CN107987649A - A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component - Google Patents

A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component Download PDF

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Publication number
CN107987649A
CN107987649A CN201711414370.XA CN201711414370A CN107987649A CN 107987649 A CN107987649 A CN 107987649A CN 201711414370 A CN201711414370 A CN 201711414370A CN 107987649 A CN107987649 A CN 107987649A
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insulating
fire
cracking resistance
powder
ball
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韩昕冉
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component, it is characterised in that:Addition accounts for the nano silicon dioxide and 0.5 5% graphene microchip of the basic Ingredients Weight 1 5% of heat-insulating and fire-proof coating in heat-insulating and fire-proof coating;The cracking resistance of coating is improved by adding nano silicon dioxide and both inorganic non-metallic materials of graphene microchip.Above-mentioned graphene microchip is (such as Diamond Deposit class) with the three-dimensional brilliant generation of cellular fashion length, and four valence electrons of each carbon atom form covalent bond and have been bound, the electron stream of displacement cannot be formed, then cannot be conductive, graphite carbon crystal utilizes the nano-milled mode of wet type after generation, ground with single direction, generation thickness is nanosizing, and area is micronized graphene microchip;Graphene microchip is added in coating can greatly promote the fusion performance of coating, have extraordinary cracking resistance.

Description

A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component
Technical field
The present invention relates to technical field of inorganic nonmetallic materials, and in particular to a kind of anti-cracking resistance heat-insulating and fire-proof coating important set Into component.
Background technology
Coating is a kind of new thermal insulation material, is the high-quality height for integrating closed pore structure and reticular fiber structure Imitate thermal insulation material.In use temperature range.Can long-time service, it is non-aging, never degenerate, be nonpoisonous and tasteless, heat-insulating property it is long-term Do not subtract, have that body is light, thermal conductivity factor is small, every cold, heat-insulated, the shockproof, sound-absorbing the features such as, can be widely used for metallurgy, chemical industry, oil, It is free from environmental pollution easy to construct in the industries such as ship, weaving, medicine, traffic, thermoelectricity, building, skin is not stimulated, construction is lossless The features such as consumption.
Thermal insulation coatings select speciality solution, and nano ceramics hollow bead, aluminosilicate fiber, various reflecting materials are main former Material, thermal conductivity factor only have 0.03W/m.K, and heatproof amplitude can effectively suppress at -80-1800 DEG C and shield the radiant heat of infrared ray With the conduction of heat, heat-insulated suppression efficiency can inhibit the heat radiation of high temp objects and scattering and disappearing for heat, to room up to 90% or so Interior heat can keep 70% not scatter and disappear, and effectively can simultaneously suppress cold damage caused by environmental radiation heat by cold insulation to cryogenic object Lose, can prevent condensation.The anti-cracking resistance heat-insulating and fire-proof coating material temperatures of 8mm are coated with regard to that can be reduced in 1100 DEG C of body surfaces Within 100 DEG C.Sprayed in the outer surface of high-temperature pipe, equipment, container, can effectively suppress heat radiation and the loss of heat, passed through Test:The anti-cracking resistance heat-insulating and fire-proof coating of 6mm thickness is only applied in Industrial Stoves outer surface can reduce thermal loss more than 30%, Brush kiln inner wall can and flame infrared reflection function more smooth than any material surfacing, reduce the heat absorption of furnace wall, make The flame temperature life of burner hearth is high.When the anti-cracking resistance heat-insulating and fire-proof coating of subzero 30 DEG C of babinets painting 10mm thickness, 24 is small in babinet Temperature be not less than 0 DEG C.In addition the anti-cracking resistance heat-insulating and fire-proof coating chloride ion content is zero, can also be prevented wet in air or technique Chloride enter, contacting metal surface, will not cause the weld seam that metal welds brittle.The insulating coefficient of coating is very high, has very Insulation effect at a high temperature of good.
World climate warms, and earth energy is increasingly exhausted.In AND ENERGY RESOURCES CONSUMPTION IN CHINA, building energy consumption accounts for mankind's energy consumption 30-40%, improve building heat preserving heat-proof quality be save the energy, improve building use function important channel.It is heat-insulated Coating, which is applied over building surface, can effectively reduce the temperature of building surface and inside.In recent years, with building energy conservation Promote, insulating moulding coating has been to be concerned by more and more people because of the advantages that economy, convenient and good heat-insulation effect.Therefore, research and develop Daily life of new, the compound insulating mold coating to the mankind is of great immediate significance.
The content of the invention
The technical problems to be solved by the invention are that improving one kind prepares simple, the low anti-cracking resistance heat-insulating and fire-proof painting of cost Expect important composition component.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component, it is characterised in that:Add and account in heat-insulating and fire-proof coating The nano silicon dioxide of the basic Ingredients Weight 1-5% of heat-insulating and fire-proof coating and the graphene microchip of 0.5-5%;By adding nanometer Silica and both inorganic non-metallic materials of graphene microchip improve the cracking resistance of coating.
The concrete composition component of heat-insulating and fire-proof building materials coating of the present invention is, by weight percentage meter:
Above-mentioned graphene microchip is to be generated so that three-dimensional cellular fashion length is brilliant (such as Diamond Deposit class), and each carbon is former Four valence electrons of son all form covalent bond and have been bound, it is impossible to the electron stream of displacement is formed, then cannot be conductive, Graphite carbon crystal utilizes the nano-milled mode of wet type after generation, is ground with single direction, and generation thickness is nanosizing, and area is micro- The graphene microchip of riceization;Graphene microchip is added in coating can greatly promote the fusion performance of coating, and it is very good to have Cracking resistance.
