CN108017883A - A kind of anti-static oil-resistant instrument cable - Google Patents

A kind of anti-static oil-resistant instrument cable Download PDF

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Publication number
CN108017883A
CN108017883A CN201711356459.5A CN201711356459A CN108017883A CN 108017883 A CN108017883 A CN 108017883A CN 201711356459 A CN201711356459 A CN 201711356459A CN 108017883 A CN108017883 A CN 108017883A
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parts
oil
rubber
mass fraction
temperature
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刘浩
张君
张欢芬
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Suzhou Hao Yan Precision Mold Ltd Co
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Suzhou Hao Yan Precision Mold Ltd Co
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/04Antistatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/04Thermoplastic elastomer

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention provides a kind of anti-static oil-resistant instrument cable, including core and protection pipe, the core is arranged in protection pipe, it is characterised in that the protection pipe includes following components according to the mass fraction:Epoxy resin:40 50 parts, oil resistant rubber:20 30 parts, polyethylene:46 parts, isophorone diisocyanate:34 parts, polystyrene:35 parts, polyurethane:36 parts, boric acid:12 parts, silicon carbide micro-powder:68 parts, kaolin:10 13 parts, methyl methacrylate:8 12 parts, N, N dimethylformamides:69 parts, graphite oxide:56 parts, hydrazine hydrate:34 parts, calcium carbonate:10 13 parts, barium sulfate:58 parts, glass fibre:26 parts, auxiliary agent:37 parts;The present invention has a good oil resistivity, and can antistatic, prolong the service life.

