CN108048255A - A kind of ageing oil cleaning agent and preparation method thereof - Google Patents
A kind of ageing oil cleaning agent and preparation method thereof Download PDFInfo
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- CN108048255A CN108048255A CN201711463608.8A CN201711463608A CN108048255A CN 108048255 A CN108048255 A CN 108048255A CN 201711463608 A CN201711463608 A CN 201711463608A CN 108048255 A CN108048255 A CN 108048255A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
- C11D1/945—Mixtures with anionic, cationic or non-ionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/08—Silicates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1213—Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2072—Aldehydes-ketones
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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Abstract
The invention discloses a kind of ageing oil cleaning agent, include the raw material of following parts by weight：32 36 parts of polyoxyethylene polyoxypropylene polyethers, 24 26 parts of polyethylene polyamine, 12 16 parts of oxalic acid, 48 parts of titanium dioxide powder, 48 parts of silicon dioxide powder, 35 parts of solvent, 13 parts of auxiliary agent, 12 parts of surfactant, 12 parts of plants essential oil；Polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, surfactant, the mass ratio of substance is (4~6)：(3~4)：(1~2)：1.The object of the present invention is to provide a kind of ageing oil cleaning agent, the cleaning agent is apparent with fragrance, demulsification, and cleaning performance is good, has higher practical value and good application prospect.
Description
Technical field
The present invention relates to ageing oil cleaning technique fields, and in particular to a kind of ageing oil cleaning agent and preparation method thereof.
Background technology
Ageing oil refers in crude oil production, processing procedure, in medicament, mechanical admixture, gum asphalt, bacterium, air, follows
It is formed under the action of the factors such as ring shearing, at present main three aspects in country ageing oil source, first, from sewage plant sewage
Buffering settling tank or inclined plate oil removing pot store the ageing oil of formation for a long time after suspension oil-collecting, and 20 dehydration settling tank dynamics are broken
During breast, the substance of different specific weight automatically forms each node layer in oil product, and a portion substance is than dense media in oil-water ratio
Weight between, through a long time add up and oil-water interfaces formed intermediate zone, aging oil reservoir thicken will destroy to a certain extent it is dynamic
State balances, and it is unusual dehydration occur；Ageing oil complicated component, stability is strong, and high risks and hidden danger are brought to production, first, increasing
Add the load of pump, pipeline and storage tank, cause corrosion and fouling, second is that tripping or directly contributing easily occur in electric dehydrator
The production accidents such as electric dehydrator pole plate breakdown, shorten service life of equipment, are set third, a large amount of ageing oils occupy to handle using liquid
Standby space, reduces treating capacity.
Traditional ageing oil processing means using centrifuge, heat chemistry settling method, effect be not it is fine, it is existing in addition
Ageing oil cleaning agent cleaning effect is undesirable, reduces work efficiency.
The content of the invention
It is an object of the invention to provide a kind of ageing oil cleaning agent and preparation method thereof, to solve in above-mentioned background technology
The problem of proposition.
To achieve the above object, the present invention provides following technical solution：
A kind of ageing oil cleaning agent, which is characterized in that include the raw material of following parts by weight：
32-36 parts of polyoxyethylene polyoxypropylene polyethers, 24-26 parts of polyethylene polyamine, 12-16 parts of oxalic acid, titanium dioxide powder
4-8 parts, 4-8 parts of silicon dioxide powder, 3-5 parts of solvent, 1-3 parts of auxiliary agent, 1-2 parts of surfactant, 1-2 parts of polyoxy second of plants essential oil
Alkene polyoxypropylene polyether；Polyethylene polyamine, solvent, surfactant, the mass ratio of substance is (4~6)：(3~4)：(1~2)：
1。
It is as further scheme of the invention：The ageing oil cleaning agent includes the raw material of following parts by weight：
34 parts of polyoxyethylene polyoxypropylene polyethers, 25 parts of polyethylene polyamine, 14 parts of oxalic acid, 6 parts of titanium dioxide powder, titanium dioxide
6 parts of silica flour, 4 parts of solvent, 2 parts of auxiliary agent, 1.5 parts of surfactant, 1.5 parts of plants essential oil；It is polyoxyethylene polyoxypropylene polyethers, more
Ethylene polyamine, solvent, surfactant, the mass ratio of substance is 5：3.5：1.5：1.
