CN108000961A - A kind of antimicrobial form dalle - Google Patents

A kind of antimicrobial form dalle Download PDF

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Publication number
CN108000961A
CN108000961A CN201711342917.XA CN201711342917A CN108000961A CN 108000961 A CN108000961 A CN 108000961A CN 201711342917 A CN201711342917 A CN 201711342917A CN 108000961 A CN108000961 A CN 108000961A
Authority
CN
China
Prior art keywords
parts
layer
dalle
projection
antimicrobial form
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711342917.XA
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Chinese (zh)
Inventor
黄少棠
杨亚东
余金铭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201711342917.XA priority Critical patent/CN108000961A/en
Publication of CN108000961A publication Critical patent/CN108000961A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02Composition of the impregnated, bonded or embedded layer
    • B32B2260/021Fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04Impregnation, embedding, or binder material
    • B32B2260/046Synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Apparatus For Disinfection Or Sterilisation (AREA)

Abstract

The present invention provides a kind of antimicrobial form dalle, including face coat, elastic layer, sheet metal layer, the connection projection layer set gradually, and the elastic layer is thermoplastic shell glycan elastomer rubber layer, and the connection projection layer is made of symmetrically arranged Rectangular Elastic projection.Functional form Novel decorative board of the present invention, the simple installation of the achievable decoration panel of the present invention, can effectively improve construction efficiency, reduce production cost, and meet green, environmentally friendly, energy saving, efficiently home life theory.

