CN108002407A - A kind of improved secondary brine rectification system - Google Patents

A kind of improved secondary brine rectification system Download PDF

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Publication number
CN108002407A
CN108002407A CN201711370314.0A CN201711370314A CN108002407A CN 108002407 A CN108002407 A CN 108002407A CN 201711370314 A CN201711370314 A CN 201711370314A CN 108002407 A CN108002407 A CN 108002407A
Authority
CN
China
Prior art keywords
brine
chelate resin
resin tower
storage tank
holding vessel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711370314.0A
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Chinese (zh)
Inventor
申红梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201711370314.0A priority Critical patent/CN108002407A/en
Publication of CN108002407A publication Critical patent/CN108002407A/en
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00Halides of sodium, potassium or alkali metals in general
    • C01D3/14Purification
    • C01D3/145Purification by solid ion-exchangers or solid chelating agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Heat Treatment Of Water, Waste Water Or Sewage (AREA)

Abstract

The invention discloses a kind of improved secondary brine rectification system,Including tubular filter,The filtered brine storage tank is connected with chelate resin tower by pipeline,The chelate resin tower is connected to deionized water holding vessel by inlet tube,Hydrochloric acid holding vessel and soda bath holding vessel,The chelate resin tower is connected to melt pit and secondary refining salt storage tank by outlet,The secondary refining salt storage tank is connected with deionization film electricity groove by pipeline,The present invention adds micro sodium sulfite into brine,Free chlorine in brine and hypochlorous acid can thoroughly be removed,In order to avoid cause chelating resin poison deactivation,Filtered brine storage tank is introduced to after brine is filtered via tubular filter,Brine after filtering is sent to chelate resin tower,Chelating resin is housed in chelate resin tower,For thoroughly removing Micro Calcium Magnesium cation contained in brine,So that the calcium and magnesium cation in brine is less than defined value.

