CN105887561A - Papermaking auxiliary composition and preparation method thereof - Google Patents

Papermaking auxiliary composition and preparation method thereof Download PDF

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Publication number
CN105887561A
CN105887561A CN201610268259.3A CN201610268259A CN105887561A CN 105887561 A CN105887561 A CN 105887561A CN 201610268259 A CN201610268259 A CN 201610268259A CN 105887561 A CN105887561 A CN 105887561A
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parts
paper
auxiliary agent
agent composition
speed
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不公告发明人
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/12—Defoamers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14—Carboxylic acids; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/52—Epoxy resins
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20—Macromolecular organic compounds
    • D21H17/33—Synthetic macromolecular compounds
    • D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/59—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/60—Waxes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/66—Salts, e.g. alums
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63—Inorganic compounds
    • D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/68—Water-insoluble compounds, e.g. fillers, pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/71—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes
    • D21H17/74—Mixtures of material ; Pulp or paper comprising several different materials not incorporated by special processes of organic and inorganic material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/06—Paper forming aids
    • D21H21/08—Dispersing agents for fibres
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/18—Reinforcing agents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Paper (AREA)

Abstract

The invention discloses a papermaking auxiliary composition and a preparation method thereof. The papermaking auxiliary composition is prepared mainly from, by weight, 12-18 parts of hemicellulose, 20-25 parts of carclazyte powder, 10-18 parts of montmorillonite, 4-8 parts of polyethylene glycol, 3-6 parts of stearic acid, 1-3 parts of propylene glycol butyl ether, 2-5 parts of sodium dodecyl benzene sulfonate, 1-2 parts of polydimethylsiloxane, 1-2 parts of sodium benzoate, 3-8 parts of white oil, 1-3 parts of ammonium sulfate, 1-4 parts of sodium pyrophosphate and 2-5 parts of mannitol. The papermaking auxiliary composition prepared by the method can be uniformly distributed in paper pulp to eliminate undesirable foam to well disperse pulp in the preparation process of the paper pulp, paper has high water retaining performance, antibacterial performance and mechanical strength, glossiness, softness, whiteness and flatness of the paper are improved, dry linting and fluffing of the paper during use are avoided, and quality of the paper is improved; the papermaking auxiliary composition has decontamination and environment protection effects and is convenient to operate.

Description

A kind of paper making auxiliary agent composition and preparation method thereof
Technical field
The present invention relates to pulp technology for making paper, particularly relate to a kind of paper making auxiliary agent composition and preparation method thereof.
Background technology
The great invention of of Zhi Shi Han nationality working people, one of ancient Chinese four inventions, papermaking technology and compass, gunpowder, typography together, provides the basis of material technology to the prosperity of ancient Chinese culture.The invention of paper finishes the history that letter in ancient times wooden tablets or slips for writing is complicated, has greatly facilitated propagation and the development of culture.Papermaking technology is accumulation and the crystallization of wisdom of Han nationality's working people's protracted experience, for writing, prints, paints or the sheet-like fiber goods of packaging etc..Tianshui city is put the Western Han Dynastry unearthed for Ma Tan and is painted with the paper of map, is to find paper the earliest in the world at present.
The production of general printing paper is divided into slurrying and two basic processes of papermaking, and slurrying is exactly the method with machinery, the method for chemistry or method that both combine dissociates plant fiber material and becomes true qualities paper pulp or bleached pulp.Papermaking is then the paper pulp fiber being suspended in water, is combined into the paper in accordance with various requirement through various processing.Enough raw materials with 4～6 months typically need to be stored in paper mill, makes raw material through natural fermentation in storage, is beneficial to slurrying, ensures the continuous production of paper plant simultaneously.Through material papering section, the raw materials such as phragmites communis, wheat straw and timber are cut into tablet (for producing chemical pulp) or wood disconnected (for producing ground wood pulp), chemical liquid is added in less tablet raw material being put into boiling vessel, steaming and decocting is carried out with steam, raw material is cooked into paper pulp, or wood forfeited on mill, wear into paper pulp, it is possible to regrind into paper pulp through a certain degree of steaming and decocting.Then with a large amount of clear water, paper pulp is washed, and by screening and purification, thick sheet, knot, stone and the sand in slurry etc. is removed.Further according to the requirement of paper kind, with bleach, paper pulp is floated to required whiteness, pulls an oar followed by beating equipment.Then add in paper pulp and improve the various adjuvants such as the filler of paper performance, sizing material, sizing agent, and again purify and screen, finally serve paper machine to batch through wet end drainage, press dewatering, cylinder dried, press polish, and carry out cutting and rewinding or cut and produce roll web and sheet paper.If producing coated printing paper to be produced, then realize through coating waste water after needing to be dried middle part or produce into roll web.Outside divided by upper basic process, also include some supporting processes, such as the preparation of cooking liquor, the preparation of bleaching liquor, the boiling and the recovery etc. of chemical drugs in cooking waste liquor and waste gas and heat energy of sizing material.