It is as further scheme of the invention：The solvent is methanol, in ethyl alcohol, espeleton, methylisobutylketone
One or more combinations.
It is as further scheme of the invention：The auxiliary agent is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, poly- silicon
Sour ferric aluminium sulfate, according to weight ratio 1:3:The mixture of 2 compositions.
It is as further scheme of the invention：The surfactant is Octoxinol, N- dodecyl-B- aminopropans
Sour sodium, according to weight ratio 1:The mixture of 2 compositions.
It is as further scheme of the invention：The plants essential oil is Rosa Damascana, lemon, orange essential oil, osmanthus
One or more combinations in flower essential oil and illawarra mountain pine essential oil.
A kind of preparation method of ageing oil cleaning agent, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1800-1900r/min, mixing time 1-2h, obtains mixture A, then will
Mixture A is added in reaction kettle, is reacted 45-55min in the case where temperature is 155-165 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 10-12 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1100-1200r/min, mixing time,
40-50 minutes, then add mixture in reaction kettle, 1-2h is reacted in the case where temperature is 175-185 DEG C, the aging of invention is made
Oily cleaning agent.
It is as further scheme of the invention：The preparation process of the ageing oil cleaning agent is：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1850r/min, mixing time 1.5h, obtains mixture A, then will mixing
Object A is added in reaction kettle, is reacted 50min in the case where temperature is 160 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 11 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1150r/min, mixing time, 45 points
Clock, then add mixture in reaction kettle, 1.5h is reacted in the case where temperature is 180 DEG C, the ageing oil cleaning agent of invention is made.
Compared with prior art, the present invention has following advantageous effect：
The ageing oil cleaning agent of the present invention adds in oxalic acid and pH is adjusted to acidity, dissolves ferrous contaminants, the polyoxy second of addition
Alkene polyoxypropylene polyether, polyethylene polyamine are as initiator, molecular structural formula：Polyethylene polyamine (polyoxypropylene) x (polyoxy second
Alkene) yH, x, y are the degree of polymerization, are a kind of polymer of two segment types, molecule is small, and branch is short, and ageing oil interfacial film is adsorbed and emulsified
The naturally occurring emulsifying agent of property makes to form mutual pulling force in interfacial film between oil and water, and then forms the table of oil-water interfacial film
Face tension, it is extremely slow because of high-strength interfaces shear viscosity during droplet coalescence in oil-water interfacial film, inhibit interface
Film drainage efficiency hinders oil in ageing oil to be separated with water, the polyoxyethylene polyoxypropylene polyethers of addition, and polyethylene polyamine, which is used as, to be drawn
Agent is sent out, forms polyethylene polyamine polyoxyethylene polyoxypropylene polyethers, in the case where solvent is assisted for methanol, polyethylene polyamine polyoxyethylene
Polar molecule in polyoxypropylene polyether is dissolved in solvent, and nonpolar molecule is dissolved in ageing oil oil reservoir, makes to produce in oil-water interfacial film
Raw polar molecule and nonpolar molecule align, and the relative tension of oil and water are formed, by the surface for reducing oil-water interfacial film
Tension generates demulsification, while surfactant is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2 groups
It closes, the two cooperates, and plays synergistic effect, effect is best, and N- dodecyl-B- alanine sodium is a kind of both sexes table
Face activating agent, anion and cation group with hydroxyl, not only has the advantages that all of amphoteric surfactant, also has
Good emulsibility, dispersiveness, surfactant of the Octoxinol as auxiliary, with N- dodecyl-B- alanine sodium phases
It is molten, when Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2 combination when, make polar molecule be dissolved in solvent,
Nonpolar molecule is dissolved in ageing oil oil reservoir degree maximum, causes the relative tension of oil and water maximum, reduces grease to the greatest extent
The surface tension of interfacial film, demulsification is best, and titanium dioxide powder, the silicon dioxide powder grain size added in addition is small, specific surface area
Greatly, stability is good, there is very strong affinity in polar group, forms titanium dioxide powder, silica powder is gathered in polar group
Around group, a greater degree of surface tension for reducing oil-water interfacial film, demulsification further improves, and has reached cleaning effect
Fruit, the plants essential oil of addition have fragrance, improve cleaning agent smell；By changing polyethylene polyamine, solvent, surfactant,
The mass ratio of substance, is dissolved in solvent probing into polar molecule, nonpolar molecule is dissolved in ageing oil oil reservoir effect, so as to probe into brokenly
Newborn optimum efficiency, then realizes optimal cleaning effect.
