CN108046817A - A kind of parapet quick change abrasion-proof prefabricated component - Google Patents

A kind of parapet quick change abrasion-proof prefabricated component Download PDF

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CN108046817A
CN108046817A CN201711492905.5A CN201711492905A CN108046817A CN 108046817 A CN108046817 A CN 108046817A CN 201711492905 A CN201711492905 A CN 201711492905A CN 108046817 A CN108046817 A CN 108046817A
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parts
parapet
powder
quick change
prefabricated component
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张静芬
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C04B35/49Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates containing also titanium oxides or titanates
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    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00Casings; Linings; Walls; Roofs
    • F27D1/04Casings; Linings; Walls; Roofs characterised by the form, e.g. shape of the bricks or blocks used
    • F27D1/045Bricks for lining cylindrical bodies, e.g. skids, tubes
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
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    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C04B2235/3222Aluminates other than alumino-silicates, e.g. spinel (MgAl2O4)
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    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
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    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/444Halide containing anions, e.g. bromide, iodate, chlorite
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    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5208Fibers
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    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

Abstract

The invention discloses a kind of parapet quick change abrasion-proof prefabricated components, belong to technical field of refractory materials, as mass fraction, including:20 ~ 30 parts of corundum aggregate;20 ~ 30 parts of zirconia titanate calcium aggregate;5 ~ 10 parts of zirconia titanate calcium powder;10 ~ 16 parts of titanium calcium aluminate powder;5 ~ 9 parts of silicon powder;5 ~ 9 parts of alumina powder;5 ~ 9 parts of aluminate cement;6 ~ 10 parts of vitrifying perlite;External feeding, including:0.15 ~ 0.18 part of sodium tripolyphosphate;0.13 ~ 0.16 part of explosion-proof fiber.For replacing the castable of the prior art, there is characteristic easy for construction, the cement kiln good thermal shock built, wear-resisting property are remarkable, short construction period, and periodic maintenance cost is also lower.