Description

A kind of anti-static oil-resistant instrument cable
Technical field
The present invention relates to one kind to be used for instrument cable, and in particular to a kind of anti-static oil-resistant instrument cable.
Background technology
Petroleum chemical industry, since its environmental condition is harsh, the technology that higher is proposed to the cable in such field will Ask, its cable is primarily adapted for use in the oil tank extra-high to naked light safety requirements, oil well and Large Oil Storage container environment and uses, directly Long Term Contact or immersion are connect in the oil as electric meter and sensing connection transmission of control signals and measuring signal;Need to its material Material have it is higher must ask, security risk can be avoided, while need to extend its service life.
The content of the invention
The object of the present invention is to provide a kind of anti-static oil-resistant instrument cable, including core and protection pipe, the core It is arranged in protection pipe, the protection pipe includes following components according to the mass fraction:Epoxy resin:40-50 parts, oil resistant rubber: 20-30 parts, polyethylene:4-6 parts, isophorone diisocyanate:3-4 parts, polystyrene:3-5 parts, polyurethane thermoplastic elasticity Body:3-6 parts, boric acid:1-2 parts, silicon carbide micro-powder:6-8 parts, kaolin:10-13 parts, methyl methacrylate:8-12 parts, N, Dinethylformamide:6-9 parts, graphite oxide:5-6 parts, hydrazine hydrate:3-4 parts, calcium carbonate:10-13 parts, barium sulfate:5-8 parts, Glass fibre:2-6 parts, auxiliary agent:3-7 parts;
The oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:40-50 parts, nitrile rubber:60-80 parts, it is hard Resin acid barium:10-15 parts, paraffin oil:3-6 parts, nano silicon dioxide:5-8 parts, nano zine oxide:4-5 parts, sulphur:7-9 parts, two Vulcanize dimorpholine:2-4 parts, plasticizer:1-3 parts, carbon black:2-4 parts, accelerating agent:1-2 parts, antioxidant:2-3 parts;
The auxiliary agent includes according to the mass fraction:Silane coupling agent:3-5 parts, crosslinking agent:2-3 parts, compatilizer:3-4 parts.
Further limits scheme is the present invention:
Foregoing protection pipe includes following components according to the mass fraction:Epoxy resin:43 parts, oil resistant rubber:25 parts, polyethylene:4 Part, isophorone diisocyanate:3 parts, polystyrene:3 parts, polyurethane termoplastic elastomer:4 parts, boric acid:1 part, carborundum Micro mist:6 parts, kaolin:11 parts, methyl methacrylate:9 parts, n,N-Dimethylformamide:7 parts, graphite oxide:5 parts, water Close hydrazine:3 parts, calcium carbonate:10 parts, barium sulfate:5 parts, glass fibre:4 parts, auxiliary agent:4 parts;
Oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:43 parts, nitrile rubber:65 parts, barium stearate:11 Part, paraffin oil:4 parts, nano silicon dioxide:5 parts, nano zine oxide:4 parts, sulphur:7 parts, dimorpholinyl disulfide:2 parts, plasticising Agent:2 parts, carbon black:3 parts, accelerating agent:1 part, antioxidant:2 parts;
Auxiliary agent includes according to the mass fraction:Silane coupling agent:4 parts, crosslinking agent:2 parts, compatilizer:3 parts.
Foregoing protection pipe includes following components according to the mass fraction:Epoxy resin:46 parts, oil resistant rubber:27 parts, poly- second Alkene:5 parts, isophorone diisocyanate:4 parts, polystyrene:4 parts, polyurethane termoplastic elastomer:6 parts, boric acid:2 parts, carbon SiClx micro mist:7 parts, kaolin:12 parts, methyl methacrylate:11 parts, n,N-Dimethylformamide:8 parts, graphite oxide:6 Part, hydrazine hydrate:4 parts, calcium carbonate:12 parts, barium sulfate:7 parts, glass fibre:5 parts, auxiliary agent:6 parts;
Oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:47 parts, nitrile rubber:74 parts, barium stearate:13 Part, paraffin oil:5 parts, nano silicon dioxide:7 parts, nano zine oxide:5 parts, sulphur:8 parts, dimorpholinyl disulfide:3 parts, plasticising Agent:3 parts, carbon black:4 parts, accelerating agent:2 parts, antioxidant:3 parts;
Auxiliary agent includes according to the mass fraction:Silane coupling agent:5 parts, crosslinking agent:3 parts, compatilizer:4 parts.
The present invention provides a kind of anti-static oil-resistant instrument cable preparation method, specifically includes following steps:
