CN108025933A - Hydrogen water generating device - Google Patents

Abstract

The application compared with prior art, improves the hydrogen concentration for the water that the hydrogen water generating device used in water by impregnating is realized.A kind of hydrogen water generating device, it is characterised in that possess：Water flowing road, it can be impregnated in water, and the inflow entrance of water is connected with flow export；Pumping section, it makes the water flowing road produce current；Electrolysis portion, it is disposed in the water flowing road；And power supply unit, it powers to the pumping section and the electrolysis portion, and the electrolysis portion has the multiple porous electrode plates for keeping certain intervals to arrange, and the pumping section produces the current of the plate face towards the porous electrode plate.

Description

Hydrogen water generating device

Technical field

The present invention relates to be impregnated in the hydrogen water generating device that is used in water.

Background technology

In the past, as the device using electrolysis water, it is known that the device that patent document 1,2 is recorded.

Patent Document 1 discloses a kind of reduced water generation device, its container of ware shape inner bottom surface close to a pair Plate electrode, the DC power supply powered to these plate electrodes is disposed in the space set below container.It is configured to The lid of container, recirculation hole is respectively arranged with the position of the top equivalent to each plate electrode, is produced in the plate electrode of a side Hydrogen flowed out from the recirculation hole of a side, flowed out in the oxygen that the plate electrode of the opposing party produces from the recirculation hole of the opposing party.Thus, energy Enough prevent the hydrogen that is produced in each plate electrode and oxygen in conjunction with and carry out the reduction of water, air.

Patent Document 2 discloses a kind of bath water electrosterilizer, its in water dipping with being provided with electrolysis in container Room.The bath water electrosterilizer, forms the lower surface of dipping container in water, from electrolysis to the inflow entrance of tank house inflow water The flow export of room outflow water forms the upper surface of dipping container in water, in tank house, has multiple positive plates and cathode Multiple electrolysis electrolytic zinc-coated steel sheets of the group of plate to laterally configuration side by side, formed between electrolysis electrode plate bath water on to path.By This, the water of dipping container in water is flowed into by being flowed out to path from flow export between electrode for electrolysis plate from inflow entrance.

Prior art literature

Patent document

Patent document 1：No. 3155538 publication of Japanese Utility Model

Patent document 2：Japanese Unexamined Patent Publication 11-342390 publications

The content of the invention

In recent years, " hydrogen water " containing many hydrogen attracts attention, and has sold for electrolysis water and has generated the device of hydrogen water.This The device of the generation hydrogen water of sample, considers to realize by the structure similar with above patent document 2, but in terms of hydrogen meltage have There is room for improvement.That is, even if the hydrogen concentration of the water above device is saturation state, tieed up in the water from the region away from device It is highly difficult to hold enough hydrogen concentrations.

The present invention in view of the above subject and make, improve the hydrogen that is used in water by impregnating its object is to compared with the past The hydrogen concentration for the water that water generating device is realized.

One embodiment of the present invention is hydrogen water generating device, it is characterised in that is possessed：Housing with water flowing road, this is logical Water route can be impregnated in water, and the inflow entrance of water is connected with flow export；Pumping section, it makes the water flowing road produce current；Electrolysis Portion, it is disposed in the water flowing road；And power supply unit, it powers to the pumping section and the electrolysis portion, and the electrolysis portion, which has, to be protected Multiple porous electrode plates of certain intervals arranging are held, the pumping section produces the current of the plate face towards the porous electrode plate.

The hydrogen water generating device so formed, is impregnated in water, and the water flowing between inflow entrance and flow export is made by pumping section Road produces current, and the water to circulate on water flowing road is electrolysed by the electrolysis portion for being disposed in water flowing road.At this time, pumping section is produced towards porous The current of the plate face of electrode plate, the porous electrode plate form electrolysis portion, keep certain intervals to arrange.That is, by porous electricity The plate face of pole plate applies the pressure of current, have by the electrolytic hydrogen in the surface of porous electrode plate, oxygen bubble in electricity The moment of solution pulls the effect in current in a manner of pushing open, the hydrogen that the water flowed out from the flow export of hydrogen producing apparatus is included Bubble microvesicle, additionally it is possible to expect the hydrogen dissolving under molecular level hydrogen, nano bubble, microvesicle state.

In addition, one of mode of selectivity of the present invention is a kind of hydrogen water generating device, it is characterised in that is possessed：Control Portion, it makes the polarity of the porous electrode plate be inverted by per scheduled time in electrolysis.

The mineral composition of the calcium being dissolved in electrolysis of water etc., particularly in water with metal existing for cationic state Ionic species are deposited in anode surface as scale, but in the hydrogen water process units so formed, are played function as cathode Porous electrode plate is switched to cathode by per scheduled time, switches as the porous electrode plate that anode plays function by per scheduled time For anode, so the deposition of scale presses a porous electrode plate approximate equality, and sink on the porous electrode plate for be switched to anode Long-pending scale be redissolved in water carry out scale removing, institute so as to suppress scale adhere to caused by electrolytic efficiency reduction.

In addition, one of mode of selectivity of the present invention is a kind of hydrogen water generating device, it is characterised in that the control Portion, carries out the reversion of the polarity in the work of the pumping section.

Through this structure, can avoid origin between porous electrode plate existing electrolysis of water cause with capacity The temporary short circuit state between porous electrode plate during polarity switching, can save from damage and carry out power supply to porous electrode plate, switching etc. Circuit.

In addition, one of mode of selectivity of the present invention is a kind of hydrogen water generating device, it is characterised in that is possessed：Control Portion, its flow that the pumping section is controlled in electrolysis and makes the current change.

Through this structure, can change the bubble footpath of the bubble hydrogen of the sur-face peeling from porous electrode plate.

In addition, one of mode of selectivity of the present invention is a kind of hydrogen water generating device, it is characterised in that is possessed to place an order Member, i.e.,：By by the pumping section in electrolysis repeatedly switching control to produce the relatively long working status and not of current The control unit of the halted state of the relative short time of current is produced, makes to adhere in porous electrode plate in the working status of the pumping section The unit that the difficult bubble of stripping of generation dissociates.

Through this structure, although can make to have reached should by bubble footpath that current are peeled off like this after Continue the bubble for being difficult to the peel off stripping for being attached to porous electrode plate, suppress origin and caused in the surface of porous electrode plate by bubble covering Electrolytic efficiency is low.

In addition, one of mode of selectivity of the present invention is a kind of hydrogen water generating device, the porous electrode is being formed at Charge concentration portion of the periphery of the bubble recirculation hole of plate formed with tip shape.

Through this structure, although the dissolubility of Xiang Shuizhong is higher, can generate can much be known by user Other bubble hydrogen.

In addition, one of mode of selectivity of the present invention is a kind of hydrogen water generating device, it is characterised in that the porous electricity Pole plate, the zoning portion between the bubble recirculation hole of the zoning porous electrode plate are with as towards the angle at the tip of the current The section polygon shape in portion.

In the hydrogen water generating device so formed, between the bubble recirculation hole of porous electrode plate, zoning portion has will The inclined plane opened of bubble recirculation hole frame for current towards the both sides that pumping section produces, thus improve the surface of porous electrode plate from bubble Property.In addition, the face clamping corner between the bubble recirculation hole of porous electrode plate is formed as discontinuous other face, so The bubble that the face of one side produces is difficult to zoarium with the bubble produced in the face of the opposing party, the bubble more microvesicle departed from from porous electrode plate Change, additionally it is possible to expect the hydrogen dissolving under molecular level hydrogen, nano bubble, microvesicle state.In addition, by porous electrode plate in bubble Have between the through hole of road towards the corner of current, it is smooth in the current that the bubble recirculation hole of multiple porous electrode plates circulates successively, The flow of water is being able to maintain that before the circulation of the bubble recirculation hole of the farthest porous electrode plate of pumping section.In addition, corner surface tension force is small, So the bubble that the corner between the bubble recirculation hole for the porous electrode plate that raising current directly contact produces is from bubble property.

In addition, one of mode of selectivity of the present invention is a kind of hydrogen water generating device, multiple porous electrode plates Bubble recirculation hole, is set between adjacent porous electrode plate with substantially mutually different position relationship.

The hydrogen water generating device so formed, it is mutual in the position for the bubble recirculation hole that multiple porous electrode plates are formed respectively It form differently, so by the current of bubble recirculation hole until each corner between porous electrode plate is along porous electrode plate stream It is logical, it is possible to increase the surface of porous electrode plate it is all from bubble property, and improve between multiple porous electrode plates the displacement of water Efficiency.

In addition, the mode of the selectivity as the present invention, is listed below.

(1) be configured to by the gap of the multiple porous electrode plate to the water stream S sprayed by the pump, will be The hydrogen of porous electrode plate generation is dissolved in current under elevated pressure.

(2) electrode hood that there is insulating properties on the top of porous electrode plate is configured with the electrolysis portion, in following position Bubble recirculation hole is provided with, i.e.,：With opposite with electrode hood porous electrode plate formation bubble recirculation hole substantially mutually not Same position.

(3) possesses luminescence unit, it projects light to the direction that the current with being flowed out from the flow export intersect.

Hydrogen water generating device described above, included in load other equipment in the state of implement or with other methods one Play the various modes of implementation etc..In addition, this technology can be realized as the hydrogen water generation system for possessing the hydrogen water generating device.

Invention effect

In accordance with the invention it is possible to the hydrogen compared to the water for improving the hydrogen water generating device realization used in water by impregnating in the past Concentration.

The hydrogen water generating device of alternative plan according to the present invention, has opposite between the bubble recirculation hole of porous electrode plate In pumping section produce the inclined shape of current, so improve porous electrode plate surface from bubble property.In addition, porous electrode plate Face clamping corner between bubble recirculation hole is formed as discontinuous other face, thus the bubble produced in the face of a side with The bubble that the face of the opposing party produces is difficult to zoarium, the bubble more microvesicle departed from from porous electrode plate, additionally it is possible to expect molecular level Hydrogen dissolving under hydrogen, nano bubble, microvesicle state.In addition, have by porous electrode plate between the through hole of bubble road towards water The corner of stream, it is smooth in the current that the bubble recirculation hole of multiple porous electrode plates circulates successively, in the porous electricity from pumping section farthest The flow of water is able to maintain that before the bubble recirculation hole circulation of pole plate.In addition, corner surface tension force is small, directly contacted so improving current Porous electrode plate bubble recirculation hole between corner produce bubble from bubble property.

The hydrogen water generating device of third program according to the present invention, in the bubble recirculation hole that multiple porous electrode plates are formed respectively Position differently from each other formed, so by the current of bubble recirculation hole until each corner between porous electrode plate is along more Pore electrod plate circulates, it is possible to increase the surface of porous electrode plate it is all from bubble property, and carried between multiple porous electrode plates The displacement efficiency of Gao Shui.

The hydrogen water generating device of fourth program according to the present invention, is configured to by the gap of the multiple porous electrode plate To by it is described pump spray water stream S, hydrogen generate in porous electrode plate is dissolved in current under elevated pressure, so as to It is dissolved in water more hydrogen.

The hydrogen water generating device of 5th scheme according to the present invention, is configured with the top of porous electrode plate in the electrolysis portion Electrode hood with insulating properties, in the bubble recirculation hole with being formed in the porous electrode plate opposite with the electrode hood substantially mutually not Same position is provided with bubble recirculation hole, prevents user from contacting electrode plate, and drop to electricity in the conductor pieces such as hair clip contingency In the case of in solution portion, short circuit that also can be between the different porous electrode plate of anti-stop polarity.

In addition, the hydrogen water generating device of the 6th scheme according to the present invention, possesses：Luminescence unit, its to from the outflow Mouthful outflow current intersect direction emergent light, institute so as to by light scattering visually from flow export flow out include hydrogen it is micro- The current of thin bubble, user can learn the diffusion-condition of hydrogen water.

Brief description of the drawings

Fig. 1 is the stereogram of the surface structure for the hydrogen water generating device for representing first embodiment.

Fig. 2 is the stereogram of the surface structure for the hydrogen water generating device for representing first embodiment.

Fig. 3 is the figure for representing to pull down the state that upper shell exposes in lower housing shell.

Fig. 4 be represent from upper shell pull down protective housing after upper shell stereogram.

Fig. 5 is the stereogram for observing upper shell inner surface from below.

Fig. 6 is the sectional view for representing the Section A-A shown in Fig. 1.

Fig. 7 is the stereogram in electrolysis portion.

Fig. 8 is the enlarged drawing of the ground plan in electrolysis portion, section B-B figure and section B-B.

Fig. 9 is the explanatory drawin of the state of the pressure between the porous electrode plate for representing electrolysis portion.

Figure 10 is the figure for the flow for representing the processing that the control unit of hydrogen water generating device performs.

Figure 11 is to represent to carry out the explanatory drawin for revealing the example of limitation above porous electrode plate.

Figure 12 is the figure for the hydrogen water generating device for illustrating second embodiment.

Figure 13 is the figure of the thin portion shape of porous electrode plate for illustrating to be made of metal otter board.

Figure 14 is the figure of the flowing for the bubble that the surface for the porous electrode version for illustrating to be made of metal otter board produces.

Figure 15 is the figure for the hydrogen water generating device for illustrating the 3rd embodiment.

Figure 16 is the figure for the hydrogen water generating device for illustrating the 4th embodiment.

Figure 17 is the exploded perspective view for the structure for representing hydrogen water generating device.

Figure 18 is the exploded perspective view for the structure for representing hydrogen water generating device.

Figure 19 is the sectional view of the construction for the first half for representing hydrogen water generating device.