Application publication number CN 103882771 A(application number 201410065585.5) Chinese patent literature disclose a kind of paper making auxiliary agent composition and preparation method thereof, this paper making auxiliary agent composition is made up of the component comprising following weight portion: polyoxyethyl propyl glycerin ether 30-35 part, glycerol stearate cruel 20-30 part, glass fibre 20-30 part, calcium carbonate crystal whisker 10-15 part, polyhexamethylene hydrochloric acid croak 10-15 part, 4,4 ' one diphenyl methane one or two Carbimide. cruel 3-5 parts and hydrogen sulfate disodium 2-5 part.Application publication number CN 104343051 A(application number 201410511132.0) Chinese patent literature disclose a kind of attapulgite clay level paper making additive, it is made up of the raw material of following weight parts: attapulgite 60-70, aluminum trifluoride 2-3, sepiolite powder 10-20, bentonite 20-30, polyoxyethylene glycerol ether 2-3, Flos Inulae soaks oil 0.3-1, sodium borohydride 1-2, 1-hydroxy ethylidene-1,1-diphosphonic acid 3-4, silver nitrate 0.3-0.5, DBDMH 0.5-2, hexadecyltrimethylammonium chloride 1-2, ammonium metavanadate 0.4-1, casein 1-2, calcium lignosulfonate 3-4, cetomacrogol 1000 2-3.Application publication number CN 104695258 A(application number 201310638918.4) Chinese patent literature disclose a kind of paper making additive mixture, it is made up of the composition of raw materials component of following mass percent: 100-200 part terphenyl quinone, 100-200 part iso-amylene naphthoquinone, 100-200 part anthrol, 100-200 part anthracene nucleus ketone, 20-50 part OPEO, 20-50 part bis-phenol a polyoxyethylene ether, 20-50 part polyoxyethylene lauryl ether, 20-50 part alkylphenol polyoxyethylene, 50-80 part calcium dodecyl benzene sulfonate, 50-80 part sodium tripolyphosphate, 50-80 part sodium laurate, 10-20 part waterproofing agent of organosilicon, 10-20 part stabilizer.
Though existing paper technology also relative maturity, its technique is extremely complex, needs through multiple tracks technique,
And need to add in every procedure respectively multiple additives.
Summary of the invention
For the deficiencies in the prior art, it is an object of the invention to provide a kind of paper making auxiliary agent composition and preparation method thereof.Products obtained therefrom of the present invention can be evenly distributed in paper pulp, bad foam is eliminated in paper pulp preparation process, make slurry good dispersion, make paper have good water-retaining property, antibiotic property and mechanical strength simultaneously, increase sheet gloss, pliability, whiteness and planarization, avoid paper in use to produce hair, the quality of the paper that fluffs, improves, and there is the effect of decontamination, environmental protection, easy to operate.
The technical scheme is that
A kind of paper making auxiliary agent composition, takes off and states the primary raw material of weight proportion and be prepared from: hemicellulose 12-18, hargil powder 20-25, montmorillonite 10-18, Polyethylene Glycol 4-8, stearic acid 3-6, propandiol butyl ether 1-3, dodecylbenzene sodium sulfonate 2-5, polydimethylsiloxane 1-2, sodium benzoate 1-2, white oil 3-8, ammonium sulfate 1-3, sodium pyrophosphate 1-4, mannitol 2-5.