Description

A kind of antimicrobial form dalle
Technical field
The invention belongs to decorative materials technology, and in particular to a kind of antimicrobial form dalle.
Background technology
Ornament materials is the material base of building decoration engineering, is the actual effect of decorative engineering and the color of ornament materials Color, texture and the specific of texture show, and decorative material for internal wall is as part important in modern house decorations, Account for the largest percentage in overall house ornamentation.
With the raising of modern life quality level, decorations of the people to home life are increasingly paid attention to, traditional Decorative board material is there are many problems, such as flameproof effect are bad, decorative layer insufficient strength, and soundproof effect is bad etc., this is just needed One kind can overcome the disadvantages that above-mentioned deficiency, and easy to make, lower-cost functional form Novel decorative board.
The content of the invention
In view of this, the present invention provides a kind of antimicrobial form dalle, and the present invention is functional form Novel decorative board, this hair The simple installation of bright achievable decoration panel, can effectively improve construction efficiency, reduce production cost, and meet green, environmental protection, section Energy, efficiently home life theory.
The technical scheme is that:A kind of antimicrobial form dalle, it is characterised in that the surface including setting gradually applies Layer, elastic layer, sheet metal layer, connection projection layer, the elastic layer is thermoplastic shell glycan elastomer rubber layer, the connection projection Layer is made of symmetrically arranged Rectangular Elastic projection;The sheet metal layer includes the component of following parts by weight:Polyvinyl chloride resin 17-29 parts, chitosan/13-25 parts of collagen composite nano fiber, 8-13 parts of chitin fiber, kaolin particle 7- 15 parts, 9-16 parts of sodium alginate, 14-21 parts of basalt fibre, 19-25 parts of mannitol, 11-23 parts of silane coupling agent.
The a diameter of 120-180nm, filament length 9-13um of the further chitin fiber;
Further, the particle diameter of the kaolin particle is 14-19um.
Further, a diameter of 230-290nm of the basalt fibre.
Further, the elastic projection is thermoplastic polyurethane's projection.The thermoplastic polyurethane that the present invention uses (Thermoplastic polyyrethane), is a kind of new organic polymer synthetic material, belongs to compound, English business The name of an article:Flexible polyurethane, are that a kind of properties are excellent, can replace rubber rubber, soft polyvinyl chloride Material pvc, excellent physical property.The characteristics of chitosan thermoplastic elastomer (TPE) protrudes be excellent in abrasion resistance, ozone resistance it is fabulous, Hardness is big, intensity is high, elasticity is good, low temperature resistant, has good oil resistant, chemical-resistant resistance and environmental resistance, in wet environment Polyether-type ester hydrolysis stability is far more than polyester-type.By the interference fit between elastic projection, it can be achieved that the peace of dalle Dress, it is simple to operate.
In the present invention, the elastic layer used is thermoplastic shell glycan elastomer rubber layer, thermoplastic shell glycan elastomer rubber Glue, TPE (Thermoplastic Elastomer) is a kind of thermoplastic elastic material, has high intensity, high resilience can The feature of injection molding, has wide range of applications, and environment-protecting and non-poisonous safety, there is excellent coloring.Soft-touch, weatherability, resists tired Labor and temperature tolerance, processing performance is superior, and without vulcanization, can recycle reduces cost, both can with secondary injection molding, with The basis material coating and bonding such as PP, PE, PC, PS, ABS, can also be separately formed.Hardness range is wide, from ultra-soft to 90A.Pass through The three dimensions framework having inside thermoplastic shell glycan elastomer rubber layer, can keep plate to have certain elasticity and thoroughly Gas performance.
The face coat includes the component of following parts by weight:Butyl acrylate 8-17, methyl methacrylate 22- 32nd, 2 hydroxy methacrylate 16-25 of acrylic acid, azodiisobutyronitrile 2-8, mannitol 8-17, molybdenum disulfide 17-29, polypropylene Acid amides 29-37, chitosan 16-28.
Energy conservation and environmental protection of the present invention, breaches the simple feature of traditional decoration plate sandwich, its traditional mode of production consumes thing Expect more, stressed effect is bad, and dalle interlayer of the invention is the thermoplastic shell glycan bullet with three dimensions framework Property body rubber Rotating fields, have more preferable supporting role and reinforcement effect, material are saved very much in manufacturing process;Pass through this at the same time The interference fit for the groove that thermoplastic polyurethane's projection is set with wall to be decorated or plate body is invented, realizes the letter of decoration panel It is easy to install, it can effectively improve construction efficiency, reduce production cost, and meet that green, environmentally friendly, energy saving, efficiently home life is managed Read.
The sheet metal layer of the present invention, the present invention pass through polyvinyl chloride resin, chitosan/collagen composite nano fiber, first The synergistic complex role of shell cellulose fiber, basalt fibre, forms the spatial arrangement structure of high intensity and regular layer structure, then Its bonding strength is strengthened by the effect of mannitol, silane coupling agent.By the observation to cross-section morphology of the present invention, each component Boundary obscures, and there is parcel and wrapped connection mode, while also there are some perforations, illustrates mannitol, silane coupled Agent can be effectively improved polyvinyl chloride resin, chitosan/collagen composite nano fiber, chitin fiber, basalt fibre it Between interface cohesion, but easily put up a bridge between the larger fiber of particle diameter so that between fiber and fiber and fiber and matrix it Between be also easy to produce hole, and then reduce the effect with reference to power, therefore arrange in pairs or groups in the present invention by using the fiber of different-grain diameter, and Filled with kaolin particle, material is avoided to produce the phenomenon of stress concentration in stress;Meanwhile pass through sheet metal layer each group of the present invention The synergistic effect divided so that sheet metal layer of the present invention has excellent anti-microbial property.