Step 1:Prepare oil resistant rubber:Chlorohydrin rubber and nitrile rubber are mixed and sent into grinder, is sent after grinding to reaction kettle In, barium stearate, paraffin oil, sulphur and dimorpholinyl disulfide are added, 30-40min is stirred with 260-300r/min, temperature rises to 75-85 DEG C, 20-30min is kept the temperature, nano silicon dioxide, nano zine oxide and carbon black is then added, is stirred with 300-350/min 40-50min, plasticizer, accelerating agent and antioxidant are added in whipping process, obtains oil resistant rubber;
Step 2:Epoxy resin, oil resistant rubber, polyethylene and polystyrene are added to temperature in reaction kettle and rise to 60-65 DEG C, And with 200-250/min stir 20-25min, then add isophorone diisocyanate, polyurethane termoplastic elastomer, Methyl methacrylate part, boric acid, n,N-Dimethylformamide and hydrazine hydrate, temperature rise to 78-85 DEG C, with 360-460r/min 30-40min is stirred, it is spare;
Step 3:Silicon carbide micro-powder, kaolin, graphite oxide, calcium carbonate, barium sulfate and glass fibre are mixed and sent to heating furnace In, heat stepwise, temperature is respectively:80-100 DEG C, 140-160 DEG C, 180-200 DEG C, then use air cooling way with 3-5 DEG C/ Min is cooled to room temperature, spare;
Step 4:Step 2 and step 3 are mixed, 55-65min is stirred with 400-450r/min, adds and helps in whipping process Agent, obtains masterbatch;
Step 5:Masterbatch is sent into injection molding machine, its parameter is:Material feeding pressure is controlled in 20-22MPa, injection temperature 400- 440 DEG C, injection time control was at 3-5 seconds, and the dwell time is 15-20 seconds, shaping;
Step 6:Casing is subjected to high-temperature process, the technological parameter of its high-temperature process is:100-120 DEG C for the treatment of temperature, during processing Between be 1-3h.
Beneficial effect:The present invention is adding polyurethane termoplastic elastomer, not only with antistatic, oil resistant characteristic, also has Have environmental protection, safety, a recyclable reuse, at the same also humidity, adapt to the special severe rings such as high salinity, difference variation be big Border, the present invention in oil resistant rubber formula made from oil resistant rubber, there is good oil resistance, high temperature resistant, corrosion-resistant, energy Enough needs effectively met in production and living;By silicon carbide micro-powder, kaolin, graphite oxide, calcium carbonate, barium sulfate and glass fibers It is added to after dimension grinding in the present invention, it can be tightly adsorbed on the surface of rubber macromolecule, not only increase its intensity, together When significantly improve its resistance to ag(e)ing and resistance to acid and alkali.
Embodiment
Embodiment 1
The present embodiment provides a kind of anti-static oil-resistant instrument cable, including core and protection pipe, core to be arranged in protection pipe, The protection pipe includes following components according to the mass fraction:Epoxy resin:43 parts, oil resistant rubber:25 parts, polyethylene:4 parts, different Buddhist That ketone diisocyanate:3 parts, polystyrene:3 parts, polyurethane termoplastic elastomer:4 parts, boric acid:1 part, silicon carbide micro-powder:6 Part, kaolin:11 parts, methyl methacrylate:9 parts, n,N-Dimethylformamide:7 parts, graphite oxide:5 parts, hydrazine hydrate:3 Part, calcium carbonate:10 parts, barium sulfate:5 parts, glass fibre:4 parts, auxiliary agent:4 parts;
Oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:43 parts, nitrile rubber:65 parts, barium stearate:11 Part, paraffin oil:4 parts, nano silicon dioxide:5 parts, nano zine oxide:4 parts, sulphur:7 parts, dimorpholinyl disulfide:2 parts, plasticising Agent:2 parts, carbon black:3 parts, accelerating agent:1 part, antioxidant:2 parts;
Auxiliary agent includes according to the mass fraction:Silane coupling agent:4 parts, crosslinking agent:2 parts, compatilizer:3 parts.
The present embodiment provides a kind of anti-static oil-resistant instrument cable preparation method, following steps are specifically included:
Step 1:Prepare oil resistant rubber:Chlorohydrin rubber and nitrile rubber are mixed and sent into grinder, is sent after grinding to reaction kettle In, barium stearate, paraffin oil, sulphur and dimorpholinyl disulfide are added, 40min is stirred with 260r/min, temperature rises to 78 DEG C, protects Warm 25min, then adds nano silicon dioxide, nano zine oxide and carbon black, 50min is stirred with 300/min, in whipping process Plasticizer, accelerating agent and antioxidant are added, obtains oil resistant rubber;
