CN108030432A - Flexibility and the preferable toiler roll of toughness and its production method - Google Patents
Flexibility and the preferable toiler roll of toughness and its production method Download PDFInfo
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- CN108030432A CN108030432A CN201711393488.9A CN201711393488A CN108030432A CN 108030432 A CN108030432 A CN 108030432A CN 201711393488 A CN201711393488 A CN 201711393488A CN 108030432 A CN108030432 A CN 108030432A
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/001—Modification of pulp properties
- D21C9/007—Modification of pulp properties by mechanical or physical means
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21D—TREATMENT OF THE MATERIALS BEFORE PASSING TO THE PAPER-MAKING MACHINE
- D21D5/00—Purification of the pulp suspension by mechanical means; Apparatus therefor
- D21D5/02—Straining or screening the pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F11/00—Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/12—Pulp from non-woody plants or crops, e.g. cotton, flax, straw, bagasse
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/16—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only modified by a particular after-treatment
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Sanitary Thin Papers (AREA)
Abstract
The invention belongs to daily chemical product technical field, and in particular to the preferable toiler roll of a kind of flexibility and toughness and its production method.The production method of toiler roll of the present invention, rely on existing paper technology and equipment, processing repeatedly only by carrying out freezing ice-melt to traditional pulp, realize the modification of paper pulp fiber property, the ductile strength between paper pulp fiber is further improved, while also improves the softness of paper pulp fiber.Modified paper pulp is that being substantially improved for roll paper performance can be achieved only with existing paper Processes and apparatus processed, further improves the softness and toughness of toiler roll, while its intensity and water absorbing properties have also been lifted.
Description
Technical field
The invention belongs to daily chemical product technical field, and in particular to the preferable toiler roll of a kind of flexibility and toughness and its
Production method.
Background technology
Roll paper is a kind of widely used daily life paper, and use is widely spread with the advantage such as its health, convenient, and
It is subject to many favors of consumer.With the increasingly increase of roll paper demand, the requirement to its quality and performance is also higher and higher.
In addition to requiring roll paper and there is preferable antibacterial and sanitation performance, the requirement of higher is it is also proposed to its softness and toughness.
Roll paper species currently on the market is more, but due between each producer manufacturing process difference, cause to be produced
Roll paper product quality it is uneven, especially the flexibility of roll paper and toughness are difficult to meet the needs of client at the same time.
Chinese patent CN103696318A discloses a kind of production method of the face tissue of soft fluffy, and this method is matched somebody with somebody with height
Weight ratio is 65-75：The cane syrup and wood pulp of 25-35 is main raw material(s), using five sand removing processs, and it is each by adjusting
Pulp density is different before and after equipment；It is aided with using flexible wire-dividing broom purification beating process；Page technique is penetrated using high speed hot wind, it is raw
Output soft fluffy, toughness are strong, cost is low and meet the face tissue of sanitary standard.This method is changed using existing paper technique processed
Into further improving the flexibility and toughness of obtained face tissue.But the improvement for technique in this method is needed to rely on and set
Standby improvement could be realized, limit the technological improvement of some small-sized Zhi Zhi enterprises.
The content of the invention
For this reason, the technical problems to be solved by the invention are to provide a kind of production method of toiler roll, it is existing to solve
There is the problem of toiler roll can not meet flexibility and toughness requirements in technology.
In order to solve the above technical problems, the production method of toiler roll of the present invention, includes the following steps：
(1) pulp modifying is handled：Obtained paper pulp in a conventional manner is taken, freezing processing is carried out under cryogenic conditions, then will
Paper pulp after freezing processing carries out ice-melt processing, and circulates the step of above-mentioned paper pulp freezing and paper pulp ice-melt are handled, and is modified
Paper pulp after processing, it is spare；
(2) desanding：Desanding processing is carried out to paper pulp using five sand removing processs；
(3) screening the pulp：Screening the pulp processing is carried out to obtained slurries, to weed out undecomposed fiber in slurries；
(4) whitewash：Slurries are sprayed on shaping screen cloth and form paper spoke；
(5) it is dehydrated：Spoke made from paper is carried out dehydrating；
(6) it is dry：Paper spoke is subjected to press dewatering and heated-air drying processing；
(7) peel off：Paper spoke is peeled off using the scraper of 75 ° of tool point angles；
(8) wind：Paper spoke after stripping is wound, obtains body paper；
(9) pack：By gained body paper through rewinding, cutting and packing processes, to obtain the final product.
