CN108046491A - Portable accurately controls the device of light degradation organic matter - Google Patents
Portable accurately controls the device of light degradation organic matter Download PDFInfo
- Publication number
- CN108046491A CN108046491A CN201711331898.0A CN201711331898A CN108046491A CN 108046491 A CN108046491 A CN 108046491A CN 201711331898 A CN201711331898 A CN 201711331898A CN 108046491 A CN108046491 A CN 108046491A
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- stainless steel
- double
- layer stainless
- steel shell
- graded tube
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- 230000015556 catabolic process Effects 0.000 title claims abstract description 26
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 26
- 239000005416 organic matter Substances 0.000 title claims abstract description 24
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 56
- 239000010935 stainless steel Substances 0.000 claims abstract description 56
- 238000005070 sampling Methods 0.000 claims abstract description 34
- 238000005286 illumination Methods 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000001514 detection method Methods 0.000 claims abstract description 11
- 230000003287 optical effect Effects 0.000 claims description 26
- 239000012528 membrane Substances 0.000 claims description 15
- 229910000831 Steel Inorganic materials 0.000 claims description 14
- 239000010959 steel Substances 0.000 claims description 14
- 238000003760 magnetic stirring Methods 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 10
- 239000005662 Paraffin oil Substances 0.000 claims description 7
- 230000001105 regulatory effect Effects 0.000 claims description 7
- 238000012806 monitoring device Methods 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 abstract description 36
- 238000002474 experimental method Methods 0.000 abstract description 12
- 239000007789 gas Substances 0.000 description 13
- 238000007664 blowing Methods 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 230000001699 photocatalysis Effects 0.000 description 5
- 238000007146 photocatalysis Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000008399 tap water Substances 0.000 description 4
- 235000020679 tap water Nutrition 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000013461 design Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000004446 light reflex Effects 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000007974 sodium acetate buffer Substances 0.000 description 1
- BHZOKUMUHVTPBX-UHFFFAOYSA-M sodium acetic acid acetate Chemical compound [Na+].CC(O)=O.CC([O-])=O BHZOKUMUHVTPBX-UHFFFAOYSA-M 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/727—Treatment of water, waste water, or sewage by oxidation using pure oxygen or oxygen rich gas
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/74—Treatment of water, waste water, or sewage by oxidation with air
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/14—Suction devices, e.g. pumps; Ejector devices
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/02—Temperature
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/06—Controlling or monitoring parameters in water treatment pH
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/38—Gas flow rate
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N1/00—Sampling; Preparing specimens for investigation
- G01N1/02—Devices for withdrawing samples
- G01N1/10—Devices for withdrawing samples in the liquid or fluent state
- G01N1/14—Suction devices, e.g. pumps; Ejector devices
- G01N2001/1418—Depression, aspiration
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Analytical Chemistry (AREA)
- Physics & Mathematics (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The present invention relates to the devices that a kind of portable accurately controls light degradation organic matter, and adjusting apparatus, intensity of illumination detection device, light supply apparatus and sampler are surveyed including double-layer stainless steel shell, lid, air charging system, programmable controller, temperature；Lid is arranged on double-layer stainless steel cover top portion；Thieff hatch and removable inflating port are respectively arranged on the side wall of double-layer stainless steel shell；Exhaust outlet is provided on lid；Air charging system is arranged on removable inflating port；Sampler is arranged on thieff hatch；Temperature surveys adjusting apparatus, intensity of illumination detection device and light supply apparatus and is arranged at double-layer stainless steel enclosure；Programmable controller, which is placed in the bottom of double-layer stainless steel shell and surveys adjusting apparatus, intensity of illumination detection device, light supply apparatus and sampler with air charging system, temperature respectively, to be connected.The present invention accurately controls reaction condition, reduces the next error of water sampling conveyer belt, is easy to carry about with one, improving experiment accuracy and can reduce the advantages of manual operation causes error to experiment.
Description
Technical field
The invention belongs to photocatalysis technology field, the device more particularly to one kind for being related to a kind of light degradation organic matter can be taken
Belt accurately controls the device of light degradation organic matter, available for accurate control ph, intensity of illumination, reaction temperature, the reaction time,
The particular contents such as air-blowing amount and self-timing quantitative sampling.
