CN108003723A - A kind of high durable, high endurance automotive hub coating varnish and preparation method thereof - Google Patents
A kind of high durable, high endurance automotive hub coating varnish and preparation method thereof Download PDFInfo
- Publication number
- CN108003723A CN108003723A CN201711308969.5A CN201711308969A CN108003723A CN 108003723 A CN108003723 A CN 108003723A CN 201711308969 A CN201711308969 A CN 201711308969A CN 108003723 A CN108003723 A CN 108003723A
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- CN
- China
- Prior art keywords
- automotive hub
- coating varnish
- endurance
- hub coating
- butyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high durable, high endurance automotive hub coating varnish, include the component of following mass percent：35 ~ 55% thermosetting acrylic resin, 5 ~ 15% epoxide modified epoxy resin, 15 ~ 20% second etherified amino resins, 1 ~ 5% enclosed type diisocyanate resin, 3 ~ 5% n-butanols, 1 ~ 3% environment-friendly type light stabilizer, 1 ~ 3% binary acid lipoprotein mixture, 5 ~ 10% n-butyl acetate, 0.02 ~ 0.5% levelling agent, 0.02 ~ 0.5% defoamer.Meanwhile the invention also discloses the preparation method of above-mentioned coating varnish.The present invention is compared with conventional art, outside the general performance requirement met needed for automotive hub while solve the problems, such as the weatherability of client, endurance, it is resistance to QUV agings, the lamp of resistance to hernia aging, acidproof, alkaline-resisting, salt spray resistance, resistance to card examination, resistance to dimethylbenzene, water-fast, easy-to-use, easy for construction.
Description
Technical field
The invention belongs to chemistry painting industry field, and in particular to a kind of high durable, high endurance automotive hub coating varnish
And preparation method thereof.
Background technology
Finishing varnish is commonly called as gloss oil, there is very high frequency of use in modelling.Commonly used in civilian model, finished goods is improved
Brightness.Complete in full car, after posting note paper, according to 1:3 ratio is blended into solvent dilution, uniformly sprays in car
Surface, several times after, it is possible to obtain satisfied result.Automobile Coatings are generally by high-weatherability hydroxy acryl acid
Resin, special addition agent and organic solvent are dispersed through modulation and form, and are two-component product.It need to be matched during construction with curing agent.
Key property is transparency height, and gloss is high, and weather resistance is excellent, and adhesive force is good, and hardness is high, and richness is good, and excellent is water-fast, resistance to
Gasoline, chemical resistance, can from it is dry also can low temperature drying, it is mainly used for medium and high classes automobile, palace car, station wagon etc.
The surface Lacquer finish paint of advanced vehicle.Traditional Automobile Coatings modulation is complicated, and water resistance is poor, resistance to acid and alkali reaches all the time
Less than theoretical value, more troublesome is that the construction needs that get up are repeated several times coating.
The content of the invention
Goal of the invention：In view of the above-mentioned deficiencies in the prior art, it is an object of the present invention to provide a kind of high durable, high endurance vapour
Wheel hub coating varnish.
Another object of the present invention is to provide the preparation method of above-mentioned coating varnish.
Technical solution：In order to reach foregoing invention purpose, the present invention is specifically achieved like this：A kind of high durable, height
Endurance automotive hub coating varnish, includes the component of following mass percent：35 ~ 55% thermosetting acrylic resin, 10
~ 20% epoxide modified epoxy resin, 15 ~ 20% second etherified amino resins, 1 ~ 5% enclosed type diisocyanate resin, 3 ~ 5% positive fourths
Alcohol, 1 ~ 3% environment-friendly type light stabilizer, 1 ~ 3% binary acid lipoprotein mixture, 5 ~ 10% n-butyl acetate, 0.02 ~ 0.5% levelling agent,
0.02 ~ 0.5% defoamer.
Wherein, thermosetting acrylic resin solid content >=70%, remaining is n-butyl acetate and isobutanol.
Wherein, epoxy modified resin solid content >=70%, remaining is n-butanol and butyl glycol ether.
Wherein, second etherified amino resins solid content >=60%, remaining is isobutanol.
Wherein, enclosed type diisocyanate resin solid content >=60%, remaining is n-butyl acetate.
Wherein, the light stabilizer belongs to hydroxyl pyrrolotriazine derivatives, solid content 100% for vapour bar Ciba TINUVIN400.
Wherein, the levelling agent is polyether modified siloxane solution, its concentration >=52%.
Wherein, the defoamer for BYK-A501 alkylbenzenes PMA solution, its concentration >=44%.