Description

A kind of improved secondary brine rectification system
Technical field
The present invention relates to secondary brine rectification technical field, is specially a kind of improved secondary brine rectification system.
Background technology
Due to adjusting chemicals band used when pH value brings calcium and magnesium ion or refined brine into during secondary refining salt Impurity entered etc. so that easily occur impurity in secondary refining salt, seriously affect the refining quality of brine, for this reason, we Release a kind of improved secondary brine rectification system.
The content of the invention
It is an object of the invention to provide a kind of improved secondary brine rectification system, to solve to carry in above-mentioned background technology The problem of going out.
To achieve the above object, the present invention provides following technical solution:A kind of improved secondary brine rectification system, including Tubular filter, the tubular filter are connected with filtered brine storage tank by pipeline, and the filtered brine storage tank passes through pipeline Chelate resin tower is connected with, the chelate resin tower is connected to deionized water holding vessel, hydrochloric acid holding vessel by inlet tube With soda bath holding vessel, the chelate resin tower is connected to melt pit and secondary refining salt storage tank, institute by outlet State secondary refining salt storage tank and deionization film electricity groove is connected with by pipeline, the inner cavity of the outlet, which is equipped with, is used for sliding aeration The sliding chute seat of plate, the middle part of the aeration board are equipped with material leakage open slot, and the side wall of the material leakage open slot is equidistantly equipped with solarization air cap, The side of the aeration board is equipped with the air inlet pipe connected with solarization air cap.
Preferably, the bottom of the chelate resin tower is provided with base, and the outlet runs through base.
Preferably, the surface of the chelate resin tower is equipped with visor, and the visor is to be placed equidistant with up and down.
Preferably, the inlet tube is four-way pipe, and inlet tube is connected to deionized water holding vessel, hydrochloric acid holding vessel Valve is mounted on the part of soda bath holding vessel.
Preferably, the outlet is three-way pipe, and outlet is connected to melt pit and secondary refining salt storage tank Part is mounted on valve.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention adds micro sodium sulfite into brine, can be thorough Free chlorine in brine and hypochlorous acid are removed in bottom, in order to avoid causing chelating resin poison deactivation, brine is filtered via tubular filter After be introduced to filtered brine storage tank, the brine after filtering is sent to chelate resin tower, chelating resin is housed in chelate resin tower, is used It is next thoroughly to remove Micro Calcium Magnesium cation contained in brine so that the calcium and magnesium cation in brine is worth less than defined, two Chelate resin tower is used in series, wherein a tower regenerates, a tower is continuing with, to ensure that brine quality meets technological requirement, resin Regenerating alkali and hydrochloric acid mix the concentration needed for cultivating with pure water and enter chelate resin tower, waste water, spent acid and salkali waste in regenerative process Melt pit is flowed into addition to handle, by the setting that outlet is three-way pipe, meanwhile, by air inlet pipe by gases at high pressure via solarization air cap Blowout, the liquid that outlet can be flowed through to chelate resin tower carry out Air Exposure, prevent from blocking, and may be such that chelate resin tower is distinguished Liquid is smoothly conveyed to melt pit and secondary refining salt storage tank.
Brief description of the drawings
Fig. 1 is schematic structural view of the invention;
Fig. 2 is chelate resin tower positive structure diagram of the present invention;
Fig. 3 is chelate resin tower mounting structure schematic diagram of the present invention;
Fig. 4 cuts open structure diagram for outlet side of the present invention;
Fig. 5 is aeration board structure schematic diagram of the present invention.
In figure:1 tubular filter, 2 filtered brine storage tanks, 3 chelate resin towers, 4 melt pits, 5 deionized water holding vessels, 6 salt Sour holding vessel, 7 soda bath holding vessels, 8 secondary refining salt storage tanks, 9 deionization film electricity grooves, 10 visors, 11 outlets, 12 enter Mouth pipe, 13 bases, 14 sliding chute seats, 15 aeration boards, 16 material leakage open slots, 17 solarization air caps, 18 air inlet pipe.
Embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work Embodiment, belongs to the scope of protection of the invention.
- 5 are please referred to Fig.1, the present invention provides a kind of technical solution:A kind of improved secondary brine rectification system, including pipe Formula filter 1, the tubular filter 1 are connected with filtered brine storage tank 2 by pipeline, and the filtered brine storage tank 2 passes through pipe Road is connected with chelate resin tower 3, and the chelate resin tower 3 is connected to deionized water holding vessel 5, hydrochloric acid by inlet tube 12 Holding vessel 6 and soda bath holding vessel 7, the chelate resin tower 3 are connected to melt pit 4 and secondary refining by outlet 11 Brine storage tank 8, the secondary refining salt storage tank 8 are connected with deionization film electricity groove 9, the inner cavity of the outlet 11 by pipeline Equipped with the sliding chute seat 14 for slipping aeration board 15, the middle part of the aeration board 15 is equipped with material leakage open slot 16, and the material leakage is opened The side wall of mouth groove 16 is equidistantly equipped with solarization air cap 17, and the side of the aeration board 15 is equipped with the air inlet pipe 18 connected with solarization air cap 17.
