CN107996677A - A kind of compound antiseptic packaging films of food preservation and preparation method thereof - Google Patents
A kind of compound antiseptic packaging films of food preservation and preparation method thereof Download PDFInfo
- Publication number
- CN107996677A CN107996677A CN201711210071.4A CN201711210071A CN107996677A CN 107996677 A CN107996677 A CN 107996677A CN 201711210071 A CN201711210071 A CN 201711210071A CN 107996677 A CN107996677 A CN 107996677A
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- CN
- China
- Prior art keywords
- chitosan
- packaging films
- food preservation
- arginine monohydrochloride
- ethanol ester
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B4/00—General methods for preserving meat, sausages, fish or fish products
- A23B4/10—Coating with a protective layer; Compositions or apparatus therefor
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
- A23B4/00—General methods for preserving meat, sausages, fish or fish products
- A23B4/14—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12
- A23B4/18—Preserving with chemicals not covered by groups A23B4/02 or A23B4/12 in the form of liquids or solids
- A23B4/20—Organic compounds; Microorganisms; Enzymes
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Microbiology (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Packages (AREA)
- Meat, Egg Or Seafood Products (AREA)
Abstract
The invention discloses a kind of compound antiseptic packaging films of food preservation, including the PE film layers and chitosan being bonded to each other/lauramide arginine monohydrochloride ethanol ester composite nano fiber layer;In the chitosan/lauramide arginine monohydrochloride ethanol ester composite nano fiber layer, the mass ratio of chitosan and lauramide arginine monohydrochloride ethanol ester is 1~5: 1.The compound antiseptic packaging films have cold fresh meat preferable antibacterial and Bao Se to act on especially suitable for the packaging to cold fresh meat.The invention also discloses the preparation method of the compound antiseptic packaging films of above-mentioned food preservation.
Description
Technical field
The present invention relates to food preservation field, more particularly to a kind of compound antiseptic packaging films of food preservation and its preparation
Method.
Background technology
Cold fresh meat, is called chilled meat, refers to strict implement veterinary quarantine system, the poultry trunk after butchering is carried out rapidly cold
But handle, make trunk temperature (using hind shank center as measurement point) is interior when 24 is small to be reduced to 0-4 DEG C, and in following process, circulation
With the fresh meat in the range of 0-4 DEG C is remained in sales process.But the refrigerated storage temperature of cold 0-4 DEG C of fresh meat can not press down completely
The growth and breeding of some cryophiles are made, therefore cold fresh meat shelf life is short, surface brown stain and juice loss are more serious.
The corruption of cold fresh meat can be slowed down cold fresh meat packaging to a certain extent, extend the shelf life of cold fresh meat.At present
The novel package mode of cold fresh meat is mainly vacuum-packed and controlled atmospheric packing.Authorize the middle promulgated by the State Council of Publication No. CN201105860Y
Bright patent gives《A kind of new raw fresh meat thermal contraction freshness protection package membrane》, its main feature is that providing a kind of fresh meat VLDPE/
Viscous/PVA/EVOH/PVA/ glues/LDPE seven-layer structure thermal contraction freshness protections.Authorize the Chinese invention of Publication No. CN1657366A
Patent gives《High oxygen antistaling packaging technology for supermarket fresh meat》, its main feature is that with the salt of 1-3% and the cooking wine of 2-5%
Carry out subtracting antibacterial processing, while using the O of 60-80%2And 20-40%CO2Gas component, loads PP thermoforming bags by cold fresh meat
Mounted box, makees the progress high oxygen modified atmosphere fresh-keeping packaging of packing box cover layer to extend its shelf-life with PA/PE or BOPP/PE composite membranes.
It is contemplated that supermarket's cost input and the operability of supermarket staff, above-mentioned patented method lack reality in the market
Border application.
The corruption of cold fresh meat is largely due to caused by the breeding of microorganism, so providing a kind of tear-use tool
The packaging material for having biocidal property is only needed for market.Antimicrobial packaging is most important one kind in active packing, is by using it
Packaging material with bactericidal effect, suppresses the growth of food microorganisms in storage and avoids the secondary pollution of food, from
And extend the shelf-life of food.Therefore compared with ordinary packing, antimicrobial packaging is to ensuring food security and extending food shelf
The effect of phase is more prominent.
