CN108027211A - Purposes of the spacer in painting method - Google Patents

Purposes of the spacer in painting method Download PDF

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Publication number
CN108027211A
CN108027211A CN201680051946.8A CN201680051946A CN108027211A CN 108027211 A CN108027211 A CN 108027211A CN 201680051946 A CN201680051946 A CN 201680051946A CN 108027211 A CN108027211 A CN 108027211A
Authority
CN
China
Prior art keywords
spacer
catalyst carrier
purposes
conveyer belt
diameter
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201680051946.8A
Other languages
Chinese (zh)
Inventor
W·哈瑟曼
C·霍尔泽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Umicore AG and Co KG
Original Assignee
Umicore AG and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Umicore AG and Co KG filed Critical Umicore AG and Co KG
Publication of CN108027211A publication Critical patent/CN108027211A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B13/00Machines or plants for applying liquids or other fluent materials to surfaces of objects or other work by spraying, not covered by groups B05B1/00 - B05B11/00
    • B05B13/02Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
    • B05B13/0221Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work characterised by the means for moving or conveying the objects or other work, e.g. conveyor belts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D3/00Charging; Discharging; Manipulation of charge
    • F27D3/12Travelling or movable supports or containers for the charge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)

Abstract

The present invention is entitled:" purposes of the spacer in painting method ".The present invention relates to purposes of the spacer in the method for coating catalyst carrier.The conveyer belt that the spacer is used to prevent from typically directly placing the catalyst carrier thereon is contacted with the catalyst carrier.The spacer in a ring, can contact the size of the size less than the catalyst carrier on surface.