Background technology
With the rapid development of Chinese society economy, a large amount of waste discharges are inevitable, and which results in serious
Environmental pollution destroys the ecological balance, affects people’s lives and health.In recent years, degrade and disappear using photocatalysis technology
Depollution object obtains the extensive concern of people, and is developed rapidly.With the development of photocatalysis technology, people's light reflex
The requirement of device is also increasingly harsher, therefore the design of novel photocatalysis reactor is of crucial importance.Especially in accurately control light reaction
Condition and the Photoreactor that can carry aspect are seldom so that there is an urgent need to this Photoreactors by people.
Nowadays, the Photoreactor build that people use is larger and can only be studied in laboratory, it has not been convenient to carry.When
Need to sample in the wild when being handled, generally require the sample that will be taken and transport to laboratory reaction treatment, and in acquisition, contain
It may result in water sample pollution in transit, influence test result, and it is also to take time and effort to gather, contain and transport, and is
Preferably light reaction is carried out in the wild, it is necessary to design a kind of Photoreactor of portable.
The light reaction of early stage is carried out under some very random reaction conditions mostly.For example some experiments are directly in room
Temperature is lower to be carried out, and ignores influence of the ambient temperature variation to experiment；Big experiment is sampled by manual time-keeping, is required for sample time
There is very big error, be not allowed so as to cause experimental data in stringent experiment.Error caused by human factor is difficult to keep away
Exempt from, therefore the accuracy and reproducibility of result can be produced bigger effect, so as to design a kind of light of accurate control reaction condition
Reactor is even more important.Publication number is to propose that one kind has for degrading phenol in the utility model patent of CN202186904U
Machine waste water ultrasound-photocatalysis combination reaction unit, realizes the control to temperature, pollutant concentration, catalyst amounts, pH value
System, but its main application, in phenolic comp ' ds pollution, there is no accurately control light intensity, air-blowing amount, sampling amount, time etc.；It is public
The number of opening is that a kind of integrated SOD enzyme activity light reaction laboratory apparatus is provided in the application for a patent for invention of CN104988061A, to light
It is controlled according to intensity, temperature, there is no accurately control time, sampling amount, pH value.
The content of the invention
In order to solve above-mentioned technical problem present in background technology, the present invention provides one kind to accurately control reaction item
Part can reduce the next error of water sampling conveyer belt, be easy to carry about with one, improving experiment accuracy and can reduce manual operation to reality
Test the device that the portable of error is caused accurately to control light degradation organic matter.
To achieve the above object, the present invention adopts the following technical scheme that：
A kind of portable accurately controls the device of light degradation organic matter, it is characterised in that：The portable is accurately controlled
The device of light degradation organic matter processed includes double-layer stainless steel shell, lid, air charging system, PLC technology with graded tube
Device, temperature survey adjusting apparatus, intensity of illumination detection device, light supply apparatus and sampler；The lid is arranged on scale
The double-layer stainless steel cover top portion of pipe；Thieff hatch is respectively arranged on the side wall of the double-layer stainless steel shell with graded tube
And removable inflating port；Exhaust outlet is provided on the lid；The removable inflating port is by carrying the bilayer of graded tube
It connects inside stainless steel casing with exhaust outlet；The air charging system is arranged on removable inflating port；The sampler is set
It puts on thieff hatch；The temperature is surveyed adjusting apparatus, intensity of illumination detection device and light supply apparatus and is arranged at graded tube
Double-layer stainless steel enclosure；The programmable controller is placed in the bottom of the double-layer stainless steel shell with graded tube and divides
Adjusting apparatus, intensity of illumination detection device, light supply apparatus and sampler is not surveyed with air charging system, temperature to be connected.
Preferably, air charging system of the present invention includes steel cylinder, gas flow valve, inlet air flow gauge, goes out air-flow
Gauge and removable inflating port；The steel cylinder is connected by gas flow valve and inlet air flow gauge with removable inflating port,
Facilitate and dismantle air charging system；The programmable controller is connected with gas flow valve；The outlet flowmeter is arranged on exhaust
On mouth.