The content of the invention
The present invention provides a kind of compound antiseptic packaging films of food preservation, and the compound antiseptic packaging films are especially suitable for right
The packaging of cold fresh meat, has cold fresh meat preferable antibacterial and Bao Se to act on.
The present invention provides following technical solution:
A kind of compound antiseptic packaging films of food preservation, including the PE film layers and chitosan being bonded to each other/lauramide essence
Propylhomoserin hydrochloride ethanol ester composite nano fiber layer;
In the chitosan/lauramide arginine monohydrochloride ethanol ester (LAE) composite nano fiber layer, chitosan with
The mass ratio of lauramide arginine monohydrochloride ethanol ester is 1~5: 1.
Can mutually it be cooperateed between chitosan and lauramide arginine monohydrochloride ethanol ester in composite nano fiber layer
Effect, makes composite nano fiber layer have a preferable antibacterial effect, at the same the PE film layers of outer layer can stop well cold fresh meat and
The contact of outside air, reduces pollution of the bacterium to cold fresh meat in air.
Preferably, the mass ratio of chitosan and lauramide arginine monohydrochloride ethanol ester is 1~2: 1.
Chitosan and lauramide arginine monohydrochloride ethanol ester ratio the two is mutually cooperateed with antibacterial effect have compared with
When big influence, chitosan and excessive lauramide arginine monohydrochloride ethanol ester mass ratio, due to lauramide arginine salt
The relatively low fungistatic effect of hydrochlorate ethanol ester content does not reach optimum efficiency;Chitosan and lauramide arginine monohydrochloride ethanol ester matter
Amount than it is too small when, due between chitosan and lauramide arginine monohydrochloride ethanol electrostatic interaction formed polymer on the contrary
The biocidal property of compound can be reduced.
There are countless tiny holes in composite nano fiber layer, considerably increase chitosan/lauramide arginine salt
The contact area of hydrochlorate ethanol ester composite nano fiber and cold fresh meat top layer air, improves chitosan and lauramide arginine salt
Hydrochlorate ethanol ester is to the inhibitory action of bacterium in the air of cold fresh meat top layer, the fungistatic effect of raising film entirety.Preferably, it is described
In chitosan/lauramide arginine monohydrochloride ethanol ester composite nano fiber layer, porosity is 65~75%;Form compound receive
A diameter of 120~200nm of the nanofiber of rice fibrous layer.
Present invention also offers the preparation method of the compound antiseptic packaging films of food preservation, comprise the following steps:
(1) chitosan and lauramide arginine monohydrochloride ethanol ester are dissolved in the acid solution that volumetric concentration is 70~90%
In, obtain electrostatic spinning liquid;
The mass ratio of chitosan and lauramide arginine monohydrochloride ethanol ester is 1~5: 1;
(2) by the electrostatic spinning liquid electrostatic spinning to the surface of PE films, to obtain the final product.
The fibre diameter that electrostatic spinning obtains is uniform and controllable, and obtained nano fibrous membrane has higher specific surface area
And porosity, add chitosan/lauramide arginine monohydrochloride ethanol ester composite nano fiber and cold fresh meat top layer air
Contact area, improve its fungistatic effect.
Preferably, in the electrostatic spinning liquid, the mass ratio of chitosan and lauramide arginine monohydrochloride ethanol ester
For 1~2: 1.
The concentration and viscous effects electrostatic spinning process of electrostatic spinning liquid, diameter and form tool to obtained nanofiber
There is large effect.The excessive solution viscosity of chitosan concentration is excessive, and electrostatic spinning process cannot be smoothed out;Chitosan concentration mistake
Hour, the intermolecular company of twining is not enough to successfully carry out electrostatic spinning process.Preferably, in the electrostatic spinning liquid, chitosan
Mass concentration is 30~50g/L.
