CN108048142A - A kind of military typed high-energy liquid fuel in alcohol group and preparation method thereof - Google Patents
A kind of military typed high-energy liquid fuel in alcohol group and preparation method thereof Download PDFInfo
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- CN108048142A CN108048142A CN201711382439.5A CN201711382439A CN108048142A CN 108048142 A CN108048142 A CN 108048142A CN 201711382439 A CN201711382439 A CN 201711382439A CN 108048142 A CN108048142 A CN 108048142A
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- parts
- liquid fuel
- military
- alcohol group
- methanol
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/12—Inorganic compounds
- C10L1/1266—Inorganic compounds nitrogen containing compounds, (e.g. NH3)
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/185—Ethers; Acetals; Ketals; Aldehydes; Ketones
- C10L1/1857—Aldehydes; Ketones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention belongs to liquid fuel technology fields, and in particular to a kind of military typed high-energy liquid fuel in alcohol group and preparation method thereof includes the raw material of following parts by weight：75 90 parts of methanol, 12 parts of C98,5 10 parts of heavy aromatics, 58 parts of glyceryl triacetate, 15 20 parts of dimethoxym ethane, 25 parts of ferric nitrate, 58 parts of N phenyl N sec-butylbenzenes diamines, 15 parts of deodorant.Typed high-energy liquid fuel in alcohol group of the present invention, each component cooperate, and burning, fully thorough, combustion heat value is high, is generated without carbon deposition phenomenon, and fuel value is up to 18000kJ/kg.
Description
Technical field
The invention belongs to liquid fuel technology fields, and in particular to a kind of military typed high-energy liquid fuel in alcohol group and its preparation side
Method.
Background technology
Alcohol-based fuel is cheap, the environmentally friendly clean type fuel based on alcohols, mainly with liquid or solid form
In the presence of, since alcohol radical itself is oxygen-containing, oxygen demand is few during burning, and can fully burn, have sanitation and hygiene, safety and environmental protection,
The advantages that easy to use, cheap, in face of the exhaustion of fossil energy, alcohol-based fuel is following most potential new replacement regeneration
Resource belongs to the Biological clean energy that country the Eleventh Five-Year Plan period encourages development.At present, it is big to be mainly used for China for alcohol-based fuel
The restaurant in middle city, hotel, the catering trades such as dining room of universities and colleges.However alcohol-based fuel exists when in use in existing technology
Combustion heat value is low, power is small, and the water for generation of burning has corrosivity with sediment, and long-time service can make combustion apparatus
It causes to seriously affect with the service life.
The content of the invention
The technical problem to be solved by the present invention is to develop a kind of military typed high-energy liquid fuel in alcohol group.
The present invention adopts the following technical scheme that：
A kind of military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：75-90 parts of methanol, C98-12 parts, again
5-10 parts of aromatic hydrocarbons, 5-8 parts of glyceryl triacetate, 15-20 parts of dimethoxym ethane, 2-5 parts of ferric nitrate, N- phenyl-N- sec-butylbenzene diamines
5-8 parts, 1-5 parts of deodorant.
Preferably, the military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：80-85 parts of methanol,
C910-12 parts, 6-8 parts of heavy aromatics, 6-8 parts of glyceryl triacetate, 17-20 parts of dimethoxym ethane, 3-5 parts of ferric nitrate, N- phenyl-N- it is secondary
6-8 parts of butyl phenylenediamine, 1-3 parts of deodorant.
Preferably, the military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：85 parts of methanol, C912
Part, 6 parts of heavy aromatics, 20 parts of dimethoxym ethane, 3 parts of ferric nitrate, 8 parts of N- phenyl-N- sec-butylbenzenes diamines, remove 8 parts of glyceryl triacetate
Smelly dose 2 parts.
Preferably, the military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：80 parts of methanol, C915
Part, 8 parts of heavy aromatics, 17 parts of dimethoxym ethane, 5 parts of ferric nitrate, 5 parts of N- phenyl-N- sec-butylbenzenes diamines, remove 5 parts of glyceryl triacetate
Smelly dose 3 parts.
Preferably, the deodorant is industrial essence or taste removal camphor.
The methanol is to meet GB 338-2011《Industrial methanol》The methanol of standard.The methanol content of the methanol is
More than 99.9%.
The invention also discloses above-mentioned military preparation method, concrete scheme is as follows：
A kind of preparation method of military typed high-energy liquid fuel in alcohol group, comprises the following steps：
(1) first glyceryl triacetate, N- phenyl-N- sec-butylbenzenes diamines are added in configurator A, are uniformly mixed, it is spare；
(2) C is added in into configurator B9, heavy aromatics, add in dimethoxym ethane after mixing, when stirring 3-5 is small, then add in
Methanol, continue stir 3-5 it is small when, be uniformly mixed, it is spare；
(3) raw material after mixing in configurator A is added in configurator B, stirred evenly, it is spare；
(4) ferric nitrate and deodorant are added in into configurator A successively, is uniformly mixed to get to the high energy alcohol-group liquid
Fuel.