Step 2:Epoxy resin, oil resistant rubber, polyethylene and polystyrene are added to temperature in reaction kettle and rise to 60-65 DEG C, And 25min is stirred with 200/min, then adds isophorone diisocyanate, polyurethane termoplastic elastomer, metering system Sour methyl esters part, boric acid, n,N-Dimethylformamide and hydrazine hydrate, temperature rise to 81 DEG C, and 40min is stirred with 360r/min, spare;
Step 3:Silicon carbide micro-powder, kaolin, graphite oxide, calcium carbonate, barium sulfate and glass fibre are mixed and sent to heating furnace In, heat stepwise, temperature is respectively:90 DEG C, 150 DEG C, 190 DEG C, air cooling way is then used to be cooled to room temperature with 3 DEG C/min, It is spare;
Step 4:Step 2 and step 3 are mixed, 65min is stirred with 400r/min, auxiliary agent is added in whipping process, is obtained female Material;
Step 5:Masterbatch is sent into injection molding machine, its parameter is:For the control of material feeding pressure in 20MPa, injection temperature is 410 DEG C, Injection time control was at 4 seconds, and the dwell time is 16 seconds, shaping;
Step 6:Casing is subjected to high-temperature process, the technological parameter of its high-temperature process is:105 DEG C for the treatment of temperature, processing time be 2.5h。
Embodiment 2
The present embodiment provides a kind of anti-static oil-resistant instrument cable, including core and protection pipe, core to be arranged in protection pipe, The protection pipe includes following components according to the mass fraction:Epoxy resin:46 parts, oil resistant rubber:27 parts, polyethylene:5 parts, different Buddhist That ketone diisocyanate:4 parts, polystyrene:4 parts, polyurethane termoplastic elastomer:6 parts, boric acid:2 parts, silicon carbide micro-powder:7 Part, kaolin:12 parts, methyl methacrylate:11 parts, n,N-Dimethylformamide:8 parts, graphite oxide:6 parts, hydrazine hydrate:4 Part, calcium carbonate:12 parts, barium sulfate:7 parts, glass fibre:5 parts, auxiliary agent:6 parts;
Oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:47 parts, nitrile rubber:74 parts, barium stearate:13 Part, paraffin oil:5 parts, nano silicon dioxide:7 parts, nano zine oxide:5 parts, sulphur:8 parts, dimorpholinyl disulfide:3 parts, plasticising Agent:3 parts, carbon black:4 parts, accelerating agent:2 parts, antioxidant:3 parts;
Auxiliary agent includes according to the mass fraction:Silane coupling agent:5 parts, crosslinking agent:3 parts, compatilizer:4 parts.
The present embodiment provides a kind of anti-static oil-resistant instrument cable preparation method, following steps are specifically included:
Step 1:Prepare oil resistant rubber:Chlorohydrin rubber and nitrile rubber are mixed and sent into grinder, is sent after grinding to reaction kettle In, barium stearate, paraffin oil, sulphur and dimorpholinyl disulfide are added, 30min is stirred with 300r/min, temperature rises to 82 DEG C, protects Warm 23min, then adds nano silicon dioxide, nano zine oxide and carbon black, 40min is stirred with 350/min, in whipping process Plasticizer, accelerating agent and antioxidant are added, obtains oil resistant rubber;
Step 2:Epoxy resin, oil resistant rubber, polyethylene and polystyrene are added to temperature in reaction kettle and rise to 65 DEG C, and And 20min is stirred with 250/min, then add isophorone diisocyanate, polyurethane termoplastic elastomer, methacrylic acid Methyl esters part, boric acid, n,N-Dimethylformamide and hydrazine hydrate, temperature rise to 83 DEG C, and 30min is stirred with 460r/min, spare;
Step 3:Silicon carbide micro-powder, kaolin, graphite oxide, calcium carbonate, barium sulfate and glass fibre are mixed and sent to heating furnace In, heat stepwise, temperature is respectively:95 DEG C, 155 DEG C, 195 DEG C, air cooling way is then used to be cooled to room temperature with 5 DEG C/min, It is spare;
Step 4:Step 2 and step 3 are mixed, 55min is stirred with 450r/min, auxiliary agent is added in whipping process, is obtained female Material;
Step 5:Masterbatch is sent into injection molding machine, its parameter is:For the control of material feeding pressure in 21MPa, injection temperature is 430 DEG C, Injection time control was at 3 seconds, and the dwell time is 15 seconds, shaping;
Step 6:Casing is subjected to high-temperature process, the technological parameter of its high-temperature process is:110 DEG C for the treatment of temperature, processing time be 2h。
In addition to the implementation, the present invention can also have other embodiment.It is all to use equivalent substitution or equivalent transformation shape Into technical solution, all fall within the protection domains of application claims.

