/h, heat preservation 2.5h takes out, and water spray is chilled to room temperature, and cooling rate is 44 DEG C/min;
S3, the ingot casting after Homogenization Treatments is warming up to 490 DEG C with the speed of 80 DEG C/h, extrusion forming, extrusion speed is 54m/min;
Then S4, the section bar blank air-blast quenching by extrusion forming are carried out ageing treatment, are first heated up with the speed of 60 DEG C/h To 150 DEG C, 1.5h is kept the temperature, then 1950 DEG C are warming up to 95 DEG C of speed, 5h is kept the temperature, cools to 175 DEG C with the furnace, then come out of the stove air-cooled To room temperature.
Embodiment 4
The present invention proposes a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions, and the aluminium alloy extrusions includes by weight percent Following component:Cu 0.46%, Si 0.27%, Fe 0.28%, Cr 0.22%, Mg 0.74%, Mn 0.42%, Zn 0.39%th, Ti 0.12%, Li 0.05%, Ni 0.06%, Nb 0.1%, Ca 0.09%, Sc 0.07%, surplus Al.
The present invention also proposes the preparation method of above-mentioned high ferro high-strength corrosion-resistant aluminium alloy extrusions, comprises the following steps:
S1, commercial-purity aluminium, various intermediate alloys are subjected to dispensing, melting, ingot casting of casting to obtain;
S2, ingot casting is placed in heating furnace, carries out Homogenization Treatments, be first warming up to 315 DEG C with the speed of 110 DEG C/h, protect Warm 1h, then 455 DEG C are warming up to the speed of 90 DEG C/h, 1.5h is kept the temperature, then 550 DEG C are warming up to the speed of 70 DEG C/h, heat preservation 2.5h takes out, and water spray is chilled to room temperature, and cooling rate is 47 DEG C/min;
S3, the ingot casting after Homogenization Treatments is warming up to 490 DEG C with the speed of 80 DEG C/h, extrusion forming, extrusion speed is 58m/min;
Then S4, the section bar blank air-blast quenching by extrusion forming are carried out ageing treatment, are first heated up with the speed of 65 DEG C/h To 155 DEG C, 1.5h is kept the temperature, then 195 DEG C are warming up to 95 DEG C of speed, 5h is kept the temperature, cools to 170 DEG C with the furnace, then come out of the stove air-cooled To room temperature.
Embodiment 5
The present invention proposes a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions, and the aluminium alloy extrusions includes by weight percent Following component:Cu 0.5%, Si 0.3%, Fe 0.3%, Cr 0.24%, Mg 0.8%, Mn 0.48%, Zn 0.5%, Ti 0.15%th, Li 0.05%, Ni 0.08%, Nb 0.12%, Ca 0.1%, Sc 0.08%, surplus Al.
The present invention also proposes the preparation method of above-mentioned high ferro high-strength corrosion-resistant aluminium alloy extrusions, comprises the following steps:
S1, commercial-purity aluminium, various intermediate alloys are subjected to dispensing, melting, ingot casting of casting to obtain;
S2, ingot casting is placed in heating furnace, carries out Homogenization Treatments, be first warming up to 320 DEG C with the speed of 110 DEG C/h, protect Warm 2h, then 460 DEG C are warming up to the speed of 90 DEG C/h, 2h is kept the temperature, then 560 DEG C are warming up to the speed of 70 DEG C/h, 3h is kept the temperature, is taken Go out, water spray is chilled to room temperature, and cooling rate is 50 DEG C/min;
S3, the ingot casting after Homogenization Treatments is warming up to 500 DEG C with the speed of 80 DEG C/h, extrusion forming, extrusion speed is 60m/min;
Then S4, the section bar blank air-blast quenching by extrusion forming are carried out ageing treatment, are first heated up with the speed of 70 DEG C/h To 160 DEG C, 2h is kept the temperature, then 200 DEG C are warming up to 100 DEG C of speed, 6h is kept the temperature, cools to 180 DEG C with the furnace, then come out of the stove and be air-cooled to Room temperature.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (6)