Preferably, the acid solution is acetic acid solution.Acetic acid contributes to chitosan and lauramide arginine monohydrochloride
The dissolving of ethanol ester, and acetic acid is nontoxic to human body.
Preferably, in step (2), electrospinning conditions are:Electric field strength is 1.5~2.5kV/cm, and it is 10 to receive distance
~15cm, electrostatic spinning flow velocity are 0.25~0.5ml/h.
It is further preferred that used specification of syringe is 5ml during electrostatic spinning, syringe needle is the 20G pins of tack
Head.
Compared with prior art, beneficial effects of the present invention are:
(1) the compound antiseptic packaging films of food preservation of the invention are prepared using electrospinning process, have fiber
Porous structure, therefore the compound antiseptic packaging films have high-specific surface area, and bacteriostatic agent LAE distributions can be made more uniform, carried
The fungistatic effect and fresh-keeping effect of high packaging film entirety;And there is mutually synergistic effect, enhancing is each other between chitosan and LAE
Fungistatic effect;When cold fresh meat carries out fresh-keeping using electrospinning chitosan/PE films, its total plate count 3 days is i.e. exceeded, and uses this hair
When bright packaging film carries out fresh-keeping, the total plate count of cold fresh meat 6 days is not exceeded, and yellowish pink keeps good;
(2) chitosan and LAE are food-grade, and are all biodegradable materials, nontoxic to human body;
(3) the preparation method technique of the compound antiseptic packaging films of food preservation of the invention is simple, suitable for industrial production.
Brief description of the drawings
Fig. 1 is the scanning electron microscope (SEM) photograph of the compound antiseptic packaging films of food preservation prepared by embodiment 3;
Pork is is packed using Application Example 1~3 and 1 gained composite membrane of comparative example by Fig. 2, the total plate count of cold fresh meat
Test result figure;
Above-mentioned pork is is packed using Application Example 1~3 and 1 gained composite membrane of comparative example by Fig. 3, the volatilization of cold fresh meat
Property alkali nitrogen test result figure;
Above-mentioned pork is is packed using Application Example 1~3 and 1 gained composite membrane of comparative example by Fig. 4, the color of cold fresh meat
Test result figure.
Embodiment
Embodiment 1
5g chitosans are dissolved in 70% acetic acid solution of 100mL, magnetic agitation is to being completely dissolved, to chitosan acetic acid
The LAE of 1.0g is added in solution, is stirred evenly, ultrasonic de-bubble, spinning solution is made;Spinning is carried out using electrostatic spinning apparatus, it is quiet
Electrospun specification of syringe is 2.5mL, and syringe needle is tack, 20G.Voltage is 15kV, flow velocity 0.3mL/h, distance 10cm, using turning
Drum receives, in rotary drum reception device overlying PE film, after the completion of obtain composite electrostatic spinning nano fibrous membrane.
Embodiment 2
5g chitosans are dissolved in 80% acetic acid solution of 100mL, magnetic agitation is to being completely dissolved, to chitosan acetic acid
The LAE of 2.5g is added in solution, is stirred evenly, ultrasonic de-bubble, spinning solution is made;Spinning is carried out using electrostatic spinning apparatus, it is quiet
Electrospun specification of syringe is 2.5mL, and syringe needle is tack, 20G.Voltage is 15kV, flow velocity 0.3mL/h, distance 10cm, using turning
Drum receives, in rotary drum reception device overlying PE film, after the completion of obtain composite electrostatic spinning nano fibrous membrane.
Embodiment 3
5g chitosans are dissolved in 70% acetic acid solution of 100mL, magnetic agitation is to being completely dissolved, to chitosan acetic acid
The LAE of 5.0g is added in solution, is stirred evenly, ultrasonic de-bubble, spinning solution is made;Spinning is carried out using electrostatic spinning apparatus, it is quiet
Electrospun specification of syringe is 2.5mL, and syringe needle is tack, 20G.Voltage is 15kV, flow velocity 0.3mL/h, distance 10cm, using turning
Drum receives, in rotary drum reception device overlying PE film, after the completion of obtain composite electrostatic spinning nano fibrous membrane.