The functional form coating of the present invention, has excellent antibiotic property and fire resistance, while salt spray resistance ability is good, is applicable in Used in large-scale promotion.
Brief description of the drawings
Fig. 1 is the structure diagram of the present invention.
Embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1
A kind of antimicrobial form dalle, it is characterised in that including set gradually face coat 1, elastic layer 2, sheet metal layer 3, even Projection layer 4 is connect, the elastic layer is thermoplastic shell glycan elastomer rubber layer, and the connection projection layer is by symmetrically arranged rectangle Elastic projection 41 forms;The sheet metal layer includes the component of following parts by weight:17 parts of polyvinyl chloride resin, chitosan/glue Former 13 parts of albumen composite nano fiber, 8 parts of chitin fiber, 7 parts of kaolin particle, 9 parts of sodium alginate, basalt fibre 14 parts, 19 parts of mannitol, 11 parts of silane coupling agent.
The a diameter of 120nm, filament length 9um of the further chitin fiber;
Further, the particle diameter of the kaolin particle is 14um.
Further, a diameter of 230nm of the basalt fibre.
Further, the elastic projection is thermoplastic polyurethane's projection.
The face coat includes the component of following parts by weight:Butyl acrylate 8, methyl methacrylate 22, third 2 hydroxy methacrylate 16 of olefin(e) acid, azodiisobutyronitrile 2, mannitol 8, molybdenum disulfide 17, polyacrylamide 29, chitosan 16。
Energy conservation and environmental protection of the present invention, breaches the simple feature of traditional decoration plate sandwich, its traditional mode of production consumes thing Expect more, stressed effect is bad, and dalle interlayer of the invention is the thermoplastic shell glycan bullet with three dimensions framework Property body rubber Rotating fields, have more preferable supporting role and reinforcement effect, material are saved very much in manufacturing process;Pass through this at the same time The interference fit for the groove that thermoplastic polyurethane's projection is set with wall to be decorated or plate body is invented, realizes the letter of decoration panel It is easy to install, it can effectively improve construction efficiency, reduce production cost, and meet that green, environmentally friendly, energy saving, efficiently home life is managed Read.
The sheet metal layer of the present invention, the present invention pass through polyvinyl chloride resin, chitosan/collagen composite nano fiber, first The synergistic complex role of shell cellulose fiber, basalt fibre, forms the spatial arrangement structure of high intensity and regular layer structure, then Its bonding strength is strengthened by the effect of mannitol, silane coupling agent.By the observation to cross-section morphology of the present invention, each component Boundary obscures, and there is parcel and wrapped connection mode, while also there are some perforations, illustrates mannitol, silane coupled Agent can be effectively improved polyvinyl chloride resin, chitosan/collagen composite nano fiber, chitin fiber, basalt fibre it Between interface cohesion, but easily put up a bridge between the larger fiber of particle diameter so that between fiber and fiber and fiber and matrix it Between be also easy to produce hole, and then reduce the effect with reference to power, therefore arrange in pairs or groups in the present invention by using the fiber of different-grain diameter, and Filled with kaolin particle, material is avoided to produce the phenomenon of stress concentration in stress.
The functional form coating of the present invention, has excellent antibiotic property and fire resistance, while salt spray resistance ability is good, is applicable in Used in large-scale promotion.
Embodiment 2
A kind of antimicrobial form dalle, it is characterised in that face coat, elastic layer, sheet metal layer, connection including setting gradually are prominent Block layer, the elastic layer are thermoplastic shell glycan elastomer rubber layer, and the connection projection layer is by symmetrically arranged Rectangular Elastic Projection forms;The sheet metal layer includes the component of following parts by weight:29 parts of polyvinyl chloride resin, chitosan/collagen 25 parts of composite nano fiber, 13 parts of chitin fiber, 15 parts of kaolin particle, 16 parts of sodium alginate, basalt fibre 21 Part, 25 parts of mannitol, 23 parts of silane coupling agent.
The a diameter of 180nm, filament length 13um of the further chitin fiber;
Further, the particle diameter of the kaolin particle is 19um.
Further, a diameter of 290nm of the basalt fibre.
Further, the elastic projection is thermoplastic polyurethane's projection.
The face coat includes the component of following parts by weight:Butyl acrylate 17, methyl methacrylate 32, third 2 hydroxy methacrylate 25 of olefin(e) acid, azodiisobutyronitrile 8, mannitol 17, molybdenum disulfide 29, polyacrylamide 37, chitosan 28。
Embodiment 3
A kind of antimicrobial form dalle, it is characterised in that face coat, elastic layer, sheet metal layer, connection including setting gradually are prominent Block layer, the elastic layer are thermoplastic shell glycan elastomer rubber layer, and the connection projection layer is by symmetrically arranged Rectangular Elastic Projection forms;The sheet metal layer includes the component of following parts by weight:22 parts of polyvinyl chloride resin, chitosan/collagen 19 parts of composite nano fiber, 10 parts of chitin fiber, 12 parts of kaolin particle, 11 parts of sodium alginate, basalt fibre 17 Part, 23 parts of mannitol, 17 parts of silane coupling agent.
The a diameter of 150nm, filament length 11um of the further chitin fiber;
Further, the particle diameter of the kaolin particle is 17um.
Further, a diameter of 260nm of the basalt fibre.
Further, the elastic projection is thermoplastic polyurethane's projection.
The face coat includes the component of following parts by weight:Butyl acrylate 12, methyl methacrylate 26, third 2 hydroxy methacrylate 18 of olefin(e) acid, azodiisobutyronitrile 6, mannitol 13, molybdenum disulfide 23, polyacrylamide 32, chitosan 21。
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can be by appointing One prior art is realized.

