CN108002546A - Heavy metal removing water quality restoration agent - Google Patents

Heavy metal removing water quality restoration agent Download PDF

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Publication number
CN108002546A
CN108002546A CN201711297422.XA CN201711297422A CN108002546A CN 108002546 A CN108002546 A CN 108002546A CN 201711297422 A CN201711297422 A CN 201711297422A CN 108002546 A CN108002546 A CN 108002546A
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CN
China
Prior art keywords
parts
weight
sodium
water quality
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711297422.XA
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Chinese (zh)
Inventor
李宗科
王凯
张小岗
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhongshan Lyulang Additives Co ltd
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Zhongshan Lyulang Additives Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Zhongshan Lyulang Additives Co ltd filed Critical Zhongshan Lyulang Additives Co ltd
Priority to CN201711297422.XA priority Critical patent/CN108002546A/en
Publication of CN108002546A publication Critical patent/CN108002546A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention provides a heavy metal removal water quality restoration agent which is prepared from the following raw materials in parts by weight: 5-8 parts of ferric chloride, 13-16 parts of sodium carbonate, 10-12 parts of sodium percarbonate, 12-14 parts of polyaluminum chloride, 3-5 parts of polyacrylamide, 2-3 parts of calcium hydroxide, 6-8 parts of bacillus pumilus and 8-12 parts of polymerized iron silicate, and compared with the prior art, the invention has the following beneficial effects: aiming at various industrial sewage, when physical equipment such as a solid-liquid separator, an air flotation machine and the like is applied to sewage treatment, the purifying agent can be used for carrying out solid-liquid separation and liquid-liquid separation on the sewage within 3-10 minutes to produce clear water, is efficient and rapid, can effectively decompose organic pollutants in water and bottom mud, and can reduce heavy metals in the water to form compounds without pollution or with light pollution degree, so that the mobility and bioavailability of the heavy metals in the water are reduced, and the pollution of the heavy metals to the water is reduced.