Specific embodiment
With reference to specific embodiment, the technical solution in the embodiment of the present invention is clearly and completely described, is shown
So, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based on the reality in the present invention
Apply example, those of ordinary skill in the art's all other embodiments obtained without making creative work all belong to
In the scope of protection of the invention.
Embodiment 1：
A kind of ageing oil cleaning agent of the present embodiment includes the raw material of following parts by weight：
32 parts of polyoxyethylene polyoxypropylene polyethers, 24 parts of polyethylene polyamine, 12 parts of oxalic acid, 4 parts of titanium dioxide powder, titanium dioxide
4 parts of silica flour, 3 parts of solvent, 1 part of auxiliary agent, 1 part of surfactant, 1 part of plants essential oil；Polyethylene polyamine, solvent, surfactant
The mass ratio of substance is 4：3：1：1.
The solvent of the present embodiment is methanol.
The auxiliary agent of the present embodiment is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight
Than 1:3:The mixture of 2 compositions.
The surfactant of the present embodiment is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2
The mixture of composition.
The plants essential oil of the present embodiment is Rosa Damascana.
A kind of preparation method of ageing oil cleaning agent of the present embodiment, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1800r/min, mixing time 1h, obtains mixture A, then by mixture A
It is added in reaction kettle, reacts 45min in the case where temperature is 155 DEG C, obtain mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 10 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1100r/min, mixing time, 40 points
Clock, then add mixture in reaction kettle, 1h is reacted in the case where temperature is 175 DEG C, the ageing oil cleaning agent of invention is made.
Embodiment 2：
A kind of ageing oil cleaning agent of the present embodiment includes the raw material of following parts by weight：
36 parts of polyoxyethylene polyoxypropylene polyethers, 26 parts of polyethylene polyamine, 16 parts of oxalic acid, 8 parts of titanium dioxide powder, titanium dioxide
8 parts of silica flour, 5 parts of solvent, 3 parts of auxiliary agent, 2 parts of surfactant, 2 parts of plants essential oil；Polyethylene polyamine, solvent, surfactant
The mass ratio of substance is 6：4：2：1.
The solvent of the present embodiment is ethyl alcohol.
The auxiliary agent of the present embodiment is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight
Than 1:3:The mixture of 2 compositions.
The surfactant of the present embodiment is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2
The mixture of composition.
The plants essential oil of the present embodiment is lemon.
A kind of preparation method of ageing oil cleaning agent of the present embodiment, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1900r/min, mixing time 2h, obtains mixture A, then by mixture A
It is added in reaction kettle, reacts 55min in the case where temperature is 165 DEG C, obtain mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 12 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1200r/min, mixing time, 50 points
Clock, then add mixture in reaction kettle, 2h is reacted in the case where temperature is 185 DEG C, the ageing oil cleaning agent of invention is made.
