CN107986763A - A kind of water-based 3D printing base substrate method and its forming method - Google Patents

A kind of water-based 3D printing base substrate method and its forming method Download PDF

Info

Publication number
CN107986763A
CN107986763A CN201711413232.XA CN201711413232A CN107986763A CN 107986763 A CN107986763 A CN 107986763A CN 201711413232 A CN201711413232 A CN 201711413232A CN 107986763 A CN107986763 A CN 107986763A
Authority
CN
China
Prior art keywords
base substrate
water
printing
slurry
printing base
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711413232.XA
Other languages
Chinese (zh)
Inventor
银锐明
徐凯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunan University of Technology
Original Assignee
Hunan University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunan University of Technology filed Critical Hunan University of Technology
Priority to CN201711413232.XA priority Critical patent/CN107986763A/en
Publication of CN107986763A publication Critical patent/CN107986763A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00—Producing shaped prefabricated articles from the material
    • B28B1/001—Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00—Processes of additive manufacturing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6023—Gel casting
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6026—Computer aided shaping, e.g. rapid prototyping

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Inorganic Chemistry (AREA)

Abstract

The present invention relates to 3D technology field, discloses a kind of water-based 3D printing forming method.The water-based 3D printing forming method comprises the following steps：S1. using water as carrier, the powder body material that addition can form suspension with water is made into powder suspension, and the solid volume fraction of the powder suspension is 20~65%, and organic monomer is added into powder suspension, and it is spare to obtain slurry A；S2. preparing can be spare with the substance B of step S1 organic monomers generation gelling reaction；S3. substance B in slurry A in step S1 and step S2 is uniformly mixed, obtains mixture C；S4. mixture C is delivered to 3D printing head and gives the condition that organic monomer can be accelerated to polymerize, printed according to three-dimensional modeling data, layer upon layer is molded, and finally obtains the base substrate of required shape；S5. base substrate is dried, obtains high intensity base substrate, then dumping and sintered, obtain final products.

