CN108034367A - A kind of high tenacity corrugated case adhesive - Google Patents
A kind of high tenacity corrugated case adhesive Download PDFInfo
- Publication number
- CN108034367A CN108034367A CN201711282943.8A CN201711282943A CN108034367A CN 108034367 A CN108034367 A CN 108034367A CN 201711282943 A CN201711282943 A CN 201711282943A CN 108034367 A CN108034367 A CN 108034367A
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- Prior art keywords
- parts
- cornstarch
- corrugated case
- high tenacity
- compound
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Medicinal Preparation (AREA)
Abstract
The invention discloses a kind of high tenacity corrugated case adhesive, its raw material includes by weight：60 70 parts of major ingredient, 1.5 parts of hydrogen peroxidase 10 .5,12 parts of potassium hydroxide, 5 11 parts of crosslinking accelerator, 28 parts of precipitated calcium carbonate, 14 parts of mica powder, 40 80 parts of deionized water.Major ingredient includes by weight：30 50 parts of Lotus Root Starch, 10 20 parts of etherification starch, 48 parts of cornstarch compound.Cornstarch compound is prepared using following technique：Cornstarch, oxidized polyethylene wax, potassium hydroxide, water are uniformly mixed, heated up, adds ethylene oxide stirring, neutralization is in neutrality to obtain cornstarch compound.High tenacity corrugated case adhesive proposed by the present invention, good toughness, stability is good, and adhesion strength is high, and water proofing property is extremely excellent with antiseptic property, is not easy the moisture absorption, and cost is low, storage cycle length.
Description
Technical field
The present invention relates to adhesive technical field, more particularly to a kind of high tenacity corrugated case adhesive.
Background technology
It is many to be presently used for carton adhesive species, there is three-aldehyde glue and white glue with vinyl etc..Some adhesive are being produced and applied
During can discharge free state formaldehyde, it is serious to human body and environmental hazard；Some adhesive, water resistance and moisture-proof are poor, easily
The moisture absorption in humid air, adhesive strength is not high, degraded toughness, causes its application significantly limited.How a kind of not only ring is prepared
Protect, and be not easy the moisture absorption, the carton adhesive of good toughness, become the current technical issues that need to address.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of high tenacity corrugated case adhesive, tough
Property it is good, stability is good, and adhesion strength is high, and water proofing property and antiseptic property are extremely excellent, are not easy the moisture absorption, and cost is low, and storage is all
Phase is grown.
A kind of high tenacity corrugated case adhesive proposed by the present invention, its raw material include by weight：Major ingredient 60-70
Part .5-1.5 parts of hydrogen peroxidase 10,1-2 parts of potassium hydroxide, 5-11 parts of crosslinking accelerator, 2-8 parts of precipitated calcium carbonate, mica powder 1-4
Part, 40-80 parts of deionized water.
Preferably, crosslinking accelerator includes by weight：1-2 parts of borax, 1-2 parts of maleic anhydride, 2-4 parts of polyvinyl alcohol,
1-3 parts of melamine resin.
Preferably, major ingredient includes by weight：30-50 parts of Lotus Root Starch, 10-20 parts of etherification starch, cornstarch is compound
4-8 parts of thing.
Preferably, cornstarch compound is prepared using following technique：By cornstarch, oxidized polyethylene wax, hydroxide
Potassium, water are uniformly mixed, heating, add ethylene oxide stirring, and neutralization is in neutrality to obtain cornstarch compound.
Preferably, in the preparation process of cornstarch compound, 130-145 DEG C is warming up to, adds ethylene oxide stirring 20-
40min。
Preferably, in the preparation process of cornstarch compound, cornstarch, oxidized polyethylene wax, potassium hydroxide, water,
The weight ratio of ethylene oxide is 30-40：4-8：1-2：80-120：4-12.