Include temperature sensor, magnetic stirring apparatus preferably, temperature of the present invention surveys adjusting apparatus and add
Hot device；The temperature sensor, magnetic stirring apparatus and heater are separately positioned on outside the double-layer stainless steel with graded tube
Inside shell；The programmable controller is connected respectively with magnetic stirring apparatus and heater.
Preferably, the double-layer stainless steel shell of the present invention with graded tube includes inner housing and is sleeved on
Outer housing outside inner housing；Cavity is provided between the inner housing and outer housing；The bilayer with graded tube is stainless
The inlet opening and fluid hole to connect with cavity is provided on the outer housing of outer steel shell；The temperature survey adjusting apparatus, which further includes, fills out
Fill filling liquid in the cavities；The filling liquid is water or paraffin oil.
Preferably, intensity of illumination detection device of the present invention includes the first audible-visual annunciator and illuminance passes
Sensor；The illuminance sensor is arranged on the inner wall of the double-layer stainless steel shell with graded tube；The first acousto-optic report
Alert device is arranged on the outer wall of lid or the double-layer stainless steel shell with graded tube；First audible-visual annunciator and illumination
Degree sensor is connected respectively with programmable controller.
Preferably, light supply apparatus of the present invention include light source, belt switch optical filter, embedded optical filter and
Vacuum (-tight) housing；The belt switch optical filter and embedded optical filter are connected respectively with light source；The vacuum (-tight) housing covers on light source, band is opened
Close the outside of optical filter and embedded optical filter；The belt switch optical filter and embedded optical filter respectively with programmable control
Device processed is connected.
Preferably, sampler of the present invention includes pH monitoring devices and real time sample device；The pH
Monitoring device and real time sample device are separately positioned on thieff hatch；The pH monitoring devices include pH detectors and and pH
The second audible-visual annunciator that detector is connected；The pH detectors are arranged on thieff hatch；The real time sample device includes can
Replaceable filter membrane, electronic type electric control valve, the time relay and pump；The changeable type filter membrane passes through electronic type electric adjustable
Section valve is connected with pump；The time relay is connected with pump；The electronic type electric control valve and the time relay respectively with
Programmable controller is connected；The changeable type filter membrane is arranged on thieff hatch.
Preferably, programmable controller of the present invention includes surveying adjusting apparatus, light with air charging system, temperature respectively
The regulating switch being connected according to intensity detecting device, light supply apparatus and sampler.
Preferably, it is provided with graded tube on the side wall of the double-layer stainless steel shell of the present invention with graded tube
And handle.
It is an advantage of the invention that：
The present invention provides the device that a kind of portable accurately controls light degradation organic matter, including carrying the double of graded tube
Layer stainless steel casing, the light source of replaceable optical filter, lid, handle, changeable type filter membrane, steel cylinder, programmable controller, pH tune
Control system, automatic sampling system；Graded tube is glass tube, is arranged on the one side of double-layer stainless steel shell；It is double with graded tube
Both ends on the side wall of layer stainless steel casing are equipped with handle；Water is passed through among double-layer stainless steel shell with graded tube；It carries
Removable inflating port and liquid outlet are provided on the double-layer stainless steel side wall of outer shell of graded tube；Steel cylinder is by carrying graded tube
Removable inflating port inflation on double-layer stainless steel side wall of outer shell；Two on double-layer stainless steel side wall of outer shell with graded tube
Liquid outlet is connected respectively with automatic sampling system and pH control systems；It is provided on lid and the double-layer stainless steel with graded tube
The exhaust outlet that enclosure connects；One end of replaceable optical filtering sheet laser is arranged on lid, and the other end is stretched into scale
The double-layer stainless steel enclosure of pipe；Magnetic stirring apparatus, temperature sensor, heater are arranged on the bilayer with graded tube not
Rust outer steel shell bottom；Illuminance sensor is arranged on the side wall of the double-layer stainless steel shell with graded tube；First acousto-optic is warned
Report device is arranged on lid；Programmable controller regulate and control respectively air charging system, temperature survey adjusting apparatus, intensity of illumination detection device,
Light supply apparatus and sampler.Using apparatus of the present invention, reaction time, reaction temperature, intensity of illumination, pH can be accurately controlled
Value, air-blowing amount, sampling amount, are easy to carry about with one, can outdoor monitoring and water quality treatment, and reduce and experiment shone by manual control
Error, significantly improve the accuracy of reaction, it is easy to operate.