A kind of paper making auxiliary agent composition, preferred scheme is, takes off and states the primary raw material of weight proportion and be prepared from: hemicellulose 14-16, hargil powder 22-24, montmorillonite 12-16, Polyethylene Glycol 5-7, stearic acid 4-5, propandiol butyl ether 1.5-2.6, dodecylbenzene sodium sulfonate 3-4, polydimethylsiloxane 1.3-1.7, sodium benzoate 1.2-1.4, white oil 4-7, ammonium sulfate 1.6-2.4, sodium pyrophosphate 1.3-2, mannitol 3-4.
A kind of paper making auxiliary agent composition, scheme more preferably is, takes off and states the primary raw material of weight proportion and be prepared from: hemicellulose 15, hargil powder 23, montmorillonite 15, Polyethylene Glycol 6, stearic acid 4.5, propandiol butyl ether 2.2, dodecylbenzene sodium sulfonate 3.5, polydimethylsiloxane 1.5, sodium benzoate 1.3, white oil 6, ammonium sulfate 1.8, sodium pyrophosphate 1.7, mannitol 3.3.
The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) Polyethylene Glycol, stearic acid, propandiol butyl ether, dodecylbenzene sodium sulfonate, polydimethylsiloxane and white oil are mixed, stir 40 minutes with the speed of 340-480r/min；
(2) hemicellulose and montmorillonite are mixed, at 75-95 DEG C, stir 2.5 hours with the speed of 360-550r/min, add hargil powder, continue stirring 20 minutes, let cool to room temperature；
(3) in step (2) gains, add sodium benzoate, ammonium sulfate, sodium pyrophosphate and mannitol, stir with the speed of 370-450r/min, stir 30-50 minute, divide 3 times and add step (1) gained, every minor tick 15-30 minute, stir, dry, pulverize, to obtain final product.
Preferably it is step (1), stirs with the speed of 370-440 r/min.
Preferably it is step (2), at 80-90 DEG C.
Preferably it is step (2), stirs with the speed of 400-500r/min.
Preferably it is step (3), stirs with the speed of 390-430r/min.
Preferably it is step (3), stirs 35-45 minute.
Preferably it is step (3), every minor tick 20-26 minute.
More preferably, step (1) stirs with the speed of 420r/min.
More preferably, step (2) is at 85 DEG C.
More preferably, step (2) stirs with the speed of 450r/min.
More preferably, step (3) stirs with the speed of 410r/min.
More preferably, step (3) stirs 40 minutes.
More preferably, the every minor tick of step (3) 24 minutes.
The paper making auxiliary agent composition scientific formulation that the present invention provides, preparation method is simple, easy to use.In addition, the excellent results of the present invention is also manifested by:
1, products obtained therefrom of the present invention can be evenly distributed in paper pulp, bad foam is eliminated in paper pulp preparation process, make slurry good dispersion, make paper have good water-retaining property, antibiotic property and mechanical strength simultaneously, increase sheet gloss, pliability, whiteness and planarization, avoid paper in use to produce hair, the quality of the paper that fluffs, improves, and there is the effect of decontamination, environmental protection；
2, stability is good, nontoxic, corrosion-free.
Detailed description of the invention
Describe technical scheme in detail below in conjunction with embodiment and experimental example, but protection domain is not limited to this.
Embodiment 1A kind of paper making auxiliary agent composition, the primary raw material taking following weight parts is prepared from (every part is 600g): hemicellulose 12 parts, 20 parts of hargil powder, montmorillonite 10 parts, Polyethylene Glycol 4 parts, stearic acid 3 parts, propandiol butyl ether 1 part, dodecylbenzene sodium sulfonate 2 parts, polydimethylsiloxane 1 part, sodium benzoate 1 part, white oil 3 parts, 1 part of ammonium sulfate, sodium pyrophosphate 1 part, mannitol 2 parts.
The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) Polyethylene Glycol, stearic acid, propandiol butyl ether, dodecylbenzene sodium sulfonate, polydimethylsiloxane and white oil are mixed, stir 40 minutes with the speed of 340r/min；
(2) hemicellulose and montmorillonite are mixed, at 75 DEG C, stir 2.5 hours with the speed of 360r/min, add hargil powder, continue stirring 20 minutes, let cool to room temperature；
(3) in step (2) gains, add sodium benzoate, ammonium sulfate, sodium pyrophosphate and mannitol, stir with the speed of 370r/min, stir 30 minutes, point 3 addition step (1) gained, every minor tick 15 minutes, stir, dry, pulverize, to obtain final product.
