CN107746554A - A kind of imitative ceramic flame-proof PET/ABS resin combinations and preparation method thereof - Google Patents

A kind of imitative ceramic flame-proof PET/ABS resin combinations and preparation method thereof Download PDF

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Publication number
CN107746554A
CN107746554A CN201711249870.2A CN201711249870A CN107746554A CN 107746554 A CN107746554 A CN 107746554A CN 201711249870 A CN201711249870 A CN 201711249870A CN 107746554 A CN107746554 A CN 107746554A
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temperature
area
abs resin
pet
imitative ceramic
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Inventor
殷年伟
卢立波
周华龙
张永
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Wuhan Kingfa Technology Co Ltd
Shanghai Kingfa Science and Technology Co Ltd
Jiangsu Kingfa New Material Co Ltd
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Wuhan Kingfa Technology Co Ltd
Shanghai Kingfa Science and Technology Co Ltd
Jiangsu Kingfa New Material Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00Making granules
    • B29B9/02Making granules by dividing preformed material
    • B29B9/06Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/9258Velocity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/0856Iron
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/30Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045Sulfates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of imitative ceramic flame-proof PET/ABS resin combinations and preparation method thereof, the imitative ceramic flame-proof PET/ABS resin combinations include following components and parts by weight:60.3 parts of PET resin 13.3 part;47 parts of ABS resin 2 part;10 parts of toughener 0 part;20 parts of bromide fire retardant 10 part;5 parts of fire retarding synergist 3 part;40 parts of filler 20 part;10 parts of metal powder 5 part;0.5 part of coupling agent;0.6 part of weather resisting agent;0.6 part of antioxidant.The imitative ceramic flame-proof PET/ABS resin combinations of the present invention have the characteristics that preferable impact resistance, surface high glaze, the larger, good toughness of density etc., and the use of ceramic product can be substituted in certain field.

