CN108046493A - A kind of novel ultrapure water treatment process - Google Patents

A kind of novel ultrapure water treatment process Download PDF

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Publication number
CN108046493A
CN108046493A CN201711419706.1A CN201711419706A CN108046493A CN 108046493 A CN108046493 A CN 108046493A CN 201711419706 A CN201711419706 A CN 201711419706A CN 108046493 A CN108046493 A CN 108046493A
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CN
China
Prior art keywords
water
processing
reverse osmosis
osmosis membrane
treatment process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711419706.1A
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Chinese (zh)
Inventor
唐建强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Huaqiang Environmental Technology Co Ltd
Original Assignee
Zhejiang Huaqiang Environmental Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Huaqiang Environmental Technology Co Ltd filed Critical Zhejiang Huaqiang Environmental Technology Co Ltd
Priority to CN201711419706.1A priority Critical patent/CN108046493A/en
Publication of CN108046493A publication Critical patent/CN108046493A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4691Capacitive deionisation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02Non-contaminated water, e.g. for industrial water supply
    • C02F2103/04Non-contaminated water, e.g. for industrial water supply for obtaining ultra-pure water

Abstract

The present invention relates to a kind of novel ultrapure water treatment process, include the following steps:(1)Pretreatment:Mechanical admixture in tap water or common deionized water is filtered out;(2)Activated carbon filters:Water after pretreatment carries out activated carbon adsorption;(3)Reverse osmosis membrane filtration:Through activated carbon adsorption, treated that water carries out reverse-osmosis treated with reverse osmosis membrane;(4)EDI processing:The first ultra-pure water is obtained after handling deep desalting by electrodeionization;(5)Ultraviolet sterilization:The first ultra-pure water obtained after EDI is handled is through ultraviolet treatment with irradiation;(6)Micro-filtration processing:Water after ultraviolet treatment with irradiation is filtered with microporous filtration, obtains the second ultra-pure water.Present invention reduces the frequency of use of ultraviolet ray generating apparatus and microporous filtration, so as to reduce the maintenance of ultraviolet ray generating apparatus and microporous filtration and maintenance cost, and then greatly reduce the use cost of ultra-pure water.