The high durable, the method for high endurance automotive hub coating varnish are prepared, is comprised the following steps：
（1）By the thermosetting acrylic resin of formula ratio, epoxy modified resin, second etherified amino resins and enclosed type diisocyanate
Ester is added in painting cylinder, is stirred 15 ~ 20 minutes under 500 ~ 1000 revs/min of rotating speeds；
（2）The defoamer, wetting agent and defoamer of formula ratio are walked into addition suddenly（1）Solution in, in 500 ~ 800 revs/min of rotating speeds
Lower mixing time 10 ~ 15 minutes；
（3）The light stabilizer of formula ratio is individually disperseed with the n-butyl acetate of formula ratio half under 300 ~ 500 revs/min of stirrings
Uniformly；
（4）Will be finely dispersed（3）Added under 500 ~ 800 revs/min of stirrings（1）With（2）In mixture, mixing time 10 ~ 15
Minute；
（5）Remaining n-butyl acetate is eventually adding, is stirred 20-30 minutes at 600-900 revs/min, packaging.
Beneficial effect：The present invention is compared with conventional art, outside the general performance requirement met needed for automotive hub at the same time
Solve the problems, such as weatherability, the endurance of client, resistance to QUV agings, the lamp of resistance to hernia aging, acidproof, alkaline-resisting, salt spray resistance, resistance to card try, are resistance to
It is dimethylbenzene, water-fast, easy-to-use, easy for construction.
Embodiment
Embodiment 1：
Take following components stand-by by mass percentage：35% thermosetting acrylic resin, 20% epoxide modified epoxy resin,
20% second etherified amino resins, 5% enclosed type diisocyanate resin, 5% n-butanol, 1% environment-friendly type light stabilizer, 3% binary acid fat mix
Compound, 10% n-butyl acetate, 0.5% levelling agent, 0.5% defoamer；By thermosetting acrylic resin, epoxide modified tree
Fat, second etherified amino resins and blocked diisocyanates are added in painting cylinder, stir 15 under 500 ~ 1000 revs/min of rotating speeds ~
20 minutes, defoamer, wetting agent and defoamer are continuously added, 10 ~ 15 minutes shapes of mixing time under 500 ~ 800 revs/min of rotating speeds
Into mixture；By light stabilizer individually with n-butyl acetate 300 ~ 500 revs/min stirring under be uniformly dispersed, 500 ~ 800 turns/
Divide stirring is lower to add in mixture, mixing time 10 ~ 15 minutes；Be eventually adding remaining n-butyl acetate, 600-900 turn/
Divide stirring 20-30 minutes, packaging.
Embodiment 2：
Take following components stand-by by mass percentage：55% thermosetting acrylic resin, 15% epoxide modified epoxy resin,
17% second etherified amino resins, 1% enclosed type diisocyanate resin, 3% n-butanol, 3% environment-friendly type light stabilizer, 1% binary acid fat mix
Compound, 9.96% n-butyl acetate, 0.02% levelling agent, 0.02% defoamer；Thermosetting acrylic resin, epoxy are changed
Property resin, second etherified amino resins and blocked diisocyanates add in painting cylinder, stirred under 500 ~ 1000 revs/min of rotating speeds
15 ~ 20 minutes, defoamer, wetting agent and defoamer are continuously added, mixing time 10 ~ 15 minutes under 500 ~ 800 revs/min of rotating speeds
Form mixture；Light stabilizer is individually uniformly dispersed with n-butyl acetate under 300 ~ 500 revs/min of stirrings, 500 ~ 800
Rev/min stirring is lower adds in mixture, mixing time 10 ~ 15 minutes；Remaining n-butyl acetate is eventually adding, in 600-900
Rev/min stirring 20-30 minute, pack.
Embodiment 3：
Take following components stand-by by mass percentage：40% thermosetting acrylic resin, 15% epoxide modified epoxy resin,
20% second etherified amino resins, 4% enclosed type diisocyanate resin, 4% n-butanol, 3% environment-friendly type light stabilizer, 3% binary acid fat mix
Compound, 10% n-butyl acetate, 0.5% levelling agent, 0.5% defoamer；By thermosetting acrylic resin, epoxide modified tree
Fat, second etherified amino resins and blocked diisocyanates are added in painting cylinder, stir 15 under 500 ~ 1000 revs/min of rotating speeds ~
20 minutes, defoamer, wetting agent and defoamer are continuously added, 10 ~ 15 minutes shapes of mixing time under 500 ~ 800 revs/min of rotating speeds
Into mixture；By light stabilizer individually with n-butyl acetate 300 ~ 500 revs/min stirring under be uniformly dispersed, 500 ~ 800 turns/
Divide stirring is lower to add in mixture, mixing time 10 ~ 15 minutes；Be eventually adding remaining n-butyl acetate, 600-900 turn/
Divide stirring 20-30 minutes, packaging.
