CN107986804A - A kind of neutral refractory - Google Patents

A kind of neutral refractory Download PDF

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Publication number
CN107986804A
CN107986804A CN201711334003.9A CN201711334003A CN107986804A CN 107986804 A CN107986804 A CN 107986804A CN 201711334003 A CN201711334003 A CN 201711334003A CN 107986804 A CN107986804 A CN 107986804A
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CN
China
Prior art keywords
parts
oxide
neutral refractory
reducing agent
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711334003.9A
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Chinese (zh)
Inventor
周军州
李蓓
袁波
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Luoyang Mingli Science and Technology Development Co Ltd
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Luoyang Mingli Science and Technology Development Co Ltd
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Priority to CN201711334003.9A priority Critical patent/CN107986804A/en
Publication of CN107986804A publication Critical patent/CN107986804A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3241Chromium oxides, chromates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3244Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3817Carbides
    • C04B2235/3826Silicon carbides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/42Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
    • C04B2235/422Carbon
    • C04B2235/425Graphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Ceramic Products (AREA)

Abstract

The present invention proposes a kind of neutral refractory, is made from the following raw materials in parts by weight:4 10 parts of carborundum, 15 parts of aluminium oxide, 15 parts of chromium oxide, 15 parts of zirconium oxide, 26 parts of graphite powder, 4 10 parts of clay, 59 parts of tar.The neutral refractory coefficient of expansion is extremely low, light weight, thermal conductivity are high, from any acid erosion, do not react with acid-base property slag.

Description

A kind of neutral refractory
Technical field
The present invention relates to fire resisting material field, and in particular to a kind of neutral refractory.
Background technology
It is believed that acid slag, caustic slag, flux and other refractory materials chemistry can be preferably resisted at high temperature The refractory material of erosion is referred to as neutral refractory.Its key component has the trivalent oxygen such as carbon, carborundum, aluminium oxide, chromium oxide Compound, Al2O3C Bricks developed in recent years, zirconium carbon brick, aluminum oxide-silicon carbide-carbon brick, silicon nitride combined silicon carbide brick etc., Belong to neutral refractory.Neutral refractory is generally used for furnace bottom, cupola well, stove the bottom position of high temperature stove, at present market On neutral refractory materials price it is high, small producer cannot be used widely, the refractory materials of other properties is again unstable It is fixed, it is easy to other substance reactions in stove.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of neutral refractory to solve refractory material presence on the market Various shortcomings.
The object of the invention to solve the technical problems is realized using following technical scheme:
A kind of neutral refractory, is made from the following raw materials in parts by weight:4-10 parts of carborundum, 1-5 parts of aluminium oxide, oxidation 1-5 parts of chromium, 1-5 parts of zirconium oxide, 2-6 parts of graphite powder, 4-10 parts of clay, 5-9 parts of tar, 0.5-2.5 parts of water-reducing agent.
Preferably, the water-reducing agent is aluminous cement.
Preferably, also it is made from the following raw materials in parts by weight:4 parts of carborundum, 1 part of aluminium oxide, 1 part of chromium oxide, zirconium oxide 1 Part, 2 parts of graphite powder, 10 parts of clay, 5 parts of tar, 0.5 part of water-reducing agent.
Preferably, also it is made from the following raw materials in parts by weight:10 parts of carborundum, 5 parts of aluminium oxide, 5 parts of chromium oxide, zirconium oxide 5 parts, 6 parts of graphite powder, 5 parts of clay, 9 parts of tar, 2.5 parts of water-reducing agent.
A kind of neutral refractory coefficient of expansion proposed by the present invention is extremely low, light weight, thermal conductivity are high, from any acidity Corrode, do not react with acid-base property slag.
Embodiment
The invention will be further elucidated with reference to specific embodiments.
A kind of neutral refractory proposed by the present invention, is made from the following raw materials in parts by weight:4-10 parts of carborundum, oxidation 1-5 parts of aluminium, 1-5 parts of chromium oxide, 1-5 parts of zirconium oxide, 2-6 parts of graphite powder, 4-10 parts of clay, 5-9 parts of tar, water-reducing agent 0.5- 2.5 part.
Further, the water-reducing agent is aluminous cement.
Embodiment one:A kind of neutral refractory, is made of the raw material of following weight parts:4 parts of carborundum, 1 part of aluminium oxide, 1 part of chromium oxide, 1 part of zirconium oxide, 2 parts of graphite powder, 10 parts of clay, 5 parts of tar, 0.5 part of water-reducing agent.
Embodiment two:A kind of neutral refractory, is made of the raw material of following weight parts:10 parts of carborundum, aluminium oxide 5 Part, 5 parts of chromium oxide, 5 parts of zirconium oxide, 6 parts of graphite powder, 5 parts of clay, 9 parts of tar, 2.5 parts of water-reducing agent.
The above described is only a preferred embodiment of the present invention, limitation in any form is not done to the present invention, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any to be familiar with this professional technology people Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification For the equivalent embodiment of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit according to the present invention To any simple modification, equivalent change and modification made for any of the above embodiments, in the range of still falling within technical solution of the present invention.