Description

Purposes of the spacer in painting method
The present invention relates to purposes of the spacer in the method for coating catalyst carrier.Spacer have prevent thereon Typically directly place the function that the conveyer belt of catalyst carrier is contacted with catalyst carrier.
The exhaust gas of internal combustion engine usually contains pernicious gas carbon monoxide (CO) and hydro carbons (HC), nitrogen oxides in motor vehicles (NOx) and possible oxysulfide (SOx) and particulate matter, the particulate matter mainly by flue dust residue and may attachment have Machine agglomerate forms.These are referred to as predominant emissions.CO, HC and particulate are the non-complete combustion of fuel in engine combustion room Product.When ignition temperature is locally exceeding 00 DEG C of Isosorbide-5-Nitrae, nitrogen and oxygen in air inlet can form nitrogen oxidation in cylinder Thing.A small amount of organosulfur compound is constantly present in non-synthetic fuel, and the burning of organosulfur compound can generate oxysulfide. In order to remove the emission that these in motor vehicle exhausts are harmful to health and environment, develop a variety of for purifying exhaust gas Catalysis technique, its basic principle, which is typically based on guiding, needs the exhaust gas that purifies to pass through by flow type or wall-flow honeycomb and painting It is overlying on the catalyst of catalytically active coatings composition thereon.This catalyst promotes the chemical reaction of different waste gas components, at the same time Harmless products are formed, such as carbon dioxide and water.
Flow type just described or wall-flow honeycomb therefore also referred to as catalyst carrier, because they are on its surface Or formed in the hole on the surface and carry catalytically active coatings.Catalytically active coatings are usually with suspension in so-called painting method Form be applied in catalyst carrier.In this respect, many such methods had turned via motor car exhaust gas catalysis in the past Hua Qi manufacturers announce (EP1064094B1, EP2521618B1, WO10015573A2, EP1136462B1).
In most cases, uncoated catalyst carrier is placed on a moving belt first and is thus supplied to reality Coating unit.The coating unit receives catalyst carrier in predominantly full automatic method, and causes carrier outstanding with coating Supernatant liquid contacts.
In order to transport coating unit and be transported and by subsequent drying oven from coating unit, with the side passed through in industry Formula uses band transmission device and/or roller transmission device.These transmission devices are transmission equipments, it is made of plastics or metal, and And endless belt run on these longitudinal bracing rollers (http://de.wikipedia.org/wiki/F%C3% B6rderband).Catalyst carrier is often damaged after whole coating station.Since the wall of catalyst carrier has Shi Feichang is thin, and highly brittle for manufacturing the material (such as SiC, aluminium titanates, cordierite) of catalyst carrier, so often hair The situation (edge abjection) of raw carrier peripheral end portion area corners abjection.
Therefore, it is an object of the invention to the possibility of specified modification painting method so that these sides do not occur as far as possible Edge is deviate from, if it cannot not occur completely, but at least occurrence frequency is reduced and less serious, because edge abjection can every time It can be the potential cause of client's complaint.
The purpose proposed is realized by the application of claim 1 according to the present invention.In accordance with the purpose of the invention Preferred embodiment is specified in the dependent claims for be subordinated to claim 1.
Spacer is being used for coating in the method for the catalyst carrier of motor car exhaust gas catalysis converter so that It is placed on conveyer belt and coated or catalyst carrier to be coated is placed to the spacer on conveyer belt On, and the catalyst carrier being therefore positioned possibly is transported in painting method on some conveyer belts, wherein preventing Catalyst carrier and conveyer belt directly contact, very easily but successful achieveed the purpose that to propose.Check Show, (and during another conveyer belt is transformed into from a conveyer belt) is applied by conveyer belt during catalyst carrier is transported The shearing force being added on carrier is clearly helpful for causing edge to be deviate to a certain extent.It is surprising that only arranged by above-mentioned Applying helps to prevent many edges from deviating from.
It is stacked on one another placement by the spacer for the appropriate size that will be independent of conveyer belt and catalyst carrier, prevents transmission The direct stress effect at about 0.1 to the 0.3mm edge that band is protruded to carrier and from upright surface.This prevent on conveyer belt The carrier of shearing force damage edge being clearly present in direct contact process and in transfer process.It is self-evident, root It will preferably be moved together all the time in catalyst carrier with conveyer belt according to the transport of this mode of the catalyst carrier of the present invention Position at perform.(that is, be for example moved to coating unit, from coating station it is mobile, by drying box, by controlling and marking Unit, until multiple package position).From anywhere in conveyer belt is possible to produce corresponding shearing force, isolation according to the present invention The use of thing can be preferable.
The specific physical space that the applicability that catalyst carrier is placed on the spacers is caused spacer to have is set Meter.Preferably, spacer has the shape identical with carrier.For example, exist with rectangle, circle, ellipse, hexagon or just The carrier of square basic configuration.However, in most cases, carrier to be coated will be circular, this is namely to be assorted The design of annular isolator is preferable.
In addition, spacer can be designed to solid, it is close main body, or on the other hand preferably can only have There is the excircle of solid form.For example, if spacer design is circle, a ring can be only included, caltalyst can be with It is placed on the ring (Fig. 1).Especially during baking oven is transported by, ring is a preferred embodiment, because here Therefore dominant dry stream can continue to flow axially through substrate.In addition, this helps to save material cost.Doing necessary change This is suitable for other embodiment after dynamic.