Figure 20 is the explanatory drawin for representing to fall the state of conductor small pieces in multilayer electrode body.

Figure 21 is the block diagram for the electric structure for representing hydrogen water generating device.

Figure 22 is the flow of the main process task performed in control unit.

Figure 23 is the flow of the stopping processing being performed in control unit.

Figure 24 is that the pump performed in control unit stops the flow of processing.

Figure 25 is the flow of the polarity inversion processing performed in control unit.

Figure 26 is the flow of the end processing performed in control unit.

Figure 27 is the timing diagram of the various signals sent by control unit.

Figure 28 is the timing diagram of the various signals sent by control unit.

Figure 29 is the stereogram of the structure for the hydrogen water generating device for representing variation.

Figure 30 is the explanatory drawin for the structure for representing electrolysis portion accommodating recess.

Embodiment

Illustrate the present invention below as order below.

(1) first embodiment；

(2) second embodiment；

(3) the 3rd embodiments；

(4) the 4th embodiments；

The variation of (5) the 4th embodiments；

(6) summarize.

(1) first embodiment

Fig. 1 and Fig. 2 is the stereogram for the surface structure for representing hydrogen water generating device, and Fig. 3 is to represent that pulling down upper shell exposes The figure of state in lower housing shell, Fig. 4 be represent from upper shell pull down protective housing after upper shell stereogram, Fig. 5 is under The stereogram of side's observation upper shell inner surface, Fig. 6 are the sectional views for representing the Section A-A shown in Fig. 1, and Fig. 7 is the vertical of electrolysis portion Body figure, Fig. 8 are the enlarged drawings of the ground plan in electrolysis portion, section B-B figure and section B-B.

The hydrogen water generating device 100 of present embodiment, in the housing 10 that can be impregnated in the container of the ponding such as bath House and arrange pumping section 20, electrolysis portion 30 and power supply unit 40, moreover, electrolysis portion 30 is configured to keep certain intervals arranging multiple more Pore electrod plate, plate face of the current from pumping section 20 towards porous electrode plate.Thus, it is compared with the past, water can be generated and contained The microvesicle of hydrogen improve, the hydrogen water that the bubble growth of the hydrogen in water relaxes.

Hereinafter, a specific mode for hydrogen water generating device 100 shown in the drawings is illustrated.

Housing 10, is formed as watertight using the impermeability material such as synthetic resin and constructs, component seam is close by sealing material etc. Envelope so that water is not invaded in the housing 10 except the water flowing road 13 led to from inflow entrance 11 to the current of flow export 12.In Fig. 1, Fig. 2 In example Deng shown in, making upper shell 10a and lower housing shell 10b, Inner Constitution is watertight by zoarium up and down, in the upper of upper shell 10a Surface is provided with the guard block 10c with rib construction.

Guard block 10c is with by the base portion 10c1 extended in a manner of covering the upper surface of upper shell 10a and in the base portion The rib 10c2 that upper surface erects, has opening at the position of 30 opposite face of electrolysis portion with being exposed to upper shell 10a upper surfaces 10c3, has opening 10c4 at the position of 15 opposite face of Operation switch with being arranged at upper shell 10a upper surfaces.In opening 10c3 On be provided with rib 10c2, the certain intervals for referring to the degree not passed through with people along the long side direction in electrolysis portion 30 are set up in parallel Rib, prevents finger contact with electrolysis portion 30 of user, and the water flowed out from electrolysis portion 30 can be from hydrogen water generating device 100 upper surface sprays upward.

The almost all of the electric structural element of hydrogen water generating device 100 is arranged in the watertight part of housing 10, but forms electricity The porous electrode plate 31~33 in solution portion 30 is disposed in the outside of watertight part, is specifically disposed in water flowing road 13.

Pumping section 20 is installed in the way on water flowing road 13, and the inside water flowing road 21 of pumping section 20 forms the part on water flowing road 13. If pumping section 20 works, pump pressure is applied to the water in internal water flowing road 21, passes through the pump pressure, all water in water flowing road 13 The flowing in water flowing road 13, attracts water from inflow entrance 11, and discharges water from flow export 12.In the present embodiment with built-in Illustrated exemplified by pumping section, but pumping section can be set outside housing 10 or be connected by pipe etc. with exterior pumping section, to logical The water in water route 13 applies the structure of pump pressure.

Inflow entrance 11, is provided with the side for being arranged at housing 10 and in the recess at the angle of lower surface opening, flow export 12 It is arranged at the upper surface of housing 10.Inflow entrance 11, flow export 12 are not arranged in the position along the lower surface of housing 10, so that Without set the inner bottom surface for making the lower surface of housing 10 from container at a distance from foot part.By the way that flow export 12 is set In the upper surface of housing 10, the bubble that growth departs from rising from electrolysis portion 30 can will be produced in electrolysis portion 30, and to be involved in hydrogen aquatic The current sprayed into device 100.The filter 14 for the intrusion for preventing dust, incrustation scale, hair etc. is set in inflow entrance 11, prevents from leading to The blocking in water route 13, make dirty.

Other, Operation switch 15 and illumination confirming operation LED16 (Light are provided with the upper surface of housing 10 Emitting Diode, light emitting diode).When being operated to Operation switch 15, hydrogen water generating device 100 can be carried out Electric power on/off, aftermentioned illumination confirming operation LED16 display ON/OFF, the various operation inputs for the switching etc. for showing color. The side of housing 10 is provided with the charging terminal 17 for the power supply unit 40 for being configured to electric power storage, be able to will be filled via AC adapters etc. Electric terminal 17 is connected to commercial ac power source, charges to power supply unit 40.

It is used to cover the cap assembly (not shown) of charging terminal 17 hydrogen water generating device 100 is attached, by installing cover portion Part cover charging terminal 17, become prevented when hydrogen water generating device 100 is impregnated in water charging terminal 17 short circuit, electric leakage Structure.

The control charging base of the fixed control main body as automatically controlled hydrogen manufacturing water generating device 100 in the watertight part of housing 10 Plate 18.From control charging substrate 18 extend multiple distributions, respectively with pumping section 20, electrolysis portion 30, power supply unit 40, Operation switch 15th, confirming operation LED16 connections are illuminated.Distribution between electrolysis portion 30 and control charging substrate 18 is only shown in attached drawing.

The distribution in electrolysis portion 30 is connected to, the electrolysis portion 30 being not directly connected in water flowing road 13, is connected to and porous electricity The top for the stub 34,35 that pole plate 31~33 connects.Stub 34,35 by the through hole 13a of 13 wall of water flowing road and Watertight part protrudes.Porous electrode plate 31,33 is connected to the stub (for example, stub 34) of a side, in porous electrode plate 32 Form the inserting hole of the stub of a side.On the other hand, porous electrode plate 32 is connected to the stub of the opposing party (for example, leading Body rod 35), porous electrode plate 31,33 formed the opposing party stub inserting hole.The through hole 13a of 13 wall of water flowing road Sealed between stub 34,35 by sealing material etc..In example as shown in Figure 5, revealed by through hole 13a in watertight part The top of the stub 34,35 gone out screws togather bolt, and the sealing material such as clamping O rings are planted between 13 wall of bolt and water flowing road, from And seal through hole 13a.

On water flowing road 13, near flow export 12, have with the balancing gate pit 13b gradually widened close to flow export 12, structure Into multiple porous electrode plates 31~33 in electrolysis portion 30, in the water flowing road 13 of the wide cut opening of balancing gate pit 13b, with being set to The flowing path section on inaccessible water flowing road 13 is substantially all respectively.Thus, the water to circulate on water flowing road 13, must pass through each porous electricity Bubble recirculation hole 31a~33a of pole plate 31~33 reaches flow export 12.In addition, by the way that the exit opening of balancing gate pit 13b is formed Than 13 heavy in section of the water flowing road product near pumping section 20, to become so as to supplying hydrogen water to the supply mouth in the seeping container of bath etc. Greatly, diffusion of the hydrogen water into container supplied from hydrogen water generating device 100 is promoted.The shape of balancing gate pit 13b is not limited to funnel-form Shape is widened, as long as applying the hydraulic pressure of equalization to electrolysis portion 30, the diffusion of the hydrogen water from flow export 12 can be promoted, then can Enough using variously-shaped.

Porous electrode plate 31~33 is formed as tabular by conductive metal materials such as gold-plated, platinum titaniums, sets multiple by plate Bubble recirculation hole 31a~33a that face penetrates through in table.Porous electrode plate 31~33, keeps certain in a manner of mutually non-touching It is fixed in the state of interval in water flowing road 13, via above-mentioned distribution and stub 34,35 from power supply unit 40 to porous electrode plate 31~33 power supplies.The plate face entirety of bubble recirculation hole 31a~33a across porous electrode plate 31~33 is formed uniformly.

Porous electrode plate 31~33, applies voltage and to produce potential difference between adjacent plate, for example, porous respectively Apply low-voltage to porous electrode plate 32 in the case of the application of electrode plate 31,33 is high-tension, apply in porous electrode plate 31,33 low Apply high voltage to porous electrode plate 32 in the case of voltage.Thus, the face opposite with the adjacent panels of porous electrode plate 31~33 Between be electrolysed, hydrogen (and oxygen) is produced near the plate face of porous electrode plate 31~33.

The wide cut opening of 31~33 occlusion pressure room 13b of porous electrode plate, pumping section 20 apply pump pressure to water flowing road 13.It is logical The pump pressure is crossed, the water up to balancing gate pit 13b is passed on water flowing road 13, is produced along broadening shape in all diffusions of flowing path section The current of the raw plate face towards porous electrode plate 31~33, in the porous electrode plate 31~33 of the flow export 12 on inaccessible water flowing road 13 Plate face apply the pressure of current so that with will exist in the bubble of the electrolytic hydrogen in the surface of porous electrode plate, oxygen The mode that the moment of electrolysis pushes open pulls in the effect in current, what the water flowed out from the flow export of hydrogen water generating device 100 included The bubble microvesicle of hydrogen.In addition, the not only visible bubble hydrogen microvesicle of eyes, the hydrogen of the sightless size of eyes is desirable to Bubble, the hydrogen before bubble growth are dissolved in the effect in current, for example, can also expect hydrogen with the molecular level after being and then electrolysed The effect that is drawn into current, hydrogen are drawn into the effect in current with nano bubble, microvesicle.In addition, as shown in deep or light in Fig. 9, It is particularly in balancing gate pit 13b in the porous electrode sheet separation of upstream side, due to configuring the bubble in the porous electrode plate in downstream The resistance of recirculation hole, water are pressurized, so hydrogen is more forcibly dissolved in water, dissolving hydrogen concentration improves.In fig.9, as setting The example of more porous electrode plates is put, shows possess porous electrode plate 31,32,33, this five electrolysis portion of 33-1,33-2 30, but it is of course possible to being three, four or more than five.In addition, balancing gate pit 13b is set, and with its outlet of occlusion And the mode of flow export 12 sets porous electrode plate 31~33, so applying the water of approximate equality comprehensively in porous electrode plate 31 Pressure, water is generally flowed into multiple bubble recirculation hole 31a of 31 entire surface of porous electrode plate, comprehensively multiple from porous electrode plate 33 The universal outflow waters of bubble recirculation hole 33a.Thus, all each bubble circulations formed of plate face of porous electrode plate 31~33 are formed in Hole 31a~33a generally spreads all over the current of water, is difficult in the universe of the board direction of porous electrode plate 31~33 near plate face Occluded water.That is, the displacement efficiency of the water in water flowing road 13 improves near the plate face of porous electrode plate 31~33.

As shown in figure 8, bubble recirculation hole 31a~33a of porous electrode plate 31~33 can be in adjacent porous electrode plate Between formed with mutually different position relationship.That is, under top view, the bubble recirculation hole 31a of porous electrode plate 31 and more The bubble recirculation hole 32a of pore electrod plate 32 is respectively formed as position relationship or the non-duplicate position that a part repeats, porous electrode The bubble recirculation hole 32a of the plate 32 and bubble recirculation hole 33a of porous electrode plate 33 is also respectively formed as the position that a part repeats Relation or non-duplicate position.

So between adjacent porous electrode plate 31~33, bubble recirculation hole 31a~33a is closed with mutually different position In the case that system is formed, flowed through by the water of porous electrode plate 31~33 with zigzag, so water circulates along porous electrode plate Until each corner between porous electrode plate 31~33, can be improved in the surface entirety of porous electrode plate from bubble property.That is, it is electrolysed The shorter residence time of hydrogen (and oxygen) bubble of plate surface, electrolysis plate surface are difficult to be covered by bubble.Thus, electrolysis effect is improved Rate, bubble are difficult to hydrogen (and oxygen) microvesicle in electrolysis plate surface growth, departed from from electrolysis plate surface, additionally it is possible to expect molecular water Hydrogen dissolving under flat hydrogen, nano bubble, microvesicle state.As a result, the hydrogen meltage for the water discharged from hydrogen water generating device 100 Improve, and, it is possible to increase the hydrogen meltage of the water of the wide scope in container.

Figure 10 is the figure for the flow for representing the processing that the control unit 50 of hydrogen water generating device 100 performs.Place shown in the figure Reason, by starting to power and since power supply unit 40 to control unit 50.Control unit 50 is by being equipped on as above-mentioned control main body The control circuit such as microcomputer of control charging substrate 18 form.

In the processing shown in Figure 10, control unit 50 indicates that operation is opened it is first determined whether having accepted via Operation switch 15 The operation of beginning starts operation input (for example, more than 2 seconds long-press etc.) (S1), is accepting the situation of operation beginning operation input Under (S1：It is), the operation start to process (S2) of hydrogen water generating device 100 is performed, is not accepting the feelings of operation beginning operation input (S1 under condition：It is no), the judgement of step S1 is periodically performed repeatedly, untill accepting operation and starting operation input.