Claims (4)

1. a kind of neutral refractory, it is characterised in that be made from the following raw materials in parts by weight:4-10 parts of carborundum, aluminium oxide 1-5 parts, 1-5 parts of chromium oxide, 1-5 parts of zirconium oxide, 2-6 parts of graphite powder, 4-10 parts of clay, 5-9 parts of tar, water-reducing agent 0.5-2.5 Part.
2. a kind of neutral refractory according to claim 1, it is characterised in that the water-reducing agent is aluminous cement.
3. a kind of neutral refractory according to claim 1, it is characterised in that be made from the following raw materials in parts by weight:Carbon 4 parts of SiClx, 1 part of aluminium oxide, 1 part of chromium oxide, 1 part of zirconium oxide, 2 parts of graphite powder, 10 parts of clay, 5 parts of tar, 0.5 part of water-reducing agent.
4. a kind of neutral refractory according to claim 1, it is characterised in that be made from the following raw materials in parts by weight:Carbon 10 parts of SiClx, 5 parts of aluminium oxide, 5 parts of chromium oxide, 5 parts of zirconium oxide, 6 parts of graphite powder, 5 parts of clay, 9 parts of tar, 2.5 parts of water-reducing agent.
CN201711334003.9A 2017-12-11 2017-12-11 A kind of neutral refractory Pending CN107986804A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711334003.9A CN107986804A (en) 2017-12-11 2017-12-11 A kind of neutral refractory

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711334003.9A CN107986804A (en) 2017-12-11 2017-12-11 A kind of neutral refractory

Publications (1)

Publication Number Publication Date
CN107986804A true CN107986804A (en) 2018-05-04

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CN201711334003.9A Pending CN107986804A (en) 2017-12-11 2017-12-11 A kind of neutral refractory

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675810A (en) * 2018-07-13 2018-10-19 贵州紫云月华新材料有限公司 A kind of production method of silica refractory

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1449312A (en) * 2000-08-31 2003-10-15 福塞科国际有限公司 Refractory articles
CN1740115A (en) * 2004-08-25 2006-03-01 武汉科技大学 Sailon corundum refractory material for permeable ladle stopper and its prepn process
CN1740114A (en) * 2004-08-25 2006-03-01 武汉科技大学 Refractory Sialon corundum brick material for blast flurnace and its prepn process
CN104130001A (en) * 2014-07-24 2014-11-05 宁国市开源电力耐磨材料有限公司 Neutral lining refractory material for electric induction furnace and manufacturing method thereof
CN105198440A (en) * 2015-11-02 2015-12-30 攀枝花学院 Silicon carbide crucible with thermal shock resistance and manufacturing technology of silicon carbide crucible

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1449312A (en) * 2000-08-31 2003-10-15 福塞科国际有限公司 Refractory articles
CN1740115A (en) * 2004-08-25 2006-03-01 武汉科技大学 Sailon corundum refractory material for permeable ladle stopper and its prepn process
CN1740114A (en) * 2004-08-25 2006-03-01 武汉科技大学 Refractory Sialon corundum brick material for blast flurnace and its prepn process
CN104130001A (en) * 2014-07-24 2014-11-05 宁国市开源电力耐磨材料有限公司 Neutral lining refractory material for electric induction furnace and manufacturing method thereof
CN105198440A (en) * 2015-11-02 2015-12-30 攀枝花学院 Silicon carbide crucible with thermal shock resistance and manufacturing technology of silicon carbide crucible

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675810A (en) * 2018-07-13 2018-10-19 贵州紫云月华新材料有限公司 A kind of production method of silica refractory

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