CN108017816A - Environment-friendly materials and use the curtain blade made by the environment-friendly materials - Google Patents
Environment-friendly materials and use the curtain blade made by the environment-friendly materials Download PDFInfo
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- CN108017816A CN108017816A CN201610954425.5A CN201610954425A CN108017816A CN 108017816 A CN108017816 A CN 108017816A CN 201610954425 A CN201610954425 A CN 201610954425A CN 108017816 A CN108017816 A CN 108017816A
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- Prior art keywords
- density polyethylene
- environment
- friendly materials
- polyolefin
- polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
- E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
- E06B9/26—Lamellar or like blinds, e.g. venetian blinds
- E06B9/36—Lamellar or like blinds, e.g. venetian blinds with vertical lamellae ; Supporting rails therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of environment-friendly materials and using the curtain blade made by the environment-friendly materials, which includes 60 to 80wt% inorganic rock salt master batch, the main chain carbon number of 15 to 35wt% polymerized monomer is two or three polyolefin and 5 to 10wt% auxiliary agent.Inorganic rock salt master batch includes calcium carbonate and polyethylene or polypropylene, and wherein calcium carbonate and polyethylene or polyacrylic weight ratio are 8 to 2.Polyolefin is linear low density polyethylene, low density polyethylene (LDPE), medium density polyethylene, high density polyethylene (HDPE) or polypropylene.Auxiliary agent is grafted elastomeric POE MA or PE MA.Whereby, the curtain blade made by the environment-friendly materials can have the required engineering properties of curtain, and the features such as have low cost concurrently at the same time and exempt from polyvinyl chloride.
Description
Technical field
The present invention is on a kind of environment-friendly materials, especially with regard to a kind of environment-friendly materials for being suitable for making curtain blade.
Background technology
Curtain is generally used in inside building window, is set up or is placed in by window with frame or track, for blocking
The light being directed through, there is provided lucifuge and the use function of protecting privacy.Common curtain is except cloth curtain, the curtain of curtain type
Outside, also there are the shutter of vertical type or horizontal type or the curtain of piece curtain, it is possible to provide the different selection of consumer.
The making that traditional horizontal type or vertical type window connect blade has using solid wood person, can provide good shading and heat-insulated effect
Fruit, however, in the case of forest resourceies now are gradually deficient, not only timber source gradually decreases, and causes cost increase, also often
There is the dispute for destroying forest land and ecological environment.
Outside traditional solid sawn curtain blade, also there is dealer to provide the curtain blade using plastic production, as curtain louver
Another option of piece.However, made plastic curtain blade (such as vertical type blade) of polyvinyl chloride, through consumer
If not properly recycling, is easily thrown aside and be mixed in conventional rubbish after use, and produces dioxin when burning, equally have easily
The problem of causing earth environment to endanger.
TaiWan, China patent TW 379272 discloses a kind of manufacture method of environment protecting paper, its be by inorganic mineral powder, polyethylene and
Auxiliary agent is made as raw material, though it, because toughness is relatively low, is not suitable for as curtain louver using the raw material more friendly to environment
Piece uses.
Therefore, on the premise of meeting curtain blade and using situation material requested toughness or impact resistance, low ring can be had concurrently
Border public hazards and the acceptable material of cost, still seek to be tried hard to pursue caused by curtain production industry and consumer.
The content of the invention
In view of this, it is a primary object of the present invention to provide a kind of material for being suitable for making curtain blade, there is provided curtain
Industry and consumer are produced as another selection outside timber and polyvinyl chloride.
The purpose of the present invention is lain also in, it is desirable to which lowering the environment caused by curtain material influences.
The purpose of the present invention is lain also in, it is desirable to which the material for making curtain has controllable or relatively low cost.
In order to realize above-mentioned and other purposes, the present invention provides a kind of environment-friendly materials, wherein including 60 to 80wt% nothing
The polyolefin and 5 to 10wt% auxiliary agent that machine rock salt master batch, the main chain carbon number of 15 to 35wt% polymerized monomer are two or three；Institute
State inorganic rock salt master batch and include calcium carbonate and polyethylene, the wherein weight ratio of calcium carbonate and polyethylene is 8 to 2；The polyolefin
For linear low density polyethylene, low density polyethylene (LDPE), medium density polyethylene, high density polyethylene (HDPE) or polypropylene；The auxiliary agent is
Grafted elastomeric POE-MA or PE-MA.