Beneficial effects of the present invention
(1) typed high-energy liquid fuel in alcohol group of the present invention is burnt fully and completely, using methanol as main combustion component without three
It is useless to generate, it is effectively protected environment；Using C9, heavy aromatics improve component, the significant calorific value for improving fuel as calorific value；First
Acetal is added in as cosolvent, methanol can be made to dissolve each other with other components, but also can be made alcohol radical liquid fuel and conventional gasoline
It is used in mixed way, intersolubility is good；Glyceryl triacetate and N- phenyl-N- sec-butylbenzene diamines, except can be carried with other material combinations
Outside the flash-point of high fuel, additionally it is possible to protective film is formed in metallic surface, has isolated contact of the corrosive deposit with metal surface, from
And can play prevents from burning to corrosion of metal, enhances the corrosion resistance of alcohol radical liquid fuel；Nitre is added in fuel
Sour iron can solve the problems, such as carbon distribution, can realize that carbon distribution does not occur in fuel continuous burning 12h；It adds in deodorant and can remove combustion
Peculiar smell in material.
(2) typed high-energy liquid fuel in alcohol group of the present invention, each component cooperate, and burn fully thorough, combustion heat value
Height is generated without carbon deposition phenomenon, and fuel value is up to 18000kJ/kg.And there is preferable intersolubility and corrosion resistance with gasoline
Can, with preferable evaporability and positive effect additive property, therefore typed high-energy liquid fuel in alcohol group provided by the invention is as efficient, environmental protection
Alternative fuel have larger development potentiality and important economic benefit, social value.High energy alcohol fluid of the present invention
The preparation method of fluid fuel, manufacture craft is simple, easily operated.
Specific embodiment
Embodiment 1
A kind of military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：85 parts of methanol, C912 parts, heavy aromatics 6
Part, 8 parts of glyceryl triacetate, 20 parts of dimethoxym ethane, 3 parts of ferric nitrate, 8 parts of N- phenyl-N- sec-butylbenzenes diamines, 2 parts of deodorant.
Embodiment 2
A kind of military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：80 parts of methanol, C915 parts, heavy aromatics 8
Part, 5 parts of glyceryl triacetate, 17 parts of dimethoxym ethane, 5 parts of ferric nitrate, 5 parts of N- phenyl-N- sec-butylbenzenes diamines, 3 parts of deodorant.
Embodiment 3
A kind of military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：75 parts of methanol, C98 parts, heavy aromatics 10
Part, 5 parts of glyceryl triacetate, 15 parts of dimethoxym ethane, 5 parts of ferric nitrate, 8 parts of N- phenyl-N- sec-butylbenzenes diamines, 1 part of deodorant.
Embodiment 4
A kind of military typed high-energy liquid fuel in alcohol group includes the raw material of following parts by weight：90 parts of methanol, C912 parts, heavy aromatics 5
Part, 8 parts of triacetic acid glycerine, 20 parts of dimethoxym ethane, 5 parts of ferric nitrate, 5 parts of N- phenyl-N- sec-butylbenzenes diamines, 5 parts of deodorant.
Embodiment 5
A kind of preparation method of military typed high-energy liquid fuel in alcohol group, comprises the following steps：
(1) first glyceryl triacetate, N- phenyl-N- sec-butylbenzenes diamines are added in configurator A, are uniformly mixed, it is spare；
(2) C is added in into configurator B9, heavy aromatics, add in dimethoxym ethane after mixing, when stirring 3-5 is small, then add in
Methanol, continue stir 3-5 it is small when, be uniformly mixed, it is spare；
(3) raw material after mixing in configurator A is added in configurator B, stirred evenly, it is spare；
(4) ferric nitrate and deodorant are added in into configurator A successively, is uniformly mixed to get to the high energy alcohol-group liquid
Fuel.
It is set by survey, the excellent properties of military typed high-energy liquid fuel in alcohol group of the present invention are as shown in table 1 below.
The performance of the military typed high-energy liquid fuel in alcohol group of the present invention of table 1.
Claims (8)
1. a kind of military typed high-energy liquid fuel in alcohol group, which is characterized in that include the raw material of following parts by weight：75-90 parts of methanol,
C98-12 parts, 5-10 parts of heavy aromatics, 5-8 parts of glyceryl triacetate, 15-20 parts of dimethoxym ethane, 2-5 parts of ferric nitrate, N- phenyl-N- it is secondary
5-8 parts of butyl phenylenediamine, 1-5 parts of deodorant.