In the step (1), the paper pulp freezing processing step controlled at -20~-25 DEG C, the paper pulp ice-melt
Processing step controlled at 4~10 DEG C.
In the step (1), the cycle-index of the paper pulp freezing and paper pulp ice-melt processing step is 3-5 times.
In the step (1), the temperature difference described in every rear one cycle between freezing processing step and ice-melt processing step
More than the temperature difference described in preceding one cycle between freezing processing step and ice-melt processing step.
In the step (1), the temperature of freezing processing is less than freezing processing step in previous circulation in every latter circulation
Temperature, the temperature that ice-melt is handled in every latter circulation are above the temperature that ice-melt is handled in previous circulation.
In the step (1), the step of adding mannitol is additionally included in paper pulp described in the forward direction of freezing processing step.
The additive amount of the mannitol is the 5-10wt% of the pulp quality.
The paper pulp is starched for sucrose and/or wood pulp.
In the step (2), the desanding step specifically includes：A, one of macropore gauze is set before pulp washing case, except coarse sand；
Sand removing machine is installed, except middle sand before defibrination B,；C, one of mesoporous gauze is set after defibrination；D, sand trap is set before stuff box is entered；E、
One of aperture gauze is set in the head box lower part of paper machine, except fine sand.
The invention also discloses the toiler roll produced by the method.
The production method of toiler roll of the present invention, relies on existing paper technology and equipment, only by conventional paper
Slurry freeze-processing repeatedly of ice-melt, the modification of paper pulp fiber property is realized, is further improved between paper pulp fiber
Ductile strength, while also improve the softness of paper pulp fiber.Modified paper pulp is only with existing paper Processes and apparatus processed
Roll paper performance can be achieved to be substantially improved, further improve the softness and toughness of toiler roll, at the same its intensity and
Water absorbing properties have also been lifted.
The production method of toiler roll of the present invention, by controlling the temperature of freezing step and ice-melt step in each circulation
Difference increase, further improves the softness and toughness of roll paper, while its intensity and water absorbing properties are also further lifted.
In addition, production method of the present invention, also further improves roll paper by adding mannitol to help modifying agent
Performance.
Embodiment
Embodiment 1
The production method of toiler roll described in the present embodiment includes the following steps：
(1) pulp modifying is handled：Obtained sucrose slurry in a conventional manner is taken, freezing processing is carried out under the conditions of -20 DEG C to complete
It is complete to freeze, the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 10 DEG C and is handled to the thawing, and according to upper completely that freezes
The temperature conditionss of freezing and ice-melt step are stated, the step 3 time of above-mentioned paper pulp freezing and paper pulp ice-melt processing is circulated, obtains modified place
Paper pulp after reason, it is spare；
(2) desanding：Using five sand removing processs, it is specially：A, one of macropore gauze is set before pulp washing case, except coarse sand；B, defibrination
Preceding installation sand removing machine, except middle sand；C, one of mesoporous gauze is set after defibrination；D, sand trap is set before stuff box is entered；E, in copy paper
The head box lower part of machine sets one of aperture gauze, except fine sand；
(3) screening the pulp：Screening the pulp processing is carried out to slurries, to weed out undecomposed block or large-size fiber in slurries；
(4) whitewash：Slurries are sprayed on shaping screen cloth and form paper spoke, spouting velocity and the ratio control of shaping screen cloth speed exist
0.925-0.945；
(5) it is dehydrated：Paper spoke is carried out dehydrating, the mass dryness fraction for making paper spoke is 8%；
(6) it is dry：Paper spoke is subjected to press dewatering and heated-air drying processing (100-150 DEG C), the mass dryness fraction to paper spoke is 96%；
(7) peel off：Paper spoke is peeled off using the scraper of 75 ° of tool point angles；
(8) wind：Paper spoke after stripping is wound, obtains body paper；
(9) pack：By body paper through rewinding, cutting and packing processes, ultra-toughness roll paper is obtained.
Embodiment 2
The production method of toiler roll described in the present embodiment is same as Example 1, it is differed only in, paper in the step (1)
It is different to starch modifying processing step, is specially：Obtained wood pulp in a conventional manner is taken, freezing processing is carried out under the conditions of -25 DEG C
Freeze to complete, the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 4 DEG C and is handled to the thawing completely that freezes, and according to
The temperature conditionss of above-mentioned freezing and ice-melt step, circulate the step 5 time of above-mentioned paper pulp freezing and paper pulp ice-melt processing, are modified
Paper pulp after processing, it is spare.
