CN108014642A - Urea pyrolysis and wide load denitrification integrated device - Google Patents

Urea pyrolysis and wide load denitrification integrated device Download PDF

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Publication number
CN108014642A
CN108014642A CN201710932766.7A CN201710932766A CN108014642A CN 108014642 A CN108014642 A CN 108014642A CN 201710932766 A CN201710932766 A CN 201710932766A CN 108014642 A CN108014642 A CN 108014642A
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China
Prior art keywords
valves
heat exchanger
urea pyrolysis
flue
fixedly connected
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CN201710932766.7A
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Chinese (zh)
Inventor
邓伟力
刘宾
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Hunan Datang Energy-Saving Science & Technology Co Ltd
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Hunan Datang Energy-Saving Science & Technology Co Ltd
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Priority to CN201710932766.7A priority Critical patent/CN108014642A/en
Publication of CN108014642A publication Critical patent/CN108014642A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)

Abstract

Urea pyrolysis of the present invention and wide load denitrification integrated device are related to boiler technology field.Using " being integrally formed by urea pyrolysis with gas bypass " key technology, its boiler, reversal chamber, flue, which is fixedly connected, forms an entirety, the upper end fragment position of its reversal chamber, A valves, heat exchanger, suction ventilator, E valves, the front end fragment position of flue is fixedly connected by pipeline, its C valve, D valves, first threeway input end and side outlet end, the arrival end of heat exchanger interior tracheae is fixedly connected by pipeline, the port of export of its heat exchanger interior tracheae, the straight-through end of two of second threeway, heater, pyrolysis oven, the rear end fragment position of flue is fixedly connected by pipeline, the straight-through port of export of its first threeway, B valves, the side entrance end of second threeway is fixedly connected by pipeline.For urea pyrolysis and wide load denitration.Simple and ingenious structure, effect stability are reliable, easily make and cost is low.

