CN108016054A - Carbon fibre composite is molded membranous disc manufacturing process - Google Patents

Carbon fibre composite is molded membranous disc manufacturing process Download PDF

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Publication number
CN108016054A
CN108016054A CN201711234088.3A CN201711234088A CN108016054A CN 108016054 A CN108016054 A CN 108016054A CN 201711234088 A CN201711234088 A CN 201711234088A CN 108016054 A CN108016054 A CN 108016054A
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prepreg
membranous disc
carbon fibre
fibre composite
manufacturing process
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CN201711234088.3A
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刘长喜
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • B29C70/345Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using matched moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/545Perforating, cutting or machining during or after moulding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Reinforced Plastic Materials (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

Carbon fibre composite is molded membranous disc manufacturing process.The invention discloses a kind of carbon fibre composite to be molded membranous disc manufacturing process, including the prepreg that prepreg is cut into definite shape and angle;Cleaning mold, coats releasing agent;The prepreg pre-add after cutting is heat-treated using heating platform;Laid to form the regular carbon fibre composite layer of shape;Using vacuum diaphragm bag encapsulation process, negative pressure is vacuumized;Curing is heated using baking oven;Carbon fibre composite layer is separated from mould after cooling;Cutting polishing is carried out to it, obtains the finished parts of carbon fibre composite shaping membranous disc.Membranous disc made from the method for the present invention has high-content fiber, surface-brightening bubble-free, and interfacial bonding strength reaches the effect of die press technology for forming, meets the requirement that aerospace navigational field produces carbon fiber composite material article.