Description

A kind of imitative ceramic flame-proof PET/ABS resin combinations and preparation method thereof
Technical field
The invention belongs to polymeric material field, and in particular to a kind of imitative ceramic flame-proof PET/ABS resin combinations and its Preparation method.
Background technology
The ceramic used in daily life, it is that the mixture by clay or containing clay makees pug mixing mostly, passes through Helical vacuum extruder is molded, and cuts into mud embryo and then calcining forms.Ceramic is natural, attractive in appearance, durable, inexpensive etc. with its Feature, it is loved by people, is seen everywhere in life.But ceramics there is also firing high energy consumption, poor toughness is frangible the shortcomings of, And manufacturing process needs valuable soil resource of using up, and also to consume the substantial amounts of energy, produces substantial amounts of discarded object, Destroy natural, ecological.
, therefore, how will processing and plastic products have the advantages that light, good toughness, convenient formation, are easily recycled Performance more excellent plastics copy ceramics, are always the direction that people make great efforts.Such as toner can is added in the plastic Plastic material outward appearance is adjusted to various ceramic outward appearances, or realizes that plastics imitate the effect of ceramics by technologies such as surface lacquers, but These measures are only the change of plastic products outward appearance, but without ceramic is thick and heavy, damage resistant, it is weather-proof etc. the advantages of.
The B of Chinese patent CN 101608055 disclose a kind of imitated ceramic plastic material, take in poly terephthalic acid fourth two The method of the substantial amounts of barium sulfate of addition realizes the purpose for imitating ceramics in alcohol ester plastics (PBT).The shortcomings that this method is that it is terrible To the density of similar ceramics, up to 71% barium sulfate is filled with plastic material.And the characteristics of due to barium sulfate itself, this Sample, which is done, not only easily makes plastic material become difficult processing, and easily causes plastic material shock resistance to decline, the system made Product are easily broken.And Chinese patent CN102321363B discloses one kind and used based on polyamide and zinc oxide, iron powder is as increasing The imitative ceramic product of heavy material, although this method can obtain the heavier imitative ceramic product of quality, because polyamide is poor Weatherability, the weather resistance of this product can be caused poor far beyond ceramic product, not a kind of really imitative ceramic product.
Therefore, in the exploitation of imitative ceramic product, the apparent high glaze for reaching ceramics is not only wanted, in density and weatherability side Face is required for reaching the level close to ceramics, and far above ceramics in terms of toughness, it is convenient to prepare, and so can be only achieved replacement The purpose of ceramics.
The content of the invention
The purpose of the present invention, exactly in order to solve the defects of current ceramic material processes are complicated, be not easily recycled, frangible, carry For a kind of imitative ceramic flame-proof PET/ABS resin combination larger with impact resistance, surface high glaze, easy-formation, density and its Preparation method.
The object of the present invention is achieved like this:
A kind of imitative ceramic flame-proof PET/ABS resin combinations of the present invention include following components and parts by weight:
PET resin is terephthalic acid monomers and second in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations The copolymer of glycol ester monomer;The PET resin intrinsic viscosity range is 0.6~1.2ml/g, between preferably 0.7-1.1ml/g, Between most preferably 0.75-9ml/g.
ABS resin is acrylonitrile-butadiene-benzene second in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations Alkene copolymer, acrylonitrile-butadiene-acrylate copolymer, MBS or third One or more of mixtures in alkene nitrile-ethylene propylene diene rubber-styrol copolymer.It is preferred that acrylonitrile-butadiene-styrene (ABS) Copolymer
Toughener is ethylene-vinyl acetate, second in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations Alkene-methyl acrylate, ethylene-ethylacrylate, Ethylene-butyl acrylate, low density polyethylene (LDPE), maleic anhydride grafted ethene- Octene copolymer, ethylene-ethylacrylate-glycidyl ester copolymer, Ethylene-butyl acrylate-glycidyl ester copolymer In one or more of mixing.
In a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations brominated flame-retardant be selected from brominated Polystyrene, One or more of mixing in TDE, brominated polycarbonate, brominated epoxy etc..
Fire retarding synergist is a kind of antimony containing compounds in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations, It is preferred that one kind or its mixture in antimony oxide or sodium antimonate.
Filler is barium sulfate, zinc oxide, titanium dioxide in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations At least one of titanium.
In a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations metal powder be iron powder, aluminium powder, in copper powder extremely Few one kind.
Coupling agent is that silane coupler or titanate esters are even in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations Join agent, preferably silane coupler.
Weather resisting agent described in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations for ultraviolet absorber and by The mixture of amine light stabilizer is hindered, ultraviolet absorber is a kind of hydroxy benzophenone ketone or hydroxy-phenyl benzotriazole class material, excellent Select hydroxy-phenyl benzotriazole class.The preferred macromolecular class hindered amine material of hindered amine as light stabilizer.
Antioxidant is pentaerythritol ester and phosphite ester in a kind of above-mentioned imitative ceramic flame-proof PET/ABS resin combinations Mixture.
The present invention also provides a kind of preparation method of imitative ceramic flame-proof PET/ABS resin combinations and comprised the following steps:
(1) raw material is prepared by following components and parts by weight:
(2) by filler, metal powder, coupling agent add homogenizer in, stir 5-10 minutes after, by PBT resin, PET resin, toughener, fire retardant, fire retarding synergist, weather resisting agent and antioxidant addition enter twin-screw extrusion after being well mixed Machine, processing technology are as follows:One 230-250 DEG C of area's temperature, two 230-250 DEG C of area's temperature, three 240-260 DEG C of area's temperature, four area's temperature 240-260 DEG C of degree, five 240-260 DEG C of area's temperature, six 240-260 DEG C of area's temperature, seven 240-260 DEG C of area's temperature, eight area's temperature 240-260 DEG C, nine 240-260 DEG C of area's temperature;300-400 revs/min of engine speed;
(3) discharge, cooling, dry, pelletizing after extrusion
The imitative ceramic flame-proof PET/ABS resin combinations of the present invention have a preferable impact resistance, surface high glaze, density compared with Greatly, good weatherability, the features such as good toughness, the use of ceramic product can be substituted in certain field.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Material is as follows used by the embodiment of the present invention 1~11:
PET resin:Inherent viscosity is 0.8, trade mark BG80, asset management Co., Ltd of SINOPEC Yizheng Engineering plastics factory of branch company.
ABS resin:The trade mark is PA757, Taiwan Qi Mei companies;
Toughener:Ethylene-butyl Acrylate-methacrylic Acid Glycerin Ester Copolymer, trade mark PTW, U.S. Du Company of nation;
Brominated flame-retardant:The trade mark is PBS-64HW, brominated polystyrene, U.S.'s Chemtura;
The trade mark is BC-52, brominated polycarbonate, U.S.'s Chemtura;