Further, the bottom of the chelate resin tower 3 is provided with base 13, and the outlet 11 runs through base 13, leads to Cross the setting of base 13 so that chelate resin tower 3 plays the protective effect to chelate resin tower 3 away from ground.
Further, the surface of the chelate resin tower 3 is equipped with visor 10, and the visor 10 leads to be placed equidistant with up and down The setting of visor 10 is crossed, easy to observe 3 inner case of chelate resin tower.
Further, the inlet tube 12 is four-way pipe, and inlet tube 12 is connected to deionized water holding vessel 5, salt The part of sour holding vessel 6 and soda bath holding vessel 7 is mounted on valve, by the setting that inlet tube 12 is four-way pipe, can divide Not Kong Zhi deionized water holding vessel 5, hydrochloric acid holding vessel 6 and soda bath holding vessel 7 to chelate resin tower 3 convey liquid.
Further, the outlet 11 is three-way pipe, and outlet 11 is connected to melt pit 4 and secondary refining salt The part of storage tank 8 is mounted on valve, by the setting that outlet 11 is three-way pipe, may be such that chelate resin tower 3 respectively to ground Hole 4 and secondary refining salt storage tank 8 convey liquid.
Specifically, in use, in order to thoroughly remove free chlorine in brine and hypochlorous acid, lost in order to avoid causing chelating resin to be poisoned Effect, micro sodium sulfite is added into brine, filtered brine storage tank 2 is introduced to after brine is filtered via tubular filter 1, will It can be 2-3 platforms that brine after filtering, which is sent to chelate resin tower 3, chelate resin tower 3, and chelating resin is housed in chelate resin tower 3, use It is next thoroughly to remove Micro Calcium Magnesium cation contained in brine so that the calcium and magnesium cation in brine is worth less than defined, two Chelate resin tower 3 is used in series, wherein a tower regenerates, a tower is continuing with, to ensure that brine quality meets technological requirement, resin Regenerating alkali and hydrochloric acid mix the concentration needed for cultivating with pure water and enter chelate resin tower 3, waste water, spent acid and salkali waste in regenerative process Flow into melt pit 4 in addition handle, by outlet 11 be three-way pipe setting, meanwhile, by air inlet pipe 18 by gases at high pressure via Solarization air cap 17 is blown out, and the liquid that outlet 11 can be flowed through to chelate resin tower 3 carries out Air Exposure, prevents from blocking, may be such that chela Resin tower 3 smoothly conveys liquid to melt pit 4 and secondary refining salt storage tank 8 respectively.
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of changes, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of improved secondary brine rectification system, including tubular filter (1), it is characterised in that:The tubular filter (1) filtered brine storage tank (2) is connected with by pipeline, the filtered brine storage tank (2) is connected with chelate resin tower by pipeline (3), the chelate resin tower (3) is connected to deionized water holding vessel (5), hydrochloric acid holding vessel (6) by inlet tube (12) With soda bath holding vessel (7), the chelate resin tower (3) is connected to melt pit (4) and secondary fine by outlet (11) Salt manufacturing water storage tank (8), the secondary refining salt storage tank (8) are connected with deionization film electricity groove (9), the outlet by pipeline (11) inner cavity is equipped with the sliding chute seat (14) for being used for slipping aeration board (15), and the middle part of the aeration board (15) is equipped with material leakage opening Groove (16), the side wall of the material leakage open slot (16) are equidistantly equipped with solarization air cap (17), the side of the aeration board (15) be equipped with The air inlet pipe (18) of solarization air cap (17) connection.
A kind of 2. improved secondary brine rectification system according to claim 1, it is characterised in that:The chelate resin tower (3) bottom is provided with base (13), and the outlet (11) runs through base (13).
A kind of 3. improved secondary brine rectification system according to claim 1, it is characterised in that:The chelate resin tower (3) surface is equipped with visor (10), and the visor (10) is to be placed equidistant with up and down.
A kind of 4. improved secondary brine rectification system according to claim 1, it is characterised in that:The inlet tube (12) For four-way pipe, and inlet tube (12) is connected to deionized water holding vessel (5), hydrochloric acid holding vessel (6) and soda bath storage The part of tank (7) is mounted on valve.
A kind of 5. improved secondary brine rectification system according to claim 1, it is characterised in that:The outlet (11) For three-way pipe, and outlet (11) is connected to melt pit (4) and the part of secondary refining salt storage tank (8) is mounted on valve Door.
CN201711370314.0A 2017-12-17 2017-12-17 A kind of improved secondary brine rectification system Withdrawn CN108002407A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711370314.0A CN108002407A (en) 2017-12-17 2017-12-17 A kind of improved secondary brine rectification system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711370314.0A CN108002407A (en) 2017-12-17 2017-12-17 A kind of improved secondary brine rectification system

Publications (1)

Publication Number Publication Date
CN108002407A true CN108002407A (en) 2018-05-08

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CN201711370314.0A Withdrawn CN108002407A (en) 2017-12-17 2017-12-17 A kind of improved secondary brine rectification system

Country Status (1)

Country Link
CN (1) CN108002407A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110255584A (en) * 2019-07-26 2019-09-20 四川永祥股份有限公司 A kind of secondary brine removes carbonic acid root device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110255584A (en) * 2019-07-26 2019-09-20 四川永祥股份有限公司 A kind of secondary brine removes carbonic acid root device

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Application publication date: 20180508