Embodiment 4：
Take following components stand-by by mass percentage：45% thermosetting acrylic resin, 20% epoxide modified epoxy resin,
15% second etherified amino resins, 5% enclosed type diisocyanate resin, 5% n-butanol, 2% environment-friendly type light stabilizer, 1% binary acid fat mix
Compound, 6% n-butyl acetate, 0.5% levelling agent, 0.5% defoamer；By thermosetting acrylic resin, epoxide modified tree
Fat, second etherified amino resins and blocked diisocyanates are added in painting cylinder, stir 15 under 500 ~ 1000 revs/min of rotating speeds ~
20 minutes, defoamer, wetting agent and defoamer are continuously added, 10 ~ 15 minutes shapes of mixing time under 500 ~ 800 revs/min of rotating speeds
Into mixture；By light stabilizer individually with n-butyl acetate 300 ~ 500 revs/min stirring under be uniformly dispersed, 500 ~ 800 turns/
Divide stirring is lower to add in mixture, mixing time 10 ~ 15 minutes；Be eventually adding remaining n-butyl acetate, 600-900 turn/
Divide stirring 20-30 minutes, packaging.
Claims (9)
1. a kind of high durable, high endurance automotive hub coating varnish, it is characterised in that include the group of following mass percent
Point：35 ~ 55% thermosetting acrylic resin, 10 ~ 20% epoxide modified epoxy resin, 15 ~ 20% second etherified amino resins, 1
~ 5% enclosed type diisocyanate resin, 3 ~ 5% n-butanols, 1 ~ 3% environment-friendly type light stabilizer, 1 ~ 3% binary acid lipoprotein mixture, 5 ~ 10%
N-butyl acetate, 0.02 ~ 0.5% levelling agent, 0.02 ~ 0.5% defoamer.
2. high durable according to claim 1, high endurance automotive hub coating varnish, it is characterised in that the heat
Solidity acrylic resin solid content >=70%, remaining is n-butyl acetate and isobutanol.
3. high durable according to claim 1, high endurance automotive hub coating varnish, it is characterised in that the ring
Oxygen modified resin solid content >=70%, remaining is n-butanol and butyl glycol ether.
4. high durable according to claim 1, high endurance automotive hub coating varnish, it is characterised in that the second
Etherified amino resins solid content >=60%, remaining is isobutanol.
5. high durable according to claim 1, high endurance automotive hub coating varnish, it is characterised in that the envelope
Closed form diisocyanate resin solid content >=60%, remaining is n-butyl acetate.
6. high durable according to claim 1, high endurance automotive hub coating varnish, it is characterised in that the light
Stabilizer is hydroxyl pyrrolotriazine derivatives, solid content 100%.
7. high durable according to claim 1, high endurance automotive hub coating varnish, it is characterised in that the stream
Flat agent is polyether modified siloxane solution, its concentration >=52%.
8. high durable according to claim 1, high endurance automotive hub coating varnish, it is characterised in that described to disappear
Infusion for alkylbenzene PMA solution, its concentration >=44%.
9. prepare high durable, the method for high endurance automotive hub coating varnish described in claim 1, it is characterised in that bag
Include following steps：
（1）By the thermosetting acrylic resin of formula ratio, epoxy modified resin, second etherified amino resins and enclosed type diisocyanate
Ester is added in painting cylinder, is stirred 15 ~ 20 minutes under 500 ~ 1000 revs/min of rotating speeds；
（2）The defoamer, wetting agent and defoamer of formula ratio are walked into addition suddenly（1）Solution in, in 500 ~ 800 revs/min of rotating speeds
Lower mixing time 10 ~ 15 minutes；
（3）The light stabilizer of formula ratio is individually disperseed with the n-butyl acetate of formula ratio half under 300 ~ 500 revs/min of stirrings
Uniformly；
（4）Will be finely dispersed（3）Added under 500 ~ 800 revs/min of stirrings（1）With（2）In mixture, mixing time 10 ~ 15
Minute；
（5）The n-butyl acetate of remaining part is eventually adding, is stirred 20-30 minutes at 600-900 revs/min, packaging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711308969.5A CN108003723A (en) | 2017-12-11 | 2017-12-11 | A kind of high durable, high endurance automotive hub coating varnish and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711308969.5A CN108003723A (en) | 2017-12-11 | 2017-12-11 | A kind of high durable, high endurance automotive hub coating varnish and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108003723A true CN108003723A (en) | 2018-05-08 |
Family
ID=62058142
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711308969.5A Pending CN108003723A (en) | 2017-12-11 | 2017-12-11 | A kind of high durable, high endurance automotive hub coating varnish and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108003723A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108944828A (en) * | 2018-06-12 | 2018-12-07 | 广西速道汽车维修服务有限公司 | A kind of method of restoring automobile wheel hub scratch |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293047A (en) * | 2014-10-31 | 2015-01-21 | 成都锦汇科技有限公司 | Acrylic acid amino stoving varnish |
-
2017
- 2017-12-11 CN CN201711308969.5A patent/CN108003723A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104293047A (en) * | 2014-10-31 | 2015-01-21 | 成都锦汇科技有限公司 | Acrylic acid amino stoving varnish |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108944828A (en) * | 2018-06-12 | 2018-12-07 | 广西速道汽车维修服务有限公司 | A kind of method of restoring automobile wheel hub scratch |
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| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180508 |
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| RJ01 | Rejection of invention patent application after publication |