CN107999095A - A kind of preparation method of sulfur doping bismoclite powder photocatalytic material - Google Patents
A kind of preparation method of sulfur doping bismoclite powder photocatalytic material Download PDFInfo
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- CN107999095A CN107999095A CN201711386821.3A CN201711386821A CN107999095A CN 107999095 A CN107999095 A CN 107999095A CN 201711386821 A CN201711386821 A CN 201711386821A CN 107999095 A CN107999095 A CN 107999095A
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- bismoclite
- biocl
- photocatalytic material
- sulfur doping
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- 239000000463 material Substances 0.000 title claims abstract description 67
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000000843 powder Substances 0.000 title claims abstract description 30
- 239000011593 sulfur Substances 0.000 title claims abstract description 29
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 29
- 230000001699 photocatalysis Effects 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000243 solution Substances 0.000 claims abstract description 48
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 claims abstract description 37
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- YUKQRDCYNOVPGJ-UHFFFAOYSA-N thioacetamide Chemical compound CC(N)=S YUKQRDCYNOVPGJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- DLFVBJFMPXGRIB-UHFFFAOYSA-N thioacetamide Natural products CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 claims abstract description 7
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical class [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011259 mixed solution Substances 0.000 claims abstract description 6
- 238000001556 precipitation Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000003760 magnetic stirring Methods 0.000 claims description 15
- 238000013019 agitation Methods 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- 125000005909 ethyl alcohol group Chemical group 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000011010 flushing procedure Methods 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 description 7
- 238000006731 degradation reaction Methods 0.000 description 7
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 5
- 229940043267 rhodamine b Drugs 0.000 description 5
- 229910052797 bismuth Inorganic materials 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- -1 Bismuth epoxide Chemical class 0.000 description 1
- 238000001237 Raman spectrum Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- RCJVRSBWZCNNQT-UHFFFAOYSA-N dichloridooxygen Chemical compound ClOCl RCJVRSBWZCNNQT-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002135 nanosheet Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/36—Organic compounds containing halogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
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Abstract
The invention discloses a kind of preparation method of sulfur doping bismoclite powder photocatalytic material, five water bismuth nitrates are placed in reaction vessel and add salpeter solution, stirred transparent to solution；Hydrochloric acid solution is added in clear solution, is stood after stirring under room temperature, flushing taking-up precipitation after solution is in neutrality, which is placed in drying box, is dried to obtain BiOCl；BiOCl is placed in reaction vessel and adds hydrochloric acid solution, stirs to BiOCl and is completely dissolved；Thioacetamide is added in above-mentioned solution, stirs to thioacetamide and is completely dissolved；Above-mentioned solution is instilled in absolute ethyl alcohol, then obtained mixed solution is placed in drying box and is dried to obtain sulfur doping bismoclite powder photocatalytic material.Preparation process of the present invention is simple and practicable, and manufacturing cycle is relatively short, and obtained sulfur doping bismoclite powder photocatalytic material is larger in the utilization rate of 350 550nm visible wavelength range interior focusing ripples, has potential application value in field of photovoltaic materials.
Description
Technical field
The invention belongs to the preparing technical field of catalysis material, and in particular to a kind of sulfur doping bismoclite powder light is urged
Change the preparation method of material.
Background technology
China's bismuth aboundresources, in recent years, for annual output up to more than 6000 tons, application is quite varied.Bismuth epoxide material has
The crystal structure of stratiform, appropriate energy gap and the special electronic structure of bismuth atom, it is past in actual light-catalyzed reaction
Toward higher activity is shown, become a kind of important catalysis material, be subjected to widely paying close attention to（Hefeng Cheng,
Baibiao Huang, Peng Wang, et al. In situ ion exchange synthesis of the novel
Ag/AgBr/BiOBr hybrid with highly efficient decontamination of pollutants.
Chem. Commun. 2011, 47(25): 7054-7056.）.Bismoclite is a kind of nontoxic, cheap and environmentally friendly light
Catalyst.Bismoclite is concentrated mainly on degradation of organic substances as the research of P-type semiconductor（Jing Jiang, Kun
Zhao, Xiaoyi Xiao, et al. Synthesis and Facet-Dependent Photoreactivity of
BiOCl Single-Crystalline Nanosheets. J. Am. Chem. Soc. 2012, 134: 4473-
4476.）.The present invention devises a kind of straightforward procedure that catalysis material is prepared to BiOCl dusty materials doping element sulphur, effectively
Improve the ability of BiOCl dusty material degradation of organic substances.