Embodiment 3：
A kind of ageing oil cleaning agent of the present embodiment includes the raw material of following parts by weight：
34 parts of polyoxyethylene polyoxypropylene polyethers, 25 parts of polyethylene polyamine, 14 parts of oxalic acid, 6 parts of titanium dioxide powder, titanium dioxide
6 parts of silica flour, 4 parts of solvent, 2 parts of auxiliary agent, 1.5 parts of surfactant, 1.5 parts of plants essential oil；Polyethylene polyamine, solvent, surface are lived
Property agent substance mass ratio be 5：3.5：1.5：1.
The solvent of the present embodiment is espeleton.
The auxiliary agent of the present embodiment is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight
Than 1:3:The mixture of 2 compositions.
The surfactant of the present embodiment is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2
The mixture of composition.
The plants essential oil of the present embodiment is orange essential oil.
A kind of preparation method of ageing oil cleaning agent of the present embodiment, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1850r/min, mixing time 1.5h, obtains mixture A, then will mixing
Object A is added in reaction kettle, is reacted 50min in the case where temperature is 160 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 11 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1150r/min, mixing time, 45 points
Clock, then add mixture in reaction kettle, 1.5h is reacted in the case where temperature is 180 DEG C, the ageing oil cleaning agent of invention is made.
Embodiment 4：
A kind of ageing oil cleaning agent of the present embodiment includes the raw material of following parts by weight：
34 parts of polyoxyethylene polyoxypropylene polyethers, 25 parts of polyethylene polyamine, 14 parts of oxalic acid, 6 parts of titanium dioxide powder, titanium dioxide
6 parts of silica flour, 4 parts of solvent, 2 parts of auxiliary agent, 1.5 parts of surfactant, 1.5 parts of plants essential oil；Polyethylene polyamine, solvent, surface are lived
Property agent substance mass ratio be 4.5：3.5：1.5：1.
The solvent of the present embodiment is espeleton.
The auxiliary agent of the present embodiment is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight
Than 1:3:The mixture of 2 compositions.
The surfactant of the present embodiment is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2
The mixture of composition.
The plants essential oil of the present embodiment is orange essential oil.
A kind of preparation method of ageing oil cleaning agent of the present embodiment, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1850r/min, mixing time 1.5h, obtains mixture A, then will mixing
Object A is added in reaction kettle, is reacted 50min in the case where temperature is 160 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 11 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1150r/min, mixing time, 45 points
Clock, then add mixture in reaction kettle, 1.5h is reacted in the case where temperature is 180 DEG C, the ageing oil cleaning agent of invention is made.
Embodiment 5：
A kind of ageing oil cleaning agent of the present embodiment includes the raw material of following parts by weight：
34 parts of ethylene oxide polyoxypropylene polyether, 25 parts of polyethylene polyamine, 14 parts of oxalic acid, 6 parts of titanium dioxide powder, silica
6 parts of powder, 4 parts of solvent, 2 parts of auxiliary agent, 1.5 parts of surfactant, 1.5 parts of plants essential oil；Polyethylene polyamine, solvent, surface-active
The mass ratio of agent substance is 4：3：1：1.
The solvent of the present embodiment is espeleton.
The auxiliary agent of the present embodiment is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight
Than 1:3:The mixture of 2 compositions.
The surfactant of the present embodiment is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2
The mixture of composition.
The plants essential oil of the present embodiment is orange essential oil.
A kind of preparation method of ageing oil cleaning agent of the present embodiment, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1850r/min, mixing time 1.5h, obtains mixture A, then will mixing
Object A is added in reaction kettle, is reacted 50min in the case where temperature is 160 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 11 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1150r/min, mixing time, 45 points
Clock, then add mixture in reaction kettle, 1.5h is reacted in the case where temperature is 180 DEG C, the ageing oil cleaning agent of invention is made.