Advantageously, spacer is designed to less small so that overall arrangement will not become too unstable.Catalyst carries Difference between the external dimensions of body and the external dimensions of spacer should be preferably no more than 40%, no more than 30%, and particularly preferably it is no more than 20% or even 10%.Minimum dimension is also defined by band transmission, wherein during transport Stability be also a standard.For preferable annular isolator, the diameter of the bearing-surface of catalyst carrier or maximum right Difference between linea angulata and the diameter of spacer should be up to 40%.With relative to the larger-diameter substrate compared with low height In, ring can preferably than catalyst carrier bearing-surface diameter or maximum diagonal smaller.
In a further advantageous embodiment, the diameter of the bearing-surface of catalyst carrier or maximum diagonal are less than spacer Outside diameter, and catalyst carrier is by the structure for being projected into the center of ring and be strongly attached to outer shroud that is placed in outer shroud On.For example, spacer preferably has inner ring and is strongly attached to the outer shroud of inner ring.The diameter of inner ring is carried less than catalyst The diameter of body.The diameter of outer shroud is more than the diameter of catalyst carrier.As described above, catalyst carrier be placed in inner ring and Therefore protected from the direct stress effect of conveyer belt.In a sense, outer shroud contributes to the catalysis placed by this way Agent carrier will not be collided mutually on a moving belt.Fig. 3 shows the corresponding example of this ring.Can during using ring as shown in Figure 4 To obtain similar result.In this case, caltalyst mutually collides in order to prevent, is selected larger than urging by outer shroud intentionally The diameter of agent body.On the contrary, catalyst carrier is by being placed on the elevated interior pillar of the ring.Follow other realities of same principle Apply example to those skilled in the art be it is contemplated that and be included in this specification claim in the range of.
Another key element in the design of spacer is its height.Its height should not be too big, otherwise catalyst carrier and The arrangement of spacer can be unstable.On the other hand, spacer design can not be obtained it is too thin, in order to avoid the dangerous change of transfer of shear forces It is too much.It is desirable that spacer has 3 to 10mm, preferably 4 to 8mm, particularly preferably 5 to 6mm height.
Decided in its sole discretion for manufacturing the material of spacer by those skilled in the art.Those skilled in the art is in this side Face into will receive guidance originally according to productibility, the applicability of method and material.Preferably for example it is made of metal Material, such as stainless steel, such as 316 stainless steels.Particularly preferably metal, because it is also used as temperature higher than 600 DEG C Arid region in spacer.If the method in baking oven be not it is contemplated that if can also use plastics, such as synthesize material Material, polyformaldehyde, HDPE etc..
It may further be preferable that spacer is adjacent on the side towards substrate.In this way it is assured that when substrate jail Admittedly it is fixed when, spacer easily slides on a moving belt, and spacer will not be moved relative to substrate.
Present invention show the simple possibility that edge abjection how is reduced in the coating procedure of catalyst carrier.To mesh Before untill, damage which partially due on a moving belt transporting catalyst carrier actually caused and unobvious.Damage Major part be substantially caused by the shearing force of conveyer belt, which proposes in a research in detail first, the research Also contemplate substrate minimum edge projection that the so-called manufacturer by these carriers provides (compared with center, catalyst carrier It is slightly convex in edge).So simply solving proposed purpose actually achieves desired success, therefore can To be considered surprising.
Fig. 1:The spacer of preferable loop design is presented in image.
Fig. 2:The schematic diagram used of spacer;
1 conveyer belt
2 catalyst carriers
Spacer in 3 collecting boxs
4 spacers
Fig. 3:Preferred annular isolator with inner ring and outer rings
Fig. 4:Preferred annular isolator with outer shroud and inner supporting structure
Fig. 5:Show that caltalyst is transported by the roller transmission device on furnace zone on the spacers
Claims (according to the 19th article of modification of treaty)
1. it is being used for urging for motor car exhaust gas catalysis converter for using coating suspension to coat independently of the spacer of conveyer belt Purposes in the method for agent carrier so as to be placed on the conveyer belt and be applied or to be coated described urge Agent carrier is placed on the spacer on the conveyer belt, and the catalyst carrier being therefore positioned It is transported in the painting method, wherein prevent the catalyst carrier from being contacted with the direct of the conveyer belt, and therefore Edge is prevented to deviate from,
It is characterized in that:
The spacer has annular shape, and is designed to less small so that the bearing-surface of the catalyst carrier it is straight Difference between the diameter of footpath or maximum diagonal and the spacer is up to 40%,
Or the diameter of the bearing-surface of the catalyst carrier or the maximum diagonal are less than the spacer Outside diameter, and the catalyst carrier by the center for being projected into ring that is placed in outer shroud and is strongly attached to the outer shroud Structure on.
2. purposes according to claim 1,
It is characterized in that:
The spacer has the height of 3mm to 10mm.
3. the purposes described in one in preceding claims,
It is characterized in that:
The spacer is made of the material selected from synthetic material such as polyformaldehyde, HDPE and metal such as stainless steel.