The content of the invention
The technical problem to be solved by the present invention is to provide a kind of preparation process, simple and relatively short manufacturing cycle sulphur is mixed
The preparation method of miscellaneous bismoclite powder photocatalytic material.
The present invention is to solve above-mentioned technical problem to adopt the following technical scheme that, a kind of sulfur doping bismoclite powder photocatalytic
The preparation method of material, it is characterised in that concretely comprise the following steps：
（1）Five water bismuth nitrates of 4.85g are placed in reaction vessel and add the salpeter solution of 200mL 1mol/L, in magnetic agitation
Stirred in device transparent to solution；
（2）The hydrochloric acid solution of 10mL 6mol/L is added to step（1）In obtained clear solution, on magnetic stirring apparatus with
The speed of 400n/min stirs 120min, is stood under room temperature, repeatedly rinses until solution takes out precipitation after being in neutrality is placed in drying
BiOCl dusty materials are dried to obtain in case；
（3）By 0.7814-1.0420g steps（2）Obtained BiOCl dusty materials are placed in reaction vessel and add 20mL
The hydrochloric acid solution of 6mol/L, is completely dissolved in stirring to BiOCl dusty materials on magnetic stirring apparatus；
（4）0.0113-0.0150g thioacetamides are added to step（3）In obtained solution, in being stirred on magnetic stirring apparatus
It is completely dissolved to thioacetamide；
（5）By step（4）Obtained solution instills in 100mL absolute ethyl alcohols dropwise, then obtained mixed solution is placed in drying
Sulfur doping bismoclite powder photocatalytic material is dried to obtain in case.
Further preferably, step（2）In drying condition be 100 DEG C temperature dry more than 150min.
Further preferably, step（5）In drying condition be 100 DEG C temperature dry more than 720min.
Preparation process of the present invention is simple and practicable, and manufacturing cycle is relatively short, and obtained sulfur doping bismoclite powder light is urged
It is larger in the utilization rate of 350-550nm visible wavelength range interior focusing ripples to change material, has in field of photovoltaic materials potential
Application value.
Brief description of the drawings
Fig. 1 is the absorption light of BiOCl dusty materials made from embodiment 1 and sulfur doping bismoclite powder photocatalytic material
Spectrogram；
Fig. 2 is the X-ray diffraction of BiOCl dusty materials made from embodiment 1 and sulfur doping bismoclite powder photocatalytic material
Figure；
Fig. 3 is that the SEM of BiOCl dusty materials made from embodiment 1 and sulfur doping bismoclite powder photocatalytic material schemes；
Fig. 4 is that the SEM of BiOCl dusty materials made from embodiment 1 and sulfur doping bismoclite powder photocatalytic material schemes；
Fig. 5 is BiOCl dusty materials made from embodiment 1 and sulfur doping bismoclite powder photocatalytic material light under visible light
Catalytic degradation rhodamine B concentration versus time curve；
Fig. 6 is the Raman spectrum of BiOCl dusty materials made from embodiment 1 and sulfur doping bismoclite powder photocatalytic material
Figure.
Embodiment
The above of the present invention is described in further details by the following examples, but this should not be interpreted as to this
The scope for inventing above-mentioned theme is only limitted to following embodiment, and all technologies realized based on the above of the present invention belong to this hair
Bright scope.
Embodiment 1
（1）Five water bismuth nitrates of 4.85g are placed in reaction vessel and add the salpeter solution of 200mL 1mol/L, in magnetic agitation
Stirred in device transparent to solution；
（2）The hydrochloric acid solution of 10mL 6mol/L is added to step（1）In obtained clear solution, on magnetic stirring apparatus with
The speed of 400n/min stirs 120min, is stood under room temperature, repeatedly rinses until solution takes out precipitation after being in neutrality is placed in drying
In case BiOCl dusty materials are obtained after 100 DEG C of dry 150min；
（3）By 0.7814g steps（2）Obtained BiOCl dusty materials are placed in reaction vessel and add the salt of 20mL 6mol/L
Acid solution, is completely dissolved in stirring to BiOCl dusty materials on magnetic stirring apparatus；
（4）0.0113g thioacetamides are added to step（3）In obtained solution, in stirring on magnetic stirring apparatus to thio
Acetamide is completely dissolved；
（5）By step（4）Obtained solution instills in 100mL absolute ethyl alcohols dropwise, then obtained mixed solution is placed in drying
In case sulfur doping bismoclite powder photocatalytic material is obtained in 100 DEG C of dry 720min.