Fire retarding synergist:The trade mark is S-05N, antimony oxide, Hu'nan Chenzhou Mining Co., Ltd.;
Filler:3000 mesh blanc fixes, trade mark AB-3000N1, Guangzhou Huangpu Tian Taihuaqing Co., Ltds;Ring Guarantor's type zinc oxide, trade mark HHB-02, Shandong Zibo sea is along Xin Ye Co., Ltds;Titanium dioxide, trade mark R103, Dupont are public Department.
Iron powder:The trade mark is HYFE-300, Chengdu Jin Chun metal materials Co., Ltd.
Coupling agent:Silane coupler, chemical name are γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane, and the trade mark is Z-6040, Dow corning company.
Weather resisting agent:Hydroxy-phenyl benzotriazole class material, the trade mark are TINUVIN 327, BASF Corp. of Germany;Macromolecular is obstructed Amine light stabilizer, the trade mark are CHIMASSORB 944, BASF Corp. of Germany.
Antioxidant:Chemical name is four [β-(3,5- di-tert-butyl -4- hydroxy phenyls) propionic acid] pentaerythritol esters, commodity Name Irganox 1010, BASF Corp. of Germany.Chemical name is three [2.4- di-tert-butyl-phenyls] phosphite esters, trade name Irganox 168, BASF Corp. of Germany.
The component of embodiment 1~11 is as shown in table 1:
The embodiment 1-11 of table 1 component (parts by weight)
The preparation of a kind of imitative ceramic flame-proof PET/ABS resin alloy compositions of the present invention, using the production of Rhea company 75A (draw ratio 40) double screw extruder produces, and processing technology is as follows:One 230-250 DEG C of area's temperature, two area temperature 230- 250 DEG C, three 240-260 DEG C of area's temperature, four 240-260 DEG C of area's temperature, five 240-260 DEG C of area's temperature, six area temperature 240-260 DEG C, seven 240-260 DEG C of area's temperature, eight 240-260 DEG C of area's temperature, nine 240-260 DEG C of area's temperature;300-400 revs/min of engine speed Clock.
Embodiment 1
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, ABS PA757, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB944, Irganox 1010, Irganox 168 adds high-speed mixer mixing, is extruded afterwards in double screw extruder.Processing conditions is:One area's temperature 240 DEG C, two 245 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 255 DEG C of area's temperature, 7th area 255 DEG C of temperature, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 2
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168 add Enter high-speed mixer mixing, extruded afterwards in double screw extruder.Processing conditions is:One 240 DEG C of area's temperature, two area's temperature 245 DEG C, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 255 DEG C of area's temperature, seven 255 DEG C of area's temperature, Eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 3
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One 240 DEG C of area's temperature, 2nd area 245 DEG C of temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 255 DEG C of area's temperature, seven area's temperature 255 DEG C, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 4
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One area's temperature 240 DEG C of degree, two 245 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 255 DEG C, seven 255 DEG C of area's temperature, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 5
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One area's temperature 240 DEG C of degree, two 245 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 255 DEG C, seven 255 DEG C of area's temperature, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 6
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One area's temperature 240 DEG C of degree, two 245 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 255 DEG C, seven 255 DEG C of area's temperature, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 7
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, ABS PA757, PTW, PBS-64HW, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One area's temperature 240 DEG C of degree, two 245 DEG C of area's temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six area's temperature 255 DEG C, seven 255 DEG C of area's temperature, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 8
By AB-3000N1, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then will PET BG80, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB 944, Irganox 1010, Irganox 168 High-speed mixer mixing is added, is extruded afterwards in double screw extruder.Processing conditions is:One 240 DEG C of area's temperature, two area's temperature 245 DEG C, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 255 DEG C of area's temperature, seven 255 DEG C of area's temperature, Eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 9
By HHB-02, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then by PET BG80, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One 240 DEG C of area's temperature, 2nd area 245 DEG C of temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 255 DEG C of area's temperature, seven area's temperature 255 DEG C, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 10
By HHB-02, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then by PET BG80, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One 240 DEG C of area's temperature, 2nd area 245 DEG C of temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 255 DEG C of area's temperature, seven area's temperature 255 DEG C, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
Embodiment 11
By R103, HYFE-300, Z-6040,5-10 minutes are mixed at room temperature in super mixer;Then by PET BG80, ABS PA757, PTW, BC-52, S-05N, TINUVIN 327, CHIMASSORB944, Irganox 1010, Irganox 168 add high-speed mixer mixing, are extruded afterwards in double screw extruder.Processing conditions is:One 240 DEG C of area's temperature, 2nd area 245 DEG C of temperature, three 250 DEG C of area's temperature, four 250 DEG C of area's temperature, five 250 DEG C of area's temperature, six 255 DEG C of area's temperature, seven area's temperature 255 DEG C, eight 255 DEG C of area's temperature, nine 245 DEG C of area's temperature;350 revs/min of engine speed.
The performance test methods of embodiment 1~11 are as follows:
Notch impact strength is tested according to the standards of ISO 180, and specimen size is 80mm × 10mm × 4mm, breach A Type is molded breach.Test equipment is the Tinius Olisen shock machines of Willow Grove companies of the U.S..
Unnotched impact strength is tested according to the standards of ISO 180, and specimen size is 80mm × 10mm × 4mm, test Equipment is the Tinius Olisen shock machines of Willow Grove companies of the U.S..
Density measurement is tested according to the standards of GB 1033, is surveyed using the notch shock batten of injection with infusion process Examination, test equipment are the XS104 type Density Measuring Instruments of Mettler Toledo Inc..
Rockwell hardness is tested according to the standards of GB 9342, and specimen size is 50mm × 50mm × 6mm, and test equipment is 3106 type hardness tester testers of German ZWICK companies.
Fire resistance is tested according to the standards of UL 94, and batten size is 125mm × 13mm × 1.6mm, and test equipment is The HVUL2 type burning testers of ATLAS companies of the U.S..
The performance test results of embodiment 1~11 are as shown in table 2:
The performance test results of 2 embodiment of table 1~11
The above results show, product of the invention be with preferable impact resistance, surface high glaze, density it is larger, with The imitative ceramic flame-proof PET/ABS resin alloy compositions of certain fire resistance, making for ceramic product can be substituted in certain field With.
Above example is used for illustrative purposes only, rather than limitation of the present invention, the technology people about technical field Member, without departing from the spirit and scope of the present invention, can also make various conversion or modification, therefore all equivalent Technical scheme should also belong to scope of the invention, should be limited by each claim.