Description

Urea pyrolysis and wide load denitrification integrated device
Technical field
Urea pyrolysis of the present invention and wide load denitrification integrated device, are related to boiler technology field;Urinated more particularly to boiler Element pyrolysis and wide load denitrification integrated device technical field.
Background technology
Thermal power generation unit has gas gas in the stove based on flue gas heater technical flow to change in urea pyrolysis technology at present Hot device technology, have in wide load denitration mainstream technology high-temperature flue gas bypass connect to draw method, which is required in boiler height Warm smoke-gas area perforate and job position is essentially identical, so two kinds of technologies can not be at the same time same due to job position conflict Realized on platform boiler.So existing known technology is obvious with deficiency, defect and drawback existing for present situation.Based on hair The professional knowledge of a person of good sense and working experience and the unremitting pursuit to cause, have in conscientiously investigation, analysis, understanding, summary, research On the basis of known technology and present situation, spy takes " being integrally formed by urea pyrolysis with gas bypass " key technology, succeeds in developing The new equipment of " urea pyrolysis and wide load denitrification integrated device ".The present invention's succeeds in developing, and effectively solves existing public affairs Know technology and deficiency, defect and drawback existing for present situation, effectively raise the technical merit of the industry.
The content of the invention
The present invention takes " being integrally formed by urea pyrolysis with gas bypass " key technology, its boiler, reversal chamber, flue are solid Surely an entirety, the upper end fragment position of its reversal chamber, A valves, heat exchanger, suction ventilator, E valves, the front end section of flue are connected and composed Put and be fixedly connected by pipeline, its C valve, D valves, first threeway input end and side outlet end, the arrival end of heat exchanger interior tracheae Be fixedly connected by pipeline, the port of export of its heat exchanger interior tracheae, two of second threeway straight-through ends, heater, pyrolysis oven, The rear end fragment position of flue is fixedly connected by pipeline, the straight-through port of export of its first threeway, B valves, the side of second threeway It is fixedly connected to arrival end by pipeline.
It is by the purpose of the invention reached:1., the present invention take " being integrally formed by urea pyrolysis with gas bypass " close Key technology, there is provided the new equipment of " urea pyrolysis and wide load denitrification integrated device ".2., the present invention take " by urea heat Solution is integrally formed with gas bypass " key technology, solve the problems, such as that two kinds of technologies are difficult to while are used on a unit, together When urea pyrolysis flue gas air passage and SCR bypass flues are combined into one, avoid repeated construction, reduce cost of investment; By taking separate unit 300MW units as an example, single unit investment can reduce by 3,000,000 yuan or so.The present invention can ensure thermal power generation unit It can be connect at the same time using high-temperature flue gas bypass and draw method and flue gas urea pyrolysis method, the out of stock operations of boiler SCR can be widened Load setting, while ensure that SCR reducing agents urea can use flue gas method, avoids existing known technology and present situation High operating cost.3., behind the out of stock operating load sections of present invention broadening boiler SCR, boiler can be made when compared with underload(Very To be grid-connected when)SCR reactors can be put into, so as to reduce NOXDischarge, reduce acid rain occurrence probability, possess very well Environmental protection and social benefit.4., ingenious, the easy to use and effect stability scientific and reasonable for structure and simple of the present invention it is reliable, easily In make with use and cost of manufacture and operation cost it is low, with science, advance, accuracy, representativeness, practicality. 5., the present invention solve existing for existing known technology and present situation deficiency, defect and drawback.6., the present invention succeed in developing, have The technical merit for having brought up to the industry of effect, can wide popularization and application.
To achieve the above object, technical solution provided by the invention is:
A kind of urea pyrolysis and wide load denitrification integrated device, by A valves, heat exchanger, B valves, heater, pyrolysis oven, C valves, D Valve, E valves, suction ventilator, flue, boiler, reversal chamber are formed;
The urea pyrolysis and wide load denitrification integrated device, it is whole that its boiler, reversal chamber, flue are fixedly connected with composition one Body, upper end fragment position, A valves, heat exchanger, suction ventilator, E valves, the front end fragment position of flue of its reversal chamber are fixed by pipeline and connected Connecing, its C valve, D valves, first threeway input end and side outlet end, the arrival end of heat exchanger interior tracheae are fixedly connected by pipeline, The port of export of its heat exchanger interior tracheae, two of second threeway straight-through ends, heater, pyrolysis oven, the rear end fragment positions of flue It is fixedly connected by pipeline, the straight-through port of export of its first threeway, B valves, the side entrance end of second threeway are by pipeline It is fixedly connected.