Description

A kind of duplicate removal metal water quality renovation agent
Technical field
The present invention is a kind of duplicate removal metal water quality renovation agent, belongs to a kind of cleanser of sewage disposal.
Background technology
China will administer water pollution, water conservation, kept ecological balance with sustainable development as energy-saving and emission-reduction work The most important thing of work.Current water technology relatively lags behind, and most area still suffers from not qualified discharge so far.
In research and development water process materialization technology, though there is larger breakthrough at present in physics aspect, in chemicals Aspect is still made slow progress.China is still using in water process at present:Iron chloride, sodium hydroxide, aluminium polychloride, alkali formula chlorination Coagulant, flocculant and the various filtrates such as the poly- propionamide of aluminium, nonionic, the poly- propionamide of cation, polychloride ferro-aluminum.These chemistry Although preparation effect is fine, have limitation and specific aim (such as coagulant can only coagulation, flocculant can only flocculate, decolorising agent only Can decoloration, remove other pollutants and be intended to select targetedly auxiliary agent).
The content of the invention
In view of the deficienciess of the prior art, it is an object of the present invention to provide a kind of duplicate removal metal water quality renovation agent, to solve Problem proposed in the above background technology.
To achieve these goals, the present invention is to realize by the following technical solutions:A kind of duplicate removal metal water quality is repaiied Multiple agent, is made of the raw material of following parts by weight:Iron chloride 5-8 parts by weight, sodium carbonate 13-16 parts by weight, SODIUM PERCARBONATE 10-12 weights Measure part, aluminium polychloride 12-14 parts by weight, polyacrylamide 3-5 parts by weight, calcium hydroxide 2-3 parts by weight, bacillus pumilus 6-8 parts by weight, polyferric silicate sulfate 8-12 parts by weight.
Further, iron content pickle or waste hydrochloric acid are placed in reaction kettle device, while add iron powder or iron filings, acid with Iron occurs the thermal energy that exothermic reaction produces and material is preheated, and then adds catalyst and is passed through oxygen, is then turned on circulating pump, makes Reaction solution circulation 3-5 it is small when, it is to be polymerized that the reaction was complete, by reaction solution be transferred to precipitation tank for precipitation or with filter type to product into Row separation and enrichment, form the iron chloride in raw material.
Further, ammonia and water and carbon dioxide reaction generate the ammonium hydrogen carbonate of a molecule, then by ammonium hydrogen carbonate with Sodium chloride reaction generation sodium acid carbonate precipitation and ammonium chloride, it is filtered to obtain sodium bicarbonate solid, the sodium acid carbonate of generation is added Thermal decomposition, generates the sodium carbonate in raw material.
Further, natrium carbonicum calcinatum is placed on thermopnore, in the case where hot-air blows boiling to continuously spraying on sodium carbonate Hydrogen peroxide solution, obtains the SODIUM PERCARBONATE in raw material.
Further, aluminium ash and sodium hydroxide first are reacted to obtain sodium aluminate solution, then with hydrochloric acid tune pH value, raw material is made In aluminium polychloride.
Further, it is made of the raw material of following parts by weight:5 parts by weight of iron chloride, 16 parts by weight of sodium carbonate, SODIUM PERCARBONATE 10 parts by weight, 14 parts by weight of aluminium polychloride, 3 parts by weight of polyacrylamide, 3 parts by weight of calcium hydroxide, 6 weight of bacillus pumilus Measure part, 12 parts by weight of polyferric silicate sulfate.
Beneficial effects of the present invention:A kind of duplicate removal metal water quality renovation agent of the present invention, for all types of industries sewage, is being answered With physical equipment such as solid-liquid separating machine, air floatation machine when treated sewage, using cleanser of the present invention, dirt can be made in 3-10 minutes Water separation of solid and liquid, Liquid liquid Separation, output clear water, efficient quick, can effectively decompose water body, Organic Pollutants in Sedimentary Mud, can be with Heavy metal in water body is reduced, pollution-free or lighter pollution level compound is formed, so as to reduce heavy metal in water body Migration and bioavailability, to mitigate pollution of the heavy metal to water body.
Embodiment
To make the technical means, the creative features, the aims and the efficiencies achieved by the present invention easy to understand, with reference to Embodiment, the present invention is further explained.
The present invention provides a kind of technical solution:A kind of duplicate removal metal water quality renovation agent, is made of the raw material of following parts by weight: Iron chloride 5-8 parts by weight, sodium carbonate 13-16 parts by weight, SODIUM PERCARBONATE 10-12 parts by weight, aluminium polychloride 12-14 parts by weight, Polyacrylamide 3-5 parts by weight, calcium hydroxide 2-3 parts by weight, bacillus pumilus 6-8 parts by weight, polyferric silicate sulfate 8-12 weights Measure part.
Iron content pickle or waste hydrochloric acid are placed in reaction kettle device, while add iron powder or iron filings, acid is put with iron The thermal energy that thermal response produces preheats material, then adds catalyst and is passed through oxygen, is then turned on circulating pump, follows reaction solution When ring 3-5 is small, to be polymerized the reaction was complete, by reaction solution be transferred to precipitation tank for precipitation or with filter type to product carry out separation and Enrichment, forms the iron chloride in raw material.
Ammonia generates the ammonium hydrogen carbonate of a molecule with water and carbon dioxide reaction, then reacts ammonium hydrogen carbonate and sodium chloride Sodium acid carbonate precipitation and ammonium chloride are generated, it is filtered to obtain sodium bicarbonate solid, by the sodium acid carbonate heat resolve of generation, generation Sodium carbonate in raw material.
Natrium carbonicum calcinatum is placed on thermopnore, it is molten to continuous sprinkling hydrogen peroxide on sodium carbonate in the case where hot-air blows boiling Liquid, obtains the SODIUM PERCARBONATE in raw material.
Aluminium ash and sodium hydroxide first are reacted to obtain sodium aluminate solution, then with hydrochloric acid tune pH value, the polymerization in raw material is made Aluminium chloride.
As one embodiment of the present of invention:It is made of the raw material of following parts by weight:5 parts by weight of iron chloride, sodium carbonate 16 Parts by weight, 10 parts by weight of SODIUM PERCARBONATE, 14 parts by weight of aluminium polychloride, 3 parts by weight of polyacrylamide, 3 parts by weight of calcium hydroxide, 6 parts by weight of bacillus pumilus, 12 parts by weight of polyferric silicate sulfate.
As one embodiment of the present of invention:A kind of duplicate removal metal water quality renovation agent of the present invention, it is dirty for all types of industries Water,, can be at 3-10 points using cleanser of the present invention when for example solid-liquid separating machine, air floatation machine are when treated sewage for Applied Physics equipment Sewage solid is separated in clock, Liquid liquid Separation, output clear water, efficient quick, can effectively decompose organic contamination in water body, bed mud Thing, the heavy metal in water body can be reduced, form pollution-free or lighter pollution level compound, exist so as to reduce heavy metal Migration and bioavailability in water body, to mitigate pollution of the heavy metal to water body.
The basic principles, main features and the advantages of the invention have been shown and described above, for this area skill For art personnel, it is clear that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and without departing substantially from the present invention spirit or In the case of essential characteristic, the present invention can be realized in other specific forms.Therefore, in all respects, should all incite somebody to action Embodiment regards exemplary as, and is non-limiting, the scope of the present invention by appended claims rather than on state Bright restriction, it is intended that including all changes fallen in the implication and scope of the equivalency of claim in the present invention It is interior.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (6)