The preparation method of above-mentioned nano silicon dioxide is as follows:
1) 1-3 in mass ratio:The ratio of 1-5 weighs SiO 2 powder and Neon SiC powder;
2) to the silica and sic powder that have weighed using absolute ethyl alcohol as decentralized medium, wherein powder and alcohol Mass ratio is 1:30, when ultrasonic disperse 1 is small on the supersonic cleaning machine of model ZB220-T;
3) mixture through ultrasonic disperse is put into nylon ball grinder, using agate ball as abrading-ball, ball material mass ratio is 7: 1, under conditions of rotating speed is 150 revs/min, when continuous ball milling 2 is small in the planetary ball mill of model QM-1SP;
4) powder that ball milling finishes is poured into powder dish together with agate abrading-ball, is dried at 80 DEG C, the type of baking oven Number it is 202-2 types;
5) powder of drying is sieved, takes out agate abrading-ball, then grind mixed powder, untill without compared with macro aggregate, So far, nano silicon dioxide is made.
The antioxidant is made of the component of following parts by weight:20 parts of dimethyl ketone oxime, 25 parts of peanut oil, soybean 4 parts of protein isolate, 2 parts of azelaic acid, 4 parts of isoamyl acetate, 2 parts of graphene, 10 parts of silicone oil, 4 parts of palm oil, 3 parts of atoleine, 4 parts of the tert-butyl alcohol.
The defoamer is made of the component of following parts by weight:12 parts of aerosil, 55 parts of mineral oil, nonyl 2 parts of diacid, 2 parts of dipotassium glycyrrhizinate, 2 parts of albutin, 8 parts of vaseline, 5 parts of microwax, 2 parts of nanometer silicon carbide, modified corn form sediment 5 parts of powder.
The beneficial effects of the invention are as follows:(1) elasticity and crack resistance are good;(2) preparation process is simple, and finished product is nonpoisonous and tasteless, green Colour circle is protected;(3) can save and not degenerate for a long time;(4) good leveling property, strong adhesive force when spreading;(5) not tortoise after long-time use Split, do not fall off.
Embodiment
To describe the technology contents of technical solution, construction feature, the objects and the effects in detail, below in conjunction with specific reality Example is applied to be explained in detail.
Embodiment 1
A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component, by weight percentage meter, are made of following components:
The cracking resistance of coating is improved by adding nano silicon dioxide and both inorganic non-metallic materials of graphene microchip Performance.
Above-mentioned graphene microchip is to be generated so that three-dimensional cellular fashion length is brilliant (such as Diamond Deposit class), and each carbon is former Four valence electrons of son all form covalent bond and have been bound, it is impossible to the electron stream of displacement is formed, then cannot be conductive, Graphite carbon crystal utilizes the nano-milled mode of wet type after generation, is ground with single direction, and generation thickness is nanosizing, and area is micro- The graphene microchip of riceization;Graphene microchip is added in coating can greatly promote the fusion performance of coating, and it is very good to have Cracking resistance.
The preparation method of above-mentioned nano silicon dioxide is as follows:
1) 1-3 is pressed:The ratio of 1-5 weighs SiO 2 powder and Neon SiC powder;
2) to the silica and sic powder that have weighed using absolute ethyl alcohol as decentralized medium, wherein powder and alcohol Mass ratio is 1:30, when ultrasonic disperse 1 is small on the supersonic cleaning machine of model ZB220-T;
3) mixture through ultrasonic disperse is put into nylon ball grinder, using agate ball as abrading-ball, ball material mass ratio is 7: 1, under conditions of rotating speed is 150 revs/min, when continuous ball milling 2 is small in the planetary ball mill of model QM-1SP;
4) powder that ball milling finishes is poured into powder dish together with agate abrading-ball, is dried at 80 DEG C, the type of baking oven Number it is 202-2 types;
5) powder of drying is sieved, takes out agate abrading-ball, then grind mixed powder, untill without compared with macro aggregate, So far, nano silicon dioxide is made.
The antioxidant is made of the component of following parts by weight:20 parts of dimethyl ketone oxime, 25 parts of peanut oil, soybean 4 parts of protein isolate, 2 parts of azelaic acid, 4 parts of isoamyl acetate, 2 parts of graphene, 10 parts of silicone oil, 4 parts of palm oil, 3 parts of atoleine, 4 parts of the tert-butyl alcohol.
During production, first check whether equipment can run well, the various raw material of accurate measurement match somebody with somebody weight/power ratio and by life Stages of labor sequence is ready to, and then, the stirring motor for starting mixer keeps spiral and is in stirring, pre- by being put into again in mixer The mixture first prepared, it is uniformly finished product to disperse stir, grind, being stirred for;Discharging, product quality inspection, metering are simultaneously packed.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to Non-exclusive inclusion, so that process, method, article or terminal device including a series of elements not only include those Key element, but also including other elements that are not explicitly listed, or further include as this process, method, article or end The intrinsic key element of end equipment.In the absence of more restrictions, limited by sentence " including ... " or " including ... " Key element, it is not excluded that also there are other key element in the process including the key element, method, article or terminal device.This Outside, herein, " being more than ", " being less than ", " exceeding " etc. are interpreted as not including this number;" more than ", " following ", " within " etc. understand It is to include this number.
Although the various embodiments described above are described, those skilled in the art once know basic wound The property made concept, then can make these embodiments other change and modification, so the foregoing is merely the embodiment of the present invention, Not thereby the scope of patent protection of the present invention, every equivalent structure made using present specification or equivalent are limited Flow converts, and is directly or indirectly used in other related technical areas, is similarly included in the patent protection model of the present invention Within enclosing.