Embodiment 3
The production method of toiler roll described in the present embodiment is same as Example 1, it is differed only in, paper in the step (1)
It is different to starch modifying processing step, is specially：Take obtained sucrose slurry and wood pulp (mass ratio 1 in a conventional manner：1), in -20
Freezing processing is carried out under the conditions of DEG C to freeze to complete, and the paper pulp after freezing processing is then subjected to ice-melt processing under the conditions of 4 DEG C
Melt completely to freezing；Paper pulp then is carried out freezing processing under the conditions of -22 DEG C again to freeze to complete, then by freezing
Paper pulp after reason carries out ice-melt under the conditions of 4 DEG C and handles to the thawing completely that freezes；Then again under the conditions of -25 DEG C by paper pulp into
Row freezing processing freezes to complete, and the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 4 DEG C and is handled to icing completely
Melt, obtain the paper pulp after modification, it is spare.
Embodiment 4
The production method of toiler roll described in the present embodiment is same as Example 1, it is differed only in, paper in the step (1)
It is different to starch modifying processing step, is specially：Take obtained sucrose slurry and wood pulp (mass ratio 1 in a conventional manner：1), in -20
Freezing processing is carried out under the conditions of DEG C to freeze to complete, and the paper pulp after freezing processing is then subjected to ice-melt processing under the conditions of 10 DEG C
Melt completely to freezing；Paper pulp then is carried out freezing processing under the conditions of -22 DEG C again to freeze to complete, then by freezing
Paper pulp after reason carries out ice-melt under the conditions of 10 DEG C and handles to the thawing completely that freezes；Then again under the conditions of -25 DEG C by paper pulp
Carry out freezing processing to freeze to complete, the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 10 DEG C and is handled to having frozen
It is complete to melt, the paper pulp after modification is obtained, it is spare.
Embodiment 5
The production method of toiler roll described in the present embodiment is same as Example 1, it is differed only in, paper in the step (1)
It is different to starch modifying processing step, is specially：Take obtained sucrose slurry and wood pulp (mass ratio 1 in a conventional manner：1), in -20
Freezing processing is carried out under the conditions of DEG C to freeze to complete, and the paper pulp after freezing processing is then subjected to ice-melt processing under the conditions of 4 DEG C
Melt completely to freezing；Paper pulp then is carried out freezing processing under the conditions of -20 DEG C again to freeze to complete, then by freezing
Paper pulp after reason carries out ice-melt under the conditions of 7 DEG C and handles to the thawing completely that freezes；Then again under the conditions of -20 DEG C by paper pulp into
Row freezing processing freezes to complete, and the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 10 DEG C and is handled to icing completely
Melt, obtain the paper pulp after modification, it is spare.
Embodiment 6
The production method of toiler roll described in the present embodiment is same as Example 1, it is differed only in, paper in the step (1)
It is different to starch modifying processing step, is specially：Take obtained sucrose slurry and wood pulp (mass ratio 1 in a conventional manner：1), in -25
Freezing processing is carried out under the conditions of DEG C to freeze to complete, and the paper pulp after freezing processing is then subjected to ice-melt processing under the conditions of 4 DEG C
Melt completely to freezing；Paper pulp then is carried out freezing processing under the conditions of -25 DEG C again to freeze to complete, then by freezing
Paper pulp after reason carries out ice-melt under the conditions of 7 DEG C and handles to the thawing completely that freezes；Then again under the conditions of -25 DEG C by paper pulp into
Row freezing processing freezes to complete, and the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 10 DEG C and is handled to icing completely
Melt, obtain the paper pulp after modification, it is spare.
Embodiment 7
The production method of toiler roll described in the present embodiment is same as Example 1, it is differed only in, paper in the step (1)
It is different to starch modifying processing step, is specially：Take obtained sucrose slurry and wood pulp (mass ratio 1 in a conventional manner：1), in -20
Freezing processing is carried out under the conditions of DEG C to freeze to complete, and the paper pulp after freezing processing is then subjected to ice-melt processing under the conditions of 4 DEG C
Melt completely to freezing；Paper pulp then is carried out freezing processing under the conditions of -22 DEG C again to freeze to complete, then by freezing
Paper pulp after reason carries out ice-melt under the conditions of 7 DEG C and handles to the thawing completely that freezes；Then again under the conditions of -25 DEG C by paper pulp into
Row freezing processing freezes to complete, and the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 10 DEG C and is handled to icing completely
Melt, obtain the paper pulp after modification, it is spare.