As shown in Figure 1, carrying out XRD analysis to obtained sulfur doping bismoclite powder photocatalytic material, doping is found
The diffraction maximum of BiOCl dusty materials and BiOCl dusty materials after element sulphur with standard PDF card JCPDS no. 85-861
Unanimously, chemical formula BiOCl.
As shown in Fig. 2, obtained sulfur doping bismoclite powder photocatalytic material compared to BiOCl dusty materials to light
Influx and translocation and the wave bands of light absorbs there is red shift.
As shown in Figure 3 and Figure 4, obtained sulfur doping bismoclite powder photocatalytic material and BiOCl dusty materials are equal
It is made of substantial amounts of nanometer sheet, but sulfur doping bismoclite powder photocatalytic material is compared to the nanometer sheet of BiOCl dusty materials
It is smaller.
As shown in figure 5, BiOCl dusty materials are under visible light（300W xenon lamps, optical filter filter below 400nm wavelength
Light wave）Rhodamine B degradation, 75min most degradation rates are about 47%, but sulfur doping bismoclite powder photocatalytic material is visible
Rhodamine B degradation under light, 75min most degradation rates have reached 99%, compared to BiOCl dusty materials, sulfur doping oxychloride bismuth meal
The degradation rate of photocatalytic degradation rhodamine B greatly improves under powder photocatalyst material visible-light, and wherein BiOCl dusty materials pass through dye
Expect sensibilization photocatalytic degradation rhodamine B.
As shown in fig. 6, BiOCl dusty materials and sulfur doping bismoclite powder photocatalytic material are in 141cm-1、199cm-1、397cm-1There are three identical vibration peaks.
Embodiment 2
（1）Five water bismuth nitrates of 4.85g are placed in reaction vessel and add the salpeter solution of 200mL 1mol/L, in magnetic agitation
Stirred in device transparent to solution；
（2）The hydrochloric acid solution of 10mL 6mol/L is added to step（1）In obtained clear solution, on magnetic stirring apparatus with
The speed of 400n/min stirs 120min, is stood under room temperature, repeatedly rinses until solution takes out precipitation after being in neutrality is placed in drying
In case BiOCl dusty materials are obtained after 100 DEG C of dry 150min；
（3）By 0.9117g steps（2）Obtained BiOCl dusty materials are placed in reaction vessel and add the salt of 20mL 6mol/L
Acid solution, is completely dissolved in stirring to BiOCl dusty materials on magnetic stirring apparatus；
（4）0.0132g thioacetamides are added to step（3）In obtained solution, in stirring on magnetic stirring apparatus to thio
Acetamide is completely dissolved；
（5）By step（4）Obtained solution instills in 100mL absolute ethyl alcohols dropwise, then obtained mixed solution is placed in drying
In case sulfur doping bismoclite powder photocatalytic material is obtained in 100 DEG C of dry 720min.
Embodiment 3
（1）Five water bismuth nitrates of 4.85g are placed in reaction vessel and add the salpeter solution of 200mL 1mol/L, in magnetic agitation
Stirred in device transparent to solution；
（2）The hydrochloric acid solution of 10mL 6mol/L is added to step（1）In obtained clear solution, on magnetic stirring apparatus with
The speed of 400n/min stirs 120min, is stood under room temperature, repeatedly rinses until solution takes out precipitation after being in neutrality is placed in drying
In case BiOCl dusty materials are obtained after 100 DEG C of dry 150min；
（3）By 1.0420g steps（2）Obtained BiOCl dusty materials are placed in reaction vessel and add the salt of 20mL 6mol/L
Acid solution, is completely dissolved in stirring to BiOCl dusty materials on magnetic stirring apparatus；
（4）0.0150g thioacetamides are added to step（3）In obtained solution, in stirring on magnetic stirring apparatus to thio
Acetamide is completely dissolved；
（5）By step（4）Obtained solution instills in 100mL absolute ethyl alcohols dropwise, then obtained mixed solution is placed in drying
In case sulfur doping bismoclite powder photocatalytic material is obtained in 100 DEG C of dry 720min.