Embodiment 2A kind of paper making auxiliary agent composition, the primary raw material taking following weight parts is prepared from (every part is 600g): hemicellulose 18 parts, 25 parts of hargil powder, montmorillonite 18 parts, Polyethylene Glycol 8 parts, stearic acid 6 parts, propandiol butyl ether 3 parts, dodecylbenzene sodium sulfonate 5 parts, polydimethylsiloxane 2 parts, sodium benzoate 2 parts, white oil 8 parts, 3 parts of ammonium sulfate, sodium pyrophosphate 4 parts, mannitol 5 parts.
The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) Polyethylene Glycol, stearic acid, propandiol butyl ether, dodecylbenzene sodium sulfonate, polydimethylsiloxane and white oil are mixed, stir 40 minutes with the speed of 480r/min；
(2) hemicellulose and montmorillonite are mixed, at 95 DEG C, stir 2.5 hours with the speed of 550r/min, add hargil powder, continue stirring 20 minutes, let cool to room temperature；
(3) in step (2) gains, add sodium benzoate, ammonium sulfate, sodium pyrophosphate and mannitol, stir with the speed of 450r/min, stir 50 minutes, point 3 addition step (1) gained, every minor tick 30 minutes, stir, dry, pulverize, to obtain final product.
Embodiment 3A kind of paper making auxiliary agent composition, the primary raw material taking following weight parts is prepared from (every part is 600g): hemicellulose 14 parts, 22 parts of hargil powder, montmorillonite 12 parts, Polyethylene Glycol 5 parts, stearic acid 4 parts, propandiol butyl ether 1.5 parts, dodecylbenzene sodium sulfonate 3 parts, polydimethylsiloxane 1.3 parts, sodium benzoate 1.2 parts, white oil 4 parts, 1.6 parts of ammonium sulfate, sodium pyrophosphate 1.3 parts, mannitol 3 parts.
The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) Polyethylene Glycol, stearic acid, propandiol butyl ether, dodecylbenzene sodium sulfonate, polydimethylsiloxane and white oil are mixed, stir 40 minutes with the speed of 370r/min；
(2) hemicellulose and montmorillonite are mixed, at 80 DEG C, stir 2.5 hours with the speed of 400r/min, add hargil powder, continue stirring 20 minutes, let cool to room temperature；
(3) in step (2) gains, add sodium benzoate, ammonium sulfate, sodium pyrophosphate and mannitol, stir with the speed of 390r/min, stir 35 minutes, point 3 addition step (1) gained, every minor tick 20 minutes, stir, dry, pulverize, to obtain final product.
Embodiment 4A kind of paper making auxiliary agent composition, the primary raw material taking following weight parts is prepared from (every part is 600g): hemicellulose 16 parts, 24 parts of hargil powder, montmorillonite 16 parts, Polyethylene Glycol 7 parts, stearic acid 5 parts, propandiol butyl ether 2.6 parts, dodecylbenzene sodium sulfonate 4 parts, polydimethylsiloxane 1.7 parts, sodium benzoate 1.4 parts, white oil 7 parts, 2.4 parts of ammonium sulfate, sodium pyrophosphate 2 parts, mannitol 4 parts.
The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) Polyethylene Glycol, stearic acid, propandiol butyl ether, dodecylbenzene sodium sulfonate, polydimethylsiloxane and white oil are mixed, stir 40 minutes with the speed of 440r/min；
(2) hemicellulose and montmorillonite are mixed, at 90 DEG C, stir 2.5 hours with the speed of 500r/min, add hargil powder, continue stirring 20 minutes, let cool to room temperature；
(3) in step (2) gains, add sodium benzoate, ammonium sulfate, sodium pyrophosphate and mannitol, stir with the speed of 430r/min, stir 45 minutes, point 3 addition step (1) gained, every minor tick 26 minutes, stir, dry, pulverize, to obtain final product.
Embodiment 5A kind of paper making auxiliary agent composition, the primary raw material taking following weight parts is prepared from (every part is 600g): hemicellulose 15 parts, 23 parts of hargil powder, montmorillonite 15 parts, Polyethylene Glycol 6 parts, stearic acid 4.5 parts, propandiol butyl ether 2.2 parts, dodecylbenzene sodium sulfonate 3.5 parts, polydimethylsiloxane 1.5 parts, sodium benzoate 1.3 parts, white oil 6 parts, 1.8 parts of ammonium sulfate, sodium pyrophosphate 1.7 parts, mannitol 3.3 parts.