Embodiment 8
The production method of toiler roll described in the present embodiment is same as Example 7, it is differed only in, in the step (1) also
It is included in paper pulp described in the forward direction of freezing processing step the step of adding mannitol, the additive amount of the mannitol is institute
State the 5wt% of pulp quality.
Embodiment 8
The production method of toiler roll described in the present embodiment is same as Example 7, it is differed only in, in the step (1) also
It is included in paper pulp described in the forward direction of freezing processing step the step of adding mannitol, the additive amount of the mannitol is institute
State the 10wt% of pulp quality.
Comparative example 1
The production method of toiler roll described in the present embodiment is same as Example 1, it is differed only in, straight in the step (1)
Connect and taken paper pulp is carried out to follow-up roll paper production, without carrying out freezing-ice-melt modification.
Comparative example 2
It is prepared by the production that roll paper body paper is carried out according to method disclosed in embodiment 1 in Chinese patent CN103696318A.
The flexibility and toughness of obtained toiler roll in above-described embodiment 1-9 and comparative example 1-2 are tested, it is surveyed
Test result is recorded in table 1 below.
The performance test results of 1 toiler roll of table
It was found from upper table data, the production method of toiler roll of the present invention, by paper pulp freeze-ice-melt repeatedly
Processing, realizes the modification of paper pulp fiber property, further improves the ductile strength between paper pulp fiber, while also improve paper
The softness of pulp fibres.Modified paper pulp is that significantly carrying for roll paper performance can be achieved only with existing paper Processes and apparatus processed
Rise, further improve the softness and toughness of toiler roll, while its intensity and water absorbing properties have also been lifted.
In addition, production method of the present invention, also further improves roll paper by adding mannitol to help modifying agent
Performance.
Obviously, the above embodiments are merely examples for clarifying the description, and the restriction not to embodiment.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of change or
Change.There is no necessity and possibility to exhaust all the enbodiments.And the obvious change thus extended out or
Among changing still in the protection domain of the invention.
Claims (1)
1. a kind of production method of toiler roll, it is characterised in that include the following steps：
(1) pulp modifying is handled：Obtained paper pulp in a conventional manner is taken, freezing processing is carried out under the conditions of -20 DEG C to complete
Freeze, the paper pulp after freezing processing is then carried out to ice-melt under the conditions of 10 DEG C and is handled to the thawing, and according to above-mentioned completely that freezes
Freezing and the temperature conditionss of ice-melt step, circulate the step 3 time of above-mentioned paper pulp freezing and paper pulp ice-melt processing, obtain modification
Paper pulp afterwards, it is spare；
(2) desanding：Desanding processing is carried out to paper pulp using five sand removing processs；
(3) screening the pulp：Screening the pulp processing is carried out to obtained slurries, to weed out undecomposed fiber in slurries；
(4) whitewash：Slurries are sprayed on shaping screen cloth and form paper spoke；
(5) it is dehydrated：Spoke made from paper is carried out dehydrating, the mass dryness fraction for making paper spoke is 8%；
(6) it is dry：Paper spoke is subjected to press dewatering and heated-air drying processing, the mass dryness fraction to paper spoke is 96%；
(7) peel off：Paper spoke is peeled off using the scraper of 75 ° of tool point angles；
(8) wind：Paper spoke after stripping is wound, obtains body paper；
(9) pack：By gained body paper through rewinding, cutting and packing processes, to obtain the final product；
In the step (1), the paper pulp freezing processing step controlled at -20~-25 DEG C, paper pulp ice-melt processing
Step controlled at 4~10 DEG C；
In the step (1), the cycle-index of the paper pulp freezing and paper pulp ice-melt processing step is 3-5 times；
In the step (1), the temperature difference described in every rear one cycle between freezing processing step and ice-melt processing step is more than
The temperature difference described in preceding one cycle between freezing processing step and ice-melt processing step；