Operation start to process (S2) mainly starts to power and pumping section 20 is started to power to porous electrode plate 31~33.It is right Porous electrode plate 31~33 is powered, for example, in the case that porous electrode plate 31,33 is is supplied to high-tension positive plate, it is porous Electrode plate 32 is the negative plate for being supplied to low-voltage, in the case that porous electrode plate 31,33 is the negative plate for being supplied to low-voltage, Porous electrode plate 32 is to be supplied to high-tension positive plate.In the present embodiment, the former is known as positive electrolysis mode, and the latter is known as Inverse electrolysis mode.In the present embodiment, become and switch positive electrolysis mode and inverse electricity at regular intervals (mode duration) The structure of solution pattern.Pumping section 20, when power supply starts, applies pump pressure to water flowing road 13, water flowing road 13 is produced the flowing of water.

Then, the process (S3) of 50 judgment model duration of control unit (for example, 29 seconds etc.).Control unit 50 is to any Pattern carries out timing to the continuous power-on time of porous electrode plate 31~33, exceedes mode duration in the continuous power-on time (S3：It is), positive and negative reversion electrolysis mode (S4), (S3 in the case where continuous power-on time is not less than mode duration：It is no), Skip step S4 and enter step S5.Between pattern switching, energization of the short time stopping to porous electrode plate 31~33 is set Energization dwell time (for example, 1 second etc.).

In this way, by being electrolysed polarity by the switching reversion of electrolysis mode at regular intervals, in the porous electricity as cathode The calcium carbonate scale dissolving of the surface attachment of pole plate, the current produced by pumping section 20 are discharged.Thereby, it is possible to realize porous electrode The maintenance of the electrolysis performance of plate 31~33 and long lifetime.

Then, control unit 50 judges the process (S5) of automatic running time.Control unit 50 from step S2 to bringing into operation The duration of operation of process carries out timing, (S5 in the case of having exceeded the automatic running time in the duration of operation：It is), (S6) the out of service, (S5 in the case where the duration of operation is not less than the automatic running time：It is no), enter step sentencing for S7 It is disconnected.In this way, hydrogen water generating device 100, become after operation starts, by being automatically stopped fortune when certain time (such as 15 grade) Capable structure.

In the step s 7, judge whether that operation out of service has been carried out to Operation switch 15 to be stopped operation (for example, 2 seconds Long-press above etc.), (S7 in the case where having carried out operation and having stopped operation：It is), (S6) out of service, stops not carrying out operation (S7 in the case of only operating：It is no), perform repeatedly step S3~processing.

In operation, the operation that can carry out lighting illumination confirming operation LED16 is shown, as illumination confirming operation In the case that LED16 settings are multi-colored led, illuminant colour can be made to shine with some cycles switching.As the switching timing of illuminant colour, For example, the timing of above-mentioned pattern switching can be set to.Specifically, consider to make illumination confirming operation under positive electrolysis mode In the case that LED16 for example puts shiny red, be powered stop during during extinguish illumination confirming operation LED16, then when cutting Make illumination confirming operation LED16 point sapphirines etc. when being changed to negative electrolysis mode at the same time.Furthermore, it is possible to it is that Operation switch 15 is carried out During predetermined operation input (for example, pressing operation when) less than 2 seconds, switch the structure of bright light color.

As described above, by control electrolysis portion 30, pumping section 20, illumination confirming operation LED16, can prevent to Porous electrode plate 31~33 adheres to calcium carbonate, maintains high electrolysis performance and makes device lifetime long lifetime.Moreover, pass through illumination The bright light of confirming operation LED16, by user's operation conditions, and can produce with as the decorative lighting in container The atmosphere of vision excitement.

In the present first embodiment, in balancing gate pit 13b, by three electrode plates by porous electrode plate 31~33, Its inaccessible wide cut opening of five porous electrode plates of 31~33-2 of porous electrode plate, so that the gap of each porous electrode plate, pressure The inside of power room 13b becomes under pressurization atmosphere, improves the dissolving of the hydrogen into water, but for example, it is also possible to by each porous electricity The downstream of pole plate, i.e., the top of each porous electrode plate carry out flow path limitation, improve the internal pressure of balancing gate pit 13b.

Specifically, as shown in (a) of Figure 11, the electrolysis portion cover body 30a on the top in covering electrolysis portion 30 can be set, and And multiple bleed hole 30b are formed in the top part of electrolysis portion cover body 30a, arranging is electrically connected to the several of bleed hole 30b The solenoid valve 30c of the control charging substrate 18 of the open occlusion of control.

In this case, when solenoid valve 30c is set to open state, the flow path limitation on water flowing road 13, shown in Fig. 9 Situation similarly carries out in the gap of porous electrode plate, and with predetermined efficiency, hydrogen is dissolved in water, but by control charging substrate During 18 occlusion control solenoid valve 30c, make the inside of balancing gate pit 13b, particularly equivalent to electrolysis portion 30 downstream electrolysis portion The interior side space part of cover body 30a, can such as be shown under pressurization atmosphere with deep or light, it is molten into water can to further improve hydrogen Solve efficiency.

In addition, solenoid valve 30c etc. is not necessarily required electrically, as shown in (b) of Figure 11, can be only fitted to being electrolysed Position opposite bleed hole 30b that portion cover body 30a is worn is equipped with the needle plate 30e of pin 30d, rotates what can be operated in user The needle lifting screw 30f that position is set, so as to manually make pin 30d come in and go out relative to bleed hole 30b, carries out flow path limitation.

Through this structure, also can be special by making pin 30d enter bleed hole 30b, so that in balancing gate pit 13b The interior side space part of the electrolysis portion cover body 30a in the downstream in electrolysis portion 30 is not comparable to to pressurize under atmosphere, can be into one Step improves dissolved efficiency of the hydrogen into water.

In addition, in the present first embodiment, it is illustrated with pumping section 20 with certain pushing quantity work, but can change Become the pushing quantity of pumping section 20, the flow velocity in water flowing road 13 (balancing gate pit 13b) can also be adjusted.

In above-mentioned example, it is big in narrow electrode sheet separation flowing water flow velocity in electrolysis portion 30, such as in minus plate The bubble for the hydrogen that surface produces, peels off rapidly in the state of very little is gone back after just producing, is effectively dissolved into water.

Herein when reducing the pushing quantity of pumping section 20, the flow velocity of the water in electrode sheet separation diminishes, and is produced in cathode plate surface The bubble of raw hydrogen is not peeled off immediately, and as time goes by, hydrogen gradually puts aside looseization, is more than in the resistance received from current Peeled off at the time of bubble is to the adhesive force of cathode plate surface from cathode plate surface.

Then, the big bubble hydrogen being released in bath, reaches rapidly hot water surface, is spread in bathroom.

In the case, fine bubble hydrogen, can not expect the efficiency of dissolved hydrogen in the hot water in bath, But the breathing of user enters in vivo in the hydrogen that bathroom is spread is by balneation, it can expect that more directly health enhancement is made With.

That is, using the hydrogen water generating device of this first embodiment as representative, the hydrogen water generating device described in this specification, Can possess the bubble footpath that the control unit (such as control charging substrate 18) of the pushing quantity by pumping section 20 and control pumping section 20 is formed Adjustment unit (bubble footpath adjustment portion), the effect of the hot bath brought thus, it is possible to the hydrogen water selectively enjoyed by high concentration and The health of both effects that the hydrogen spread in bathroom is brought promotes effect.

(2) second embodiment：

The hydrogen water generating device of present embodiment is aquatic with the hydrogen of above-mentioned first embodiment except the structure in electrolysis portion The structure same into device 100, so being said to the structure beyond electrolysis portion using mark identical with first embodiment It is bright.

Figure 12 is the figure for the hydrogen water generating device for illustrating present embodiment.

Electrolysis portion 30 keeps certain intervals to arrange multiple porous electrode plates 231~233, and (porous electrode plate 232,233 is being schemed In do not expose).Porous electrode plate 231~233 keeps being fixed on water flowing in the state of certain intervals in a manner of mutually non-touching In road 13, via above-mentioned distribution and stub 34,35 to porous electrode plate 231~233 from power supply unit 40 power in terms of, it is and upper It is same to state first embodiment.

On the other hand, the porous electrode plate 231~233 of present embodiment, the bubble of zoning porous electrode plate 231~233 Zoning portion between recirculation hole becomes the section polygon shape in the corner at the tip with the current produced towards pumping section 20.That is, Porous electrode plate 231~233, each face formed respectively towards the bubble recirculation hole holding angle portion of the both sides in zoning portion become to general The inclined inclined plane in direction that the current that pumping section 20 produces are opened towards each bubble recirculation hole frame.Pass through what is flowed along the inclined plane Current, are improved in the bubble that the surface of porous electrode plate 231~233 produces from bubble property.In addition, porous electrode plate 231~233 Bubble recirculation hole between face, clamping corner is formed as discontinuous other face, so the bubble produced in the face of a side Bubble with being produced in the face of the opposing party is difficult to zoarium, the bubble more microvesicle departed from from porous electrode plate 231~233, additionally it is possible to Expect the hydrogen dissolving under molecular level hydrogen, nano bubble, microvesicle state.In addition, pass through the porous electrode between bubble recirculation hole Plate 231~233 has towards the corner of current, smooth in the current that the bubble recirculation hole of porous electrode plate 231~233 circulates, Until being able to maintain that the flow of water untill circulating from the bubble recirculation hole of the farthest porous electrode plate 233 of pumping section 20.In addition, corner table Face tension force is small, so the bubble that the corner between the bubble recirculation hole for the porous electrode plate 231~233 that current directly contact produces From bubble property improve.The section polygon shape in corner that is such, having the current produced towards pumping section 20, has as in gas An example for the porous electrode plate 231~233 that the plate face between recirculation hole is formed is steeped in metal otter board described below.

Figure 13 is the figure of the thin portion shape of porous electrode plate 231~233 for illustrating to be made of metal otter board.Present embodiment Porous electrode plate 231~233 be made of metal otter board, which is put into crack in sheet metal, with fractuer direction Generally vertical direction elongation sheet metal is formed as rhombus net eye shape.The porous electrode plate 231~233 being made of metal otter board, For the mesh members for configuring ride W with cross-like, the opening surrounded with ride W becomes the bubble recirculation hole that current lead to 231a~233a.Bubble recirculation hole 231a~233a is diamond shape, and the first diagonal L 1 is longer than the second diagonal L 2, the first diagonal The angle of top H1, H2 on L1 are less than the angle of top H3, H4 in the second diagonal L 2.

As described above, metal otter board is by being set up in parallel a plurality of dotted line shape that cracking initiation is intermittently put into sheet metal Cracking, makes rift portion is formed as rhombus net eye shape with fractuer direction generally vertical direction elongation sheet metal, empty Connecting portion X between the crack and crack of wire cracking is positioned at the centre in the crack that adjacent dotted line shape is cracked.

When by formed crannied sheet metal dotted line shape be cracked when being set up in parallel direction elongation, between dotted line shape Linear parts by the length direction of linear parts for axis it is rotating in a manner of bend.Therefore, the section of the mesh of metal otter board is formed The ride W of general square shape shape, its square face have inclined square relative to the face direction of porous electrode plate 231~233 Inclined plane.In the present embodiment, it is substantially 45 ° relative to the tiltangleθ in the face direction of porous electrode plate 231~233, it is square Inclined plane is substantially same inclination relative to the plate face of porous electrode plate 231~233.

As shown in figure 14, in the porous electrode plate 231~233 so formed, the ride W between bubble recirculation hole is The section polygon shape in the corner with the current produced towards pumping section 20, ride W have inclined square relative to current Inclined plane.Therefore, the bubble produced on the surface of porous electrode plate 231~233 is improved from bubble property.In addition, ride W directions The side clamping corner for the current that pumping section 20 produces is formed as discontinuous other face, so the bubble produced in the face of a side Bubble with being produced in the face of the opposing party is difficult to zoarium, the bubble more microvesicle that will depart from from porous electrode plate 231~233, moreover it is possible to Enough expect the hydrogen dissolving under molecular level hydrogen, nano bubble, microvesicle state.In addition, the corner top of ride W is matched somebody with somebody towards current To, so the impetus in the current of the bubble recirculation hole circulation of porous electrode plate 231~233 is difficult to be hindered by ride W, until Untill circulating from the bubble recirculation hole of the farthest porous electrode plate 233 of pumping section 20, a degree of flow of water is able to maintain that.This Outside, the angled surface tension force of ride W is small, is improved in the bubble that corner produces from bubble property.The corner top of ride W also has There is the function as charge concentration portion.For the charge concentration portion, then illustrate in the 4th embodiment.That is, can also solve It is interpreted as in the case where using metal otter board as porous electrode plate, also the periphery of the bubble recirculation hole in the porous electrode plate Form charge concentration portion.

(3) the 3rd embodiments：

The hydrogen water generating device of present embodiment, except the shape on water flowing road, for the hydrogen water with above-mentioned first embodiment Generating means 100 are same structure, are carried out for the structure beyond water flowing road using mark identical with first embodiment Explanation.Figure 15 is the figure for the hydrogen water generating device for illustrating present embodiment.