2. military typed high-energy liquid fuel in alcohol group according to claim 1, which is characterized in that include the raw material of following parts by weight：
80-85 parts of methanol, C910-12 parts, 6-8 parts of heavy aromatics, 6-8 parts of glyceryl triacetate, 17-20 parts of dimethoxym ethane, ferric nitrate 3-5
Part, 6-8 parts of N- phenyl-N- sec-butylbenzene diamines, 1-3 parts of deodorant.
3. military typed high-energy liquid fuel in alcohol group according to claim 1, which is characterized in that include the raw material of following parts by weight：
85 parts of methanol, C912 parts, 6 parts of heavy aromatics, 8 parts of glyceryl triacetate, 20 parts of dimethoxym ethane, 3 parts of ferric nitrate, N- phenyl-N- Zhong Ding
8 parts of base phenylenediamine, 2 parts of deodorant.
4. military typed high-energy liquid fuel in alcohol group according to claim 1, which is characterized in that include the raw material of following parts by weight：
80 parts of methanol, C915 parts, 8 parts of heavy aromatics, 5 parts of glyceryl triacetate, 17 parts of dimethoxym ethane, 5 parts of ferric nitrate, N- phenyl-N- Zhong Ding
5 parts of base phenylenediamine, 3 parts of deodorant.
5. military typed high-energy liquid fuel in alcohol group according to claim 1, it is characterised in that：The deodorant for industrial essence or
Taste removal camphor.
6. military typed high-energy liquid fuel in alcohol group according to claim 1, it is characterised in that：The methanol is to meet GB 338-
The methanol of 2011 industrial methanol standards.
7. military typed high-energy liquid fuel in alcohol group according to claim 1, it is characterised in that：The methanol content of the methanol is
More than 99.9%.
8. the preparation method of any military typed high-energy liquid fuel in alcohol group of claim 1-7, which is characterized in that including following step
Suddenly：
First glyceryl triacetate, N- phenyl-N- sec-butylbenzenes diamines are added in configurator A, are uniformly mixed, it is spare；
C9, heavy aromatics are added in into configurator B, dimethoxym ethane is added in after mixing, when stirring 3-5 is small, then adds in methanol, after
When continuous stirring 3-5 is small, it is uniformly mixed, it is spare；
Raw material after mixing in configurator A is added in configurator B, is stirred evenly, it is spare；
Ferric nitrate and deodorant are added in into configurator A successively, is uniformly mixed to get to the typed high-energy liquid fuel in alcohol group.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711382439.5A CN108048142A (en) | 2017-12-19 | 2017-12-19 | A kind of military typed high-energy liquid fuel in alcohol group and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711382439.5A CN108048142A (en) | 2017-12-19 | 2017-12-19 | A kind of military typed high-energy liquid fuel in alcohol group and preparation method thereof |
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| CN108048142A true CN108048142A (en) | 2018-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711382439.5A Pending CN108048142A (en) | 2017-12-19 | 2017-12-19 | A kind of military typed high-energy liquid fuel in alcohol group and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112251263A (en) * | 2020-09-15 | 2021-01-22 | 深圳源圭能源有限公司 | Formula and preparation method of novel environment-friendly high-energy alcohol-based industrial fuel |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101412933A (en) * | 2007-10-15 | 2009-04-22 | 李隆梅 | Broadspectrum environment-protective alcohol-base liquid fuel and preparation thereof |
| CN103173253A (en) * | 2013-02-28 | 2013-06-26 | 鲁书华 | Alcoholic composition fuel for vehicle |
| CN104059700A (en) * | 2014-07-03 | 2014-09-24 | 无锡昊华新能源有限公司 | Efficient liquid fuel additive and liquid fuel with additive |
-
2017
- 2017-12-19 CN CN201711382439.5A patent/CN108048142A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101412933A (en) * | 2007-10-15 | 2009-04-22 | 李隆梅 | Broadspectrum environment-protective alcohol-base liquid fuel and preparation thereof |
| CN103173253A (en) * | 2013-02-28 | 2013-06-26 | 鲁书华 | Alcoholic composition fuel for vehicle |
| CN104059700A (en) * | 2014-07-03 | 2014-09-24 | 无锡昊华新能源有限公司 | Efficient liquid fuel additive and liquid fuel with additive |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112251263A (en) * | 2020-09-15 | 2021-01-22 | 深圳源圭能源有限公司 | Formula and preparation method of novel environment-friendly high-energy alcohol-based industrial fuel |
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Application publication date: 20180518 |
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| RJ01 | Rejection of invention patent application after publication |