The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) Polyethylene Glycol, stearic acid, propandiol butyl ether, dodecylbenzene sodium sulfonate, polydimethylsiloxane and white oil are mixed, stir 40 minutes with the speed of 420r/min；
(2) hemicellulose and montmorillonite are mixed, at 85 DEG C, stir 2.5 hours with the speed of 450r/min, add hargil powder, continue stirring 20 minutes, let cool to room temperature；
(3) in step (2) gains, add sodium benzoate, ammonium sulfate, sodium pyrophosphate and mannitol, stir with the speed of 410r/min, stir 40 minutes, point 3 addition step (1) gained, every minor tick 24 minutes, stir, dry, pulverize, to obtain final product.
Primary raw material used by the present invention:
Hemicellulose: hemicellulose: being the heteromultimer being made up of several different types of monosaccharide, these sugar are pentose and hexose, including xylose, arabinose and galactose etc..Hemicellulose xylan accounts for the 50% of total amount in lignum, and it is combined in the surface of cellulose microfibers, and is connected with each other, and these fibers constitute the interconnective network of hard cell.
Hargil powder: Chalk, native, white kind, white also known as hargil powder, chalk, white clay.Chalk is the deposit of a kind of fine calcium carbonate, is the mutation of calcite.Chalk is typically primarily referred to as being distributed in the cretaceous stratum in West Europe, and the Cretaceous period one comes the most therefrom.Chalk as mineral is generally used to manufacture the products such as chalk.
Montmorillonite: montmorillonite has another name called montmorillonite or montmorillonite, is a kind of aluminosilicate, it is mainly composed of octahedra hectorite microparticle, names in the covering de-city of France because it is originally found.For diarrhea class nonprescription drugs medicine.Clinic is applicable to adult and the acute and chronic diarrhoea of child.Utilize its cation exchange property to make montmorillonite organic complex, be widely used in high gentle fat, rubber, plastics, paint；Utilize its absorption property, for edible oil refinery decolorization except poison, purification oil, nuclear waste disposal, sewage disposal；Utilize its caking property can make casting sand binding agent etc.；Utilize its dispersion suspension for drilling mud.Owing to many performances of sodium montmorillonite are better than calcium montmorillonite, thus often utilize the cation exchange property of montmorillonite, carry out remodeling process, calcium montmorillonite is transformed into sodium montmorillonite.Montmorillonite is widely used in medicine, can do medical carrier, plays controlled release agent effect, has matured product montmorillonite powder at field of medicaments, almost become the synonym of montmorillonite, play antidiarrheal efficacy.Montmorillonite has application very well, especially young, the HUANGBAI(sic) dysentery of piglets, having loose bowels of rabbit in domestic animal (pig, rabbit) cultivate, and plays prevention effects, in view of the characteristic of montmorillonite, moreover it is possible to as the first-selection of classic feedstuff mildew removing agent.
Polyethylene Glycol: Polyethylene Glycol series of products are nontoxic, nonirritant, mildly bitter flavor, has good water solublity, and has good intermiscibility with many organic matter components.They have excellent lubricity, moisture retention, dispersibility, bonding agent, antistatic additive and softening agent etc., in cosmetics, pharmacy, chemical fibre, rubber, plastics, papermaking, paint, electroplate, all have extremely wide application in the industry such as pesticide, intermetallic composite coating and food processing.
Stearic acid: stearic acid is the most driven, the solid fatty acid that obtains in Vegetable oil lipoprotein, is mainly composed of stearic acid (C18H36O2) and Palmic acid (C16H32O2).Sterling is the band soft small pieces of glossiness white.Stearic acid is widely used in the manufacture of PVC plastic pipe, sheet material, section bar, thin film.It is PVC heat stabilizer, there is good lubricity and preferable light, heat stabilization.In plastic pvc pipe, stearic acid contributes to preventing in the course of processing " coking ", adding in PVC film is processed is a kind of effective heat stabilizer, can defend cruelly to be placed in sulfide caused finished films variable color simultaneously.Stearic acid is presented in glyceride in Animal fat, oil and some vegetable oil, and these oil i.e. obtain stearic acid through hydrolyzing.