Comparative example 1：
A kind of ageing oil cleaning agent of the present embodiment includes the raw material of following parts by weight：
34 parts of ethylene oxide polyoxypropylene polyether, 25 parts of polyethylene polyamine, 14 parts of oxalic acid, 6 parts of titanium dioxide powder, silica
6 parts of powder, 4 parts of solvent, 2 parts of auxiliary agent, 1.5 parts of surfactant, 1.5 parts of plants essential oil；Polyethylene polyamine, solvent, surface-active
The mass ratio of agent substance is 4：3：1：1.
The solvent of the present embodiment is espeleton.
The auxiliary agent of the present embodiment is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight
Than 1:3:The mixture of 2 compositions.
The surfactant of the present embodiment is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2
The mixture of composition.
The plants essential oil of the present embodiment is orange essential oil.
A kind of preparation method of ageing oil cleaning agent of the present embodiment, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1850r/min, mixing time 1.5h, obtains mixture A, then will mixing
Object A is added in reaction kettle, is reacted 50min in the case where temperature is 160 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 11 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1150r/min, mixing time, 45 points
Clock, then add mixture in reaction kettle, 1.5h is reacted in the case where temperature is 180 DEG C, the ageing oil cleaning agent of invention is made.
Embodiment 3 to 5 and comparative example 1 keep other amounts constant, change polyethylene polyamine, solvent, surfactant, substance
Mass ratio variation prepare invention ageing oil cleaning agent the performance test results it is as follows
| Disengaging time | Separation situation | Water in oil (%) | |
| Embodiment 3 | 36min | Interface is clear | 5.3 |
| Embodiment 4 | 45min | Interface is clear | 5.8 |
| Embodiment 5 | 41min | Interface is clear | 4.5 |
| Comparative example 1 | 56min | Interface is more visible | 6.8 |
Comparative example 2：
A kind of ageing oil cleaning agent of the present embodiment includes the raw material of following parts by weight：
30 parts of polyoxyethylene polyoxypropylene polyethers, 22 parts of polyethylene polyamine, 10 parts of oxalic acid, 3 parts of titanium dioxide powder, titanium dioxide
3 parts of silica flour, 2 parts of solvent, 0.5 part of auxiliary agent, 0.6 part of surfactant, 0.6 part of plants essential oil；Polyethylene polyamine, solvent, surface
The mass ratio of active agent materials is 3：3：0.5：1.
The solvent of the present embodiment is methanol.
The auxiliary agent of the present embodiment is polyaluminum ferric chloride, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight
Than 1:3:The mixture of 2 compositions.
The surfactant of the present embodiment is Octoxinol, N- dodecyl-B- alanine sodium, according to weight ratio 1:2
The mixture of composition.
The plants essential oil of the present embodiment is Rosa Damascana.
A kind of preparation method of ageing oil cleaning agent of the present embodiment, comprises the following steps：
Step 1 weighs each component raw material on request；
Step 2, by polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant in order according to
Secondary be added in homogenizer is stirred, speed of agitator 1750r/min, mixing time 0.8h, obtains mixture A, then will mixing
Object A is added in reaction kettle, is reacted 40min in the case where temperature is 145 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 8 is small, obtain mixture C by step 3；
Step 4 adds mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2
Enter in high-speed mixer, be sufficiently stirred so that all material is uniformly mixed, mixing speed 1050r/min, mixing time, 35 points
Clock, then add mixture in reaction kettle, 0.8h is reacted in the case where temperature is 170 DEG C, the ageing oil cleaning agent of invention is made.
The performance test results for the ageing oil cleaning agent that embodiment 1 to 5 and comparative example 1, comparative example 2 prepare invention are as follows
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims
Variation is included within the present invention.
Moreover, it will be appreciated that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
Using specification as an entirety, the technical solutions in each embodiment can also be properly combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (8)
1. a kind of ageing oil cleaning agent, which is characterized in that include the raw material of following parts by weight：
32-36 parts of polyoxyethylene polyoxypropylene polyethers, 24-26 parts of polyethylene polyamine, 12-16 parts of oxalic acid, titanium dioxide powder 4-8
Part, 4-8 parts of silicon dioxide powder, 3-5 parts of solvent, 1-3 parts of auxiliary agent, 1-2 parts of surfactant, 1-2 parts of plants essential oil；Polyoxyethylene
Polyoxypropylene polyether, polyethylene polyamine, solvent, surfactant, the mass ratio of substance is (4~6)：(3~4)：(1~2)：1.