Description

A kind of parapet quick change abrasion-proof prefabricated component
Technical field
The present invention relates to technical field of refractory materials, in particular to a kind of parapet quick change abrasion-proof prefabricated component and preparation method.
Background technology
At present, many positions of building material industry liner parapet body are all by castable moulding by casting at the construction field (site), operation work Sequence is relatively more, it is necessary to complete the processes such as the removing of cylinder lining, anchor studs welding, shuttering supporting, cast, maintenance, the demoulding, pours and finishes After also need to conserve, toast after can come into operation, generally speaking, arbitrariness is also big for cast-in-site amount of water, and casting quality is not Easy to control, construction labor intensity is also big, and construction period is longer, and the kiln liner body Chang Yinwei constructions that existing castable pours into Etc. factors cause that casting material strength is low, wears no resistance, the defects of thermal shock resistance is poor, thermal conductivity factor is big, kiln cylinder body outer wall temperature Height, thermal losses is big, service life is shorter, and fire resisting liner body replaces more frequent, time-consuming and laborious and influence production.It is entire in order to improve The running rate of firing system enhances the market competitiveness of enterprise, and there is an urgent need to the fire proofed woods of high quality for building material industry manufacturing enterprise Material is applied to wherein.
The content of the invention
The purpose of the present invention is mainly to provide a kind of parapet quick change abrasion-proof prefabricated component, to replace the castable of the prior art, Its with easy for construction, anti-thermal shock effect is good, thermal losses is small, cylinder thermal conductivity factor is small, it is easy for construction, exempt to toast, repair stops kiln Many advantages, such as time is short.
To achieve the above object, a kind of parapet quick change abrasion-proof prefabricated component according to the present invention, as mass fraction, under Row component is formed:
Major ingredient, including:
20 ~ 30 parts of corundum aggregate;
20 ~ 30 parts of zirconia titanate calcium aggregate;
5 ~ 10 parts of zirconia titanate calcium powder;
10 ~ 16 parts of titanium calcium aluminate powder;
5 ~ 9 parts of silicon powder;
5 ~ 9 parts of alumina powder;
5 ~ 9 parts of aluminate cement;
6 ~ 10 parts of vitrifying perlite;
External feeding, including:
0.15 ~ 0.18 part of sodium tripolyphosphate;
0.13 ~ 0.16 part of explosion-proof fiber.
As the preferred of above-mentioned technical proposal, a kind of parapet quick change abrasion-proof prefabricated component, which is characterized in that by quality Fraction meter, is made of following component:
Major ingredient, including:
22 parts of corundum aggregate;
25 parts of titanium calcium zirconate aggregate;
10 parts of zirconia titanate calcium powder;
10 parts of titanium calcium aluminate powder;
5 parts of silicon powder;
9 parts of alumina powder;
9 parts of aluminate cement;
10 parts of vitrifying perlite;
External feeding, including:
0.08 ~ 0.1 part of sodium tripolyphosphate;
0.06 ~ 0.1 part of explosion-proof fiber.
As the preferred of above-mentioned technical proposal, a kind of parapet quick change abrasion-proof prefabricated component according to claim 1 or 2, It is characterized in that, titanium aluminic acid calcium content >=85%.
A kind of parapet quick change abrasion-proof prefabricated component according to claim 1 or 2, which is characterized in that the vitrifying is precious The aluminium content of Zhu Yan is >=20%.
A kind of preparation method of parapet quick change abrasion-proof prefabricated component, which is characterized in that include the following steps:
1. batch mixing:Major ingredient according to formula is prepared, is placed in mixer and is stirred, external feeding is then added in and is stirred, Chlorination zirconium solution is continuously added into whipping process;
2. it shapes:The mixture being stirred is added in mold, the dead weight and surface tension by mixture are shakeout, and erase surface Extra mixture;
3. it conserves:Mold equipped with mixture is put into 20 DEG C of isoperibol, is demoulded after hardening, it is small to place 24 after the demoulding again When;
4. it dries:The adobe conserved is placed in tunnel oven and is dried, room temperature is naturally cooled to after drying;
5. it fires:Dried adobe is put into heating furnace, and 200 DEG C are warming up to according to the heating rate of 5 DEG C/min, then with 10 DEG C/heating rate of min is warming up to 800 DEG C, and keep the temperature 2 it is small when, then naturally cool to room temperature, both preformed bricks.
The preparation method of a kind of parapet quick change abrasion-proof prefabricated component according to claim 5, which is characterized in that step is 4. The temperature setting of middle electrical kiln is 110 DEG C, when drying time is 20 small.
Compared with prior art, the present invention haing the following advantages and advantageous effect:The prefabricated component titanium calcium aluminate aggregate has Protrusion can have preferable combination with matrix, and bond strength is high, and titanium calcium aluminate has good antiacid alkali erosiveness, tool Have relatively to force and use environmental suitability;Zirconium chloride, magnesium titanate can also be with the silicon powder in material, alumina powder generation highly heatproof and shockproofs Substance substantially increases the thermal shock resistance anti-erosion low heat conductivity energy of castable.
It is easy for construction using prefabricated component, it without formwork, pours, the processes such as maintenance;Preformed bricks of the present invention are built Cement kiln thermal shock resistance effect is good, heat-insulating property is remarkable.
The short construction period built using prefabricated component of the present invention, cement kiln stops kiln life cycle costing can be lower.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, and the present invention is not limited to these implementations Example, the every and example of the present invention for solving the problems, such as thinking and being adapted, within the scope of the present invention.
The preformed bricks preparation flow of 1 ~ embodiment of embodiment 3 is as described below:
1. batch mixing:Major ingredient according to formula is prepared, is placed in mixer and is stirred, external feeding is then added in and is stirred, Chlorination zirconium solution is continuously added into whipping process;The magnesium chloride solution that wherein embodiment 1 ~ 3 adds in is 7 parts, 8 parts, 9 parts;
2. it shapes:The mixture being stirred is added in mold, the dead weight and surface tension by mixture are shakeout, and erase surface Extra mixture;
3. it conserves:Mold equipped with mixture is put into 20 DEG C of isoperibol, is demoulded after hardening, it is small to place 24 after the demoulding again When;
4. it dries:The adobe conserved is placed in tunnel oven and is dried, room temperature is naturally cooled to after drying;
5. it fires:Dried adobe is put into heating furnace, and 200 DEG C are warming up to according to the heating rate of 5 DEG C/min, then with 10 DEG C/heating rate of min is warming up to 800 DEG C, and keep the temperature 2 it is small when, then naturally cool to room temperature, both preformed bricks.
Embodiment 1
22 parts of corundum aggregate;
25 parts of titanium calcium zirconate aggregate;
10 parts of zirconia titanate calcium powder;
10 parts of titanium calcium aluminate powder;
5 parts of silicon powder;
9 parts of alumina powder;
9 parts of aluminate cement;
10 parts of vitrifying perlite;
External feeding, including:
0.08 ~ 0.1 part of sodium tripolyphosphate;
0.06 ~ 0.1 part of explosion-proof fiber.
Embodiment 2
20 parts of corundum aggregate;
27 parts of titanium calcium zirconate aggregate;
10 parts of zirconia titanate calcium powder;
10 parts of titanium calcium aluminate powder;
5 parts of silicon powder;
9 parts of alumina powder;
9 parts of aluminate cement;
10 parts of vitrifying perlite;
External feeding, including:
0.08 ~ 0.1 part of sodium tripolyphosphate;
0.06 ~ 0.1 part of explosion-proof fiber.
Embodiment 3
25 parts of corundum aggregate;
22 parts of titanium calcium zirconate aggregate;
10 parts of zirconia titanate calcium powder;
10 parts of titanium calcium aluminate powder;
5 parts of silicon powder;
9 parts of alumina powder;
9 parts of aluminate cement;
10 parts of vitrifying perlite;
External feeding, including:
0.08 ~ 0.1 part of sodium tripolyphosphate;
0.06 ~ 0.1 part of explosion-proof fiber.
Preformed bricks performance parameter of the table prepared by 1 ~ embodiment of embodiment 3
The above result shows that:Prefabricated component of the present invention has the spy of high-heat resistance shock resistant, high compressive strength and lower thermal conductivity Property can ensure the service life and heat-insulating property of cement kiln outer wall;
By table as it can be seen that prefabricated component wearability of the present invention is smaller than 4, at the same time, in 1100 DEG C ~ air-cooled thermal shock resistance Can be up to 56 times or more, compression strength is in more than 1410Mpa, and highest refractory temperature is 1700 DEG C or so, meets cement kiln Refractory lining requirement