Propandiol butyl ether: propandiol butyl ether, has another name called 1,2-PD-1-monobutyl ether or 1-butoxy-2-propanol；2-hydroxypropyl butyl ether.Colourless transparent liquid.Due to the toxicity that it is extremely low, thus be accordingly used in industry or household cleaning agent prescription, safety is high.
Polydimethylsiloxane: polydimethylsiloxane, also referred to as dimethicone, be the organosilicon material of a kind of hydrophobic class.All having application in each fields such as medicine, cosmetics of everyday use, food, buildings, its derivant has reached hundreds of, and conventional polysiloxanes mainly has: polydimethylsiloxane, cyclomethicone, amino silicone, PSI, polysiloxane polyether copolymer.Wherein Cyclomethicone is just a kind of for conventional polysiloxanes.
White oil: white oil, another name paraffin oil, white oil, mineral oil.This product is by the mixture of oil gained refine liquid hydrocarbon, the most saturated cycloalkane and alkane mixture, crude oil through normal pressure and vacuum fractionation, solvent extraction and dewaxing, hydrofinishing and must be used for manufacturing detergent, synthetic detergent, synthetic petroleum albumen, farm chemical emulgent etc..
Mannitol: mannitol is a kind of polyhydric alcohol or sugar alcohol, and its natural product are widely present in the organisms such as plant, algae, edible fungi and lichens.Owing to mannitol has special physics and chemical property, therefore in industry extensive application such as food, medicine and chemical industry.Mannitol industrialized production mainly uses Thallus Laminariae (Thallus Eckloniae) extraction method and chemical synthesis at present.
Test exampleIn order to test the performance of gained paper making auxiliary agent composition of the present invention (embodiment 5), being determined its performance, result is as shown in table 1.
Table 1: products obtained therefrom performance test of the present invention
Can be drawn by table 1, products obtained therefrom of the present invention can increase paper ring crush intensity, tear index, burst index and tensile index, improves the quality of paper.
Finally it should be noted that, embodiment is the detailed description of the invention that the present invention is optimum, it is not limited to the present invention, although the present invention being described in detail with reference to previous embodiment, for a person skilled in the art, technical scheme described in foregoing embodiments still can be modified by it, or wherein portion of techniques feature is carried out equivalent.All within the spirit and principles in the present invention, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (10)

1. a paper making auxiliary agent composition, it is characterised in that take off and state the primary raw material of weight proportion and be prepared from: hemicellulose 12-18, hargil powder 20-25, montmorillonite 10-18, Polyethylene Glycol 4-8, stearic acid 3-6, propandiol butyl ether 1-3, dodecylbenzene sodium sulfonate 2-5, polydimethylsiloxane 1-2, sodium benzoate 1-2, white oil 3-8, ammonium sulfate 1-3, sodium pyrophosphate 1-4, mannitol 2-5.
2. paper making auxiliary agent composition as claimed in claim 1, it is characterised in that take off and state the primary raw material of weight proportion and be prepared from: hemicellulose 14-16, hargil powder 22-24, montmorillonite 12-16, Polyethylene Glycol 5-7, stearic acid 4-5, propandiol butyl ether 1.5-2.6, dodecylbenzene sodium sulfonate 3-4, polydimethylsiloxane 1.3-1.7, sodium benzoate 1.2-1.4, white oil 4-7, ammonium sulfate 1.6-2.4, sodium pyrophosphate 1.3-2, mannitol 3-4.
3. paper making auxiliary agent composition as claimed in claim 1, it is characterised in that take off and state the primary raw material of weight proportion and be prepared from: hemicellulose 15, hargil powder 23, montmorillonite 15, Polyethylene Glycol 6, stearic acid 4.5, propandiol butyl ether 2.2, dodecylbenzene sodium sulfonate 3.5, polydimethylsiloxane 1.5, sodium benzoate 1.3, white oil 6, ammonium sulfate 1.8, sodium pyrophosphate 1.7, mannitol 3.3.