In the step (1), the temperature of freezing processing is less than the temperature of freezing processing step in previous circulation in every latter circulation,
The temperature that ice-melt is handled in per latter circulation is above the temperature that ice-melt is handled in previous circulation；
In the step (2), the desanding step specifically includes：A, one of macropore gauze is set before pulp washing case, except coarse sand；B, grind
Installation sand removing machine before slurry, except middle sand；C, one of mesoporous gauze is set after defibrination；D, sand trap is set before stuff box is entered；E, copying
The head box lower part of paper machine sets one of aperture gauze, except fine sand.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711393488.9A CN108030432A (en) | 2016-08-30 | 2016-08-30 | Flexibility and the preferable toiler roll of toughness and its production method |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610769005.XA CN106245420B8 (en) | 2016-08-30 | 2016-08-30 | A kind of production method of toiler roll |
| CN201711393488.9A CN108030432A (en) | 2016-08-30 | 2016-08-30 | Flexibility and the preferable toiler roll of toughness and its production method |
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| CN201610769005.XA Division CN106245420B8 (en) | 2016-08-30 | 2016-08-30 | A kind of production method of toiler roll |
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| CN108030432A true CN108030432A (en) | 2018-05-15 |
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| CN201711393488.9A Pending CN108030432A (en) | 2016-08-30 | 2016-08-30 | Flexibility and the preferable toiler roll of toughness and its production method |
| CN201610769005.XA Active CN106245420B8 (en) | 2016-08-30 | 2016-08-30 | A kind of production method of toiler roll |
| CN201711396830.0A Pending CN108035183A (en) | 2016-08-30 | 2016-08-30 | Intensity and the preferable toiler roll of water absorbing properties, production method |
| CN201711396585.3A Withdrawn CN108030433A (en) | 2016-08-30 | 2016-08-30 | A kind of intensity and the preferable toiler roll of water absorbing properties |
| CN201711393454.XA Withdrawn CN108030431A (en) | 2016-08-30 | 2016-08-30 | A kind of preferable toiler roll of flexibility and toughness |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610769005.XA Active CN106245420B8 (en) | 2016-08-30 | 2016-08-30 | A kind of production method of toiler roll |
| CN201711396830.0A Pending CN108035183A (en) | 2016-08-30 | 2016-08-30 | Intensity and the preferable toiler roll of water absorbing properties, production method |
| CN201711396585.3A Withdrawn CN108030433A (en) | 2016-08-30 | 2016-08-30 | A kind of intensity and the preferable toiler roll of water absorbing properties |
| CN201711393454.XA Withdrawn CN108030431A (en) | 2016-08-30 | 2016-08-30 | A kind of preferable toiler roll of flexibility and toughness |
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| CN108691248B (en) * | 2018-05-18 | 2021-04-27 | 汕头方大印刷包装科技有限公司 | Freezing-resistant twisted paper and production process thereof |
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| CN102178484B (en) * | 2011-03-29 | 2012-12-12 | 湖北一致魔芋生物科技有限公司 | Konjak facecloth having washing and massaging functions and preparation method thereof |
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- 2016-08-30 CN CN201711393488.9A patent/CN108030432A/en active Pending
- 2016-08-30 CN CN201610769005.XA patent/CN106245420B8/en active Active
- 2016-08-30 CN CN201711396830.0A patent/CN108035183A/en active Pending
- 2016-08-30 CN CN201711396585.3A patent/CN108030433A/en not_active Withdrawn
- 2016-08-30 CN CN201711393454.XA patent/CN108030431A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101011163A (en) * | 2006-12-13 | 2007-08-08 | 董忠蓉 | Villiform edible keep-fit massage towel made of konjak and grain |
| CN102493245A (en) * | 2011-11-16 | 2012-06-13 | 陕西科技大学 | Method for paper-making pulping |
| CN104364441A (en) * | 2012-05-25 | 2015-02-18 | 金伯利-克拉克环球有限公司 | High strength macroalgae pulps |
| WO2014005697A3 (en) * | 2012-07-03 | 2014-04-03 | Huhtamäki Oyj | A recyclable sheet material and a container thereof |
| CN104452429A (en) * | 2014-10-23 | 2015-03-25 | 广东比伦生活用纸有限公司 | Super-soft super-tough household paper and production method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108030431A (en) | 2018-05-15 |
| CN106245420B (en) | 2018-01-09 |
| CN106245420B8 (en) | 2018-02-06 |
| CN106245420A (en) | 2016-12-21 |
| CN108035183A (en) | 2018-05-15 |
| CN108030433A (en) | 2018-05-15 |
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