The present invention uses Lotus Root Starch, etherification starch, cornstarch compound to be handed over for major ingredient using hydrogen peroxide
Connection, oxidation effectiveness is good, and mutual degree of scatter is high, and stability is good, is not easy the moisture absorption, and adhesion strength is high；The cornstarch of the present invention
In compound, cornstarch under the cooperation of oxidized polyethylene wax after basification, with ethylene oxide with firm ehter bond knot
Structure combines, and not only stablizing effect is good, and with it is good emulsify, disperse, soaking, solubilizing effect；Cornstarch compound with
Lotus Root Starch, the degree of scatter of etherification starch are high, and stability is good, good toughness, then coordinate precipitated calcium carbonate, mica powder effect,
Solid content is high, and stability is good, and uniformity is good, and adhesion strength is high, and cost is low, storage cycle length；And borax and polyvinyl alcohol,
Melamine resin effect can improve crosslink density, make the adhesion strength, water proofing property and antiseptic property of the present invention extremely excellent
Different, wherein melamine resin can effectively strengthen the good fluidity of the present invention, and Lotus Root Starch, etherification starch, corn form sediment
The mixing uniformity of flour complexes is good, not only can shorten drying time, but also coordinates with maleic anhydride, is ensureing water proofing property with sticking
On the premise of degree, it can effectively strengthen glued membrane pliability.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of high tenacity corrugated case adhesive, its raw material include：Major ingredient 60g, hydrogen peroxide 1.5g, potassium hydroxide
1g, crosslinking accelerator 11g, precipitated calcium carbonate 2g, mica powder 4g, deionized water 40g.
Major ingredient includes：Lotus Root Starch 50g, etherification starch 10g, cornstarch compound 8g.Crosslinking accelerator includes：Borax
1g, maleic anhydride 2g, polyvinyl alcohol 2g, melamine resin 3g.
Cornstarch compound is prepared using following technique：By 30g cornstarch, 8g oxidized polyethylene wax, 1g hydroxides
Potassium, 120g water are uniformly mixed, and are warming up to 130 DEG C, add 12g ethylene oxide stirring 20min, and neutralization is in neutrality to obtain cornstarch
Compound.
By detection, the adhesive strength of 4 gained adhesive of embodiment is 28Mpa, is put into 40 DEG C of water and soaks 2h, and bonding is strong
Degree is still 23Mpa.
Embodiment 2
A kind of high tenacity corrugated case adhesive, its raw material include：Major ingredient 70g, hydrogen peroxidase 10 .5g, potassium hydroxide
2g, crosslinking accelerator 5g, precipitated calcium carbonate 8g, mica powder 1g, deionized water 80g.
Major ingredient includes：Lotus Root Starch 30g, etherification starch 20g, cornstarch compound 4g.Crosslinking accelerator includes：Borax
2g, maleic anhydride 1g, polyvinyl alcohol 4g, melamine resin 1g.
Cornstarch compound is prepared using following technique：By 40g cornstarch, 4g oxidized polyethylene wax, 2g hydroxides
Potassium, 80g water are uniformly mixed, and are warming up to 145 DEG C, add 4g ethylene oxide stirring 40min, and neutralization, which is in neutrality to obtain cornstarch, answers
Compound.
By detection, the adhesive strength of 4 gained adhesive of embodiment is 27Mpa, is put into 40 DEG C of water and soaks 2h, and bonding is strong
Degree is still 20Mpa.
Embodiment 3
A kind of high tenacity corrugated case adhesive, its raw material include：Major ingredient 64g, hydrogen peroxide 1.2g, potassium hydroxide
1.2g, crosslinking accelerator 9g, precipitated calcium carbonate 4g, mica powder 3g, deionized water 50g.
Major ingredient includes：Lotus Root Starch 45g, etherification starch 12g, cornstarch compound 7g.Crosslinking accelerator includes：Borax
1.2g, maleic anhydride 1.7g, polyvinyl alcohol 2.5g, melamine resin 2.5g.
Cornstarch compound is prepared using following technique：By 33g cornstarch, 7g oxidized polyethylene wax, 1.2g hydrogen-oxygens
Change potassium, 110g water are uniformly mixed, and are warming up to 135 DEG C, add 10g ethylene oxide stirring 25min, and neutralization is in neutrality to obtain corn shallow lake
Flour complexes.
By detection, the adhesive strength of 4 gained adhesive of embodiment is 29Mpa, is put into 40 DEG C of water and soaks 2h, and bonding is strong
Degree is still 21Mpa.
Embodiment 4
A kind of high tenacity corrugated case adhesive, its raw material include：Major ingredient 66g, hydrogen peroxidase 10 .8g, potassium hydroxide
1.8g, crosslinking accelerator 7g, precipitated calcium carbonate 6g, mica powder 2g, deionized water 70g.
Major ingredient includes：Lotus Root Starch 35g, etherification starch 18g, cornstarch compound 5g.Crosslinking accelerator includes：Borax
1.8g, maleic anhydride 1.3g, polyvinyl alcohol 3.5g, melamine resin 1.5g.
Cornstarch compound is prepared using following technique：By 37g cornstarch, 5g oxidized polyethylene wax, 1.8g hydrogen-oxygens
Change potassium, 90g water are uniformly mixed, and are warming up to 140 DEG C, add 6g ethylene oxide stirring 35min, and neutralization is in neutrality to obtain cornstarch
Compound.