Description of the drawings
Fig. 1 is the structure diagram for the device that portable provided by the present invention accurately controls light degradation organic matter；
Fig. 2 is the structure diagram of graded tube of the present invention；
Fig. 3 is the structure diagram of cover of the present invention；
Fig. 4 is the structure diagram of pedestal of the present invention；
Fig. 5 is the structure diagram of sampling control system of the present invention；
The reference numerals are as follows：
1- light sources；2- belt switch optical filters；The embedded optical filters of 3-；4- vacuum (-tight) housings；5- lids；6- is double with graded tube
Layer stainless steel casing；The first audible-visual annunciators of 7-；8- illuminance sensors；9- temperature sensors；10- magnetic stirring apparatuses；11-
Heater；12- steel cylinders；The removable inflating ports of 13-；14- gas flow valves；15- graded tubes；16- handles；17- exhaust outlets；18-
Changeable type filter membrane；19- electronic type electric control valves；20- is pumped；21-pH detectors；The second audible-visual annunciators of 22-；23- air inlets
Flowmeter；24- outlet flowmeters；25- centrifuge tubes.
Specific embodiment
In order to be better understood from the above-mentioned technical proposal of the present invention, the present invention is made in the following with reference to the drawings and specific embodiments
It is described in further detail.
Referring to Fig. 1, Fig. 2, Fig. 3, Fig. 4 and Fig. 5, the present invention provides a kind of portables accurately to control light degradation organic matter
Device, the device of light degradation organic matter is by carrying the double-layer stainless steel shell 6 of graded tube, the light source 1 of replaceable optical filter, lid
Son 5, handle 16, changeable type filter membrane 18, steel cylinder 12, programmable controller, pH regulator control systems, automatic sampling system.Graded tube
15 be glass tube, is arranged on the one side of double-layer stainless steel shell；Whole double-layer stainless steel shell 6 with graded tube is that one end is opened
Mouth, the concave tubular structure in middle and lower part；Liquid outlet and removable is provided on 6 side wall of double-layer stainless steel shell with graded tube
Inflating port 13；Removable inflating port 13 on 6 side wall of double-layer stainless steel shell with graded tube is connected with steel cylinder 12；With quarter
Two liquid outlets spent on 6 side wall of double-layer stainless steel shell of pipe are connected respectively with automatic sampling system and pH regulator control systems；Lid
Son 5 is arranged on the top of the double-layer stainless steel shell 6 with graded tube；It is provided on lid 5 with the bilayer with graded tube not
The exhaust outlet 17 to connect inside rust outer steel shell 6；One end of replaceable optical filtering sheet laser 1 is arranged on lid 5, and the other end stretches into
Inside double-layer stainless steel shell 6 with graded tube；Heater 11 is in 6 bottom of double-layer stainless steel shell with graded tube.
Both ends of the handle 16 on the side wall of the double-layer stainless steel shell 6 with graded tube.
Water or paraffin oil are passed through among double-layer stainless steel shell 6 with graded tube, water or paraffin oil are passed through by control
Temperature, the controllable temperature entirely reacted.
The exhaust outlet 17 of cover is general ground, can be connected with drying tube, to prevent the effusion of steam in reaction process.
Portable accurately controls the device of light degradation organic matter to further include and is arranged on the double-layer stainless steel with graded tube
Magnetic stirring apparatus 10, temperature sensor 9 and the heater 11 of 6 bottom of shell, accurately control reaction temperature.
Portable accurately controls the device of light degradation organic matter to further include and is arranged on the double-layer stainless steel with graded tube
The changeable type filter membrane 18 at liquid outlet on 6 side wall of shell.
Illuminance sensor 8 on 6 inner wall of double-layer stainless steel shell with graded tube and the first acousto-optic report on lid 5
Alert device 7 is connected, and reaction intensity of illumination is accurately controlled by programmable controller.