Claims (4)

1. a kind of anti-static oil-resistant instrument cable, including core and protection pipe, the core are arranged in protection pipe, its feature It is, the protection pipe includes following components according to the mass fraction:Epoxy resin:40-50 parts, oil resistant rubber:20-30 parts, it is poly- Ethene:4-6 parts, isophorone diisocyanate:3-4 parts, polystyrene:3-5 parts, polyurethane termoplastic elastomer:3-6 parts, Boric acid:1-2 parts, silicon carbide micro-powder:6-8 parts, kaolin:10-13 parts, methyl methacrylate:8-12 parts, N, N- dimethyl methyls Acid amides:6-9 parts, graphite oxide:5-6 parts, hydrazine hydrate:3-4 parts, calcium carbonate:10-13 parts, barium sulfate:5-8 parts, glass fibre: 2-6 parts, auxiliary agent:3-7 parts;
The oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:40-50 parts, nitrile rubber:60-80 parts, it is hard Resin acid barium:10-15 parts, paraffin oil:3-6 parts, nano silicon dioxide:5-8 parts, nano zine oxide:4-5 parts, sulphur:7-9 parts, two Vulcanize dimorpholine:2-4 parts, plasticizer:1-3 parts, carbon black:2-4 parts, accelerating agent:1-2 parts, antioxidant:2-3 parts;
The auxiliary agent includes according to the mass fraction:Silane coupling agent:3-5 parts, crosslinking agent:2-3 parts, compatilizer:3-4 parts.
2. anti-static oil-resistant instrument cable according to claim 1, it is characterised in that:The protection pipe presses mass fraction Meter includes following components:Epoxy resin:43 parts, oil resistant rubber:25 parts, polyethylene:4 parts, isophorone diisocyanate:3 parts, Polystyrene:3 parts, polyurethane termoplastic elastomer:4 parts, boric acid:1 part, silicon carbide micro-powder:6 parts, kaolin:11 parts, methyl Methyl acrylate:9 parts, n,N-Dimethylformamide:7 parts, graphite oxide:5 parts, hydrazine hydrate:3 parts, calcium carbonate:10 parts, sulfuric acid Barium:5 parts, glass fibre:4 parts, auxiliary agent:4 parts;
The oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:43 parts, nitrile rubber:65 parts, stearic acid Barium:11 parts, paraffin oil:4 parts, nano silicon dioxide:5 parts, nano zine oxide:4 parts, sulphur:7 parts, dimorpholinyl disulfide:2 parts, Plasticizer:2 parts, carbon black:3 parts, accelerating agent:1 part, antioxidant:2 parts;
The auxiliary agent includes according to the mass fraction:Silane coupling agent:4 parts, crosslinking agent:2 parts, compatilizer:3 parts.
3. anti-static oil-resistant instrument cable according to claim 1, it is characterised in that:The protection pipe presses mass fraction Meter includes following components:Epoxy resin:46 parts, oil resistant rubber:27 parts, polyethylene:5 parts, isophorone diisocyanate:4 parts, Polystyrene:4 parts, polyurethane termoplastic elastomer:6 parts, boric acid:2 parts, silicon carbide micro-powder:7 parts, kaolin:12 parts, methyl Methyl acrylate:11 parts, n,N-Dimethylformamide:8 parts, graphite oxide:6 parts, hydrazine hydrate:4 parts, calcium carbonate:12 parts, sulfuric acid Barium:7 parts, glass fibre:5 parts, auxiliary agent:6 parts;
The oil resistant rubber includes following components according to the mass fraction:Chlorohydrin rubber:47 parts, nitrile rubber:74 parts, stearic acid Barium:13 parts, paraffin oil:5 parts, nano silicon dioxide:7 parts, nano zine oxide:5 parts, sulphur:8 parts, dimorpholinyl disulfide:3 parts, Plasticizer:3 parts, carbon black:4 parts, accelerating agent:2 parts, antioxidant:3 parts;
The auxiliary agent includes according to the mass fraction:Silane coupling agent:5 parts, crosslinking agent:3 parts, compatilizer:4 parts.
4. according to any anti-static oil-resistant instrument cable preparation methods of claim 1-3, it is characterised in that:Specific bag Include following steps:
Step 1:Prepare oil resistant rubber:Chlorohydrin rubber and nitrile rubber are mixed and sent into grinder, is sent after grinding to reaction kettle In, barium stearate, paraffin oil, sulphur and dimorpholinyl disulfide are added, 30-40min is stirred with 260-300r/min, temperature rises to 75-85 DEG C, 20-30min is kept the temperature, nano silicon dioxide, nano zine oxide and carbon black is then added, is stirred with 300-350/min 40-50min, plasticizer, accelerating agent and antioxidant are added in whipping process, obtains oil resistant rubber;
Step 2:Epoxy resin, oil resistant rubber, polyethylene and polystyrene are added to temperature in reaction kettle and rise to 60-65 DEG C, And with 200-250/min stir 20-25min, then add isophorone diisocyanate, polyurethane termoplastic elastomer, Methyl methacrylate part, boric acid, n,N-Dimethylformamide and hydrazine hydrate, temperature rise to 78-85 DEG C, with 360-460r/min 30-40min is stirred, it is spare;
Step 3:Silicon carbide micro-powder, kaolin, graphite oxide, calcium carbonate, barium sulfate and glass fibre are mixed and sent to heating furnace In, heat stepwise, temperature is respectively:80-100 DEG C, 140-160 DEG C, 180-200 DEG C, then use air cooling way with 3-5 DEG C/ Min is cooled to room temperature, spare;
Step 4:Step 2 and step 3 are mixed, 55-65min is stirred with 400-450r/min, adds and helps in whipping process Agent, obtains masterbatch;
Step 5:Masterbatch is sent into injection molding machine, its parameter is:Material feeding pressure is controlled in 20-22MPa, injection temperature 400- 440 DEG C, injection time control was at 3-5 seconds, and the dwell time is 15-20 seconds, shaping;
Step 6:Casing is subjected to high-temperature process, the technological parameter of its high-temperature process is:100-120 DEG C for the treatment of temperature, during processing Between be 1-3h.
CN201711356459.5A 2017-12-16 2017-12-16 A kind of anti-static oil-resistant instrument cable Pending CN108017883A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110396263A (en) * 2019-06-25 2019-11-01 安徽上华电缆有限公司 A kind of underwater long-acting special antibacterial cable material and preparation method thereof
CN117259105A (en) * 2023-10-07 2023-12-22 山东力强钢板有限公司 Antistatic color-coated plate and color-coated plate production device

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105885135A (en) * 2016-05-20 2016-08-24 安徽德源电缆集团有限公司 Cable sheath material

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105885135A (en) * 2016-05-20 2016-08-24 安徽德源电缆集团有限公司 Cable sheath material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110396263A (en) * 2019-06-25 2019-11-01 安徽上华电缆有限公司 A kind of underwater long-acting special antibacterial cable material and preparation method thereof
CN117259105A (en) * 2023-10-07 2023-12-22 山东力强钢板有限公司 Antistatic color-coated plate and color-coated plate production device

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Application publication date: 20180511