Claims (3)

1. a kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component, it is characterised in that percentage meter by weight is by following component system Into:
A kind of 2. anti-cracking resistance heat-insulating and fire-proof coating important composition component according to claim 1, it is characterised in that above-mentioned stone Black alkene microplate is that graphite carbon crystal utilizes the nano-milled mode of wet type after generation, with list with three-dimensional cellular fashion length brilliant generation One direction is ground, and generation thickness is nanosizing, and area is micronized graphene microchip.
3. a kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component according to claim 1, it is characterised in that above-mentioned to receive The preparation method of rice silica is as follows:
1) 1-3 in mass ratio:The ratio of 1-5 weighs SiO 2 powder and Neon SiC powder;
2) to the silica and sic powder that have weighed using absolute ethyl alcohol as decentralized medium, the wherein quality of powder and alcohol Than for 1:30, when ultrasonic disperse on supersonic cleaning machine 1 is small;
3) mixture through ultrasonic disperse is put into nylon ball grinder, using agate ball as abrading-ball, ball material mass ratio is 7:1, Under conditions of rotating speed is 150 revs/min, when continuous ball milling 2 is small;
4) powder that ball milling finishes is poured into powder dish together with agate abrading-ball, is dried at 80 DEG C, the model of baking oven 202-2 types;
5) powder of drying is sieved, takes out agate abrading-ball, then grind mixed powder, untill without compared with macro aggregate, so far, Nano silicon dioxide is made.
CN201711414370.XA 2017-12-25 2017-12-25 A kind of anti-cracking resistance heat-insulating and fire-proof coating important composition component Pending CN107987649A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877496A (en) * 2015-04-24 2015-09-02 安徽华强防水防腐材料有限公司 Important component of crack-resistant insulated flame-retardant building material coating

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104877496A (en) * 2015-04-24 2015-09-02 安徽华强防水防腐材料有限公司 Important component of crack-resistant insulated flame-retardant building material coating

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