The light source 1 of replaceable optical filter includes vacuum (-tight) housing 4, light source 1, the composite absorber 2 of belt switch and embedded filter
Mating plate 3.Vacuum (-tight) housing 4 is arranged on 3 outside of light source 1, the composite absorber of belt switch and embedded optical filter, plays protection light source
1 effect, constant light source 1 are xenon lamp, and light source 1 is adjusted by belt switch optical filter 2 and embedded optical filter 3, so as to
Reach the accurate control to visible ray, ultraviolet light, near infrared light and all-wave length light.
Air charging system include steel cylinder 12, gas flow valve 14, inlet air flow gauge 23, outlet flowmeter 24 and it is closable can
Tear formula inflating port 13 open, gas ducting inside the double-layer stainless steel shell 6 with graded tube with communicating.Steel cylinder 12 passes through gas flow
Valve 14 and inlet air flow gauge 23 are connected with removable inflating port 13, facilitate and dismantle air charging system；Programmable controller with
Gas flow valve is connected；Outlet flowmeter 24 is arranged on exhaust outlet 17.
Sampling system includes changeable type filter membrane 18, electronic type electric control valve 19, pump 20, the time relay, centrifuge tube
25, the time relay is connected with the motor of pump 20, controls sample time, passes through the adjustable sampling of electronic type electric control valve 19
Amount so as to accurately be controlled reaction sample time and sampling amount, avoids manual sampling from shining into error；Pass through the time relay
Sample interval, the opening and closing of control pump 20, by the programmable controller controls time relay, so as to reach are set
Automatic time sampling.
PH detecting systems include the second audible-visual annunciator 22, pH detectors 21, accurately control the pH value of reaction.
Programmable controller is arranged on the lower part of the double-layer stainless steel shell 6 with graded tube 15, is filled including magnetic agitation
Put control switch, the time sets switch, temperature adjusting switch, source current regulating switch, pH detector switch, sampling system control
System switch and air-blowing switch regulate and control reaction time, reaction light intensity, reaction temperature, pH value, air-blowing by adjusting button up and down
Amount and sampling amount reach accurate control reaction system.
In the use of the present invention, first carrying device to place needed for reaction, lid 5 is first opened, adjusts and filters needed for experiment
Piece powers on, and turns on the power switch；Then, pour into and treat degraded solutions and catalyst, observe the scale of solution, record reaction
Preceding liquor capacity covers lid 5；Water or paraffin oil are passed through according to experiment required temperature, water or paraffin oil are from graded tube
6 times mouths of double-layer stainless steel shell flow into, outflow suitable for reading；Magnetic stirring apparatus control switch is opened, rotating speed is set；Open air-blowing
Switch, adjusting gas flow valve 14 are filled with one kind of ozone, oxygen or air, record the reading of inlet air flow gauge 23, see simultaneously
Examine the reading of outlet flowmeter 24；Opening time sets switch, by adjusting switch, sets initial time, end time and takes
Sample time interval；Temp control switch is opened, adjusts the temperature to required temperature, is run by center determination key, when temperature is less than real
It when testing required temperature, can be heated by heater 11, when temperature is higher than experiment required temperature, water cooling can be passed through, so as to accurate
Control reaction temperature；Source current regulating switch is opened, setting electric current scope adjusts size of current, sensed by illuminance
Device Real-time Feedback intensity of illumination on a display screen, so as to control intensity of illumination, when electric current is beyond control, the first acoustooptic alarm 7
It beeps and flickers feux rouges, size of current is manually adjusted；PH detector switch is opened, pH scopes are set, reaction is super
It crosses or less than set pH scopes, the second acoustooptic alarm 22 will beep and flicker feux rouges, add in buffer solution tune
Save pH；Sampling control switch is opened, time relay operation controls automatic sampling time interval, replaces the filter membrane of suitable dimension,
Sampling amount is controlled by adjusting electronic type electric control valve 19, finally, liquid is flowed into centrifuge tube 25.
After reaction, turn off the power switch, stop being passed through for water or paraffin oil, record reading and the calculating of remaining liq
Throughput cleans reaction unit with tap water.