The urea pyrolysis and wide load denitrification integrated device, the A valves are the heat exchanger to be exchanged heat in a manner of gas gas The flapper valve of the heat-resisting material of import, for the heat exchanger to be provided with the structure of tracheae in housing, the B valves are cold wind tune The electronic adjustment valve of bypass is saved, for the heater to be provided with the electric heater of resistance wire in housing, the pyrolysis oven is housing The structure of nozzle is inside provided with, the C valves dilute the pneumatic Shuttoff Valve of wind for import, and the D valves dilute the electronic of wind for mouth Valve is adjusted, the E valves are the outlet damper valve of heat exchanger, and the suction ventilator is frequency conversion fan, and the flue is justified for selection A kind of structure in shape structure, polygonized structure, the boiler are the boiler for power generation, and the reversal chamber is denitration entrance cigarette A kind of structure in road and selection circular configuration, polygonized structure.
The urea pyrolysis and wide load denitrification integrated device, the A valves, heat exchanger, suction ventilator, the common structure of E valves Into gas bypass device.
The urea pyrolysis and wide load denitrification integrated device, the heat exchanger, B valves, heater, pyrolysis oven, C Valve, D valves collectively form urea pyrolysis device.
The urea pyrolysis and wide load denitrification integrated device, the heat exchanger is in the urea pyrolysis and wide load In denitrification integrated device, belong to the shared device of the gas bypass device and the urea pyrolysis device, it is described to change Hot device role is the effect for passing through flue gas and gives the heat transfer extracted in flue gas to dilution wind action.
The present invention operation principle and the course of work be:As shown in Figure of description 1, operation principle of the invention and work Process is extremely simple to be understood, the present invention has given full play to the work of " being integrally formed by urea pyrolysis with gas bypass " key technology With.In the urea pyrolysis and wide load denitrification integrated device, the A valves 1, heat exchanger 2, suction ventilator 9, E valves 8 are common Gas bypass device is formed, when the temperature of flue 10 is less than 320 DEG C, A valves 1, heat exchanger 2, suction ventilator 9, E valves 8 are opened entirely, and Control the flow of suction ventilator 9 will height;When the temperature of flue 10 is higher than 320 DEG C, A valves 1, heat exchanger 2, suction ventilator 9, E valves 8 are also complete Open, and control the flow of suction ventilator 9 low.It is described to change in the urea pyrolysis and wide load denitrification integrated device Hot device 2, B valves 3, heater 4, pyrolysis oven 5, C valves 6, D valves 7 collectively form urea pyrolysis device, in the urea pyrolysis device In, 2 role of heat exchanger is the effect to dilution wind heating;In the urea pyrolysis device, for B valves 3 just Be dilute wind by heat exchanger 2 temperature it is high, turn on B valves 3, dilution wind by heat exchanger 2 temperature it is low, be shut off B Valve 3;In the urea pyrolysis device, for heater 4, if dilution wind still reached to after heat exchanger 2 less than The requirement of temperature, just start heater 4, if dilution wind reached by heat exchanger 2 after temperature requirement, if do not start add Hot device 4.In the urea pyrolysis and wide load denitrification integrated device, heat exchanger 2 belongs to gas bypass device and urea The shared device of pyrolysis installation, 2 role of heat exchanger are the effect for passing through flue gas and the heat that will be extracted in flue gas Amount passes to dilution wind action.Design is scientific and reasonable by the present invention, simple and ingenious structure, is easy to low manufacture cost, uses effect Fruit is reliable and stable, solves existing known technology and deficiency, defect and drawback existing for present situation, has effectively brought up to the industry Technical merit.
As a result of technical solution provided by the present invention;Since this invention takes " by urea pyrolysis and flue gas Road is integrally formed " key technology;Due to described in the operation principle and the course of work of the present invention;Due to its boiler of the invention, turn to Room, flue are fixedly connected forms an entirety, the upper end fragment position of its reversal chamber, A valves, heat exchanger, suction ventilator, E valves, flue Front end fragment position is fixedly connected by pipeline, its C valve, D valves, first threeway input end and side outlet end, heat exchanger interior tracheae Arrival end be fixedly connected by pipeline, the port of export of its heat exchanger interior tracheae, two of second threeway straight-through ends, heating Device, pyrolysis oven, the rear end fragment position of flue are fixedly connected by pipeline, the straight-through port of export of its first threeway, B valves, second The side entrance end of a threeway is fixedly connected by pipeline.So that it is of the invention with existing known technology compared with present situation, acquisition Beneficial effect is:
1st, the present invention takes " being integrally formed by urea pyrolysis with gas bypass " key technology, so as to provide " urea pyrolysis and The new equipment of wide load denitrification integrated device ".