The scanning electron microscope (SEM) photograph of the composite electrostatic spinning nano fibrous membrane of preparation is as shown in Figure 1.
Comparative example 1
5g chitosans are dissolved in 70% acetic acid solution of 100mL, to being completely dissolved, ultrasonic de-bubble, makes magnetic agitation
Obtain spinning solution;Spinning is carried out using electrostatic spinning apparatus, electrostatic spinning specification of syringe is 2.5mL, and syringe needle is tack, 20G.Electricity
Pressing as 15kV, flow velocity 0.3mL/h, distance 10em, is received using rotary drum, in rotary drum reception device overlying PE film, after the completion of
Obtain chitosan Electrospun nano-fibers film.
Application examples
The fresh pork under the cutting of pig farm is chosen, with sterile packed, 4 DEG C of refrigerating boxes are transported to laboratory, are randomly divided into 4
Group, every group 5 pieces.Meat is put into the common ABS pallets of supermarket in super-clean bench.
Application Example 1~3 and 1 gained composite membrane of comparative example pack above-mentioned pork, are sterilized with ultra violet lamp
PE films determine pork total plate count, Volatile Base Nitrogen and face in the environment of 4 DEG C under the conditions of Different Package as control
The change of color, respectively as shown in Figure 2, Figure 3 and Figure 4.
According to Fig. 2, Fig. 3 and Fig. 4, when cold fresh meat carries out fresh-keeping using electrospinning chitosan/PE films, its total plate count 3
It is i.e. exceeded, and when packaging film using the present invention carries out fresh-keeping, and the total plate count 6 days of cold fresh meat is not exceeded, and yellowish pink protects
The compound antiseptic packaging films for well, illustrating the present invention are held especially suitable for the packaging to cold fresh meat, are had to cold fresh meat preferable
Antibacterial and Bao Se effects.
Total plate count is measured according to the assay method of national standard GB4789.2-2016 food microorganisms total plate counts;Wave
Hair property alkali nitrogen is measured according to the assay method of Volatile Base Nitrogen in national standard GB 5009.228-2016 food;Color becomes
Change according to CIE1976 (L*a*b*) colour space method is measured.
Technical scheme and beneficial effect is described in detail in embodiment described above, it should be understood that
The foregoing is merely the specific embodiment of the present invention, it is not intended to limit the invention, it is all to be done in the spirit of the present invention
Any modification, supplementary, and equivalent replacement etc., should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of compound antiseptic packaging films of food preservation, it is characterised in that including the PE film layers being bonded to each other and chitosan/moon
Osmanthus acid amides arginine monohydrochloride ethanol ester composite nano fiber layer;
In the chitosan/lauramide arginine monohydrochloride ethanol ester composite nano fiber layer, chitosan and lauramide
The mass ratio of arginine monohydrochloride ethanol ester is 1~5: 1.
2. the compound antiseptic packaging films of food preservation according to claim 1, it is characterised in that the chitosan/moon
In the acid amides arginine monohydrochloride ethanol ester composite nano fiber layer of osmanthus, chitosan and lauramide arginine monohydrochloride ethanol ester
Mass ratio is 1~2: 1.
3. the compound antiseptic packaging films of food preservation according to claim 1 or 2, it is characterised in that the chitosan/
In lauramide arginine monohydrochloride ethanol ester composite nano fiber layer, porosity is 65~75%;Form composite nano fiber
A diameter of 100~200nm of the nanofiber of layer.
4. a kind of preparation method of the compound antiseptic packaging films of food preservation, it is characterised in that comprise the following steps:
(1) chitosan and lauramide arginine monohydrochloride ethanol ester are dissolved in the acid solution that volumetric concentration is 70~90%,
Obtain electrostatic spinning liquid;
The mass ratio of chitosan and lauramide arginine monohydrochloride ethanol ester is 1~5: 1;
(2) by the electrostatic spinning liquid electrostatic spinning to the surface of PE films, to obtain the final product.