4. the preparation method of the paper making auxiliary agent composition as described in claims 1 to 3 is arbitrary, it is characterised in that step is as follows:
(1) Polyethylene Glycol, stearic acid, propandiol butyl ether, dodecylbenzene sodium sulfonate, polydimethylsiloxane and white oil are mixed, stir 40 minutes with the speed of 340-480r/min；
(2) hemicellulose and montmorillonite are mixed, at 75-95 DEG C, stir 2.5 hours with the speed of 360-550r/min, add hargil powder, continue stirring 20 minutes, let cool to room temperature；
(3) in step (2) gains, add sodium benzoate, ammonium sulfate, sodium pyrophosphate and mannitol, stir with the speed of 370-450r/min, stir 30-50 minute, divide 3 times and add step (1) gained, every minor tick 15-30 minute, stir, dry, pulverize, to obtain final product.
5. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (1) stirs (preferably stirring) with the speed of 420r/min with the speed of 370-440 r/min.
6. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (2) (is preferable at 85 DEG C) at 80-90 DEG C.
7. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (2) stirs (preferably stirring) with the speed of 450r/min with the speed of 400-500r/min.
8. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (3) stirs (preferably stirring) with the speed of 410r/min with the speed of 390-430r/min.
9. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (3) stirs 35-45 minute (preferably stirring 40 minutes).
10. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (3) every minor tick 20-26 minute (preferably every minor tick 24 minutes).
CN201610268259.3A 2016-04-27 2016-04-27 Papermaking auxiliary composition and preparation method thereof Pending CN105887561A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106245420A (en) * 2016-08-30 2016-12-21 山东德广工贸有限公司 A kind of production method of toiler roll
CN106498802A (en) * 2016-12-19 2017-03-15 钦州市钦南区科学技术情报研究所 A kind of paper grade (stock) stiffener and preparation method thereof
CN106947045A (en) * 2017-02-16 2017-07-14 华南理工大学 A kind of modified hemicellulose group paper strengthening agent and preparation method thereof
CN115145236A (en) * 2022-08-31 2022-10-04 南京狮尚生物科技有限公司 Intelligent production control system and method for decontamination aerobic foam washing powder composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050069704A1 (en) * 2003-09-25 2005-03-31 Thomas Rathschlag Encapsulated pigments
CN1875150A (en) * 2003-10-27 2006-12-06 巴斯福股份公司 Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion
CN103866606A (en) * 2014-02-25 2014-06-18 苏州恒康新材料有限公司 Paper additive with high water holding capacity and preparation method thereof
CN103866608A (en) * 2014-02-28 2014-06-18 苏州恒康新材料有限公司 Composition for papermaking and preparation method thereof
CN103882771A (en) * 2014-02-25 2014-06-25 苏州恒康新材料有限公司 Papermaking additive composition and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050069704A1 (en) * 2003-09-25 2005-03-31 Thomas Rathschlag Encapsulated pigments
CN1875150A (en) * 2003-10-27 2006-12-06 巴斯福股份公司 Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion
CN103866606A (en) * 2014-02-25 2014-06-18 苏州恒康新材料有限公司 Paper additive with high water holding capacity and preparation method thereof
CN103882771A (en) * 2014-02-25 2014-06-25 苏州恒康新材料有限公司 Papermaking additive composition and preparation method thereof
CN103866608A (en) * 2014-02-28 2014-06-18 苏州恒康新材料有限公司 Composition for papermaking and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106245420A (en) * 2016-08-30 2016-12-21 山东德广工贸有限公司 A kind of production method of toiler roll
CN106245420B (en) * 2016-08-30 2018-01-09 山东德广工贸有限公司 A kind of production method of toiler roll
CN106245420B8 (en) * 2016-08-30 2018-02-06 常州快高儿童卫生用品有限公司 A kind of production method of toiler roll
CN106498802A (en) * 2016-12-19 2017-03-15 钦州市钦南区科学技术情报研究所 A kind of paper grade (stock) stiffener and preparation method thereof
CN106947045A (en) * 2017-02-16 2017-07-14 华南理工大学 A kind of modified hemicellulose group paper strengthening agent and preparation method thereof
CN106947045B (en) * 2017-02-16 2019-10-18 华南理工大学 A kind of modified hemicellulose group paper strengthening agent and preparation method thereof
CN115145236A (en) * 2022-08-31 2022-10-04 南京狮尚生物科技有限公司 Intelligent production control system and method for decontamination aerobic foam washing powder composition

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