By detection, the adhesive strength of 4 gained adhesive of embodiment is 28Mpa, is put into 40 DEG C of water and soaks 2h, and bonding is strong
Degree is still 22Mpa.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of high tenacity corrugated case adhesive, it is characterised in that its raw material includes by weight：60-70 parts of major ingredient, mistake
0.5-1.5 parts of hydrogen oxide, 1-2 parts of potassium hydroxide, 5-11 parts of crosslinking accelerator, 2-8 parts of precipitated calcium carbonate, 1-4 parts of mica powder, goes
40-80 parts of ionized water.
2. high tenacity corrugated case adhesive according to claim 1, it is characterised in that crosslinking accelerator wraps by weight
Include：1-2 parts of borax, 1-2 parts of maleic anhydride, 2-4 parts of polyvinyl alcohol, 1-3 parts of melamine resin.
3. high tenacity corrugated case adhesive according to claim 1 or claim 2, it is characterised in that major ingredient includes by weight：
30-50 parts of Lotus Root Starch, 10-20 parts of etherification starch, 4-8 parts of cornstarch compound.
4. high tenacity corrugated case adhesive according to claim 3, it is characterised in that cornstarch compound is using such as
It is prepared by lower technique：Cornstarch, oxidized polyethylene wax, potassium hydroxide, water are uniformly mixed, heated up, adds ethylene oxide stirring,
Neutralization is in neutrality to obtain cornstarch compound.
5. high tenacity corrugated case adhesive according to claim 4, it is characterised in that the preparation of cornstarch compound
In technique, 130-145 DEG C is warming up to, adds ethylene oxide stirring 20-40min.
6. according to the high tenacity corrugated case adhesive of claim 4 or 5, it is characterised in that cornstarch compound
In preparation process, cornstarch, oxidized polyethylene wax, potassium hydroxide, water, the weight ratio of ethylene oxide are 30-40：4-8：1-2：
80-120：4-12.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711282943.8A CN108034367A (en) | 2017-12-07 | 2017-12-07 | A kind of high tenacity corrugated case adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711282943.8A CN108034367A (en) | 2017-12-07 | 2017-12-07 | A kind of high tenacity corrugated case adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108034367A true CN108034367A (en) | 2018-05-15 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711282943.8A Pending CN108034367A (en) | 2017-12-07 | 2017-12-07 | A kind of high tenacity corrugated case adhesive |
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| CN (1) | CN108034367A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112277392A (en) * | 2020-10-26 | 2021-01-29 | 无锡市辰华包装有限公司 | Preparation method of antibacterial anti-static corrugated board |
| CN113583589A (en) * | 2021-07-23 | 2021-11-02 | 临沂天勤塑业有限公司 | Sterilization sticky mat for pets and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115551A (en) * | 2010-12-31 | 2011-07-06 | 永港伟方（北京）科技股份有限公司 | Starch-based nano biological latex and preparation method thereof |
| CN102965066A (en) * | 2012-12-04 | 2013-03-13 | 苏州井上高分子新材料有限公司 | Adhesive for environment-friendly regeneration sponge and preparation method thereof |
| CN104194672A (en) * | 2014-09-26 | 2014-12-10 | 无锡海特信成高分子科技有限公司 | Adhesive for engineered wood floor |
-
2017
- 2017-12-07 CN CN201711282943.8A patent/CN108034367A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102115551A (en) * | 2010-12-31 | 2011-07-06 | 永港伟方（北京）科技股份有限公司 | Starch-based nano biological latex and preparation method thereof |
| CN102965066A (en) * | 2012-12-04 | 2013-03-13 | 苏州井上高分子新材料有限公司 | Adhesive for environment-friendly regeneration sponge and preparation method thereof |
| CN104194672A (en) * | 2014-09-26 | 2014-12-10 | 无锡海特信成高分子科技有限公司 | Adhesive for engineered wood floor |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112277392A (en) * | 2020-10-26 | 2021-01-29 | 无锡市辰华包装有限公司 | Preparation method of antibacterial anti-static corrugated board |
| CN112277392B (en) * | 2020-10-26 | 2022-05-10 | 无锡市辰华包装有限公司 | Preparation method of antibacterial anti-static corrugated board |
| CN113583589A (en) * | 2021-07-23 | 2021-11-02 | 临沂天勤塑业有限公司 | Sterilization sticky mat for pets and preparation method thereof |
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Application publication date: 20180515 |
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