1. a kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions, which is characterized in that the aluminium alloy extrusions includes by weight percent Following component:Cu 0.35-0.5%, Si 0.2-0.3%, Fe 0.15-0.3%, Cr 0.16-0.24%, Mg 0.5- 0.8%th, Mn 0.32-0.48%, Zn 0.2-0.5%, Ti 0.08-0.15%, Li 0.02-0.05%, Ni 0.03- 0.08%th, Nb 0.06-0.12%, Ca 0.05-0.1%, Sc 0.04-0.08%, surplus Al.
2. high ferro according to claim 1 high-strength corrosion-resistant aluminium alloy extrusions, which is characterized in that the aluminium alloy extrusions is pressed Mass percent includes following component:Cu 0.42-0.46%, Si 0.23-0.27%, Fe 0.24-0.28%, Cr 0.18- 0.22%th, Mg 0.68-0.74%, Mn 0.37-0.42%, Zn 0.34-0.39%, Ti 0.1-0.12%, Li 0.03- 0.05%th, Ni 0.04-0.06%, Nb 0.08-0.1%, Ca 0.07-0.09%, Sc 0.05-0.07%, surplus Al.
3. high ferro according to claim 1 or 2 high-strength corrosion-resistant aluminium alloy extrusions, which is characterized in that Ti, Nb, Sc's expires Sufficient relational expression:0.7≤Ti/(Nb+Sc)≤0.8.
It is 4. a kind of based on any high ferro preparation methods of high-strength corrosion-resistant aluminium alloy extrusions of claim 1-3, feature It is, comprises the following steps:
S1, commercial-purity aluminium, various intermediate alloys are subjected to dispensing, melting, ingot casting of casting to obtain;
S2, ingot casting is placed in heating furnace, carries out Homogenization Treatments, be first warming up to 300-320 DEG C with the speed of 110 DEG C/h, protect Warm 1-2h, then 440-460 DEG C is warming up to the speed of 90 DEG C/h, 1-2h is kept the temperature, then 540-560 is warming up to the speed of 70 DEG C/h DEG C, 2-3h is kept the temperature, is taken out, water spray is chilled to room temperature;
S3, the ingot casting after Homogenization Treatments is warming up to 480-500 DEG C with the speed of 80 DEG C/h, extrusion forming;
Then S4, the section bar blank air-blast quenching by extrusion forming are carried out ageing treatment, are first heated up with the speed of 50-70 DEG C/h To 140-160 DEG C, 1-2h is kept the temperature, then 190-200 DEG C is warming up to 90-100 DEG C of speed, 4-6h is kept the temperature, cools to the furnace 170-180 DEG C, then come out of the stove and be air-cooled to room temperature.
5. the high ferro according to claim 4 preparation method of high-strength corrosion-resistant aluminium alloy extrusions, which is characterized in that the S2 In, cooling rate is 40-50 DEG C/min.
6. the high ferro according to claim 4 preparation method of high-strength corrosion-resistant aluminium alloy extrusions, which is characterized in that the S3 In, extrusion speed 50-60m/min.
CN201711466504.2A 2017-12-28 2017-12-28 A kind of high ferro high-strength corrosion-resistant aluminium alloy extrusions and preparation method thereof Pending CN108048711A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111575558A (en) * 2020-07-07 2020-08-25 福建祥鑫股份有限公司 Heat treatment method of high-strength corrosion-resistant 6-series aluminum alloy

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105220034A (en) * 2014-05-30 2016-01-06 安徽鑫发铝业有限公司 Anodized aluminum alloy section bar closed by a kind of nickel salt
CN106244874A (en) * 2016-08-27 2016-12-21 来安县科来兴实业有限责任公司 A kind of special heat-resisting aluminium alloy of EMU gear case body and preparation method thereof
CN106435302A (en) * 2016-11-28 2017-02-22 安徽省煜灿新型材料科技有限公司 Corrosion-resistant high-temperature-resistant aluminum alloy sectional material and preparing method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105220034A (en) * 2014-05-30 2016-01-06 安徽鑫发铝业有限公司 Anodized aluminum alloy section bar closed by a kind of nickel salt
CN106244874A (en) * 2016-08-27 2016-12-21 来安县科来兴实业有限责任公司 A kind of special heat-resisting aluminium alloy of EMU gear case body and preparation method thereof
CN106435302A (en) * 2016-11-28 2017-02-22 安徽省煜灿新型材料科技有限公司 Corrosion-resistant high-temperature-resistant aluminum alloy sectional material and preparing method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111575558A (en) * 2020-07-07 2020-08-25 福建祥鑫股份有限公司 Heat treatment method of high-strength corrosion-resistant 6-series aluminum alloy
CN111575558B (en) * 2020-07-07 2021-04-06 福建祥鑫股份有限公司 Heat treatment method of high-strength corrosion-resistant 6-series aluminum alloy

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