2nd, the present invention takes " being integrally formed by urea pyrolysis with gas bypass " key technology, solves two kinds of technologies and is difficult to At the same time used on a unit the problem of, while urea pyrolysis flue gas air passage and SCR bypass flues are combined into one, kept away Exempt from repeated construction, reduce cost of investment;By taking separate unit 300MW units as an example, investment can reduce by 3,000,000 yuan or so.
3rd, the present invention can ensure that thermal power generation unit can be connect using high-temperature flue gas bypass at the same time and be drawn method and flue gas Urea pyrolysis method, can widen the out of stock operating load sections of boiler SCR, while ensure that SCR reducing agents urea can use Flue gas method, avoids the high operating cost of existing known technology and present situation.
4th, behind operating load section out of stock present invention broadening boiler SCR, boiler can be made when compared with underload(Even When grid-connected)SCR reactors can be put into, so as to reduce NOXDischarge, reduce acid rain occurrence probability, possess good ring Guarantor and social benefit.
5th, scientific and reasonable for structure and simple ingenious, easy to use and effect stability of the invention is reliable, easy to make with making With and cost of manufacture and operation cost it is low, have science, advance, accuracy, representativeness, practicality.
6th, the present invention solves the deficiency, defect and drawback of existing known technology and present situation.
7th, the present invention has effectively improved industry technical merit, can wide popularization and application.
Brief description of the drawings
Fig. 1 is the schematic diagram of the specific embodiment of the invention.
Label in figure:1st, A valves, 2, heat exchanger, 3, B valves, 4, heater, 5, pyrolysis oven, 6, C valves, 7, D valves, 8, E valves, 9th, suction ventilator, 10, flue .11, boiler, 12, reversal chamber.
Embodiment
With reference to Figure of description, the present invention is described in detail.As shown in Figure of description 1:
A kind of urea pyrolysis and wide load denitrification integrated device, by A valves 1, heat exchanger 2, B valves 3, heater 4, pyrolysis oven 5, C Valve 6, D valves 7, E valves 8, suction ventilator 9, flue 10, boiler 11, reversal chamber 12 are formed;
The urea pyrolysis and wide load denitrification integrated device, its boiler 11, reversal chamber 12, flue 10 are fixedly connected with composition one A entirety, upper end fragment position, A valves 1, heat exchanger 2, suction ventilator 9, E valves 8, the front end fragment position of flue 10 of its reversal chamber 12 are equal It is fixedly connected by pipeline, its C valve 6,7, first threeway input ends of D valves and side outlet end, the arrival end of 2 interior tracheae of heat exchanger are equal It is fixedly connected by pipeline, the port of export of its 2 interior tracheae of heat exchanger, two of second threeway straight-through ends, heater 4, pyrolysis ovens 5th, the rear end fragment position of flue 10 is fixedly connected by pipeline, 3, second threeways of the straight-through port of export, B valves of its first threeway Side entrance end be fixedly connected by pipeline.
The urea pyrolysis and wide load denitrification integrated device, the A valves 1 are the heat exchanger to be exchanged heat in a manner of gas gas The flapper valve of the heat-resisting material of import, for the heat exchanger 2 to be provided with the structure of tracheae in housing, the B valves 3 are cold wind The electronic adjustment valve of bypass is adjusted, to be provided with the electric heater of resistance wire in housing, the pyrolysis oven 5 is the heater 4 The structure of nozzle is provided with housing, the C valves 6 dilute the pneumatic Shuttoff Valve of wind for import, and the D valves 7 dilute wind for mouth Electronic adjustment valve, the E valves 8 are the outlet damper valve of heat exchanger, and the suction ventilator 9 is frequency conversion fan, the flue 10 be selection circular configuration, a kind of structure in polygonized structure, and the boiler 11 is the boiler for power generation, the reversal chamber 12 be a kind of structure in denitration gas approach and selection circular configuration, polygonized structure.
The urea pyrolysis and wide load denitrification integrated device, the A valves 1, heat exchanger 2, suction ventilator 9, E valves 8 is common With composition gas bypass device.
The urea pyrolysis and wide load denitrification integrated device, the heat exchanger 2, B valves 3, heater 4, pyrolysis oven 5th, C valves 6, D valves 7 collectively form urea pyrolysis device.
The urea pyrolysis and wide load denitrification integrated device, the heat exchanger 2 are negative in the urea pyrolysis and width In lotus denitrification integrated device, belong to the shared device of the gas bypass device and the urea pyrolysis device, it is described 2 role of heat exchanger is the effect for passing through flue gas and gives the heat transfer extracted in flue gas to dilution wind action.
The urea pyrolysis and wide load denitrification integrated device, it is relatively large due to being carried in 12 high-temperature flue gas of reversal chamber Dust, therefore be internally provided with soot blower in heat exchanger 2.
The foregoing is merely presently preferred embodiments of the present invention, not makees limitation in any form to the present invention;All one's own professions The those of ordinary skill of industry, can be shown in by specification attached drawing and described above and swimmingly implement the present invention;But do not departing from Technical solution of the present invention and the equivalent variations for making differentiation, are the equivalent embodiment of the present invention, still fall within protection of the present invention Technical solution.