The water flowing road 313 of present embodiment, near flow export 12, has with the pressure gradually widened close to flow export 12 Power room 313b, forms multiple porous electrode plates 31~33 in electrolysis portion 30, in the water flowing of the wide cut opening close to balancing gate pit 313b Road 313, it is same with first embodiment with the substantially all aspects for being set to the flowing path section on inaccessible water flowing road 313 respectively.With First embodiment is same, and the shape of balancing gate pit 313b is not limited to funnel-form broadening shape, as long as applying equalization to electrolysis portion 30 Hydraulic pressure, diffusion of the hydrogen water from flow export 12 into container can be promoted, then can be used variously-shaped.

The side of balancing gate pit 313b is penetrated through, forms the tubular water route 313c of the part on the water flowing road connected with pumping section 20 Extend near the center of balancing gate pit 313b, the reducing diameter part 313d of top towards the balancing gate pit 313b of tubular water route 313c are open. That is, sprayed water by the reducing diameter part 313d of the water that tubular water route 313c is flowed into towards balancing gate pit.In balancing gate pit 313b, reducing diameter part The occlusion of 313d sides, expanding side 313e sides are open towards flow export 12, but wide diameter portion 313e is with being set to the inaccessible flow path in electrolysis portion 30.Cause This, the water sprayed from tubular water route 313c, in balancing gate pit, the reducing diameter part 313d of 313b is collided, and becomes the wall along balancing gate pit 313b Facing to wide diameter portion 313e flowing water streams, the rear side interflow of the opening of 313c in tubular water route, near wide diameter portion 313e In balancing gate pit, the water route section of 313b is all forms substantially homogeneous current.Thereby, it is possible to realize be disposed in wide diameter portion 313e Comprehensive structure for applying substantially equal hydraulic pressure of the porous electrode plate 31~33 in neighbouring electrolysis portion 30.

In addition, in the example shown in Figure 15, it is complete in order to improve the water route section of the balancing gate pit 313b near wide diameter portion 313e The homogeneity of the current of body, is provided with commutator segment 313f1~313f4.That is, it is equipped with commutator segment 313f1~313f4 so that area The bottom surface of zoned pressure room 313b.From tubular water route 313c spray current, by commutator segment 313f1~313f4 with zoning ratio The mode that the current that distribute accordingly flow into each zoning shunts, the current of shunting become press per zoning collide in reducing diameter part 313d and The current risen along the wall of balancing gate pit 313b towards porous electrolytic zinc-coated steel sheet 31~33.Thus, cut in the water route of balancing gate pit 313b Face is all, and the homogeneity of the current near wide diameter portion 313e improves, the water that the porous electrode plate 31~33 in electrolysis portion 30 applies The homogeneity of pressure improves.

Tubular water route 313c tops can be opened to other side walls direction of the balancing gate pit 313b beyond reducing diameter part 313d Mouthful structure, it is also contemplated that for example spray towards forming funnelform inclined plane, or erect new collision wall and towards this Wall ejection etc..That is, if not the direction for being directly toward electrolysis portion 30 towards the structure in various directions, can also realize Comprehensive structure for applying substantially equal hydraulic pressure of porous electrode plate 31~33.

Even in this way, to 31~33 other directions of porous electrode plate spray water structure, can be on inaccessible water flowing road The plate face of the porous electrode plate 31~33 of 13 flow export 12 applies the pressure of current, by the surface of porous electrode plate 31~33 Electrolytic hydrogen, the bubble of oxygen are drawn into current in a manner of the moment in electrolysis pushes open, from hydrogen water generating device 300 The bubble microvesicle of hydrogen that includes of the water that flows out of flow export 12, or can also expect molecular level hydrogen, nano bubble, microvesicle Hydrogen dissolving under state.

(4) the 4th embodiments

Referring to the hydrogen water generating device explanation of the 4th embodiment of Figure 16~28 pair.

As shown in (a) of Figure 16, the hydrogen water generating device 400 of this 4th embodiment is equal with hydrogen water generating device 100 Sample, to configure the bottom in bath, for supplying the device of electrolyzed hydrogen water into bath.

As shown in (b) of Figure 16, hydrogen water generating device 400, elliptical makeup is regarded in all appearances without corner The inside of framework 405, houses composition and is built-in with above-mentioned water flowing road 13, control charging substrate 18, pumping section 20, electrolysis portion 30, power supply The hydrogen water generation body 410 of the watertight shape of the grade of portion 40.

Figure 17 is the exploded perspective view for the construction for showing hydrogen water generating device 400.As can be seen from Figure 17, hydrogen water generating device 400 by including grip plate 401, upper makeup cover 402, the makeup framework 405 of lower makeup cover 403 and the main body that is generated as hydrogen water Hydrogen water generation main part 410 is formed.

The 403 makeup framework 405 formed fit up and down is covered by grip plate 401, upper makeup cover 402 and lower makeup, except It is used in beyond the hydrogen water generation of bath, is configured to be positioned in charge to the power supply unit 40 in hydrogen water generation body 410 On the battery charger cradle 406 of tray shape.

Battery charger cradle 406, be open on the top box, the i.e. periphery of the battery charger cradle bottom plate 406a of general square shape shape erect perisporium 406b, is hypocrateriform by Inner Constitution, in addition, in one corner, in the hydrogen water generation body 410 to being loaded on top Power supply unit 40 power energization connecting portion 406c be formed as convex.

Mark 406d represents the energising terminal that is provided projectingly in energization connecting portion 406c, and energising terminal 406d is via being disposed in The transforming circuit substrate connection of the inside of battery charger cradle 406 connects in live wire 410e (shown in dotted line) in the terminal of live wire 410e The plug (not shown) of socket can be connected to by being connected to.

In addition as described later, when hydrogen water generating device 400 impregnates in bath, be formed as makeup framework 405 inside, Hot water is immersed as the clearance space (following to become immersion space) in the outside of hydrogen water generation body 410.Therefore, from bath In hydrogen water generating device 400 after interior just taking-up, if temporarily residual solid carbon dioxide, but battery charger cradle 406 is formed as erecting perisporium 406b's Hypocrateriform, so in the case of battery charger cradle 406 is positioned in after just being taken out out of bath, in hydrogen water generating device 400 Residual water will not accumulate in perisporium 406b, drench surrounding.

In addition, energization connecting portion 406c, energising terminal 406d are formed in the position higher than perisporium 406b.Therefore, charging In the case of a large amount of water are stockpiled in platform 406, the water also spilling water before energising terminal 406d is reached, institute is so as to prevent energization end Sub- 406d floods.

By loading hydrogen water generating device 400 on the battery charger cradle 406 so formed, into hydrogen water generation body 410 Power supply unit 40 power, using the electric power in the hydrogen water generating device 400 by electrolytically generated hydrogen, to hydrogen water generating device 400 Bath water in outer bathing bath releases hydrogen, the dissolved hydrogen in bath water.

As shown in Figure 16 and Figure 17, grip plate 401 be with by the elliptical long axis direction central portion of top view to short axle The slight curvature upward of the narrow shape in direction into the hollow platy of convex component, in the carrying of hydrogen water generating device 400 When etc., the part of the narrow shape is played function as handle part.

In addition, as Figure 16 (b) shown in, the grip plate 401 make up on being configured at cover 402 in the state of, with this The missing discharge port 401a of substantially semicircle arcuation is formed between upper makeup cover 402.Missing discharge port 401a is as flow export 12 positions played function, release electrolyzed hydrogen water, the bubble sprayed from hydrogen water generation body 410.

In addition, form a plurality of airport 401b at the top of the face side of grip plate 401, in hydrogen water generating device 400 to bath When groove sinks, water is immersed at leisure in the inside for the grip plate 401 for being formed as hollow form, is configured to be gradually reduced buoyancy, hydrogen water Generating means 400 are deposited in underwater.

It is in addition, opposite in the rear side of grip plate 401, i.e., the electrolysis portion 30 that body 410 is generated with hydrogen water described later Part, divides formed with the current for will be released from the electrolysis portion 30, bubble to both of the aforesaid missing discharge port 401a shuntings Stream portion 401c.

Figure 19 is the sectional view represented in the first half of the hydrogen water generating device 400 of the B-B positions of Figure 16 (b) cut-out. As can be seen from Figure 19, the back side of grip plate 401, is formed as towards short-axis direction both ends upward inclining from central portion prominent downwards Oblique ramped shaped, the electrolyzed hydrogen water sprayed from electrolysis portion 30 together with bubble in central portion to short-axis direction both sides branch, along Slope using distributary division 401c as starting point is flowed at the back side of grip plate 401, by missing discharge port 401a to be brought by current Some directive property are released.

As shown in figure 17, upper makeup cover 402 regards substantially to house the appearance for the substantially first half that hydrogen water generates body 410 The hemispherical hollow form makeup cover of truncated oval, practises physiognomy in its top surface formed with the electrolysis portion 30 for making hydrogen water generate body 410 Pair and that exposes rectangular-shaped expose opening portion 402a and make the illumination confirming operation for being equally disposed in hydrogen water generation body 410 Multiple circular hole 402b that LED16, Operation switch 15 are exposed.

Lower makeup cover 403 is configured to the case of top liberation to house the makeup cover that hydrogen water generates the lower half of body 410 Type, all shapes are set to generally rectangular, and four corner entirety of bending are configured to substantially oblong shape.

The rectangular-shaped bottom for exposing the bottom of hydrogen water generation body 410 is provided with the bottom of lower makeup cover 403 Be open 403a, in addition, facing formed with the inflow entrance 11 for making to arrange in the bottom of hydrogen water generation body 410 on its periphery Water intaking opening 403b, make the charging terminal 17 for equally generating the bottom arranging of body 410 in hydrogen water facing by electrical aperture 403c。

In addition, it is lower makeup cover 403 lower sidewall, on makeup cover 402 top surface periphery, formed with for making hydrogen water Generating means 400 settle in bath, or are flowed into from the outflow that the air in makeup framework 405 is carried out during bath pull-up, heat The slit 421 that the outflow of water flows into.

The hydrogen water generating device 400 of present embodiment as described above, is formed as the hot water when being impregnated in bath and immerses leaching Hydrospace is (for example, as the immersion space shown in mark 430 in Figure 19.), with being formed at the top of the face side of grip plate 401 A plurality of airport 401b is same, is configured to immerse hot water from these slits 421 to immersion space, reduces buoyancy, hydrogen water generation dress Put 400 and be deposited to underwater.

In addition, to flow into hot water at leisure to immersion space, the opening of air is run out of from immersion space at leisure for slit 421 Shape, area are formed so that are decontroled in water before bottom even if user configures in hydrogen water generating device 400 in bath In the case of hand, hydrogen water generating device 400 will not sharp be settled and collided in bath bottom.

Hydrogen water generation body 410 is to be used as hydrogen water with the structure substantially same with above-mentioned hydrogen water generating device 100 The component of approximately parallelepiped body shape that plays function of generation main body, if external appearance characteristic be described in fig. 17, Its upper surface substantially central portion arranges the electrolysis portion 30 of top view substantially rectangular shape, and on the outside of the long side in the electrolysis portion 30 Side is provided with four illumination confirming operation LED16 and Operation switch 15.

Illumination confirming operation LED16 from it is above-mentioned it is upper makeup cover 402 circular hole 402b expose and upward with predetermined photograph Firing angle emergent light, but as shown in figure 19, illumination confirming operation LED16 configurations are being emitted by illumination confirming operation LED16 The position that light intersects with the bubble, the current that are directed toward and released to the direction on the slope along distributary division 401c from missing discharge port 401a Put.

Therefore, from illumination confirming operation LED16 outgoing light by the current of the bubble comprising hydrogen scatter in the state of quilt User is depending on recognizing, the scattering state of the visual light of user, so as to confirm the generation of the current of the micro air bubble comprising hydrogen State, diffusion.

In addition, flickeringly being changed in bath by the light that the current comprising bubble scatter, institute in bathroom so as to perform The atmosphere of illusion, can loosening user, offer is comfortable to take a shower the time.That is, illuminate confirming operation LED16 be used as to from The luminescence unit (illuminating part) for the direction emergent light that the current of flow export outflow intersect plays function.

The explanation of Figure 17 is returned to, in the bottom of hydrogen water generation body 410, configuration will be generated in body 410 to hydrogen water Inflow entrance 11 that the water of supply is filtered and fetched water by filter 14 and for hydrogen water generating device 400 to be positioned in battery charger cradle Being contacted and powered charging terminal 17 with energization connecting portion 406c by electrical aperture 403c via lower makeup cover 403 when 406.

In addition on hydrogen water generation body 410 internal structure, as shown in figure 18, by possess control charging substrate 18, Pumping section 20, power supply unit 40 function part 422, house the function part 422 upper shell 410a and lower housing shell 410b and electrolysis portion 30。

Function part 422 is substantially same with above-mentioned hydrogen water generating device 100, so simplify explanation, but based on control charging base The control of plate 18, driven by power pumping section 20 is obtained from power supply unit 40, and to electrolysis portion 30 with predetermined polarity supply electric power.This Outside, it is also equipped with the water flowing road 13 for leading to current via pumping section 20.

Lower housing shell 410b is for the housing for the substantially lower half for housing function part, top view substantially rectangular shape, is formed For the box-like with upper opening.

In the state of the top of lower housing shell 410b, the upper shell 410a collecting function parts 422 that inverse box is opened in lower section Loaded and fixed with seal shape.That is, lower housing shell 410b and upper shell 410a seals against each other conjunction via filler 423 of the configuration in peripheral part Body.

Therefore, even if making hydrogen water generating device 400 sink in bathing bath, bath water will not invade lower housing shell 410b and The inside of upper shell 410a.