1 catalyst Visible Light Induced Photocatalytic sewage (accurate control time, light intensity, air-blowing amount, sampling amount) of embodiment
(1) device is carried to South Lake side, opens lid 5, it is visible filter to adjust experiment optical filter manually, connects electricity
Source turns on the power switch, and is passed through water；
(2) take in 100mg catalyst-adding devices, add at South Lake sewage to the 100mL graduation marks of glass graduated tube 15,
Cover lid 5；
(3) manual unlocking magnetic stirring apparatus control switch, is initialized by reset key, and rotating speed initial value is 100rpm, is pressed
It is 1000rpm that left button and upper plus key, which adjust rotating speed, is finally run by determination key；
(4) manual unlocking air-blowing switchs, adjusting gas flow valve 14, is filled with air, the reading of record inlet air flow gauge 23
For 450m3/ h, while the reading for observing air-flow gauge 24 is 242m3/ h subtracts gas output by air inflow, calculates reaction institute
The air capacity of consumption；
(5) the manual unlocking time sets switch, is initialized by reset key, initial time initial value is shown as 00：00, by a left side
It is 14 that key and upper plus-minus, which adjust initial time,：00, the setting of next exercise end time is entered by determination key, adjusts the end time
For 16：00 and by determination key, settings sample interval is 30min, is finally run by determination key；
(6) manual unlocking source current regulating switch, initial current 5A, setting electric current scope is 7.7~8.3A, by upper
It is 8A that plus key, which adjusts size of current, by illuminance sensor Real-time Feedback intensity of illumination on a display screen, when electric current beyond 7.7~
During 8.3A, the first acoustooptic alarm 7 beeps and flickers feux rouges, and it is 8A to need to adjust electric current manually again, so as to reach essence
The really purpose of control intensity of illumination；
(7) manual unlocking sampling control switch, time relay operation control the automatic sampling time to be taken every 0.5h
Sample replaces the filter membrane of 0.45um, is 4.5mL by adjusting electronic type electric control valve 19 to control sampling amount.At this point, pump starts to transport
Row, respectively 14：00、14：30、15：00、15：30、16：00 is sampled, and samples taken is fitted into centrifuge tube.
(8) after reaction, general supply is closed, the reading of remaining liq is recorded and calculates throughput, stops water, by device
Laboratory is carried go back to, reaction unit is cleaned with tap water.
2 catalyst ultraviolet degradation sulfosalicylic acid (accurate control time, light intensity, sampling amount and pH value) of embodiment
(1) lid 5 is opened, manual unlocking uv filter switch powers on, turns on the power switch, is passed through water；
(2) take in 100mg catalyst-adding devices, adding in sulfosalicylic acid, (concentration is 1 × 10-3Mol/L, 1mL), add water
To the 100mL graduation marks of glass graduated tube 15, lid 5 is covered；
(3) manual unlocking magnetic stirring apparatus control switch, is initialized by reset key, and rotating speed initial value is 100rpm, is pressed
It is 1100rpm that left button and upper plus key, which adjust rotating speed, is finally run by determination key；
(4) pH detector switch is opened, is initialized by reset key, it is 6.5~7.5 to set pH scopes, with the NaOH of 0.2M
Solution adjusts pH value of solution ≈ 7, and reaction will beep and flicker red beyond the pH scopes set, the second acoustooptic alarm 22
Acetic acid-sodium acetate buffer solution adjusting pH to 7 or so is added dropwise into reaction for light；
(5) the manual unlocking time sets switch, is initialized by reset key, initial time initial value is shown as 00：00, by a left side
It is 9 that key and upper plus-minus, which adjust initial time,：00, the setting of next exercise end time is entered by determination key, adjusts the end time
For 11：00 and by determination key, settings sample interval is 30min, is finally run by determination key；
(6) manual unlocking source current regulating switch, initial current 5A, setting electric current scope is 7.7~8.3A, by upper
It is 8A that plus key, which adjusts size of current, by illuminance sensor Real-time Feedback intensity of illumination on a display screen, when electric current beyond 7.7~
During 8.3A, acoustooptic alarm 7 beeps and flickers feux rouges, and it is 8A to need to adjust electric current manually again, so as to reach accurate control
The purpose of intensity of illumination processed；
(7) manual unlocking sampling control switch, time relay operation control the automatic sampling time to be taken every 0.5h
Sample replaces the filter membrane of 0.2um, is 4.5mL by adjusting electronic type electric control valve 19 to control sampling amount.At this point, pump starts to transport
Row, respectively 9:00、9：30、10：00、10：30、11：00 is sampled, and samples taken is fitted into centrifuge tube.