Claims (5)

1. a kind of urea pyrolysis and wide load denitrification integrated device, it is characterised in that:By A valves(1), heat exchanger(2), B valves (3), heater(4), pyrolysis oven(5), C valves(6), D valves(7), E valves(8), suction ventilator(9), flue(10), boiler(11), turn to Room(12)Form;
The urea pyrolysis and wide load denitrification integrated device, its boiler(11), reversal chamber(12), flue(10)It is fixedly connected Form an entirety, its reversal chamber(12)Upper end fragment position, A valves(1), heat exchanger(2), suction ventilator(9), E valves(8), flue (10)Front end fragment position be fixedly connected by pipeline, its C valve(6), D valves(7), first threeway input end and side outlet end, Heat exchanger(2)The arrival end of interior tracheae is fixedly connected by pipeline, its heat exchanger(2)The port of export of interior tracheae, second threeway Two straight-through ends, heaters(4), pyrolysis oven(5), flue(10)Rear end fragment position be fixedly connected by pipeline, it first The straight-through port of export, the B valves of a threeway(3), second threeway side entrance end be fixedly connected by pipeline.
2. urea pyrolysis according to claim 1 and wide load denitrification integrated device, it is characterised in that:The A valves(1) Flapper valve for the heat-resisting material of heat exchanger import to be exchanged heat in a manner of gas gas, the heat exchanger(2)To be set in housing There are the structure of tracheae, the B valves(3)The electronic adjustment valve of bypass, the heater are adjusted for cold wind(4)To be provided with housing The electric heater of resistance wire, the pyrolysis oven(5)To be provided with the structure of nozzle, the C valves in housing(6)Wind is diluted for import Pneumatic Shuttoff Valve, the D valves(7)The electronic adjustment valve of wind, the E valves are diluted for mouth(8)For the exit catch of heat exchanger Plate valve door, the suction ventilator(9)For frequency conversion fan, the flue(10)For one kind in selection circular configuration, polygonized structure Structure, the boiler(11)For the boiler for power generation, the reversal chamber(12)For denitration gas approach and selection circular configuration, A kind of structure in polygonized structure.
3. urea pyrolysis according to claim 1 and wide load denitrification integrated device, it is characterised in that:The A valves (1), heat exchanger(2), suction ventilator(9), E valves(8)Collectively form gas bypass device.
4. urea pyrolysis according to claim 1 and wide load denitrification integrated device, it is characterised in that:The heat exchanger (2), B valves(3), heater(4), pyrolysis oven(5), C valves(6), D valves(7)Collectively form urea pyrolysis device.
5. urea pyrolysis according to claim 1 and wide load denitrification integrated device, it is characterised in that:The heat exchanger (2)In the urea pyrolysis and wide load denitrification integrated device, belong to gas bypass device and the institute of the claim 3 State the shared device of the urea pyrolysis device of claim 4, the heat exchanger(2)Role is the effect for passing through flue gas And give the heat transfer extracted in flue gas to dilution wind action.
CN201710932766.7A 2017-10-10 2017-10-10 Urea pyrolysis and wide load denitrification integrated device Pending CN108014642A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108816020A (en) * 2018-06-08 2018-11-16 湖南大唐节能科技有限公司 A kind of full load combined denitration optimal control method
CN109453665A (en) * 2018-10-16 2019-03-12 中国华电科工集团有限公司 A kind of urea liquid pyrolysis installation and method applied to denitrating system
CN114288852A (en) * 2022-02-16 2022-04-08 西安西热锅炉环保工程有限公司 Wide-load coal-fired boiler denitration system and working method thereof
CN115475513A (en) * 2022-09-28 2022-12-16 马鞍山钢铁股份有限公司 SCR denitration pyrolysis furnace air inlet temperature regulation and control device and regulation and control method thereof

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN204873861U (en) * 2015-06-08 2015-12-16 大唐环境产业集团股份有限公司 Denitration urea pyrolysis device with heat source switches function
CN106370034A (en) * 2016-08-30 2017-02-01 哈尔滨锅炉厂有限责任公司 Flue gas heat exchange system for urea pyrolysis
CN206424766U (en) * 2016-10-20 2017-08-22 北京巴布科克·威尔科克斯有限公司 A kind of wide load urea direct-injection pyrolysis smoke denitrating system of boiler
CN207445987U (en) * 2017-10-10 2018-06-05 湖南大唐节能科技有限公司 Urea pyrolysis and wide load denitrification integrated device

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN204873861U (en) * 2015-06-08 2015-12-16 大唐环境产业集团股份有限公司 Denitration urea pyrolysis device with heat source switches function
CN106370034A (en) * 2016-08-30 2017-02-01 哈尔滨锅炉厂有限责任公司 Flue gas heat exchange system for urea pyrolysis
CN206424766U (en) * 2016-10-20 2017-08-22 北京巴布科克·威尔科克斯有限公司 A kind of wide load urea direct-injection pyrolysis smoke denitrating system of boiler
CN207445987U (en) * 2017-10-10 2018-06-05 湖南大唐节能科技有限公司 Urea pyrolysis and wide load denitrification integrated device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108816020A (en) * 2018-06-08 2018-11-16 湖南大唐节能科技有限公司 A kind of full load combined denitration optimal control method
CN109453665A (en) * 2018-10-16 2019-03-12 中国华电科工集团有限公司 A kind of urea liquid pyrolysis installation and method applied to denitrating system
CN114288852A (en) * 2022-02-16 2022-04-08 西安西热锅炉环保工程有限公司 Wide-load coal-fired boiler denitration system and working method thereof
CN115475513A (en) * 2022-09-28 2022-12-16 马鞍山钢铁股份有限公司 SCR denitration pyrolysis furnace air inlet temperature regulation and control device and regulation and control method thereof

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Application publication date: 20180511