5. the preparation method of the compound antiseptic packaging films of food preservation according to claim 4, it is characterised in that described
In electrostatic spinning liquid, the mass ratio of chitosan and lauramide arginine monohydrochloride ethanol ester is 1~2: 1.
6. the preparation method of the compound antiseptic packaging films of food preservation according to claim 4 or 5, it is characterised in that institute
In the electrostatic spinning liquid stated, the mass concentration of chitosan is 30~50g/L.
7. the preparation method of the compound antiseptic packaging films of food preservation according to claim 4 or 5, it is characterised in that institute
The acid solution stated is acetic acid solution.
8. the preparation method of the compound antiseptic packaging films of food preservation according to claim 4, it is characterised in that step
(2) in, electrospinning conditions are:Electric field strength is 1.5~2.5kV/cm, and it is 10~15cm to receive distance, electrostatic spinning liquid stream
Speed is 0.25~0.5ml/h.
9. the preparation method of the compound antiseptic packaging films of food preservation according to claim 8, it is characterised in that Static Spinning
Used specification of syringe is 5ml during silk, and syringe needle is the 20G syringe needles of tack.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109252293A (en) * | 2018-09-03 | 2019-01-22 | 内蒙古农业大学 | A kind of nano polymer fibers film and preparation method thereof and purposes |
CN111269515A (en) * | 2020-04-04 | 2020-06-12 | 北京农学院 | Degradable film with antibacterial function and preparation method thereof |
CN113529274A (en) * | 2021-08-19 | 2021-10-22 | 澜海生态农业(杭州)有限公司 | Nanofiber membrane and application thereof, nanofiber membrane sterilization liquid and application method thereof |
CN114589976A (en) * | 2022-03-02 | 2022-06-07 | 江苏洁雅家居用品有限公司 | Antibacterial nanofiber preservative film and preparation method thereof |
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CN102919337A (en) * | 2012-10-29 | 2013-02-13 | 南京大地冷冻食品有限公司 | Compound chilled meat preservative |
US20130136832A1 (en) * | 2010-04-03 | 2013-05-30 | Anthony Joseph Sawyer | Methods of preservation |
CN106432774A (en) * | 2016-09-28 | 2017-02-22 | 东北林业大学 | Preparation method of chitosan/Nisin composite preservative film, and application of chitosan/Nisin composite preservative film to pork fresh preservation |
CN106668930A (en) * | 2016-11-24 | 2017-05-17 | 浙江大学 | Method for preparing Nisin/chitosan/polylactic acid composite nanofiber mats by coaxial electrospinning |
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2017
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Patent Citations (4)
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US20130136832A1 (en) * | 2010-04-03 | 2013-05-30 | Anthony Joseph Sawyer | Methods of preservation |
CN102919337A (en) * | 2012-10-29 | 2013-02-13 | 南京大地冷冻食品有限公司 | Compound chilled meat preservative |
CN106432774A (en) * | 2016-09-28 | 2017-02-22 | 东北林业大学 | Preparation method of chitosan/Nisin composite preservative film, and application of chitosan/Nisin composite preservative film to pork fresh preservation |
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Non-Patent Citations (1)
Title |
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LAURA HIGUERAS等: "Development of a novel antimicrobial film based on chitosan with LAE (ethyl-Nα-dodecanoyl-L-arginate) and its application to fresh chicken", 《INTERNATIONAL JOURNAL OF FOOD MICROBIOLOGY》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109252293A (en) * | 2018-09-03 | 2019-01-22 | 内蒙古农业大学 | A kind of nano polymer fibers film and preparation method thereof and purposes |
CN111269515A (en) * | 2020-04-04 | 2020-06-12 | 北京农学院 | Degradable film with antibacterial function and preparation method thereof |
CN113529274A (en) * | 2021-08-19 | 2021-10-22 | 澜海生态农业(杭州)有限公司 | Nanofiber membrane and application thereof, nanofiber membrane sterilization liquid and application method thereof |
CN114589976A (en) * | 2022-03-02 | 2022-06-07 | 江苏洁雅家居用品有限公司 | Antibacterial nanofiber preservative film and preparation method thereof |
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