Basic principle, main features and advantages embodiment above describes the present invention, the technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe the original of the present invention
Reason, under the scope for not departing from the principle of the invention, various changes and modifications of the present invention are possible, these changes and improvements are each fallen within
In the scope of protection of the invention.
Claims (3)
1. a kind of preparation method of sulfur doping bismoclite powder photocatalytic material, it is characterised in that concretely comprise the following steps：
（1）Five water bismuth nitrates of 4.85g are placed in reaction vessel and add the salpeter solution of 200mL 1mol/L, in magnetic agitation
Stirred in device transparent to solution；
（2）The hydrochloric acid solution of 10mL 6mol/L is added to step（1）In obtained clear solution, on magnetic stirring apparatus with
The speed of 400n/min stirs 120min, is stood under room temperature, repeatedly rinses until solution takes out precipitation after being in neutrality is placed in drying
BiOCl dusty materials are dried to obtain in case；
（3）By 0.7814-1.0420g steps（2）Obtained BiOCl dusty materials are placed in reaction vessel and add 20mL
The hydrochloric acid solution of 6mol/L, is completely dissolved in stirring to BiOCl dusty materials on magnetic stirring apparatus；
（4）0.0113-0.0150g thioacetamides are added to step（3）In obtained solution, in being stirred on magnetic stirring apparatus
It is completely dissolved to thioacetamide；
（5）By step（4）Obtained solution instills in 100mL absolute ethyl alcohols dropwise, then obtained mixed solution is placed in drying
Sulfur doping bismoclite powder photocatalytic material is dried to obtain in case.
2. the preparation method of sulfur doping bismoclite powder photocatalytic material according to claim 1, it is characterised in that：Step
Suddenly（2）In drying condition be 100 DEG C temperature dry more than 150min.
3. the preparation method of sulfur doping bismoclite powder photocatalytic material according to claim 1, it is characterised in that：Step
Suddenly（5）In drying condition be 100 DEG C temperature dry more than 720min.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108970629A (en) * | 2018-07-20 | 2018-12-11 | 河南师范大学 | A kind of preparation method of carbon doping BiOCl visible light responsible photocatalytic material |
| CN112875751A (en) * | 2020-12-29 | 2021-06-01 | 内蒙古工业大学 | Preparation method of sulfur-doped bismuth trioxide, negative electrode material and supercapacitor |
| CN114797908A (en) * | 2022-04-26 | 2022-07-29 | 西安理工大学 | Preparation method of tantalum oxynitride/bismuth oxide/sulfur-doped bismuth oxychloride composite material |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102513134A (en) * | 2011-11-03 | 2012-06-27 | 山东大学 | Compound photocatalysis material with bismuth sulfide nano particles/bismuth oxychloride and preparation method thereof |
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2017
- 2017-12-20 CN CN201711386821.3A patent/CN107999095B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102513134A (en) * | 2011-11-03 | 2012-06-27 | 山东大学 | Compound photocatalysis material with bismuth sulfide nano particles/bismuth oxychloride and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| ZAIYONG JIANG等: "One-pot solvothermal synthesis of S doped BiOCl for solar water oxidation", 《RSC ADV.》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108970629A (en) * | 2018-07-20 | 2018-12-11 | 河南师范大学 | A kind of preparation method of carbon doping BiOCl visible light responsible photocatalytic material |
| CN112875751A (en) * | 2020-12-29 | 2021-06-01 | 内蒙古工业大学 | Preparation method of sulfur-doped bismuth trioxide, negative electrode material and supercapacitor |
| CN112875751B (en) * | 2020-12-29 | 2022-09-02 | 内蒙古工业大学 | Preparation method of sulfur-doped bismuth trioxide, negative electrode material and supercapacitor |
| CN114797908A (en) * | 2022-04-26 | 2022-07-29 | 西安理工大学 | Preparation method of tantalum oxynitride/bismuth oxide/sulfur-doped bismuth oxychloride composite material |
| CN114797908B (en) * | 2022-04-26 | 2023-08-22 | 西安理工大学 | Preparation method of tantalum oxynitride/bismuth oxide/sulfur-doped bismuth oxychloride composite material |
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