In order to realize above-mentioned and other purposes, the present invention also provides a kind of environment-friendly materials, wherein including the inorganic of 80wt%
The main chain carbon number of the polymerized monomer of rock salt master batch and 20wt% is two or three polyolefin；The inorganic rock salt master batch includes carbonic acid
The weight ratio of calcium and polyethylene, wherein calcium carbonate and polyethylene is 8 to 2；The polyolefin is linear low density polyethylene, low close
Spend polyethylene, medium density polyethylene, high density polyethylene (HDPE) or polypropylene.
In order to realize above-mentioned and other purposes, the present invention also provides a kind of environment-friendly materials, be by 60 to 80wt% it is inorganic
The polyolefin and 5 to 10wt% auxiliary agent institute group of rock salt master batch, the main chain carbon number of 15 to 35wt% polymerized monomer for two or three
Into；The inorganic rock salt master batch includes calcium carbonate and polyethylene, and the wherein weight ratio of calcium carbonate and polyethylene is 8 to 2；It is described poly-
Alkene is linear low density polyethylene, low density polyethylene (LDPE), medium density polyethylene, high density polyethylene (HDPE) or polypropylene；It is described to help
Agent is POE-MA or PE-MA.
In order to realize above-mentioned and other purposes, the present invention also provides a kind of curtain blade, is with above-mentioned environment-friendly materials institute
It is made.
By above-mentioned design, making for polyvinyl chloride can be excluded using the curtain blade made by the environment-friendly materials of the present invention
With, environmental problem caused by dioxin can be avoided or reduce, meanwhile, considerable degree of calcium carbonate is contained in environment-friendly materials, is belonged to
Inexpensive and handy material, contributes to curtain correlation dealer to control production cost, and has required engineering properties concurrently.
Brief description of the drawings
Fig. 1 is the schematic perspective view of the curtain blade made by environment-friendly materials of the present invention.
【Description of reference numerals】
Curtain blade 1
Drawstring 2
Track 3
Embodiment
For the object, technical solutions and advantages of the present invention are more clearly understood, below in conjunction with specific embodiment, and reference
Attached drawing, the present invention is described in further detail.
The present invention provides a kind of environment-friendly materials, can be made as sheet, and available in making curtain blade.Environmentally friendly material
Material is suitable for the curtain blade of making, can be curtain blade used in piece curtain, or vertical type or the shutter of horizontal type, such as
Vertical blinds shown in Fig. 1, track 3 is connected to using drawstring 2 by curtain blade 1, and drawstring control window is utilized for user
The open position and angle of blind blade 1.In addition, it may also be fitted according to the design of the producer or according to consumer demand, curtain blade
For other kinds of curtain.In addition, environment-friendly materials can also be made as block or tabular, and can be used for making ground
Brick, window frame, spike, Folding curtain or other appropriate occasions.
The present invention environment-friendly materials mainly including 60 to 80wt% (percentage by weights) inorganic rock salt master batch, 15 to
The polyolefin of 35wt% and 5 to the 10wt% auxiliary agent that may be added.
Inorganic rock salt master batch for parts by weight 8 calcium carbonate and parts by weight 2 polyethylene (PE) mixture, normal after mixing
It is in solid granular that temperature is lower, and the weight ratio of calcium carbonate and polyethylene is 8 to 2 in inorganic rock salt master batch, without other additives
Under situation inorganic rock salt master batch be 80wt% calcium carbonate and 20wt% polyethylene, precisely because in may be mixed with a small amount of impurity.
Main chain is that the polyolefin of two or three carbons is linear low density polyethylene (LLDPE), low density polyethylene (LDPE)
(LDPE), medium density polyethylene (MDPE), high density polyethylene (HDPE) (HDPE) or polypropylene (PP), wherein with linear low density polyethylene
Alkene, high density polyethylene (HDPE) and polypropylene are more common, and are preferable using linear low density polyethylene.
Auxiliary agent is maleic anhydride stem grafting polyolefin (maleic anhydride-grafted polyolefin
Elastomer, POE-MA) or maleic anhydride stem grafting polyolefin polyethylene (maleic anhydride-grafted
Polyethylene, PE-MA), wherein being preferable using POE-MA.
In addition to the aforementioned ingredients, environment-friendly materials of the invention also can not significantly affect material thing according to the demand of applicable situation
In the case of rationality matter is with chemical property, other function additives are added on a small quantity, such as addition bleaching agent, toner or pigment can change
Become the color of curtain blade, the service life of curtain blade can be improved by adding antioxidant or UV resistant agent, add ultraviolet
Absorbent can add in curtain blade and provide the function of reducing indoor ultraviolet, in addition also may add lubrication prescription, elasticity helps
Agent or antistatic additive.