Upper shell 410a top surface substantially central portion formed with electrolysis portion accommodating recess 424.In electrolysis portion accommodating recess In 424, the opening portion 425 that the water flowing road 13 extended is connected from pumping section 20 is open upward, further on water flowing road 13 The top of opening portion 425 storage electrolysis portion 30.At this time, electrolysis portion 30 formation water flowing road terminal formed below balancing gate pit 13b。

In addition, the left and right portion of the electrolysis portion accommodating recess 424 in upper shell 410a, is configured to configure on function part 422 During upper shell 410a, vertically set with watertight shape in the stub 34,35 that the charging substrate 18 for being powered to electrolysis portion 30 erects Put.The stub 34,35 is turned in its week face with electrolysis portion 30, and bottom is connected with the control arranged in function part 422 System charging substrate 18, is configured to power from power supply unit 40 to electrolysis portion 30 via stub 34,35.That is, with power supply unit 40 Conducting, is powered from power supply unit 40 to electrolysis portion 30, is configured to be electrolysed.In figure, mark 34a and mark 35a are for by after The multiple porous electrode plates stated are set to contact or contactless state relative to each stub 34,35 and are alternately set to different polarity Holding member.

Electrolysis portion 30 has by five levels of the porous electrode plate 31,32,33,33-1,33-2 of holding certain intervals The folded multilayer electrode body 426 formed, applies voltage in relatively adjacent porous electrode plate and differently from each other to become height respectively Current potential and low potential, occur the electrolysis of bath water between opposite plate face, and hydrogen and oxygen are generated near plate face.

Specifically, electrolytically generated hydrogen, the gas of oxygen are passed through on porous electrode plate 31,32,33, the surface of 33-1,33-2 Bubble by the current of the pressure water from pumping section 20 with micro situation by current scour, become the dissolving of the hydrogen dissolved with micro situation Hydrogen.

Especially in the present invention, as described previously by the flow velocity of current of the adjustment from pumping section 20, can adjust in water Time untill being washed by being electrolysed the bubble that becomes larger, adjustment bubble footpath.

, can correspondingly can be early if bubble footpath forms larger in the case where so bubble footpath can be adjusted Depart from and early released in water in air, if opposite bubble footpath forms smaller, can correspondingly be kept for a long time in bath water The bubble regime of hydrogen.

Therefore, size adjustment is carried out to hydrogen bubble diameter by adjusting the flow velocity of the current from pumping section 20, can obtained Meet the hydrogen water using purpose of hydrogen water generating device.

Incidentally, receive the resistance produced by current in the state of bubble adheres on electrode plate, produced by the resistance Raw peeling force is peeled off when exceeding to the adhesive force of electrode plate, but by varying flow velocity, can be produced when bubble is small exceed it is attached The peeling force puted forth effort makes tiny bubble dissociate in water, or as time goes by bubble parameters and at the time of surface area becomes larger It is free that the peeling force produced more than adhesive force makes air duck in drink, and can freely adjust the bubble footpath of the hydrogen of releasing.

In addition, in the case where the flow velocity of current is fast, additionally it is possible to obtain between electrode plate of the current in relative configuration with When sawtooth state flows, in the bubble hydrogen that the plate face of minus plate generates, pass through what is produced in porous edge point (marginal portion) The function of injection of current, receives shearing force and miniaturization, the effect effectively dissolved in water.

In addition, in the top of multilayer electrode body 426, the substantially rectangular tabular that is formed by the insulator of resin etc. is equipped Electrode hood 427.The electrode hood 427, has and is mistakenly inserted trick via the missing discharge port 401a shown in (b) of Figure 16 in user Situation etc., carry out protection so that the effect of electrode is not directly contacted with, in addition, regularly being worn in the same manner as porous electrode plate more A hole 427a so that the releasing of the electrolyzed hydrogen water, bubble that are generated in multilayer electrode body 426 will not be hindered.

Particularly, the multiple hole 427a formed in the electrode hood 427, the position with the opposite mutual hole of porous electrode plate Relation similarly, is configured with the mutually different position relationship of the porous electrode plate 31 relative to topmost.

Therefore, as shown in (a) of Figure 20, in the case of no electrode hood 427, such as conductive small pieces 428 When dropping on multilayer electrode body 426, may contact it is short-circuit with the opposite two porous electrode plate of opposed polarity respectively, But possess electrode hood 427 as the hydrogen water generating device 400 of present embodiment, as shown in (b) of Figure 20, even if small pieces 428 contact porous electrode plates 31,427 no power of electrode hood of the opposing party and also without electric conductivity thus will not short circuit, can Ensure the security of higher.

In addition, the feature of the multilayer electrode body 426 as the hydrogen water generating device 400 of present embodiment, such as (b) of Figure 20 Enlarged drawing shown in, in charge concentration portion 432 of the periphery formed with tip shape of the bubble recirculation hole 431 of each porous electrode plate. In the enlarged drawing of (b) of Figure 20, charge concentration portion 432 for easy understanding structure and exaggerate and schematically illustrate, with it is each porous In the relation of the thickness of electrode plate etc., its size, quantity are not necessarily correct.

In the present embodiment, each porous electrode plate the surface of the substrate 433a of titanium formed with plating platinum layer 433b, but Implement punching processing in the titanium-base for so forming platinum plating and perforate, form the porous electrode plate with bubble recirculation hole 431.

Therefore, by the press machine for the titanium-base that platinum plating is penetrated through in the punching processing, in the bubble recirculation hole of formation 431 periphery forms the charge concentration portion 432 of edge shape.

Charge concentration portion 432 is in hydrogen water generating device 400 in use, can be depending on recognizing degree with user with generation Bubble footpath bubble hydrogen effect.

Originally, if electrolyzed hydrogen water of the electrolysis of water generation containing hydrogen in electrolytic bath, bubble hydrogen path is molten It is higher to solve efficiency, it is advantageous to.

But when being that the bubble of extremely path produces entirely as nano bubble, there are the following problems：Hydrogen water generating device The situation that 400 user can not produce depending on recognizing actual bubble, it is difficult to obtain the true feeling in electrolyzed hydrogen water balneation.

Then, in hydrogen water generating device 400, the charge concentration portion of tip shape is set in the periphery of bubble recirculation hole 431 432, electric charge is concentrated in the charge concentration portion 432 and partly promotes to be electrolysed, so as to generate hydrogen that can be with gonorrhoea shape depending on recognizing Bubble.

Through this structure, although the dissolubility of Xiang Shuizhong is higher, can generate can much be regarded by user The bubble hydrogen recognized, can play the performing effect of hydrogen generation and user is had the true feeling in electrolyzed hydrogen water balneation.

Charge concentration portion 432 is formed by being punched out processing to the titanium-base of platinum plating, but if possessing tip shape Charge concentration portion 432, then can will the titanium-base for implementing punching processing carry out platinum plating processing plate as each porous Electrode plate.But, if carrying out plating after perforation, with the marginal portion rust of tip shape formation, existing can be with gonorrhoea The situation that the formation efficiency of bubble hydrogen of the shape depending on recognizing declines, this needs to pay attention to.

In addition, in present embodiment, charge concentration portion 432 is formed by punching processing, but might not be defined to punching Processing, as long as forming the charge concentration portion 432 of tip shape, its forming method can be applicable in known all methods.

Therefore, in the enlarged drawing of such as (b) of Figure 20, only electricity is formed in the one side of the hole portion periphery of each porous electrode plate Lotus collection middle part 432, but charge concentration portion 432 can certainly be set in the two sides of hole portion periphery.

In the following, the electric structure of the hydrogen water generating device 400 of present embodiment is illustrated.Herein first, in order to easy Understand, refer to several feature functionalities that hydrogen water generating device 400 has.

As the function that should especially write out, hydrogen water generating device 400 have the function of to peel off difficult bubble dissociate, polarity it is anti- Rotating function, short circuit prevent function.

First, it is that the bubble for making the stripping produced in electrode surface difficult dissociates to peel off difficult bubble function of dissociating, and is multiplied Function of the current from missing discharge port 401a diffusions.

As described above, hydrogen water generating device 400, is produced towards the porous electrode for forming multilayer electrode body 426 by pumping section 20 Plate 31,32,33, the current of the plate face of 33-1,33-2, so that effectively being shelled in the bubble hydrogen that each porous electrode plate surface produces From and be diffused into bath.

However, in the present inventors are by the wholwe-hearted research that carries out all the year round, new discovery is in electrode plate surface, with generation Most of bubble hydrogens (hereinafter also referred to as peeling off easy bubble) mixing being easily peeled off, the hydrogen difficult from the stripping of electrode surface Bubble is produced with predetermined ratio.

It is most to peel off easy bubble, it is easily peeled off simultaneously from electrode surface by the current of the stabilization produced by pumping section 20 Diffusion, but the stripping difficulty bubble do not allowed by the flowing water of constant flow it is easily peelable.

Therefore, the stripping difficulty bubble produced as time goes by with certain proportion, as electrolysis time passes through, in electrode Surface gradually occupies more areas, becomes a reason of electrolytic efficiency reduction.

Then, in the hydrogen water generating device 400 of present embodiment, water is changed in electrolysis by control unit control pumping section 20 The flow of stream, gives the change of resistance to water-flow to the difficult bubble of stripping and promotes to peel off, and dissociates so as to fulfill difficult bubble is peeled off Function.

More specifically, in electrolysis, by control unit by pumping section 20 repeatedly switching control for produce current it is relatively long when Between working status and do not produce current relative short time halted state, make its carry out intermitten.

In this way, the stripping for including working status and halted state by being performed by control unit by pumping section in electrolysis follows Ring, so that when becoming working status again after halted state, will can before peel off difficult stripping difficulty bubble from electrode Sur-face peeling, it is ensured that to the effective area of electrolysis in each porous electrode plate surface, can realize the maintenance of electrolytic efficiency.

The presence for peeling off difficult bubble might not be entirely to hinder for hydrogen water generating device 400, exist from electricity After the sur-face peeling of pole, the bubble of extremely excellent effect is played.

The difficult bubble of stripping after free passes through to be once that easily peelable bubble is not allowed from electrode surface in electrode surface The bubble of attachment for a long time is crossed, so its bubble footpath, which is more than, peels off easy bubble.

Therefore, bigger buoyancy is obtained after dissociating in water, promptly reaches the water surface, the gas phase diffusion in bathroom.Should Hydrogen after diffusion is directly entered in vivo by the breathing of user via lung, except the effect of hydrogen water generated in bath, energy Enough expect more efficient redox reaction effect.

In addition, it is much so-called nano bubble to peel off easy bubble, and it is difficult by the visual bubble hydrogen of user, peel off difficult gas To steep bigger than the bubble footpath for peeling off easy bubble, institute makes it visually feel the generation of hydrogen so as to visually confirmed by user, Further promote the redox reaction effect based on hydrogen from spiritual side.

That is, it is also understood that in the hydrogen water generating device 400 of present embodiment, in order to be intended to collect and releasing base In the larger bubbles for peeling off difficult bubble, possess and strip cycles are repeated, regularly or aperiodically carry out pumping section 20 again The stripping difficulty bubble of work dissociates unit (peel off difficult bubble dissociate portion).

The working status of pumping section 20 and the time scale of halted state of strip cycles are formed, as long as opposite working status It is long and halted state is short, it is not particularly limited.In addition, the time of strip cycles a cycle is also not particularly limited.

If describing an example limited to understand structure, the time of strip cycles a cycle can be set to 30 Second~120 seconds, in addition, the distribution of the time of working status and halted state can be set to 57~59.5:3~0.5.In addition, more If restriction, the time of strip cycles a cycle is set to 30 seconds~120 seconds, preferably 45 seconds~90 seconds, and halted state Time be set to 0.5 second~3 seconds, during the residue that the time that halted state is subtracted from the time of strip cycles a cycle is obtained Between be set to the working time.

Polarity inversion function is the mineral composition for the calcium for preventing from dissolving in electrolysis of water etc., particularly in water The function of being sticked together using metal ion class existing for the state of cation in electrolysis as scale.

Particularly, in the hydrogen water generating device 400 of present embodiment, polarity is carried out by every strip cycles predetermined period Reversion.

Therefore, anode is switched to by per scheduled time as the porous electrode plate that cathode plays function, is played as anode The porous electrode plate of function is switched to cathode by per scheduled time, so the deposition of scale presses each porous electrode plate approximate equality, Moreover, the scale deposited on the porous electrode plate for being switched to anode be redissolved in water carry out scale removing, institute so as to The reduction of electrolytic efficiency caused by suppressing scale attachment.

Short circuit prevents that function from being the interelectrode short circuit for preventing the reversion with polarity, and protection carries out the switching of electrode Circuit etc. function.

As described above, multilayer electrode body 426 by keep certain intervals make multiple (five) porous electrode plates 31,32,33, 33-1,33-2 are oppositely disposed and form, and alternately apply positive and negative voltage by each porous electrode plate, so as to be electrolysed.

Here, be conceived to any pair opposite of porous electrode plate of positive and negative application in these each porous electrode plates, to In the case that the power supply of porous electrode plate stops, at first sight thinking the potential difference between porous electrode plate due to via in period Existing water is turned on and eliminated, but actually becomes the state that suitable potential difference is maintained between respective porous electrode plate, This becomes clear and definite by the research of the present inventors.

This is because the water for receiving electrolysis is also then with capacitance, this opinion if present between porous electrode plate The phenomenon newly known further is parsed by the present inventors.

If carrying out the switching of electrode in this state, the supply of electric power is carried out, then is likely to become real with short-circuit condition The identical state of matter, the circuit of switching to carrying out electrode etc., which is given, to be damaged.Particularly, it is real in the semiconductor element by FET etc. In the case of the circuit now switched, there is the problem of induced malfunction raising.