Description

A kind of novel ultrapure water treatment process
Technical field
The present invention relates to water treatment fields, and in particular to a kind of novel ultrapure water treatment process.
Background technology
Ultra-pure water is widely used in the industries such as electric power, electronics, chemical industry, pharmacy, if the water quality of ultra-pure water does not reach requirement, It will influence the quality of product or the result of scientific experiment.
At present in the processing of ultra-pure water, water is gone forward side by side after reverse osmosis membrane filtration and EDI processing, then through ultraviolet sterilization The processing of row micro-filtration, to remove the bacterium retained in water, the high frequency use of ultraviolet sterilization apparatus and microporous filtration increases greatly Daily maintenance and repair cost is added, so as to considerably increase the use cost of ultra-pure water, however in actual production and science In experiment, some experiments or production process and from the bacteria effect retained in water.
The content of the invention
In order to solve the problems, such as that ultra-pure water use cost is excessively high in the prior art, the present invention provides a kind of novel ultrapure waters Treatment process, the technique reduce the frequency of use of ultraviolet sterilization apparatus and microporous filtration, so as to reduce ultraviolet light The maintenance of sterilizing unit and microporous filtration and maintenance cost, and then greatly reduce the use cost of ultra-pure water.
The present invention above-mentioned technical purpose technical scheme is that:
A kind of novel ultrapure water treatment process, includes the following steps:(1)Pretreatment:It will be in tap water or common deionized water Mechanical admixture filters out;(2)Activated carbon filters:Water after pretreatment carries out activated carbon adsorption;(3)Reverse osmosis membrane filtration:Through work Water after property charcoal adsorption treatment carries out reverse-osmosis treated with reverse osmosis membrane;(4)EDI processing:Depth is handled by electrodeionization to remove The first ultra-pure water is obtained after salt;(5)Ultraviolet sterilization:The first ultra-pure water obtained after EDI is handled is through ultraviolet treatment with irradiation; (6)Micro-filtration processing:Water after ultraviolet treatment with irradiation is filtered with microporous filtration, obtains the second ultra-pure water.
When the bacteria effect that experiment or production process retain in by water, using the second ultra-pure water, and when experiment or production When process is from the bacteria effect retained in water, will through EDI, treated that the first ultra-pure water directly uses, reduce ultraviolet light and kill The frequency of use of bacterium device and microporous filtration so as to greatly reduce regular maintenance cost, reduces the use of ultra-pure water Cost.
Preferably, water is through step(2)After carrying out activated carbon filtration treatment, sterilization processing, Ran Houzai are carried out with ultraviolet light Through step(3)Carry out reverse osmosis membrane filtration processing.
Sterilized using ultraviolet light, prevent bacterium on reverse osmosis membrane or EDI processing in grow, so as to film generate It blocks.
Preferably, pretreatment is to be carried out by sand core filter plate and fibre columns.
Mechanical admixture is filtered out, such as iron rust and other suspended matters.
Preferably, reverse osmosis membrane filtration is two-pass reverse osmosis membrane filtration.
Heavy metal ion, hardness and the salinity in water are reduced, to mitigate the load of follow-up EDI deep desaltings, is in addition prevented EDI module foulings, influence normal use.
Preferably, reverse osmosis membrane is surface is negatively charged or the reverse osmosis membrane of the anti-organic pollution of electroneutral.
With negative electrical charge, reverse osmosis membrane surface is negatively charged or electroneutral, has prevented for most organic pollutants in water Organic pollutants are attached on reverse osmosis membrane, so as to block reverse osmosis membrane.
Preferably, the reverse osmosis membrane is cellulose acetate rolled film.
Such film is not easy to be dissolved the blockings such as solid, colloid, particle and silicate.
Preferably, the EDI processing is two level EDI processing.
Deep desalting is carried out to water.
Preferably, first order EDI processing and second level EDI processing are cascaded structure, first order EDI processing runners load Be cation exchange resin, what EDI processing runners in the second level loaded is Ion Exchange Resin In The Mixing Bed.
The cation exchange resin that first order EDI processing runners load can remove heavy metal ion and calcium and magnesium excessive in water The easy fouling components such as ion ensure to flow into the water hardness index in second level EDI processing runners in level of security.
Preferably, the wavelength of ultraviolet light is 180nm-254nm.
Kill the microorganism retained in water.
Preferably, micro-filtration membrane aperture is 0.2-0.3 μm.
Particle and bacterium corpse in water removal are removed in retention.
A kind of novel ultrapure water treatment process provided by the invention, by reducing ultraviolet ray generating apparatus and micro-filtrate membrane filtration The frequency of use of device, so as to reduce the maintenance of ultraviolet ray generating apparatus and microporous filtration and maintenance cost, and then significantly Reduce the use cost of ultra-pure water.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art The modification of no creative contribution can be made to the present embodiment as needed after this specification is read, but as long as in this hair It is all protected in bright right be subject to Patent Law.
Embodiment 1:A kind of novel ultrapure water treatment process, includes the following steps:(1)Pretreatment:By tap water or common Mechanical admixture in deionized water filters out;(2)Activated carbon filters:Water after pretreatment carries out activated carbon adsorption;(3)It is reverse osmosis Membrane filtration:Through activated carbon adsorption, treated that water carries out reverse-osmosis treated with reverse osmosis membrane;(4)EDI processing:Pass through electrodeionization The first ultra-pure water is obtained after processing deep desalting;(5)Ultraviolet sterilization:The first ultra-pure water obtained after EDI is handled is through ultraviolet Line treatment with irradiation;(6)Micro-filtration processing:Water after ultraviolet treatment with irradiation is filtered with microporous filtration, obtains second Ultra-pure water.
It pre-processes to carry out by sand core filter plate and fibre columns.
Reverse osmosis membrane filtration is two-pass reverse osmosis membrane filtration.
Reverse osmosis membrane is the reverse osmosis membrane of the negatively charged anti-organic pollution in surface.
Reverse osmosis membrane is cellulose acetate rolled film.
EDI processing is two level EDI processing.
First order EDI processing and second level EDI processing for cascaded structure, what first order EDI processing runners loaded is sun from Sub-exchange resin, what EDI processing runners in the second level loaded is Ion Exchange Resin In The Mixing Bed.
The wavelength of ultraviolet light is 180nm-254nm.
Micro-filtration membrane aperture is 0.2-0.3 μm.
Embodiment 2:A kind of novel ultrapure water treatment process, includes the following steps:(1)Pretreatment:By tap water or common Mechanical admixture in deionized water filters out;(2)Activated carbon filters:Water after pretreatment carries out activated carbon adsorption, then carries out Ultraviolet sterilization;(3)Reverse osmosis membrane filtration:Through activated carbon adsorption, treated that water carries out reverse-osmosis treated with reverse osmosis membrane;(4) EDI processing:The first ultra-pure water is obtained after handling deep desalting by electrodeionization;(5)Ultraviolet sterilization:After EDI is handled The first ultra-pure water arrived is through ultraviolet treatment with irradiation;(6)Micro-filtration processing:Water micro-filtrate membrane filtration after ultraviolet treatment with irradiation Device is filtered, and obtains the second ultra-pure water.
It pre-processes to carry out by sand core filter plate and fibre columns.
Reverse osmosis membrane filtration is two-pass reverse osmosis membrane filtration.
Reverse osmosis membrane is the reverse osmosis membrane for the anti-organic pollution that surface is electroneutral.
Reverse osmosis membrane is cellulose acetate rolled film.
EDI processing is two level EDI processing.
First order EDI processing and second level EDI processing for cascaded structure, what first order EDI processing runners loaded is sun from Sub-exchange resin, what EDI processing runners in the second level loaded is Ion Exchange Resin In The Mixing Bed.
The wavelength of ultraviolet light is 180nm-254nm.
Micro-filtration membrane aperture is 0.2-0.3 μm.