The component of foregoing environment-friendly materials can be granulated using kneading machine after mixing it is spare, or with screw rod extruder be kneaded after
Direct extrusion slabbing is spare, for be subsequently processed further being made as required moulding and as curtain blade or other be made
Product.
To determine that above-mentioned environment-friendly materials may conform to the use demand of curtain blade, present inventor further selects number
A specific embodiment, its physical property is tested after the environment-friendly materials of sheet are made.Its testing procedure system is first made with twin-screw mixer
Grain machine in 170 DEG C to 210 DEG C carry out mixing granulators, then with heat give as security forming machine in 180 DEG C heat give as security shaping, and be cut into 90mm ×
12mm × 1mm by sample, tested under room temperature environment with impact resistance tester by sample, as various proportional components
Whether environment-friendly materials mechanical strength is suitable for the reference frame for making curtain blade.
The specific embodiment and comparative example component and test result of tested person, refer to table 1 below:
Table 1:By the component and test result comparison sheet of sample
In test result, to meet the general use situation of curtain, more than 7 pounds with impact resistance of empirical tests are straight suitable for making
The main evaluation benchmark of vertical curtain curtain blade, it is found that above example can be tested by impact resistance, opposite, than
Compared with example 1 and 2, inorganic rock salt master batch proportion is higher, its impact resistance test result is far below 7 pounds, it can be determined that above-mentioned
Comparative example is not suitable as the material of curtain blade.
In addition, by embodiment 3 with 4 comparison it can be found that using linear low density polyethylene and POE-MA compared to adopting
Significantly excellent impact resistance property can be obtained with high density polyethylene (HDPE) and PE-MA；
By embodiment 4 compared with 5 and embodiment 6 compared with 7 then it can be found that polyolefin in environment-friendly materials uses
Polypropylene and linear low density polyethylene can obtain a degree of preferable shock resistance.
If both compare with embodiment 1 and 3, increase inorganic rock salt master batch content, reduce PE contents, impact resistance will be reduced
Power, 7 pounds are reduced to by 9 pounds.
If both compare with embodiment 1 and 2, increase grafted elastomeric PE-MA contents, impact resistance can be lifted, carried by 7 pounds
It is raised to 9 pounds.
If being compared with both embodiment 7 and embodiment 8, grafted elastomeric POE-MA is added, impact resistance will be lifted, by 12
Pound lifting is to 18 pounds.
If being compared with both embodiment 7 and embodiment 9, compare the non-grafted elastomer POE and grafted elastomeric POE- of addition
MA, although still preferable to add the performance of grafted elastomeric POE-MA person, embodiment 9 is still to be not added with auxiliary agent than embodiment 8
Person's impact resistance is good, meets the standard requirement of curtain impact resistance.
If both compare with comparative example 1 and comparative example 2, when inorganic rock salt master batch content increases to 90%, even if addition connects
Branch elastomer POE-MA, lifting impact resistance effect is limited, only by 2 pounds of liftings to 3 pounds.
In test described above, although polyolefin only tests linear low density polyethylene, high density polyethylene (HDPE) with gathering
Propylene, but low density polyethylene (LDPE) in polyolefin and medium density polyethylene also have the material similar to high density polyethylene (HDPE)
Matter, under reasonable expectation, can also make the material of environment-friendly materials special in polyolefin using low density polyethylene (LDPE) and medium density polyethylene
Property meet make curtain blade demand.
Based on result above, it can be found that the environment-friendly materials of the present invention have the engineering properties for being suitable for making curtain really,
Environmental issue without the use of polyvinyl chloride without burning and exhausting dioxin, and the calcium carbonate containing significant proportion in component, have
Help control or reduce material cost, surely belong to the material that industry is welcome with market.
Particular embodiments described above, has carried out the purpose of the present invention, technical solution and beneficial effect further in detail
Describe in detail bright, it should be understood that the foregoing is merely the present invention specific embodiment, be not intended to limit the invention, it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution, improvement and etc. done, should be included in the protection of the present invention
Within the scope of.
Claims (10)
1. a kind of environment-friendly materials, including：
60 to 80wt% inorganic rock salt master batch, the inorganic rock salt master batch include calcium carbonate and polyethylene or polypropylene, wherein
Calcium carbonate is 8 to 2 with polyethylene or polyacrylic weight ratio；
The main chain carbon number of 15 to 35wt% polymerized monomer is two or three polyolefin, and the polyolefin is linear low density polyethylene
Alkene, low density polyethylene (LDPE), medium density polyethylene, high density polyethylene (HDPE) or polypropylene；
5 to 10wt% auxiliary agent, the auxiliary agent is POE, grafted elastomeric POE-MA or PE-MA.