(8) after reaction, general supply is closed, the reading of remaining liq is recorded and calculates throughput, stopping is passed through water, uses
Tap water cleans reaction unit.
The infrared light degradation acetone of 3 catalyst of embodiment (accurate control time, light intensity, sampling amount, air-blowing amount, temperature)
(1) lid 5 is opened, manual unlocking infrared light optical filter switch powers on, turns on the power switch；
(2) take in 100mg catalyst-adding devices, adding in acetone, (concentration is 1 × 10-3Mol/L, 1mL), add water to glass
At the 100mL graduation marks of graded tube 15, lid 5 is covered；
(3) manual unlocking magnetic stirring apparatus control switch, is initialized by reset key, and rotating speed initial value is 100rpm, is pressed
It is 1100rpm that left button and upper plus key, which adjust rotating speed, is finally run by determination key；
(4) manual unlocking air-blowing switchs, adjusting gas flow valve 14, is filled with air, the reading of record inlet air flow gauge 23
For 600m3/ h, while the reading for observing air-flow gauge 24 is 350m3/ h subtracts gas output by air inflow, calculates reaction institute
The air capacity of consumption；
(5) open temp control switch, initialized by reset key, initial temperature be 25 DEG C, by using left button and it is upper plus
Key assignments temperature is for 120 DEG C and by acknowledgement key, and the heater under temperature control is begun to warm up, until temperature reaches 120 DEG C；
(6) the manual unlocking time sets switch, is initialized by reset key, initial time initial value is shown as 00：00, by a left side
It is 15 that key and upper plus key, which adjust initial time,：00, the setting of next exercise end time is entered by determination key, adjusts the end time
For 16：00 and by determination key, settings sample interval is 15min, is finally run by determination key；
(7) manual unlocking source current regulating switch, initial current 5A, setting electric current scope is 7.7~8.3A, by upper
It is 8A that plus key, which adjusts size of current, by illuminance sensor Real-time Feedback intensity of illumination on a display screen, when electric current beyond 7.7~
During 8.3A, the first acoustooptic alarm 7 beeps and flickers feux rouges, and it is 8A to need to adjust electric current manually again, so as to reach essence
The really purpose of control intensity of illumination；
(8) manual unlocking sampling control switch, time relay operation control the automatic sampling time to be taken every 15min
Sample replaces the filter membrane of 0.45um, is 4.5mL by adjusting electronic type electric control valve 19 to control sampling amount.At this point, pump starts to transport
Row, respectively 15：00、15：15、15：30、15：45、16：00 is sampled, and samples taken is fitted into centrifuge tube and label.
(9) after reaction, general supply is closed, the reading of remaining liq is recorded and calculates throughput, with tap water to anti-
Device is answered to clean.
Claims (9)
1. a kind of portable accurately controls the device of light degradation organic matter, it is characterised in that：The portable accurately controls
The device of light degradation organic matter includes the double-layer stainless steel shell with graded tube（6）, lid（5）, air charging system, programmable control
Device processed, temperature survey adjusting apparatus, intensity of illumination detection device, light supply apparatus and sampler；The lid（5）It is arranged on and carries
The double-layer stainless steel shell of graded tube（6）Top；The double-layer stainless steel shell with graded tube（6）Side wall on set respectively
It is equipped with thieff hatch and removable inflating port（13）；The lid（5）On be provided with exhaust outlet（17）；The removable inflating port
（13）By the double-layer stainless steel shell for carrying graded tube（6）Internal and exhaust outlet（17）It connects；The air charging system is set
In removable inflating port（13）On；The sampler is arranged on thieff hatch；The temperature surveys adjusting apparatus, intensity of illumination detection
Device and light supply apparatus are arranged at the double-layer stainless steel shell with graded tube（6）It is internal；The programmable controller is put
In the double-layer stainless steel shell with graded tube（6）Bottom and respectively with air charging system, temperature survey adjusting apparatus, intensity of illumination examine
Device, light supply apparatus and sampler is surveyed to be connected.