Claims (6)

1. spacer is for coating for the purposes in the method for the catalyst carrier of motor car exhaust gas catalysis converter so that It is placed on conveyer belt and the coated or catalyst carrier to be coated is placed on the conveyer belt The spacer on, and the catalyst carrier being therefore positioned in the painting method be transported, wherein preventing The catalyst carrier is directly contacted with the conveyer belt.
2. purposes according to claim 1,
It is characterized in that:
The spacer has annular shape.
3. purposes according to claim 2,
It is characterized in that:
Difference between the diameter or maximum diagonal of the bearing-surface of the catalyst carrier and the diameter of the spacer is most Up to 40%.
4. purposes according to claim 2,
It is characterized in that:
The diameter of the bearing-surface of the catalyst carrier or the maximum diagonal are less than the outside diameter of the spacer, And the catalyst carrier is by the center for being projected into ring that is placed in outer shroud and is strongly attached to the knot of the outer shroud On structure.
5. according to the purposes described in claim 2 and/or 3,
It is characterized in that:
The spacer has the height of 3mm to 10mm.
6. the purposes described in one in preceding claims,
It is characterized in that:
The spacer is made of the material selected from synthetic material such as polyformaldehyde, HDPE and metal such as stainless steel.
CN201680051946.8A 2015-09-09 2016-09-01 Purposes of the spacer in painting method Pending CN108027211A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102015115124.3 2015-09-09
DE102015115124.3A DE102015115124A1 (en) 2015-09-09 2015-09-09 Use of spacers in the coating process
PCT/EP2016/070602 WO2017042085A1 (en) 2015-09-09 2016-09-01 Use of spacers in the coating method

Publications (1)

Publication Number Publication Date
CN108027211A true CN108027211A (en) 2018-05-11

Family

ID=56979520

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201680051946.8A Pending CN108027211A (en) 2015-09-09 2016-09-01 Purposes of the spacer in painting method

Country Status (7)

Country Link
EP (1) EP3356754A1 (en)
CN (1) CN108027211A (en)
BR (1) BR112018004666A2 (en)
CA (1) CA2996654A1 (en)
DE (1) DE102015115124A1 (en)
WO (1) WO2017042085A1 (en)
ZA (1) ZA201801573B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114650881A (en) * 2019-12-10 2022-06-21 庄信万丰股份有限公司 Apparatus and method for coating a substrate with a washcoat

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210220813A1 (en) * 2020-01-16 2021-07-22 Johnson Matthey Public Limited Company Pallet for supporting a catalyst monolith during coating

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US5265346A (en) * 1991-03-26 1993-11-30 Ngk Insulators, Ltd. Drying carrier adapted for carrying honeycomb structure
CN2694202Y (en) * 2004-02-17 2005-04-20 攀枝花钢铁(集团)公司 Belt type hopper carrier plate for high temperature reaction furnace
CN103157521A (en) * 2013-03-08 2013-06-19 无锡威孚环保催化剂有限公司 Full-automatic quantitative honeycomb carrier catalyst coating device
CN103551206A (en) * 2008-08-06 2014-02-05 巴斯夫欧洲公司 Positioning device and method with rotary indexing table for monolith-based automobile and chemical catalysts

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GB9805815D0 (en) 1998-03-19 1998-05-13 Johnson Matthey Plc Manufacturing process
DE10014547B4 (en) 2000-03-23 2005-09-29 Umicore Ag & Co. Kg Method of partially coating a support body
JP2003106773A (en) * 2001-09-26 2003-04-09 Micro Denshi Kk Microwave continuous heating device
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Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5265346A (en) * 1991-03-26 1993-11-30 Ngk Insulators, Ltd. Drying carrier adapted for carrying honeycomb structure
CN2694202Y (en) * 2004-02-17 2005-04-20 攀枝花钢铁(集团)公司 Belt type hopper carrier plate for high temperature reaction furnace
CN103551206A (en) * 2008-08-06 2014-02-05 巴斯夫欧洲公司 Positioning device and method with rotary indexing table for monolith-based automobile and chemical catalysts
CN103157521A (en) * 2013-03-08 2013-06-19 无锡威孚环保催化剂有限公司 Full-automatic quantitative honeycomb carrier catalyst coating device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114650881A (en) * 2019-12-10 2022-06-21 庄信万丰股份有限公司 Apparatus and method for coating a substrate with a washcoat
US11759818B2 (en) 2019-12-10 2023-09-19 Johnson Matthey Public Limited Company Apparatus and method for coating substrates with washcoats
CN114650881B (en) * 2019-12-10 2023-11-10 庄信万丰股份有限公司 Apparatus and method for coating a substrate with a washcoat

Also Published As

Publication number Publication date
DE102015115124A1 (en) 2017-03-09
EP3356754A1 (en) 2018-08-08
WO2017042085A1 (en) 2017-03-16
BR112018004666A2 (en) 2018-09-25
CA2996654A1 (en) 2017-03-16
ZA201801573B (en) 2019-01-30

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Application publication date: 20180511