Then, in the hydrogen water generating device 400 of present embodiment, in the switching of polarity, stop first to each porous The power supply of electrode plate, is further supplied the fresh water for not receiving electrolysis, the water between each porous electrode plate by pumping section 20 Be replaced into the scheduled time of 0.3 second~2 seconds or so (hereinafter also referred to as current time swap) of fresh water carries out pole after The switching of property.

Through this structure, the capacitance between porous electrode plate can be reduced, in addition by the potential difference between porous electrode plate The degree that can be ignored is eliminated, substantive short-circuit condition during polarity switching can be prevented or be set to the journey that can be allowed Degree, suppresses the damage to the circuit of switching for carrying out electrode etc..

In addition, the switching timing of the polarity, is preferably after above-mentioned pumping section just works again for the viewpoint of protection circuit The few state of the difficult bubble of stripping.

This aspect, in hydrogen water generating device 400, the reversion of polarity is carried out by every strip cycles predetermined period, so The easily timing of metering switch polarity after strip cycles just start, can securely carry out the protection of circuit.Pumping section 20 it is firm There is a situation where that flow velocity is not substantially stabilized after just working again, so in polarity switching, in the electric power confession to each porous electrode plate Before stopping, it can setting standby until the flow speed stability of current turns to time of 0.3 second~2 seconds or so only (below The referred to as waterflow stabilization time).

In the following, based on the explanation of these functions, the electricity of the hydrogen water generating device 400 of present embodiment is tied with reference to Figure 21 Structure illustrates.In the hydrogen water generating device 400 of present embodiment, the working status time is set to 58 seconds as by strip cycles, 60 seconds of 2 seconds halted state time, the switching of polarity is carried out by every five cycles of strip cycles, and the waterflow stabilization time is set to 0.5 second, current time swap was set to 0.5 second, to terminate electric formal similarity automatically within about 15 minutes as strip cycles 15 times Illustrate, but not limited to this.

Figure 21 is the explanatory drawin for the electric structure for representing hydrogen water generating device 400.The control built on control charging substrate 18 Portion 440 processed, possesses CPU441, ROM442, RAM443, EEPROM444, RTC446 etc. as its structure, it is aquatic to be able to carry out hydrogen Into the required program of work of device 400.

Specifically, ROM442 is stored in program needed in the processing of CPU441 etc., and RAM443 is performing the program etc. Shi Zuowei temporary storage areas play function.

For example, in the presumptive area of ROM442, in addition to the program for being used for realization processing, store and be maintained pumping section 20 The value (58 seconds) of the time of working status, that is, working status time, the time i.e. halted state that pumping section 20 is maintained to halted state The value (2 seconds) of time, the value of waterflow stabilization time (0.5 second), the value (0.5 second) of current time swap, switching interval time Value (0.1 second), be powered open value (0.1 second) of stand-by time etc. again.Value in this paragraph brace is in present embodiment Setting value, can suitably be changed according to specification etc. certainly.

In addition, for example " the polarity inversion mark for the timing for making polarity inversion is indicated whether in the presumptive area of RAM443, storage Will ", " the polarity switching counter " that is counted to the periodicity of strip cycles for polarity switching, terminate pair to be electrolysed " circulation counter ", the long-press switch 15 in the work of hydrogen water generating device 400 that the periodicity of strip cycles is counted When interrupting electrolysis " interrupt identification " of reference etc..

In addition, EEPROM444, is stored in which stub when electrolysis is interrupted (in the present embodiment, is stored in for anode Which anode signal have issued in two kinds of anode signals described later), or the period of storage at this time.EEPROM444, as The non-transformer storage part of storage is kept to play function after power supply cut-out, when restarting by CPU441 references, according to interruption When polarity when restarting of polarity, period selection, also change the strip cycles number of execution.

The RTC (Real Time Clock, real-time clock) represented by mark 446 is to become for producing for after execution The clock pulses of the benchmark for the stopping processing stating.CPU441, it is every according to being pressed from RTC446 even in the state for being carrying out processing The clock pulses interrupt processing that predetermined period (such as 2 milliseconds) produces, performs stopping processing.

In control unit 440, Operation switch 15, LED16, pumping section 20, power supply unit 40, the first stub 34, second are connected with Stub 35, the execution state for the program being configured in control unit 440 is referenced, or control driving.

For example, control unit 440 sends pumping section working signal to pumping section 20.Pumping section 20 is configured to according to the pumping section working signal State action, when have sent state (open state) of pumping section working signal, pumping section 20 works, do not send state (close State) when, pumping section 20 stops.

In addition, possesses polarity switching circuit 445 in control unit 440.The polarity switching circuit 445, receives CPU441 and sends The first stub anode signal, the second stub anode signal, voltage apply signal, by the electric power from power supply unit 40 to the One stub 34 and the second stub 35 supply, or the positive and negative polarity of the first stub 34 of progress and the second stub 35 is cut Change.Specifically, the polarity switching circuit 445 of the first stub anode signal is have received, applies voltage and causes the first stub 34 be anode and the second stub 35 is cathode, when have received the second stub cathode signal, applying voltage and causing first to lead Body rod 34 is cathode and the second stub 35 is anode.In addition, the polarity switching circuit 445 that voltage applies signal is have received, root The power supply to each stub is carried out according to the anode signal of reception.

The processing for illustrating to perform in control unit 440 referring to Figure 22~Figure 26.Figure 22 is by the CPU441 of control unit 440 The main process task flow of execution, Figure 23~Figure 26 are the flows represented in the processing of each subprogram.

As shown in figure 22, in main process task, CPU441 (is pressed dynamic to whether Operation switch 15 start work first Make) judged (step S11).Here, (the step S11 in the case where being judged as that Operation switch 15 start work： It is no), CPU441 will be handled to be returned to step S11 again.On the other hand, it is being judged as that Operation switch 15 carried out the feelings for starting work (step S11 under condition：It is), processing is moved to step S12 by CPU441.

CPU441 is performed in step s 12 is handled when starting.In being handled in this startup, CPU441 reference EEPROM444, Carry out the reading of the species and electrode switching count value of the anode signal sent at the end of last time.Here, the end of last time It is not caused by interruption, it is also assumed that terminated with have sent the state of the second stub anode signal, in being handled in this startup, CPU441 determines to send the first stub anode signal.In addition, in being handled in this startup, the various countings of RAM443 are carried out The replacement of value, the value of mark.In the case of interrupt identification is stored when CPU441 is with reference to EEPROM444 as open state, CPU441, In being handled in this startup, the electrode switching read in from EEPROM444 is carried out with presumptive address of the count value on RAM443 Write-in, determines to send out the anode signal for the species read in.

Then, CPU441 pumps driving processing in step s 13, when carrying out first.When this is first pump driving processing, for for Formed before electrolysis starts (for example, before 1~3 second of the energization start to process being described below in advance) between porous electrode plate The processing of current, sends pumping section working signal, pumping section 20 is become working status.

Then, CPU441 performs energization start to process in step S14.In energization start to process, CPU441 is to polarity The anode signal for the species that processing determines and voltage apply signal during the starting of 445 forwarding step S12 of switching circuit, so that the Between one stub 34 and the second stub 35, i.e., voltage is applied with predetermined polarity between each porous electrode plate.

Then, CPU441 performs pump driving processing, and starts timing (step S15).In this pump driving processing, CPU441 sends pumping section working signal to pumping section 20, and pumping section 20 is set to working status.Pumping section work has been sent out in step s 13 In the case of making signal, the persistently submitting of pumping section working signal like this.

Then, whether CPU441 is to drive row into polarity inversion mark in step s 16 with reference to the presumptive address of RAM443 Judge.Here, (the S16 in the case where being judged as that polarity inversion mark is not out：It is no), processing is moved to step S19 by CPU441. On the other hand, (S16 in the case of being judged as polarity inversion mark to open：It is), processing is moved to step S17 by CPU441.

In step S17, CPU441 carries out polarity inversion processing.Polarity inversion processing is to switch in the first stub 34 With the second stub 35 apply voltage polarity processing, behind illustrated with reference to Figure 25.

Then, the value of the polarity inversion mark stored in the presumptive address of RAM443 is set to off (step S18) by CPU441, Processing is moved into step S19.

In step S19, CPU441, with reference to the timer for starting timing in step S15, to working status time (this It is 58 seconds in embodiment) whether by being judged.Here, (the step in the case where being judged as without the working status time Rapid S19：It is no), CPU441 returns process to step S19.On the other hand, it is being judged as have passed through the situation of working status time Under (step S19：It is), processing is moved to step S20 by CPU441.

In step S20, the electrode switching counter stored in the presumptive address of RAM443 is added 1 by CPU441, and Circulation counter is added 1.

Then, whether CPU441 is 15 to be judged (step to the value for circulating counter with reference to the presumptive address of RAM443 Rapid S21).Here, (step S21 in the case of being 15 in the value for being judged as circulating counter：It is), CPU441 is performed at end Manage (step S22), terminate a series of program execution (or back to main program processing beginning.).On the other hand, sentencing The value to circulate counter of breaking is not (step S21 in the case of 15：It is no), CPU441 performs pump stopping processing (step S23), Processing is again returned into step S15.For step S22 end processing and step S23 pump stopping handle, behind reference Figure 24 and Figure 26 are illustrated.

In the following, stopping processing being illustrated with reference to Figure 23.During even if CPU441 presence is carrying out in the state of processing Disconnected processing performs the situation for stopping processing.According to the clock pulses produced from RTC446 by often predetermined cycle (such as 2 milliseconds), Perform following stopping processing.

In stopping processing, whether CPU441 is that long-press state is judged (step S31) to Operation switch 15.Exist herein It is not (step S31 in the case of long-press state to be judged as Operation switch 15：It is no), CPU441 returns process to the ground before branch Location.On the other hand, be judged as Operation switch 15 be long-press state in the case of (step S31：It is), CPU441 moves to processing Step 32.

In step S32, CPU441 is with reference to the presumptive address of RAM443, the write-in being set to out into the value for being about to interrupt identification.

Then, CPU441, performs end processing (aftermentioned) in step S33, referring again to the presumptive address of RAM443, into It is about to the write-in that the value of interrupt identification is set to off, terminates execution (or the beginning back to main process task of a series of program.).

In the following, with reference to Figure 24, the pump stopping processing being performed in the step S23 of main process task is illustrated.

In pump stopping processing, CPU441 carries out pumping section 20 by stopping the submitting to the pumping section working signal of pumping section 20 Stopping (step S41).

Then, CPU441, to stopping whether have passed through the halted state time (in this implementation from the submitting of pumping section working signal It is 2 seconds in mode) judged (step S42).Here, (the step in the case where being judged as without the halted state time S42：It is no), processing is again returned to step S42 by CPU441.On the other hand, it is being judged as have passed through the feelings of halted state time (step S42 under condition：It is), for CPU441 with reference to the presumptive address of RAM443, whether the value for carrying out electrode switching timer is 5 Judge (step S43).

Here, (the step S43 in the case where the value for being judged as electrode switching counter is 5：It is), with reference to RAM443's Presumptive address, the value of polarity inversion mark is set to out, and resets the value (step S44) of polarity switching count value, will be handled Back to the address before branch.On the other hand, the value for being judged as electrode switching counter in step S43 is not 5 situation Under (step S43：It is no), CPU441 returns process to the address before branch.

The polarity inversion processing performed in the step S17 of main process task is illustrated referring to Figure 25.

In polarity inversion processing, CPU441 is steady to whether have passed through current at the time of timing in step S15 Surely the change time, (being 0.5 second in present embodiment) was judged (step S51).Here, it is being judged as without waterflow stabilization (step S51 in the case of time：It is no), CPU441 returns process to step S51.On the other hand, it is being judged as have passed through water Stream stabilizes (step S51 in the case of the time：It is), processing is moved to step S52 by CPU441.

In step S52, CPU441 stops applying the voltage of polarity switching circuit 445 submitting of signal, is powered Stopping processing (step S52).

Then, CPU441, to whether have passed through waterflow stabilization time and current time swap (this implementation since timing Be 0.5 second in mode) time (being 1 second in present embodiment) of sum judged.Herein being judged as without above-mentioned and Time in the case of (step S53：It is no), CPU441 returns process to step S53.On the other hand, it is being judged as have passed through (step S53 in the case of the time of sum：It is), CPU441 stops the anode signal (step S54) sent out.

Then, whether CPU441 since timing to have passed through between waterflow stabilization time and current time swap and switching Judged (step S55) every the time of the sum of time (being 0.1 second in present embodiment).It is being judged as herein without above-mentioned (step S55 in the case of the time of sum：It is no), CPU441 will be handled and be moved to step S55 herein.On the other hand, be judged as through (step S55 in the case of the time for having crossed sum：It is), CPU441 starts the other species of anode signal sent out and sent out before Anode signal, i.e., the anode signal sent out before then start sending for the second stub anode signal for the first stub anode signal Go out, the anode signal sent out before then starts the submitting (step of the first stub anode signal for the second stub anode signal S56), processing is moved into step S57.

In step S57, whether CPU441 since timing to have passed through waterflow stabilization time and current time swap Judged with the time of switching interval time and the sum for opening stand-by time (being in the present embodiment 0.1 second) again that is powered. This (step S57 in the case where being judged as the time without above-mentioned sum：It is no), CPU441 will be handled returns to step herein S57.On the other hand, (the step S57 in the case where being judged as have passed through the time of sum：It is), processing is moved to step by CPU441 S58。

In step S58, CPU441 sends out voltage to polarity switching circuit 445 and applies signal, so that what is be powered opens Beginning is handled, and will handle the address before being back to branch.

In the following, with reference to Figure 26 to handling and carrying out in the step S22 of main process task, the end for the step S33 execution for stopping processing Explanation.