Description

Carbon fibre composite is molded membranous disc manufacturing process
Technical field:
The present invention relates to a kind of carbon fibre composite to be molded membranous disc manufacturing process, more particularly to a kind of prepreg carbon fiber Composite material, that is, mold closing internally pressuring shaping technique.
Background technology:
Resin-based carbon fiber strengthens phase composite materials, and quality is lighter than metallic aluminium, but intensity is higher than steel, and with resistance to The characteristic of burn into high-modulus.With many excellent performances, the axial strength and modulus of carbon fiber are high, and density is low, higher than performance, Without creep, superhigh temperature resistant under non-oxidizing atmosphere, fatigue durability is good, and between nonmetallic between metal, heat is swollen for specific heat and electric conductivity Swollen coefficient is small and has anisotropy, good corrosion resistance, and radiolucency is good.Good electrical and thermal conductivity performance, electromagnetic wave shielding OK etc..
Die press technology for forming be in composite material production a kind of most ancient and forming method rich in unlimited vigor it be A certain amount of prepreg is added into metal in mould, heated, pressurization carrys out a kind of method of curing molding.The master of die press technology for forming It is production efficiency height to want advantage, is easy to implement specialized and automated production, can effectively reduce manufacture cost;Product size precision Height, it is reproducible;Any surface finish, without secondary modification;Can the baroque product of one-pass molding.The shortcoming of compression molding It is mold manufacturing complexity, investment is larger.With metalworking technology, press manufacture level and synthetic resin processing performance not It is disconnected to improve and develop, the forming temperature of molding compound and the relative reduction of pressure so that the productivity of compression molding product significantly carries Height, quality progressively develop to the development that becomes more meticulous, size to maximization, can produce full-sized car component, bathtub, entirety at present and defend Component etc. between life.
The content of the invention:
This is the purpose of the present invention is clearly a kind of carbon fibre composite shaping membranous disc manufacturing process, in order to solve existing skill The problem of membranous disc that light weight, intensity are high, wearability is strong can not be produced in art with carbon fibre composite, and then provide a kind of Carbon fibre composite is molded the manufacture craft of membranous disc.
Above-mentioned purpose is realized by following technical scheme:
A kind of carbon fibre composite is molded membranous disc manufacturing process, and the technique is realized by following steps:
Step 1, prepreg cutting processing procedure, including:The prepreg of web-like is assembled on rack, prepreg is being passed through Paved on latitude cutting machine and calibrate spacing, debugging cutting machine, according to laying requirement and laying the difference of angle, according to cutting machine The figure drawn is cut, and is repeated the above steps and is completed until all prepreg cloths are cut, and collects the preimpregnation cut Material;
Step 2, membranous disc mold cleaning and prepreg warm:
First, membranous disc die surface is cleared up to free from admixture attachment state using acetone, it is then, equal in membranous disc die surface The even epoxy resin release agent for coating 2-3 times, finally, the prepreg obtained using heating platform to step 1 cutting are preheated Heating operation;
Step 3, prepreg laid course, including:
Step 2 is preheated into the prepreg of after-tack according to the machine direction of design conclusion, lay on preheating heating platform Order is laid, and is extruded the bubble of interlayer along machine direction during lay, is finally paved into the regular carbon fiber composite of shape The bed of material;This kind of bubble extrusion method can effectively avoid material prepreg fiber when carrying out molding processing out of shape, made Product can guarantee that the characteristics such as its uniform, smooth, air-gap-free;
Step 4, molding processing procedure, including:
It is multiple according to PTFE release cloths, carbon fiber in membranous disc fixture after obtaining the regular carbon fibre composite layer of shape The laying order of condensation material layer and PTFE release cloths is laid, and then, is protected membranous disc mold-locked using connection clamp system Hold pressure;
Step 5, cure knockout course, including:
First, the mould of locking is put into baking oven, toasted at a temperature of 140 DEG C the curing course of 120min;So Afterwards, treat that product is cooled to 20 ± 5 DEG C, the carbon fibre composite layer is demoulded;Finally, product cut, beaten Mill and surface treatment, obtain carbon fibre composite shaping membranous disc.
Beneficial effect:
The method of the present invention specify that carbon fibre composite is molded membranous disc manufacturing process, this kind of technique has many advantages: Product intensity and modulus is high, and density is low, higher than performance, no creep, and superhigh temperature resistant under non-oxidizing atmosphere, fatigue durability is good, and heat is swollen Swollen coefficient is small and has anisotropy, good corrosion resistance.
The moulding process of the present invention processes manufactured composite material shaping membranous disc, and fiber content is up to more than 55%, table Face light bubble-free, interfacial bonding strength reach the effect of die press technology for forming, realize lighter stronger purpose, can meet boat The requirement that empty space flight navigational field produces carbon fiber composite material article.
Brief description of the drawings:
Fig. 1 is that prepreg cloth cuts processing structure schematic diagram in embodiment 1;
Fig. 2 is mold structure diagram in embodiment 1;
Fig. 3 is solidification process structure diagram in embodiment 1;
Wherein:1- prepreg cloth retractable frames, 2- vibration cutter, 3- Cutting platforms, 4- prepreg cloths;5- punch-pin, 6- molding spiral shells Bolt, 7- positioning pins, 8- cavity plates, 9- movable wedges;10- baking ovens, the mould after 11- assemblings.
Embodiment:
Embodiment one:
The carbon fibre composite shaping membranous disc manufacturing process of present embodiment, this kind of carbon fibre composite are molded membranous disc Manufacturing process, it is related to the cutting method of resin-based carbon fiber prepreg cloth, i.e., first by the assembling of web-like prepreg cloth on rack, Prepreg cloth edge and position correction mechanical structure are fixed, it is multiple fingers to be cut prepreg cloth using vibrations cutter The prepreg being sized, the prepreg cut is collected, and is repeated the above steps and is completed until all prepreg cloths are cut.
Prepreg made from the cutting method of this kind of resin-based carbon fiber prepreg cloth has thickness uniformly and accurate size, right Compactness, uniformity, the dimensional accuracy of product have very significant raising.
This kind of carbon fibre composite is molded membranous disc manufacturing process, it is related to pre- heat working technological process, i.e., in mould Non-contact thermal nearby is carried out to mould using heating equipment, mould is heated up from inside to outside uniformly.The heating process method Temperature-controllable precision can reach ± 0.2 DEG C, can effectively control mold temperature and energy loss to be less than 20%.
This kind of mould preheating heating process method has the advantage that compared with traditional infrared heating:Mould be by it is interior to Outer heating, temperature can keep stablizing and uniformly, can guarantee that interlayer gas is effectively extruded when prepreg is laid with;Non-contact thermal Temperature control it is exactly accurate, temperature-controllable precision can reach ± 0.2 DEG C, can guarantee that the viscosity and stream of resin when being laid with Dynamic property;Energy loss is less than 20%, and the security risk of operator is reduced during manufacturing.
This kind of carbon fibre composite is molded membranous disc manufacturing process, i.e., applies pretightning force, the carbon that will be cut out using mould Fibrous composite prepreg, is laid according to designed machine direction, laying order, is paved into the regular carbon fiber of shape Composite layer is positioned over mould inside, and the method for forming carbon fibre composite layer, is realized according to following steps.
The technique is realized by following steps:
Step 1, prepreg cutting processing procedure, including:The prepreg of web-like is assembled on rack, prepreg is being passed through Paved on latitude cutting machine and calibrate spacing, debugging cutting machine, according to laying requirement and laying the difference of angle, according to cutting machine The figure drawn is cut, and is repeated the above steps and is completed until all prepreg cloths are cut, and collects the preimpregnation cut Material;Prepreg made from the cutting method of this kind of resin-based carbon fiber prepreg cloth has thickness uniformly and accurate size, to product Compactness, uniformity, dimensional accuracy have very significant raising;
Step 2, membranous disc mold cleaning and prepreg warm:
First, membranous disc die surface is cleared up to free from admixture attachment state using acetone, it is then, equal in membranous disc die surface The even epoxy resin release agent for coating 2-3 times, finally, the prepreg obtained using heating platform to step 1 cutting are preheated Heating operation;
Step 3, prepreg laid course, including:
Step 2 is preheated into the prepreg of after-tack according to the machine direction of design conclusion, lay on preheating heating platform Order is laid, and is extruded the bubble of interlayer along machine direction during lay, is finally paved into the regular carbon fiber composite of shape The bed of material;This kind of bubble extrusion method can effectively avoid material prepreg fiber when carrying out molding processing out of shape, made Product can guarantee that the characteristics such as its uniform, smooth, air-gap-free;
Step 4, molding processing procedure, including:
It is multiple according to PTFE release cloths, carbon fiber in membranous disc fixture after obtaining the regular carbon fibre composite layer of shape The laying order of condensation material layer and PTFE release cloths is laid, and then, is protected membranous disc mold-locked using connection clamp system Hold pressure;
Step 5, cure knockout course, including:
First, the mould of locking is put into baking oven, toasted at a temperature of 140 DEG C the curing course of 120min;So Afterwards, treat that product is cooled to 20 ± 5 DEG C, the carbon fibre composite layer is demoulded;Finally, product cut, beaten Mill and surface treatment, obtain carbon fibre composite shaping membranous disc.Maximum stress through the forces testing product is 172.3MPa, maximum displacement compensation are 6.7mm, and maximum angle compensation is 1.8 °.
Embodiment two:
Unlike embodiment one, the carbon fibre composite shaping membranous disc manufacturing process of present embodiment, The figure drawn according to cutting machine described in step 1 is cut, and is repeated the above steps until all prepreg cloths have been cut During, prepreg is carried out by cutting processing using the cutting method of coordinate cutting machine vibrations cutter.
Embodiment three:
Unlike embodiment one or two, the carbon fibre composite shaping membranous disc manufacture work of present embodiment Skill, when the prepreg obtained using heating unit to step 1 cutting described in step 2 carries out preheating heating operation, used adds Hot charging is set to digitlization heating platform device.