Claims (10)

1. a kind of imitative ceramic flame-proof PET/ABS resin combinations, it is characterised in that including following components and parts by weight:
A kind of 2. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that described PET classes Resin is the copolymer of terephthalic acid monomers and glycol ester monomer;The PET resin intrinsic viscosity range is 0.6~ 1.2ml/g。
A kind of 3. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that described ABS classes Resin is selected from acrylonitrile-butadiene-styrene copolymer, acrylonitrile-butadiene-acrylate copolymer, methyl methacrylate One or more of mixing in ester-BS or acrylonitrile-ethylene propylene diene rubber-styrol copolymer Thing.
A kind of 4. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that described toughness reinforcing Agent is selected from ethylene-vinyl acetate, ethylene-methyl acrylate, ethylene-ethylacrylate, Ethylene-butyl acrylate, low-density Polyethylene, maleic anhydride grafted ethene-octene copolymer, ethylene-ethylacrylate-glycidyl ester copolymer, ethylene-propylene One or more of mixing in acid butyl ester-glycidyl ester copolymer.
A kind of 5. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that the brominated resistance It is one or more of mixed in brominated Polystyrene, TDE, brominated polycarbonate, brominated epoxy etc. to fire agent Close.
A kind of 6. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that the fire-retardant association Effect agent is antimony containing compounds.
A kind of 7. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that described filling Thing is at least one of barium sulfate, zinc oxide, titanium dioxide.
A kind of 8. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that described metal Powder is selected from least one of iron powder, aluminium powder, copper powder.
A kind of 9. imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that described coupling Agent is silane coupler or titanate coupling agent;
Described weather resisting agent is the mixture of ultraviolet absorber and hindered amine as light stabilizer;
The antioxidant is the mixture of pentaerythritol ester and phosphite ester.
A kind of 10. preparation method of imitative ceramic flame-proof PET/ABS resin combinations as claimed in claim 1, it is characterised in that Comprise the following steps:
(1) raw material is prepared by following components and parts by weight:
(2) filler, metal powder, coupling agent are added in homogenizer, after stirring 5-10 minutes, by PBT resin, PET trees Fat, toughener, fire retardant, fire retarding synergist, weather resisting agent and antioxidant addition enter double screw extruder after being well mixed, and process Technique is as follows:One 230-250 DEG C of area's temperature, two 230-250 DEG C of area's temperature, three 240-260 DEG C of area's temperature, four area temperature 240- 260 DEG C, five 240-260 DEG C of area's temperature, six 240-260 DEG C of area's temperature, seven 240-260 DEG C of area's temperature, eight area temperature 240-260 DEG C, nine 240-260 DEG C of area's temperature;300-400 revs/min of engine speed;
(3) discharge, cooling, dry, pelletizing after extrusion.
CN201711249870.2A 2017-12-01 2017-12-01 A kind of imitative ceramic flame-proof PET/ABS resin combinations and preparation method thereof Pending CN107746554A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109161170A (en) * 2018-08-02 2019-01-08 宣城市聚源精细化工有限公司 A kind of processing technology of flame retardant plastics
WO2020150209A1 (en) * 2019-01-18 2020-07-23 Eastman Chemical Company Polymer compositions with improved weathering resistance

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101418111A (en) * 2008-11-14 2009-04-29 上海金发科技发展有限公司 Weather resistant halogen-free flame retardant ABS resin and preparation process thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101418111A (en) * 2008-11-14 2009-04-29 上海金发科技发展有限公司 Weather resistant halogen-free flame retardant ABS resin and preparation process thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109161170A (en) * 2018-08-02 2019-01-08 宣城市聚源精细化工有限公司 A kind of processing technology of flame retardant plastics
WO2020150209A1 (en) * 2019-01-18 2020-07-23 Eastman Chemical Company Polymer compositions with improved weathering resistance

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