2. a kind of ageing oil cleaning agent according to claim 1, which is characterized in that the ageing oil cleaning agent includes following
The raw material of parts by weight：
34 parts of polyoxyethylene polyoxypropylene polyethers, 25 parts of polyethylene polyamine, 14 parts of oxalic acid, 6 parts of titanium dioxide powder, silicon dioxide powder
6 parts, 4 parts of solvent, 2 parts of auxiliary agent, 1.5 parts of surfactant, 1.5 parts of plants essential oil；Polyoxyethylene polyoxypropylene polyethers, more ethylene
Polyamines, solvent, surfactant, the mass ratio of substance is 5：3.5：1.5：1.
3. a kind of ageing oil cleaning agent according to claim 1 or 2, which is characterized in that the solvent for methanol, ethyl alcohol,
One or more combinations in espeleton, methylisobutylketone.
4. a kind of ageing oil cleaning agent according to claim 1 or 2, which is characterized in that the auxiliary agent is aluminium polychloride
Iron, Polymeric Ferric Ferric Chloride aluminium, polysilicate ferric aluminum sulfate, according to weight ratio 1:3:The mixture of 2 compositions.
5. a kind of ageing oil cleaning agent according to claim 1 or 2, which is characterized in that the surfactant is pungent benzene
Former times alcohol, N- dodecyl-B- alanine sodium, according to weight ratio 1:The mixture of 2 compositions.
6. a kind of ageing oil cleaning agent according to claim 1 or 2, which is characterized in that the plants essential oil is rhodamine toner
One or more combinations in oil, lemon, orange essential oil, osmanthus essential oil and illawarra mountain pine essential oil.
7. a kind of prepare such as the method for claim 1-6 any one of them ageing oil cleaning agents, which is characterized in that including following
Step：
Step 1 weighs each component raw material on request；
Step 2 adds polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant successively in order
Enter and stirred into homogenizer, speed of agitator 1800-1900r/min, mixing time 1-2h obtain mixture A, then will mixing
Object A is added in reaction kettle, is reacted 45-55min in the case where temperature is 155-165 DEG C, is obtained mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 10-12 is small, obtain mixture C by step 3；
Step 4 adds in mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2 high
In fast mixer, it is sufficiently stirred so that all material is uniformly mixed, mixing speed 1100-1200r/min, mixing time, 40-50
Minute, then add mixture in reaction kettle, 1-2h is reacted in the case where temperature is 175-185 DEG C, the ageing oil that invention is made is clear
Lotion.
8. the preparation method of a kind of ageing oil cleaning agent according to claim 7, which is characterized in that the step is：
Step 1 weighs each component raw material on request；
Step 2 adds polyoxyethylene polyoxypropylene polyethers, polyethylene polyamine, solvent, auxiliary agent, surfactant successively in order
Enter and stirred into homogenizer, speed of agitator 1850r/min, mixing time 1.5h obtain mixture A, then mixture A added
Enter into reaction kettle, react 50min in the case where temperature is 160 DEG C, obtain mixture B；
Titanium dioxide powder, silicon dioxide powder are added in ball mill, when grinding 11 is small, obtain mixture C by step 3；
Step 4 adds in mixture C obtained, oxalic acid, plants essential oil in mixture B obtained, step 3 in step 2 high
In fast mixer, it is sufficiently stirred so that all material is uniformly mixed, mixing speed 1150r/min, mixing time, 45 minutes, then
It adds mixture in reaction kettle, reacts 1.5h in the case where temperature is 180 DEG C, the ageing oil cleaning agent of invention is made.
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Application publication date: 20180518 |