In end processing, for CPU441 with reference to the presumptive address of RAM443, whether the value to interrupt identification is to drive row into sentence Disconnected (step S61).(step S61 in the case of herein being judged as interrupt identification to open：It is), CPU441 stops to polarity switching The voltage that circuit 445 is sent out applies signal, and after having carried out the processing (step S62) that stopping is powered, processing is moved to step S66.On the other hand, (the step S61 in the case where being judged as that interrupt identification is not out：It is no), processing is moved to step by CPU441 S63。

In step S63, CPU441 to before whether being off 0.1 second of the time, i.e., whether make in the present embodiment from Start to be judged at the time of timing rises 59.9 seconds.(the step in the case where being judged as not being off before 0.1 second of time herein S63：It is no), processing is returned again to step S63 by CPU441.On the other hand, before being judged as YES 0.1 second of dwell time In the case of (step S63：It is), processing is moved to step S64 by CPU441.

In step S64, CPU441 stops applying signal to the voltage that polarity switching circuit 445 is sent out, and stop logical The processing of electricity.

Then, whether CPU441 is to being off the time and being judged (step S65).It is being judged as not being off the time herein In the case of (step S65：It is no), processing is again returned to step S65 by CPU441.On the other hand, when being judged as YES stopping Between in the case of (step S65：It is), processing is moved to step S66 by CPU441.

In step S66, CPU441 stops the anode signal being sent out to polarity switching circuit 445 and to the submitting of pumping section 20 Pumping section working signal.

Then, the species for the anode signal that CPU441 is transmitted in the presumptive address of EEPROM444, electrode toggle count The write-in (step S67) of the value of device, the value of interrupt identification etc., will handle the address before being back to branch.

The action for possessing the hydrogen water generating device 400 of said structure is illustrated referring to Figure 27 and Figure 28.Figure 27 It is the state of various signals for representing to be transmitted by the Operation switch 15 and control unit 440 (CPU441) of hydrogen water generating device 400 Timing diagram, Figure 28 are the timing diagrams that the portion of time shown in enlarged drawing 27 represents.

As shown in figure 27, hydrogen water generating device 400, presses action as opportunity with the Operation switch 15 of user, passes through Perform various processing within (about 900 seconds) about 15 minutes, and be electrolysed the generation that electrolysis of water carries out hydrogen.

In addition, hydrogen water generating device 400, by the working status time (ETAD expected time of arrival and departure) including pumping section working signal and stops shape The a cycle of the strip cycles of state time (closing the time) regards illusory Action clock signal as benchmark, performs various places Reason.For example, the switching for being set to the polarity of each porous electrode plate (each stub) was pressed per i.e. often about 5 minutes five cycles of strip cycles Perform, electrolysis processing is about 15 minutes structures terminated automatically with 15 cycles of strip cycles.

In the following, illustrated with reference to various signals etc. by action of each main matter to hydrogen water generating device 400.

The left enlarged drawing of Figure 28 represents the timing diagram in the startup of hydrogen water generating device 400, and middle enlarged drawing represents will pump Portion 20 is set to timing diagram during halted state, and right enlarged drawing represents timing diagram during polarity switching action.

It was found from the left enlarged drawing of Figure 28, when by user's push switch 15, control unit 440 pumps when performing first Driving handles (step S13), so as to start the generation of current before being electrolysed about 2 seconds.

Then, control unit 440, by handle on startup (step S12) determine transmit anode signal, first is led herein Body rod anode signal is sent together with by the execution of energization start to process (step S14) applying signal with voltage, is started to the One stub 34 is anode and each porous electrode plate supply electric power with the second stub 35 for cathode.In addition, start by step The timing that S15 is carried out.

Then, control unit 440, as shown in the middle enlarged drawing of Figure 28, are being judged as have passed through working status from beginning timing (step S19 during time (58 seconds)：It is), pump stopping processing (step S41) is performed, stops the transmission of pumping section working signal, is stopped The work of pumping section 20.

After the halted state lasts about 2 seconds, control unit 440 is by performing pump driving processing (step S15), again by pumping section 20 are set to working status.

Here, the timing to work again of the pumping section 20 in figure shown in black arrow, peel off difficult bubble from porous The stripping of electrode plate surface.That is, control unit 440, as by performing the stopping of the pumping section 20 in work and work again as described above The processing of work, makes the stripping difficulty bubble that the difficult bubble of stripping in porous electrode plate apposition growth the dissociates unit that dissociates (peel off Difficult bubble dissociates portion) play function.

Then, about 300 seconds shown in Figure 27 are then being judged as from step S15 nearby with reference to the right enlarged drawing of Figure 28 Timing has begun to pass through the working status time (58 seconds：Here, four cycle of strip cycles i.e.+58 seconds 240 seconds=298 seconds) when (step Rapid S19：It is), then pump stopping processing (step S41) is performed, stops the transmission of pumping section working signal, stops the work of pumping section 20.

" 5 " are changed into by the execution of step S20 with the value of counter in the electrode switching of RAM443 storages herein, are stopped in pump Polarity inversion mark is changed into out (step S44) in only handling, and into the strip cycles of period 6, is become by step S15 pumping section 20 After being in working condition, polarity inversion processing (step S17) is carried out.That is, polarity inversion processing is configured in the work of pumping section 20 Carry out.

Therefore, it is possible to avoid origin between porous electrode plate the existing water being electrolysed there is capacitance to cause polarity to be cut The temporary short circuit state between porous electrode plate when changing, can save the circuit carried out to the power supply of porous electrode plate, switching etc. from damage.

In addition, the reversion processing of polarity is configured to after the working again of pumping section 20, standby waterflow stabilization time (0.5 second) Performed with after the amount of current time swap (0.5 second), institute is so as to more securely avoid short-circuit condition.

The variation of (5) the 4th embodiments：

The variation of the hydrogen water generating device 400 of above-mentioned 4th embodiment is said referring to Figure 29 and Figure 30 It is bright.

The hydrogen water generating device of this variation has the structure substantially same with hydrogen water generating device 400, but aquatic with hydrogen Compared into device 400, have and be used to improve in balancing gate pit 13b (in electrolysis portion accommodating recess 424), form multilayer electrode body 426 31~33-2 of porous electrode plate between water flowing structure this aspect it is different.

Specifically, as this variation hydrogen water generating device characteristic point, enumerate in the electrolysis portion of upper shell 410a The bottom surface of accommodating recess 424 erects current restriction plate, (is in present embodiment in the porous electrode plate opposite with opening portion 425 Porous electrode plate 33-2) form aporate area, be configured with occlusion in the part of the bubble recirculation hole for being arranged in porous electrode plate Piece.

Figure 29 generates main part 410 on the hydrogen water of the hydrogen water generating device of this variation, and electrolysis portion 30 has been decomposed in expression State stereogram.For convenience of explanation, to the part-structure illustration omitted of the grade of electrode hood 427.

As shown in figure below of Figure 29, housed in the electrolysis portion for being formed at the top view substantially rectangular shape of upper shell 410a recessed The bottom surface 510 in portion 424, be equipped with L-shaped current restriction plate 511, the second current restriction plate 512, the 3rd current restriction plate 513 and 4th current restriction plate 514.

As shown in (a) of Figure 30, the bottom surface 510 of accommodating recess 424 in electrolysis portion, by by the electrolysis portion of substantially rectangular shape The auxiliary line y1 zonings that the auxiliary line x1 that the long side direction of accommodating recess 424 is halved halves short side direction in the same manner as The substantial middle position of top left region, i.e., in long side direction and the position of short side direction bias on bottom surface 510, form opening portion 425.In the following description, in a pair of long side wall for forming rectangular-shaped electrolysis portion accommodating recess 424, it will be close to opening portion 425 long side wall is known as the long side wall 530n of peri position, remote long side wall is known as the long side wall 530f of amphi position, in same a pair of short edges wall In, the short side wall that will be close to opening portion 425 is known as peri position short side wall 531n, and remote short side wall is known as amphi position short side wall 531f.

515 He of the first current restriction plate that L-shaped current restriction plate 511 is configured by passing through length P1 in auxiliary line y1 extensions The 5th current restriction plate 516 extended from the end of the first current restriction plate 515 with L-shaped is formed.

First current restriction plate 515 be for limiting the current near opening portion 425 and arranging the component of flowing, with The position intersected to the auxiliary line x2 of the short side direction of crosscutting opening portion 425, such as the extension side with the first current restriction plate 515 The mode being located to midpoint on auxiliary line x2 or near it erects.In addition, length of the length P1 relative to electrolysis portion accommodating recess 424 The long P on side, is configured to P/3 ＜ P1≤P/4.5, is more preferably configured to substantially P/4.

5th current restriction plate 516 is from amphi position short side wall 531f sides in the both ends of the first current restriction plate 515 The current restriction plate that end is extended to the long side wall 530f of amphi position with L-shaped, there is limitation to be sprayed and short from peri position by opening portion 425 Flowings of the side wall 531n along the long side wall 530f of amphi position.In present embodiment, the 5th current restriction plate 516, is configured to one end Be connected with the first current restriction plate 515, the other end be connected with the long side wall 530f of amphi position, but with the first current restriction plate 515 Between gap somewhat can be set between the long side wall 530f of amphi position.As long as that is, by the first current restriction plate 515, (hereinafter referred to as the 3rd vortex in the region that the long side wall 530f of 5th current restriction plate 516, amphi position and peri position short side wall 531n is surrounded Forming region) degree of aftermentioned vortex can be formed, above-mentioned gap can be formed.

Second current restriction plate 512 is to be configured to by substantially four points of the long M's of short side direction of electrolysis portion accommodating recess 424 In each auxiliary line y2, auxiliary line y1, auxiliary line y3, extend on the auxiliary line y2 near the long side wall 530n of peri position through long P2 Current restriction plate.Long P2 is configured to P/3 ＜ P2≤P/4.5 relative to the long P of the long side direction of electrolysis portion accommodating recess 424, More preferably it is configured to substantially P/4.

3rd current restriction plate 513, in the same manner as the second current restriction plate 512, is configured near the long side wall of amphi position The current restriction plate extended on the auxiliary line y3 of 530f through long P3.Long P3 relative to electrolysis portion accommodating recess 424 long side side To long P, be configured to P/3 ＜ P3≤P/4.5, be more preferably configured to substantially P/4.

These the second current restriction plates 512 and the 3rd current restriction plate 513 are all for arranging electrolysis portion accommodating recess 424 Substantially central portion current component, configure in the position intersected with auxiliary line x1, such as the second current restriction plate 512, The extending direction midpoint of three current restriction plates 513 is located on auxiliary line x1 or near it.

4th current restriction plate 514 is for limiting the current from the remote position in opening portion 425 and arranging flowing water Ductility limit making sheet, is configured on auxiliary line y1 extend through long P4.Long P4 relative to electrolysis portion accommodating recess 424 long side direction Long P, be configured to P/3 ＜ P4≤P/4.5, be more preferably configured to substantially P/4.

In addition, the 4th current restriction plate 514 is configured with the long P tetra- of the long side direction of electrolysis portion accommodating recess 424 is divided When near the position that the auxiliary line x3 of amphi position short side wall 531f intersects, such as in the extending direction of the 4th current restriction plate 514 Point is on auxiliary line x3 or near it.

In addition, the first current restriction plate 515, the second current restriction plate 512, the 3rd current restriction plate 513, the 4th current limit Making sheet 514 configures at predetermined spaced intervals in long side direction respectively.

Specifically, the first current restriction plate 515 interval d1 between peri position short side wall 531n is configured, and the Two current restriction plates 512 between the first current restriction plate 515 interval d2a configure, the 3rd current restriction plate 513 with Between first current restriction plate 515 interval d2b configure, the 4th current restriction plate 514 with the second current restriction plate 512 and Interval d3a is spaced one between 3rd current restriction plate 513 and is spaced d3b, the interval between amphi position short side wall 531f D4 is configured.

These intervals d1~d4, as long as to be shorter than the length of long P1~P4, is not particularly limited.Received for above-mentioned electrolysis portion Hold the long P, P=d1+P1+d2a+P2+d3a+P4+d4 (P=d1+P1+d2b+P3+d3b+P4+d4) of the long side direction of recess 424 Set up.

In addition, the first current restriction plate 515 erected on bottom surface 510, the second current restriction plate 512, the 3rd current limit Making sheet 513, the 4th current restriction plate 514, the height of the 5th current restriction plate 516, if it is possible to form vortex described later, then do not have It is particularly limited to, but can be set to form the undermost porous electrode plate of multilayer electrode body 426 (in the present embodiment to be more Pore electrod plate 33-2) and the distance between bottom surface 510 i.e. 0.5 times~1 times of the height of balancing gate pit 13b.

On the other hand, as shown in figure 29, in the 31~33-2 of porous electrode plate for forming multilayer electrode body 426, most lower The porous electrode plate 33-2 of layer, in the position opposite with opening portion 425, formed with the imperforate section for not forming bubble recirculation hole 431 Domain 517 (is represented by dotted lines) in figure.

Particularly, in this variation, by implementing punching processing of interlocking to the titanium-base of platinum plating, more specifically with 45 ° staggeredly or 60 ° staggeredly implement punching processings, bubble recirculation hole 431 is regularly formed, in the bubble opposite with opening portion 425 Recirculation hole 431, aporate area 517 is formed by the occlusion piece 518 for installing the inaccessible bubble recirculation hole 431.The aporate area 517 Be not limited by occlusion formation bubble recirculation hole 431 formed situation, can by the position opposite with opening portion 425 not Wear bubble recirculation hole 431 and form aporate area 517.