Claims (10)

1. a kind of novel ultrapure water treatment process, which is characterized in that include the following steps:(1)Pretreatment:By tap water or common Mechanical admixture in deionized water filters out;(2)Activated carbon filters:Water after pretreatment carries out activated carbon adsorption;(3)It is reverse osmosis Membrane filtration:Through activated carbon adsorption, treated that water carries out reverse-osmosis treated with reverse osmosis membrane;(4)EDI processing:Pass through electrodeionization The first ultra-pure water is obtained after processing deep desalting;(5)Ultraviolet sterilization:The first ultra-pure water obtained after EDI is handled is through ultraviolet Line treatment with irradiation;(6)Micro-filtration processing:Water after ultraviolet treatment with irradiation is filtered with microporous filtration, obtains second Ultra-pure water.
2. a kind of novel ultrapure water treatment process according to claim 1, which is characterized in that water is through step(2)It lives After property charcoal filtration treatment, sterilization processing is carried out with ultraviolet light, then again through step(3)Carry out reverse osmosis membrane filtration processing.
3. a kind of novel ultrapure water treatment process according to claim 1, which is characterized in that the pretreatment is to pass through sand Core filter plate and fibre columns carry out.
4. a kind of novel ultrapure water treatment process according to claim 1, which is characterized in that the reverse osmosis membrane filtration is Two-pass reverse osmosis membrane filtration.
5. a kind of novel ultrapure water treatment process according to claim 4, which is characterized in that the reverse osmosis membrane is surface The reverse osmosis membrane of negatively charged or electroneutral anti-organic pollution.
6. a kind of novel ultrapure water treatment process according to claim 5, which is characterized in that the reverse osmosis membrane is acetic acid Cellulose rolled film.
7. a kind of novel ultrapure water treatment process according to claim 1, which is characterized in that the EDI processing is two level EDI processing.
8. a kind of novel ultrapure water treatment process according to claim 7, which is characterized in that first order EDI processing and the Two level EDI processing is cascaded structure, and what first order EDI processing runners loaded is cation exchange resin, second level EDI processing streams What road loaded is Ion Exchange Resin In The Mixing Bed.
9. a kind of novel ultrapure water treatment process according to claim 1, which is characterized in that the wavelength of the ultraviolet light is 180nm-254nm。
10. a kind of novel ultrapure water treatment process according to claim 1, which is characterized in that the micro-filtration membrane aperture is 0.2-0.3μm。
CN201711419706.1A 2017-12-25 2017-12-25 A kind of novel ultrapure water treatment process Pending CN108046493A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109179817A (en) * 2018-08-29 2019-01-11 江苏奇星流体设备有限公司 A kind of EDI water treatment technology
CN111453900A (en) * 2020-04-27 2020-07-28 苏州华新达饮品技术有限公司 Ultrapure water treatment process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN200992500Y (en) * 2007-01-24 2007-12-19 张茂科 Laboratory-level superpure water purifier
CN205011525U (en) * 2015-07-31 2016-02-03 天津邦盛净化设备工程有限公司 Electron industrial water's purification device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN200992500Y (en) * 2007-01-24 2007-12-19 张茂科 Laboratory-level superpure water purifier
CN205011525U (en) * 2015-07-31 2016-02-03 天津邦盛净化设备工程有限公司 Electron industrial water's purification device

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
梁毅: "《GMP教程》", 31 August 2015 *
王方: "《绿色电去离子水处理技术》", 31 May 2010 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109179817A (en) * 2018-08-29 2019-01-11 江苏奇星流体设备有限公司 A kind of EDI water treatment technology
CN111453900A (en) * 2020-04-27 2020-07-28 苏州华新达饮品技术有限公司 Ultrapure water treatment process

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Application publication date: 20180518

RJ01 Rejection of invention patent application after publication