Embodiment four:
Unlike embodiment three, the carbon fibre composite shaping membranous disc manufacturing process of present embodiment, It is that prepreg is heated to 29 ± 1 DEG C when the prepreg obtained to step 1 cutting described in step 2 carries out preheating heating operation.
Embodiment five:
Unlike embodiment one, two or four, the carbon fibre composite shaping membranous disc system of present embodiment Make technique, in the prepreg laid course described in step 3, membranous disc mould has cavity plate and punch-pin two parts, membranous disc mould it is convex The taper of mould is identical with the design variations amount of membranous disc.
Embodiment six:
Unlike embodiment five, the carbon fibre composite shaping membranous disc manufacturing process of present embodiment, Prepreg described in step 3 is laid according to the machine direction of design conclusion table 2, laying order, by the gas of interlayer during lay It is to extrude the bubble of interlayer along machine direction during bubble extrusion.
Embodiment seven:
Unlike embodiment one, two, four or six, the carbon fibre composite shaping membranous disc of present embodiment Manufacturing process, in the prepreg laid course described in step 3, is paved into the outer contour ruler of the regular carbon fibre composite layer of shape The very little Internal periphery size than the membranous disc mould is big 2.75mm~3.15mm.The deviation can effectively lift carbon fibre composite Deformation and packing phenomenon of the layer in heating process is cured.
Embodiment eight:
Unlike embodiment seven, the carbon fibre composite shaping membranous disc manufacturing process of present embodiment, In curing knockout course described in step 5, female die of die border is equipped with movable wedge, and when demoulding can utilize movable wedge by product Ejection.
Embodiment nine:
Unlike embodiment one, two, four, six or eight, the carbon fibre composite shaping of present embodiment Membranous disc manufacturing process, mould described in mould laying step are equipped with 4 positioning pins, 9 die bolts.
Embodiment ten:
Unlike embodiment nine, the carbon fibre composite shaping membranous disc manufacturing process of present embodiment, In molding processing procedure described in step 4, pretightning force used is during using connection clamp system, membranous disc mold-locked is operated 95-135N.Using the pretightning force in the range of this can control resin spill-out of the mould product in the solidification process of next step with Finished size is maintained in normal range (NR).
Embodiment 11:
Unlike embodiment one, two, four, six, eight or ten, the carbon fibre composite of present embodiment into Type membranous disc manufacturing process, the pretightning force are 103N.
Embodiment 12:
Unlike embodiment 11, the carbon fibre composite shaping membranous disc manufacture work of present embodiment Skill, it is described to carry out cured process according to the curing course of design using baking oven in the curing knockout course described in step 5 In, baking oven used is welded using stainless steel material, its internal internal fan makes air keep Convection states, make inside it by It is hot uniform.
Embodiment 1:
Carbon fiber epoxy prepreg cloth is 5228 carbon of SYT700S/ epoxies of Zhongfu Shenying Carbon Fiber Limited Liability Company Fiber prepreg, its one-way slabs mechanical property is as shown in table 1, is placed horizontally at Jingwei Systemtechnik Ltd. On FH-RM composite industry coordinate cutting machines, installation cutting angle is 26 ° of cutting blades, and adjustment knife depth is 42.00mm, such as Limiting devices of the Fig. 1 along fiber extending direction installation cutting equipment;And the end face of prepreg is arranged to horizontal with limiting device Edge aligns, and wide cut prepreg cloth to be cut is entirely absorbed and fixed at the work of cutting machine by the air draught fixation for opening cutting machine Table top;Using cutting process software positional dissection knife initial position and draw cutting path, start wide cut prepreg cutting Work, that is, the cutting for starting prepreg tape make;Finally the prepreg after cutting is laid on shown in Fig. 2 in mould to complete the step Suddenly.
Mould 11 in Fig. 3 is to elect No. 45 steel molds with pattern draft as, and mould is cleared up to nothing with acetone Impurity attachment state, after being evenly applied to die surface 2-3 times using epoxy resin release agent afterwards, mould is heated to 29℃±1℃。
After prepreg is carried out pre- thermal softening, prepreg is laid according to machine direction, the laying order of table 2, is spread If when every layer all the bubble of fiber interlayer is extruded with scraper plate, be paved into the regular carbon fibre composite layer of shape.
It is laid with and stops heating when completing, carbon fibre composite layer, the PTFE completed according to PTFE release cloths, lay is demoulded The order of cloth is laid to mould, is locked mould with the pretightning force of 103N using connection clamp system.
Start and debug baking oven, set it is corresponding cure course, by the mould of locking be put into baking oven with 140 DEG C/ 120min is curing course;After curing after mould is cooled to room temperature, the carbon fibre composite layer is demoulded; Cutting polishing is carried out to product, is surface-treated, obtains carbon fibre composite shaping membranous disc.Through the forces testing product Maximum stress is 172.3MPa, and maximum displacement compensation is 6.7mm, and maximum angle compensation is 1.8 °.
Table 1, one-way slabs mechanical property:
Longitudinal tensile strength 1910MPa Longitudinal tensile 130GPa
Longitudinal compressive strength 1154MPa Cross directional stretch modulus 10.3GPa
Transverse tensile strength 22MPa In-plane Shear Modulus 4.7GPa
Transverse compression intensity 150MPa Poisson's ratio 0.3
Shear strength 79MPa
Table 2, machine direction, laying order of the prepreg according to table 2, design parameter requires designed and actual use:

Claims (10)

1. a kind of carbon fibre composite is molded membranous disc manufacturing process, it is characterized in that:The technique is realized by following steps:
Step 1, prepreg cutting processing procedure, including:The prepreg of web-like is assembled on rack, prepreg is cut in longitude and latitude Paved on cutting mill and calibrate spacing, debugging cutting machine, according to laying requirement and laying the difference of angle, painted according to cutting machine The figure of system is cut, and is repeated the above steps and is completed until all prepreg cloths are cut, and collects the prepreg cut;
Step 2, membranous disc mold cleaning and prepreg warm:
First, membranous disc die surface is cleared up to free from admixture attachment state using acetone, then, is uniformly applied in membranous disc die surface The epoxy resin release agent of 2-3 times is covered, finally, the prepreg obtained using heating platform to step 1 cutting carries out preheating heating Operation;
Step 3, prepreg laid course, including:
Step 2 is preheated to the prepreg of after-tack on preheating heating platform according to machine direction, the laying order for designing conclusion Laid, the bubble of interlayer is extruded along machine direction during lay, be finally paved into the regular carbon fibre composite layer of shape;
Step 4, molding processing procedure, including:
After obtaining the regular carbon fibre composite layer of shape, according to PTFE release cloths, carbon fiber composite in membranous disc fixture The laying order of the bed of material and PTFE release cloths is laid, and then, keeps pressing by membranous disc mold-locked using connection clamp system Power;
Step 5, cure knockout course, including:
First, the mould of locking is put into baking oven, toasted at a temperature of 140 DEG C the curing course of 120min;Then, treat Product is cooled to 20 ± 5 DEG C, and the carbon fibre composite layer is demoulded;Finally, product is cut, polish and Surface treatment, obtains carbon fibre composite shaping membranous disc.
2. carbon fibre composite according to claim 1 is molded membranous disc manufacturing process, it is characterised in that:Described in step 1 The figure drawn according to cutting machine cut, repeat the above steps until by all prepreg cloths cutting complete process In, prepreg is carried out by cutting processing using the cutting method of coordinate cutting machine vibrations cutter.
3. carbon fibre composite according to claim 1 or 2 is molded membranous disc manufacturing process, it is characterised in that:Step 2 institute When the prepreg obtained using heating unit to step 1 cutting stated carries out preheating heating operation, heating unit used is number Word heating platform device.
4. carbon fibre composite according to claim 3 is molded membranous disc manufacturing process, it is characterised in that:Described in step 2 When carrying out preheating heating operation to the obtained prepreg of step 1 cutting, be that prepreg is heated to 29 ± 1 DEG C.
5. the carbon fibre composite shaping membranous disc manufacturing process according to claim 1,2 or 4, it is characterised in that:Step 3 In the prepreg laid course, membranous disc mould has cavity plate and punch-pin two parts, the taper and film of the punch-pin of membranous disc mould The design variations amount of disk is identical.
6. carbon fibre composite according to claim 5 is molded membranous disc manufacturing process, it is characterised in that:Described in step 3 Prepreg laid according to the design machine direction of conclusion, laying order, the process that when lay extrudes the bubble of interlayer In, it is to extrude the bubble of interlayer along machine direction.
7. the carbon fibre composite shaping membranous disc manufacturing process according to claim 1,2,4 or 6, it is characterised in that:Step In prepreg laid course described in rapid 3, the outer profile size of the regular carbon fibre composite layer of shape is paved into than the film Big 2.75mm~the 3.15mm of Internal periphery size of disk mould.
8. carbon fibre composite according to claim 7 is molded membranous disc manufacturing process, it is characterised in that:Described in step 4 Molding processing procedure in, pretightning force used is 95-135N during using connection clamp system, membranous disc mold-locked is operated.
9. carbon fibre composite according to claim 8 is molded membranous disc manufacturing process, it is characterised in that:The pretightning force For 103N.
10. the carbon fibre composite shaping membranous disc manufacturing process according to claim 1,2,4,6,8 or 9, its feature exist In:It is described to carry out cured process according to the curing course of design using baking oven in curing knockout course described in step 5 In, baking oven used is welded using stainless steel material, its internal internal fan makes air keep Convection states, make inside it by It is hot uniform.
CN201711234088.3A 2017-11-20 2017-11-20 Carbon fibre composite is molded membranous disc manufacturing process Pending CN108016054A (en)

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CN112873902A (en) * 2020-12-31 2021-06-01 浙江恒源洁具股份有限公司 Carbon fiber integrated basin and preparation process thereof

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CN109318507A (en) * 2018-10-23 2019-02-12 西安康本材料有限公司 A kind of big L/D ratio carbon fibre reinforced pipe production mold and forming method
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CN112210192A (en) * 2020-10-30 2021-01-12 大连交通大学 Carbon fiber composite material, unmanned aerial vehicle wing and preparation method thereof
CN112210192B (en) * 2020-10-30 2022-06-10 大连交通大学 Carbon fiber composite material, unmanned aerial vehicle wing and preparation method thereof
CN112757663A (en) * 2020-12-31 2021-05-07 中国商用飞机有限责任公司北京民用飞机技术研究中心 Automatic filament-laying forming method for continuous fiber reinforced thermoplastic composite material
CN112848371A (en) * 2020-12-31 2021-05-28 安徽佳力奇先进复合材料科技股份公司 Preparation process of carbon fiber composite rib
CN112873902A (en) * 2020-12-31 2021-06-01 浙江恒源洁具股份有限公司 Carbon fiber integrated basin and preparation process thereof

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