Claims (6)

  1. A kind of 1. antimicrobial form dalle, it is characterised in that including set gradually face coat, elastic layer, sheet metal layer, connection Projection layer, the elastic layer are thermoplastic shell glycan elastomer rubber layer, and the connection projection layer is by symmetrically arranged rectangle bullet Property projection composition;The sheet metal layer includes the component of following parts by weight:17-29 parts of polyvinyl chloride resin, chitosan/collagen 13-25 parts of albumen composite nano fiber, 8-13 parts of chitin fiber, 7-15 parts of kaolin particle, 9-16 parts of sodium alginate, 14-21 parts of basalt fibre, 19-25 parts of mannitol, 11-23 parts of silane coupling agent.
  2. 2. antimicrobial form dalle according to claim 1, it is characterised in that a diameter of 120- of the chitin fiber 180nm, filament length 9-13um.
  3. 3. antimicrobial form dalle according to claim 1, it is characterised in that the particle diameter of the kaolin particle is 14- 19um。
  4. 4. antimicrobial form dalle according to claim 1, it is characterised in that a diameter of 230- of the basalt fibre 290nm。
  5. 5. antimicrobial form dalle according to claim 1, it is characterised in that the elasticity projection is thermoplastic polyurethane Projection.
  6. 6. antimicrobial form dalle according to claim 1, it is characterised in that the face coat includes following parts by weight Several components:Butyl acrylate 8-17, methyl methacrylate 22-32,2 hydroxy methacrylate 16-25 of acrylic acid, azo two Isobutyronitrile 2-8, mannitol 8-17, molybdenum disulfide 17-29, polyacrylamide 29-37, chitosan 16-28.
CN201711342917.XA 2017-12-14 2017-12-14 A kind of antimicrobial form dalle Pending CN108000961A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711342917.XA CN108000961A (en) 2017-12-14 2017-12-14 A kind of antimicrobial form dalle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711342917.XA CN108000961A (en) 2017-12-14 2017-12-14 A kind of antimicrobial form dalle

Publications (1)

Publication Number Publication Date
CN108000961A true CN108000961A (en) 2018-05-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711342917.XA Pending CN108000961A (en) 2017-12-14 2017-12-14 A kind of antimicrobial form dalle

Country Status (1)

Country Link
CN (1) CN108000961A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111619169A (en) * 2020-06-10 2020-09-04 杭州强容智能科技有限公司 Impact-resistant PVC (polyvinyl chloride) wall panel and processing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111619169A (en) * 2020-06-10 2020-09-04 杭州强容智能科技有限公司 Impact-resistant PVC (polyvinyl chloride) wall panel and processing method thereof

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Application publication date: 20180508