In addition, in the porous electrode plate 32 and porous electrode plate 33-1 of this variation, regularly worn with staggered The bubble recirculation hole 431 of a part in bubble recirculation hole 431, is installed and configured the occlusion piece of the inaccessible bubble recirculation hole 431 518。

In this way, the hydrogen water generating device of this variation, has following (1), the feature of (2) for succinct.

(1) in undermost porous electrode plate in the position opposite with opening portion 425 formed with aporate area 517.

(2) long side direction and short side in the bottom surface 510 of the electrolysis portion accommodating recess 424 of top view substantially rectangular shape The position of direction bias forms opening portion 425, in the bottom surface 510 and in the electrolysis portion 30 that electrolysis portion accommodating recess 424 is installed Between the lower space (balancing gate pit) that is formed possess from bottom surface 510 erect the long side direction with the long side direction substantially First~the 4th current restriction plate of 1/3~1/4.5 length extension, the first current restriction plate 515 are configured in the crosscutting opening The short side direction substantially central portion in portion 425, the second current restriction plate 512 and the 3rd current restriction plate 513 configure short at four points Substantially the 1/4 of edge direction configures in short side direction substantially central portion with substantially 3/4 position, the 4th current restriction plate 514, and And near the end or end of the first current restriction plate 515, until from the remote long side wall, that is, amphi position long side in opening portion 425 Wall 530f or its near, the 5th current restriction plate 516 is erected with substantially L-shaped.

Moreover, in the hydrogen water generating device of this variation, by possessing the structure of (1), can make in porous electrode The speed of the current of horizontal direction (propagation direction in space) in the space formed between plate 33-1 and porous electrode plate 33-2 The approximate homogenization of vector.

That is, aporate area 517 is being not provided with, the position opposite with opening portion 425 on porous electrode plate 33-2 is worn In the case of bubble recirculation hole 431, the current sprayed from opening portion 425 to balancing gate pit 13b are just directly via bubble recirculation hole 431 Into the space formed between porous electrode plate 33-1 and porous electrode plate 33-2, with porous electrode plate 33-1 collisions to water Flat Directional Extension, so forming bias in flowing.

On the other hand, aporate area 517 is set by such as this variation, prevents that the water spray from opening portion 425 from flowing directly into The space formed between porous electrode plate 33-1 and porous electrode plate 33-2, and make the flowing once in balancing gate pit 13b Buffering, suppresses the bias of the flowing in the space that is formed between porous electrode plate 33-1 and porous electrode plate 33-2, can make The approximate homogenization of the velocity of current in the space.

In addition, in the hydrogen water generating device of this variation, can be positive in balancing gate pit 13b by possessing the structure of (2) Ground forms vortex, can realize the homogenization of the current towards multilayer electrode body 426.

Herein with reference to Figure 30 (b) to vortex formation explanation, first, from the current F3 in the water spray of opening portion 425 by First current restriction plate 515 shunts, and is split into current F1 from opening portion 425 towards amphi position short side wall 531f directions and towards near The current F2 in position short side wall 531n directions.

Current F1 is shunted by the second current restriction plate 512 and the 3rd current restriction plate 513, is split into respectively in peri position long side Flowing water stream F1a between wall 530n and the second current restriction plate 512, limit in the second current restriction plate 512 and the 3rd current Flowing water stream F1b, the flowing water stream F1c between the 3rd current restriction plate 513 and the long side wall 530f of amphi position between plate 513.

In addition, current F1b is further split into towards the 4th current restriction plate 514 and near by the 4th current restriction plate 514 The current F1b1 and the 4th current of direction in the region (hereinafter referred to as the first vortex forming region) between bit length side wall 530n are limited The current F1b2 in the region (hereinafter referred to as the second vortex forming region) between plate 514 and the long side wall 530f of amphi position.

Moreover, in the first vortex forming region, current F1a and current F1b1 interflow are collided, and form mixed and disorderly flowing, from And form vortex.

In addition, in the second vortex forming region, current F1b2 and current F1c interflow are collided, and form mixed and disorderly flowing, This also forms vortex.Vortex shown in (b) of Figure 30 only is illustrated diagrammatically only by forming vortex, its size, quantity, shape, winding Direction is not necessarily correct.

In addition, when current F2 meets peri position short side wall 531n, along peri position short side wall 531n towards the long side wall of amphi position 530f flows, and then starts to flow along the long side wall 530f of amphi position.

Start flowing water stream F2 in the 5th current restriction plate along the long side wall 530f of the amphi position to amphi position short side wall 531f 516 collide.That is, it is segmented by the 5th current restriction plate 516 along the current F2 of the long side wall 530f of amphi position, is limited to along the 5th current The direction of making sheet 516 changes direction, further becomes the current along the first current restriction plate 515, and area is formed in the 3rd vortex Domain is mutually worked with the current F2 newly flowed into, forms the flowing of complexity, forms vortex.

In this way, in the hydrogen water generating device of this variation, each current restriction plate is as rectification unit (rectification part), zoning list First (zoning portion), dividing cell (distributary division), vortex form unit (vortex forming portion) and play function, and lead in balancing gate pit 13b The presence for crossing each current restriction plate energetically forms multiple vortexs, realizes the homogenization of the current towards multilayer electrode body 426.

Moreover, according to the hydrogen water generating device with said structure, in long side direction and the bottom surface 510 of short side direction bias On position set opening portion 425 in the case of, also can approximately uniformly be released comprising bubble hydrogen from the top in electrolysis portion 30 Current.

In addition, include can be in the case of the current depending on the bubble hydrogen recognized, as possessing by user releasing Structure, compared to being compared depending on the bubble hydrogen recognized with the situation that the state biased is released, can make user entertain hydrogen and bathing The impression generally spread in groove, the redox reaction effect brought from psychological side promotion bubble hydrogen, hydrogen water.

(5) summarize：

Each embodiment from the description above, can realize a kind of hydrogen water generating device, possess：With water flowing road 313 Housing 10, which can be impregnated in water, the inflow entrance 11 of water is connected with flow export 12；Pumping section 20, it is housed In housing 10, water flowing road 313 is set to produce current；Electrolysis portion 30, it is disposed in water flowing road 313；With power supply unit 40, it is contained in shell Body 10, powers to institute's pumping section 20 and electrolysis portion 30, and electrolysis portion 30 has the multiple porous electrode plates 31 for keeping certain intervals to arrange ~33, pumping section 20 produces the current of the plate face towards the porous electrode plate 31~33.

The hydrogen water generating device so formed, dipping in water, by pumping section 20 housing 10 inflow entrance 11 and flow export Water flowing road 313 between 12 produces current, and the water to circulate on water flowing road 313 is electrolysed by the electrolysis portion 30 arranged on water flowing road 313. At this time, pumping section 20 produces the water of the plate face towards the porous electrode plate 31~33 for keeping certain intervals to arrange for forming electrolysis portion 30 Stream.In this way, the pressure by applying current in the plate face of porous electrode plate 31~33, having will be in 31~33 table of porous electrode plate The mode that the electrolytic hydrogen in face, the bubble of oxygen are pushed open in the moment of electrolysis is drawn into the effect in current, is generated from hydrogen water The bubble microvesicle of hydrogen that the water of the flow export outflow of device includes, or can also expect molecular level hydrogen, nano bubble, micro- Hydrogen dissolving under blister state.

In addition, porous electrode plate 231~233, the zoning between the bubble recirculation hole of zoning porous electrode plate 231~233 Line W becomes the section polygon shape in the corner with the tip for becoming the current produced towards pumping section 20.

In the hydrogen water generating device so formed, between the bubble recirculation hole of porous electrode plate 231~233, zoning Line W has the inclined plane for opening the bubble recirculation hole frame of the current that pumping section 20 produces towards both sides, so porous electrode plate 231~ Improved from bubble property on 233 surface.In addition, the face between the bubble recirculation hole of porous electrode plate 231~233, clamping corner is made Formed for other face, thus the bubble produced in the face of a side not with the bubble zoarium produced in the face of the opposing party, from porous electrode The bubble more microvesicle that plate 231~233 departs from, additionally it is possible to expect that the hydrogen under molecular level hydrogen, nano bubble, microvesicle state is molten Solution.In addition, the porous electrode plate 231~233 between bubble recirculation hole has towards the corner of current, so that in porous electrode plate The current of 231~233 bubble recirculation hole circulation are smooth, until in the gas from the farthest porous electrode plate 231~233 of pumping section 20 The flow of water is able to maintain that untill bubble recirculation hole circulation.In addition, corner surface tension force is small, so the porous electrode directly contacted in current The bubble that corner between the bubble recirculation hole of plate 231~233 produces is improved from bubble property.

In addition, bubble recirculation hole 31a~33a of multiple porous electrode plates 31~33 between adjacent porous electrode plate with Substantially mutually different position relationship is set.

In the hydrogen water generating device so formed, in the bubble recirculation hole that multiple porous electrode plates 31~33 are formed respectively The position of 31a~33a is differently from each other formed, so the current passed through in bubble recirculation hole 31a~33a are until porous electrode plate Between corner untill circulate along porous electrode plate, improve in the surface entirety of porous electrode plate from bubble property, and more The displacement efficiency of water is improved between a porous electrode plate.

The invention is not restricted to the above embodiment, also comprising will disclosed each structure phase double replacement in the above-described embodiment Or structure, by common knowledge and in the above-described embodiment disclosed each structure phase double replacement or change combination after change combination Structure afterwards etc..In addition, the present invention technical scope be not limited to the above embodiment, be related to claim record item and Its equipollent.

For example, in the above-described embodiment, power supply unit 40 is configured to electric power storage, but not limited to this, can be by power supply unit 40 are configured to be connected to source power supply lamp and obtain electric power from outside.

Description of symbols

10 housings, 10a upper shells, 10b lower housing shells, 10c guard blocks, 10c1 base portions, 10c2 ribs, 10c3 openings, 10c4 Opening, 11 inflow entrances, 12 flow exports, 13 water flowing roads, 13a through holes, 13b balancing gate pits, 14 filters, 15 Operation switches, 16 are shone Bright confirming operation LED, 17 charging terminals, 18 charging substrates, 20 pumping section, 21 inside water flowing roads, 30 electrolysis portions, 31 porous electrodes Plate, 31~33 porous electrode plates, 31a~33a bubbles recirculation hole, 32 porous electrode plates, 33 porous electrode plates, 34 stubs, 35 Stub, 40 power supply units, 50 control units, 100 hydrogen water generating devices, 231~233 porous electrode plates, 231a~233a bubble streams Through hole, 232 porous electrode plates, 233 porous electrode plates, 313 water flowing roads, 313b balancing gate pits, 313c tubulars water route, 313d undergauges Portion, 313e wide diameter portions, 313f1~313f4 commutator segments, charge concentration portion 432, control unit 440, H1 tops, H2 tops, H3 tops Portion, H4 tops, the first diagonal of L1, the second diagonal of L2, W rides, X connecting portions.

Claims (11)

1. a kind of hydrogen water generating device, it is characterised in that possess：

Water flowing road, it can be impregnated in water, and the inflow entrance of water is connected with flow export；

Pumping section, it makes the water flowing road produce current；

Electrolysis portion, it is disposed in the water flowing road；And

Power supply unit, it powers to the pumping section and the electrolysis portion,

The electrolysis portion has the multiple porous electrode plates for keeping certain intervals to arrange,

The pumping section produces the current of the plate face towards the porous electrode plate.

2. hydrogen water generating device according to claim 1, it is characterised in that

Possesses control unit, which makes the polarity of the porous electrode plate be inverted by per scheduled time in electrolysis.

3. hydrogen water generating device according to claim 2, it is characterised in that

The control unit, carries out the reversion of the polarity in the work of the pumping section.

4. hydrogen water generating device according to any one of claim 1-3, it is characterised in that

Possesses control unit, which controls the pumping section in electrolysis and change the flow of the current.

5. hydrogen water generating device according to claim 4, it is characterised in that

Possess with lower unit, i.e.,：By the way that by the pumping section, switching control is the relatively long of generation current repeatedly in electrolysis Working status and do not produce current relative short time halted state control unit, make under the working status of the pumping section In the unit that the difficult bubble of stripping of porous electrode plate attachment generation dissociates.

6. the hydrogen water generating device according to any one of claim 1-5, it is characterised in that

It is being formed at charge concentration portion of the periphery of the bubble recirculation hole of the porous electrode plate formed with tip shape.

7. the hydrogen water generating device according to any one of claim 1-6, it is characterised in that

In the porous electrode plate, zoning portion between the bubble recirculation hole of the porous electrode plate is divided as with as towards institute State the section polygon shape in the corner at the tip of current.

8. the hydrogen water generating device according to any one of claim 1-7, it is characterised in that

The bubble recirculation hole of multiple porous electrode plates, is substantially differently from each other set with adjacent porous electrode plate.

9. the hydrogen water generating device according to any one of claim 1-8, it is characterised in that

Be configured to by the gap of the multiple porous electrode plate to by it is described pump spray water stream S so that will be porous The hydrogen of electrode plate generation is dissolved in current under elevated pressure.

10. the hydrogen water generating device according to any one of claim 1-9, it is characterised in that

The electrode hood that there is insulating properties on the top of porous electrode plate is configured with the electrolysis portion, following position is provided with gas Recirculation hole is steeped, i.e.,：The position substantially mutually different with the bubble recirculation hole in the porous electrode plate formation opposite with the electrode hood.

11. the hydrogen water generating device according to any one of claim 1-10, it is characterised in that

Possesses luminescence unit, which projects light to the direction that the current with being flowed out from the flow export intersect.