2. a kind of environment-friendly materials, including：
The inorganic rock salt master batch of 80wt%, the inorganic rock salt master batch include calcium carbonate and polyethylene or polypropylene, wherein carbonic acid
Calcium is 8 to 2 with polyethylene or polyacrylic weight ratio；
The main chain carbon number of the polymerized monomer of 20wt% be two or three polyolefin, the polyolefin for linear low density polyethylene,
Low density polyethylene (LDPE), medium density polyethylene, high density polyethylene (HDPE) or polypropylene.
3. a kind of environment-friendly materials, are made of following component：
60 to 80wt% inorganic rock salt master batch, the inorganic rock salt master batch include calcium carbonate and polyethylene or polypropylene, wherein
Calcium carbonate is 8 to 2 with polyethylene or polyacrylic weight ratio；
The main chain carbon number of 15 to 35wt% polymerized monomer is two or three polyolefin, and the polyolefin is linear low density polyethylene
Alkene, low density polyethylene (LDPE), medium density polyethylene, high density polyethylene (HDPE) or polypropylene；
5 to 10wt% auxiliary agent, the auxiliary agent is POE, grafted elastomeric POE-MA or PE-MA.
4. according to claims 1 to 3 any one of them environment-friendly materials, wherein the polyolefin be linear low density polyethylene,
High density polyethylene (HDPE) or polypropylene.
5. according to claims 1 to 3 any one of them environment-friendly materials, wherein the polyolefin for linear low density polyethylene or
Polypropylene.
6. the environment-friendly materials according to claim 1 or 3, wherein the auxiliary agent is grafted elastomeric POE-MA.
A kind of 7. curtain blade, using as made by claims 1 to 3 any one of them environment-friendly materials.
8. curtain blade according to claim 7, wherein the polyolefin is linear low density polyethylene, high-density polyethylene
Alkene or polypropylene.
9. curtain blade according to claim 7, wherein the polyolefin is linear low density polyethylene or polypropylene.
10. curtain blade according to claim 7, wherein the auxiliary agent is grafted elastomeric POE-MA.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610954425.5A CN108017816A (en) | 2016-11-03 | 2016-11-03 | Environment-friendly materials and use the curtain blade made by the environment-friendly materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610954425.5A CN108017816A (en) | 2016-11-03 | 2016-11-03 | Environment-friendly materials and use the curtain blade made by the environment-friendly materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108017816A true CN108017816A (en) | 2018-05-11 |
Family
ID=62070829
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610954425.5A Pending CN108017816A (en) | 2016-11-03 | 2016-11-03 | Environment-friendly materials and use the curtain blade made by the environment-friendly materials |
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| Country | Link |
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| CN (1) | CN108017816A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6403721B1 (en) * | 2000-09-29 | 2002-06-11 | Solvay Engineered Polymers | Engineered polyolefin materials with enhanced surface durability |
| CN1934186A (en) * | 2004-02-13 | 2007-03-21 | 德古萨公司 | Highly filled polyolefin compounds |
| CN102070918A (en) * | 2009-11-19 | 2011-05-25 | 台州市黄岩明江塑胶有限公司 | Preparation method of calcium carbonate masterbatch |
| CN105037911A (en) * | 2015-07-28 | 2015-11-11 | 浙江万马高分子材料有限公司 | Easy-peel highlighted silane crosslinking flame-retardant polyolefin insulation material, preparation method and application thereof |
-
2016
- 2016-11-03 CN CN201610954425.5A patent/CN108017816A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6403721B1 (en) * | 2000-09-29 | 2002-06-11 | Solvay Engineered Polymers | Engineered polyolefin materials with enhanced surface durability |
| CN1934186A (en) * | 2004-02-13 | 2007-03-21 | 德古萨公司 | Highly filled polyolefin compounds |
| CN102070918A (en) * | 2009-11-19 | 2011-05-25 | 台州市黄岩明江塑胶有限公司 | Preparation method of calcium carbonate masterbatch |
| CN105037911A (en) * | 2015-07-28 | 2015-11-11 | 浙江万马高分子材料有限公司 | Easy-peel highlighted silane crosslinking flame-retardant polyolefin insulation material, preparation method and application thereof |
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Application publication date: 20180511 |
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