2. portable according to claim 1 accurately controls the device of light degradation organic matter, it is characterised in that：It is described to fill
Device of air includes steel cylinder（12）, outlet flowmeter（24）, removable inflating port（13）, inlet air flow gauge（23）And gas flow
Valve（14）；The steel cylinder（12）Pass through gas flow valve（14）And inlet air flow gauge（23）With removable inflating port（13）Connect
It is logical；The programmable controller and gas flow valve（14）It is connected；The outlet flowmeter（24）It is arranged on exhaust outlet（17）On.
3. portable according to claim 2 accurately controls the device of light degradation organic matter, it is characterised in that：The temperature
Surveying adjusting apparatus includes temperature sensor（9）, magnetic stirring apparatus（10）And heater（11）；The temperature sensor（9）、
Magnetic stirring apparatus（10）And heater（11）It is separately positioned on the double-layer stainless steel shell with graded tube（6）It is internal；Institute
State programmable controller respectively with magnetic stirring apparatus（10）And heater（11）It is connected.
4. portable according to claim 3 accurately controls the device of light degradation organic matter, it is characterised in that：The band
There is the double-layer stainless steel shell of graded tube（6）Including inner housing and the outer housing being sleeved on outside inner housing；The inner housing
Cavity is provided between outer housing；The double-layer stainless steel shell with graded tube（6）Outer housing on be provided with it is empty
The inlet opening and fluid hole that chamber connects；The temperature surveys adjusting apparatus and further includes the filling liquid of filling in the cavities；It is described to fill out
Filling liquid is water or paraffin oil.
5. portable according to claim 4 accurately controls the device of light degradation organic matter, it is characterised in that：The light
Include the first audible-visual annunciator according to intensity detecting device（7）And illuminance sensor（8）；The illuminance sensor（8）If
It puts in the double-layer stainless steel shell with graded tube（6）Inner wall on；First audible-visual annunciator（7）It is arranged on lid（5）
And/or the double-layer stainless steel shell with graded tube（6）Outer wall on；First audible-visual annunciator（7）And illuminance passes
Sensor（8）It is connected respectively with programmable controller.
6. portable according to claim 5 accurately controls the device of light degradation organic matter, it is characterised in that：The light
Source device includes light source（1）, belt switch optical filter（2）, embedded optical filter（3）And vacuum (-tight) housing（4）；The belt switch filters
Piece（2）And embedded optical filter（3）Respectively with light source（1）It is connected；The vacuum (-tight) housing（4）Cover on light source（1）, belt switch filter
Piece（2）And embedded optical filter（3）Outside；The belt switch optical filter（2）And embedded optical filter（3）Respectively with can
Programmable controller is connected.
7. portable according to claim 6 accurately controls the device of light degradation organic matter, it is characterised in that：It is described to take
Sampling device includes pH monitoring devices and real time sample device；The pH monitoring devices and real time sample device are separately positioned on
On thieff hatch；The pH monitoring devices include pH detectors（21）And with pH detectors（21）The second connected audible-visual annunciator
（22）；The pH detectors（21）It is arranged on thieff hatch；The real time sample device includes changeable type filter membrane（18）, electronics
Formula electric control valve（19）, the time relay and pump（20）；The changeable type filter membrane（18）Pass through electronic type motorized adjustment
Valve（19）With pump（20）It is connected；The time relay and pump（20）It is connected；The electronic type electric control valve（19）With timely
Between relay be connected respectively with programmable controller；The changeable type filter membrane（18）It is arranged on thieff hatch.
8. the device of light degradation organic matter is accurately controlled according to any portables of claim 1-7, it is characterised in that：
The programmable controller include respectively with air charging system, temperature survey adjusting apparatus, intensity of illumination detection device, light supply apparatus and
The regulating switch that sampler is connected.
9. portable according to claim 8 accurately controls the device of light degradation organic matter, it is characterised in that：The band
There is the double-layer stainless steel shell of graded tube（6）Side wall on be provided with graded tube（15）And handle（16）.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201711331898.0A CN108046491A (en) | 2017-12-13 | 2017-12-13 | Portable accurately controls the device of light degradation organic matter |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711331898.0A CN108046491A (en) | 2017-12-13 | 2017-12-13 | Portable accurately controls the device of light degradation organic matter |
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| CN108046491A true CN108046491A (en) | 2018-05-18 |
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