Claims (7)

1. a kind of parapet quick change abrasion-proof prefabricated component, which is characterized in that as mass fraction, be made of following component:
Major ingredient, including:
20 ~ 30 parts of corundum aggregate;
20 ~ 30 parts of zirconia titanate calcium aggregate;
5 ~ 10 parts of zirconia titanate calcium powder;
10 ~ 16 parts of titanium calcium aluminate powder;
5 ~ 9 parts of silicon powder;
5 ~ 9 parts of alumina powder;
5 ~ 9 parts of aluminate cement;
6 ~ 10 parts of vitrifying perlite;
External feeding, including:
0.15 ~ 0.18 part of sodium tripolyphosphate;
0.13 ~ 0.16 part of explosion-proof fiber.
2. a kind of parapet quick change abrasion-proof prefabricated component according to claim 1, which is characterized in that as mass fraction, under Row component is formed:
Major ingredient, including:
22 parts of corundum aggregate;
25 parts of zirconia titanate calcium aggregate;
10 parts of zirconia titanate calcium powder;
10 parts of titanium calcium aluminate powder;
5 parts of silicon powder;
9 parts of alumina powder;
9 parts of aluminate cement;
10 parts of vitrifying perlite;
External feeding, including:
0.08 ~ 0.1 part of sodium tripolyphosphate;
0.06 ~ 0.1 part of explosion-proof fiber.
A kind of 3. parapet quick change abrasion-proof prefabricated component according to claim 1 or 2, which is characterized in that the zirconia titanate calcium aluminium Content >=45%.
A kind of 4. parapet quick change abrasion-proof prefabricated component according to claim 1 or 2, which is characterized in that the vitrifying pearl The aluminium content of rock is >=20%.
5. a kind of preparation method of parapet quick change abrasion-proof prefabricated component, which is characterized in that include the following steps:
1. batch mixing:Major ingredient according to formula is prepared, is placed in mixer and is stirred, external feeding is then added in and is stirred, Chlorination zirconium solution is continuously added into whipping process;
2. it shapes:The mixture being stirred is added in mold, the dead weight and surface tension by mixture are shakeout, and erase surface Extra mixture;
3. it conserves:Mold equipped with mixture is put into 20 DEG C of isoperibol, is demoulded after hardening, it is small to place 24 after the demoulding again When;
4. it dries:The adobe conserved is placed in tunnel oven and is dried, room temperature is naturally cooled to after drying;
5. it fires:Dried adobe is put into heating furnace, and 200 DEG C are warming up to according to the heating rate of 5 DEG C/min, then with 10 DEG C/heating rate of min is warming up to 800 DEG C, and keep the temperature 2 it is small when, then naturally cool to room temperature, both preformed bricks.
6. a kind of preparation method of parapet quick change abrasion-proof prefabricated component according to claim 5, which is characterized in that step 4. in The temperature setting of electrical kiln is 110 DEG C, when drying time is 20 small.
7. a kind of preparation method of parapet quick change abrasion-proof prefabricated component according to claim 5, which is characterized in that step 1. in As mass fraction, 20 parts of zirconium chloride is contained in 100 parts of chlorination zirconium solutions.
CN201711492905.5A 2017-12-31 2017-12-31 A kind of parapet quick change abrasion-proof prefabricated component Withdrawn CN108046817A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108046818A (en) * 2017-12-31 2018-05-18 张静芬 A kind of parapet quick change abrasion-proof prefabricated component and preparation method
CN108069721A (en) * 2017-12-31 2018-05-25 张静芬 A kind of high-performance low-heat leads preformed bricks
CN108218447A (en) * 2017-12-31 2018-06-29 张静芬 A kind of high-strength high abrasion prefabricated component
CN108249931A (en) * 2017-12-31 2018-07-06 张静芬 A kind of high-strength high abrasion prefabricated component and preparation method
CN108774071A (en) * 2018-06-21 2018-11-09 华北理工大学 A kind of air pipe of blast furnace castable and preparation method thereof

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102227389A (en) * 2008-09-29 2011-10-26 西门子公司 Material composition for producing fireproof material and use thereof, and fireproof moulding body and method for production thereof
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CN108069721A (en) * 2017-12-31 2018-05-25 张静芬 A kind of high-performance low-heat leads preformed bricks
CN108218447A (en) * 2017-12-31 2018-06-29 张静芬 A kind of high-strength high abrasion prefabricated component
CN108249931A (en) * 2017-12-31 2018-07-06 张静芬 A kind of high-strength high abrasion prefabricated component and preparation method
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