  1. A kind of 1. duplicate removal metal water quality renovation agent, it is characterised in that:It is made of the raw material of following parts by weight:Iron chloride 5-8 weight Part, sodium carbonate 13-16 parts by weight, SODIUM PERCARBONATE 10-12 parts by weight, aluminium polychloride 12-14 parts by weight, polyacrylamide 3-5 Parts by weight, calcium hydroxide 2-3 parts by weight, bacillus pumilus 6-8 parts by weight, polyferric silicate sulfate 8-12 parts by weight.
  2. A kind of 2. duplicate removal metal water quality renovation agent according to claim 1, it is characterised in that:By iron content pickle or abraum salt Acid is placed in reaction kettle device, while adds iron powder or iron filings, and with iron the thermal energy of exothermic reaction generation occurs for acid to material pre-add Heat, then adds catalyst and is passed through oxygen, be then turned on circulating pump, and when making reaction solution circulation 3-5 small, to be polymerized the reaction was complete, Reaction solution is transferred to precipitation tank for precipitation or product is separated and is enriched with filter type, forms the iron chloride in raw material.
  3. A kind of 3. duplicate removal metal water quality renovation agent according to claim 1, it is characterised in that:Ammonia and water and carbon dioxide The ammonium hydrogen carbonate of reaction one molecule of generation, then generates sodium acid carbonate precipitation and ammonium chloride by ammonium hydrogen carbonate and sodium chloride reaction, It is filtered to obtain sodium bicarbonate solid, by the sodium acid carbonate heat resolve of generation, generate the sodium carbonate in raw material.
  4. A kind of 4. duplicate removal metal water quality renovation agent according to claim 1, it is characterised in that:Natrium carbonicum calcinatum is placed in stream On dynamic bed, in the case where hot-air blows boiling to continuous sprinkling hydrogenperoxide steam generator on sodium carbonate, the SODIUM PERCARBONATE in raw material is obtained.
  5. A kind of 5. duplicate removal metal water quality renovation agent according to claim 1, it is characterised in that:First by aluminium ash and sodium hydroxide Reaction obtains sodium aluminate solution, then with hydrochloric acid tune pH value, the aluminium polychloride in raw material is made.
  6. A kind of 6. duplicate removal metal water quality renovation agent according to claim 1, it is characterised in that:By the raw material of following parts by weight Form:5 parts by weight of iron chloride, 16 parts by weight of sodium carbonate, 10 parts by weight of SODIUM PERCARBONATE, 14 parts by weight of aluminium polychloride, polypropylene 3 parts by weight of acid amides, 3 parts by weight of calcium hydroxide, 6 parts by weight of bacillus pumilus, 12 parts by weight of polyferric silicate sulfate.
CN201711297422.XA 2017-12-08 2017-12-08 Heavy metal removing water quality restoration agent Withdrawn CN108002546A (en)

Priority Applications (1)

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CN201711297422.XA CN108002546A (en) 2017-12-08 2017-12-08 Heavy metal removing water quality restoration agent

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Country Status (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101462776A (en) * 2009-01-07 2009-06-24 金月祥 Process for preparing poly ferric chloride
CN105384201A (en) * 2015-12-11 2016-03-09 马鞍山清净环保科技有限公司 Treatment agent for treating heavy metal sewage, and preparation method and application thereof
CN105540812A (en) * 2016-01-30 2016-05-04 范洲卫 Heavy metal wastewater treatment agent and preparation method of heavy metal wastewater treatment agent
CN106277354A (en) * 2016-08-26 2017-01-04 夏百庆 A kind of duplicate removal metal water quality renovation agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101462776A (en) * 2009-01-07 2009-06-24 金月祥 Process for preparing poly ferric chloride
CN105384201A (en) * 2015-12-11 2016-03-09 马鞍山清净环保科技有限公司 Treatment agent for treating heavy metal sewage, and preparation method and application thereof
CN105540812A (en) * 2016-01-30 2016-05-04 范洲卫 Heavy metal wastewater treatment agent and preparation method of heavy metal wastewater treatment agent
CN106277354A (en) * 2016-08-26 2017-01-04 夏百庆 A kind of duplicate removal metal water quality renovation agent

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
曾金棠: "《肥皂的制造》", 31 July 1977, 香港万里书店出版 *
符德学等编: "《实用无机化工工艺学》", 30 September 1999, 西安交通大学出版社 *
陈亚萍等编: "《乡镇供排水技术》", 31 January 2015, 黄河水利出版社 *

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Application publication date: 20180508