Description

A kind of water-based 3D printing base substrate method and its forming method
Technical field
The present invention relates to 3D technology field, more particularly, to a kind of water-based 3D printing base substrate method and its forming method.
Background technology
3D printing technique is a kind of emerging rapid shaping technique, by being successively superimposed material manufacture 3 D stereo
The technology of structure material object, different from traditional removal material manufacture technology, therefore also known as increasing material manufacturing, 3D printing are main Selective laser sintering technology (SLS), melting sedimentation (FDM) and Stereo Lithography technology (SLA).
The high-strength high hardware features of advanced ceramics material and hard material, make it be difficult to be molded, development in science and technology to ceramics, Hard alloy product complexity and required precision are higher and higher, this has become the biggest obstacle of its application.And increasing material manufacturing（3D Printing）The appearance of technology, then make it possible breakthrough advanced ceramics application biggest obstacle i.e. difficult forming.3D printing ceramics nothing Proembryo and mould are needed, is also not required to process, just can be directly according to computer graphics data, the method by increasing material generates any The complex structure of shape, therefore paid close attention to be subject to domestic and international ceramic field expert height.The Gao Rong of ceramics and hard alloy Point, high hard brittleness cause its increasing material manufacturing to be most difficult to the material of printing shaping, usually to make by high molecular material or metal material 3D printing is carried out for binding agent.Adopt selective laser sintering, selective laser fusing, laser near-net-shape, electron beam selective melting etc. Straight forming mode can often produce larger thermal stress in rapid solidification, so that more micro-crack is formed, it is uncomfortable Close increasing material manufacturing ceramic material.Fused glass pellet mixes ceramic powders and organic binder bond, with extruder or capillary Blood vessel rheometer makes silk, and then layer molding mode makes ceramic member raw embryo, prepared by follow-up sintering.The shortcomings that the method It is that surface zonal texture occurs, formed precision is poor, needs follow-up grinding process.Photocuring is 3D printing technique formed precision highest, And efficiently, highly integrated, stock utilization is high, its print the operation principle of ceramic powders be by by laser added with ceramics Powder or presoma liquid photosensitive resin optionally curing molding complex parts, then through drying, degreasing, sintering, so can Although to protect the high accuracy of sign forming ceramic products, costly, system operates liquid requires harsh, shaping to its equipment Part is mostly resin, and material price is expensive and limited capacity, is unfavorable for storing for a long time, environmental pollution is serious.
For existing 3D printing technique there are the defects of, the present invention gel-casting technology is combined with 3D printing, proposition A kind of water-based 3D printing forming method, the principle of gel injection molding and forming technology is that situ-gel cures, and shaping speed is very fast, can Near-net-shape complex component, and even green body is good, high mechanical strength, sintering character are excellent, therefore expand gel note Mold forming technology is combined with 3D printing techniques, it will thus provide a kind of brand-new 3D printing technique, so as to solve existing 3D printing skill The defects of art, expand and apply the molding Material Fields of 3D significantly.
The content of the invention
The technical problem to be solved in the present invention in view of the deficiencies of the prior art, introduces casting molding technique, using water as carrier, With reference to 3D printing technique, there is provided a kind of brand-new water-based 3D printing base substrate method.
The present invention also provides a kind of water-based 3D printing forming method.
The purpose of the present invention is achieved by the following technical programs：
A kind of water-based 3D printing forming method is provided, is comprised the following steps：
S1. using water as carrier, the powder body material that addition can form suspension with water is made into powder suspension, the powder suspension Solid volume fraction be 20~65%, and organic monomer is added into powder suspension, it is spare to obtain slurry A；
S2. preparing can be spare with the substance B of step S1 organic monomers generation gelling reaction；
S3. substance B in slurry A in step S1 and step S2 is uniformly mixed, obtains mixture C；
S4. mixture C is delivered to 3D printing head and gives the condition that organic monomer can be accelerated to polymerize, according to three-dimensional modeling data Printed, layer upon layer shaping, finally obtain the base substrate of required shape.
The principle of the present invention forms the preferable powder of dispersiveness after being, using water as carrier, to add the powder body material of low-density Suspension, the powder suspension viscosity is low, and solid concentration is high, good fluidity, after adding organic monomer, by finely dispersed powder Particles coat in liquid suspension is allowed to fixation in situ, so as to obtain the suspension of the composite material of powder and macromolecule organic Liquid, the substance B by the way that gelling reaction occurs with organic monomer mix make organic monomer in suspension liquid occur to be chemically crosslinked or Three-dimensional network-like structure is physical crosslinking into, the base substrate of advanced base intensity and precision is quickly prepared with reference to 3D printing technique.
Preferably, powder body material described in step S1 be low-density ceramic powders or submicron metal, and can and water Form powder suspension.
Preferably, it is made into step S1 during powder suspension and is also added into crosslinking agent, is more preferably also added into point Powder, defrother, levelling agent, additive, the one or more of catalyst, addition dispersant further improve powder and are suspending Dispersiveness in liquid, adds crosslinking agent and forms multicomponent gel rubber system, for different organic monomer systems, it is necessary to using not Same corresponding initiator.
Preferably, substance B described in step S2 is initiator or light curing agent, according to actual conditions, in limited trials The best of breed that can make organic monomer that gelling reaction occur can be selected down, wherein initiator and catalyst cannot add at the same time, And need to separate storage before addition, therefore catalyst can be added in slurry A in advance.
Preferably, slurry A is mixed by way of gravity or injection with substance B described in step S3.
Wherein, slurry A of the present invention is using water as carrier, and the preferable powder of dispersiveness is formed after adding the powder body material of low-density Liquid suspension, its good fluidity, the two mixing can be achieved without ambient pressure.
The condition of the present invention that organic monomer can be accelerated to polymerize is that suitable condition is determined according to gel rubber system.
Preferably, it is ultraviolet light or laser beam that can accelerate the condition that organic monomer polymerize described in step S4.
Preferably, it is temperature that can accelerate the condition that organic monomer polymerize described in step S4.
Preferably, it is focused microwave that can accelerate the condition that organic monomer polymerize described in step S4.
The present invention also provides a kind of water-based 3D printing manufacturing process, the base substrate being prepared using the above method is done It is dry, high intensity base substrate is obtained, then dumping and sinters, obtains final products.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention for existing 3D printing technique there are the defects of, gel-casting technology is combined with 3D printing, propose one kind Water-based 3D printing forming method, the situ-gel principle of solidification is combined with 3D printing, without proembryo and mold developing, is also not required to add Work, just can be directly according to computer graphics data, and the method by increasing material generates the complex structure of any shape, should Method even green body in ensure that gel-casting technology is good, high mechanical strength, excellent sintering character the advantages of at the same time, also pole The earth improves production efficiency, and the base substrate green strength printed is high, precision is high.
The present invention using low viscosity, high solid volume fraction, good fluidity powder suspension as 3D printing raw material, without Conveying, mixing and extrusion can be realized in 3D printing equipment by ambient pressure, with cost is low, reliability is high, operational The advantages that strong, and hardening time is fast, it is high to cure precision, it is easy to accomplish industrialized production.
The present invention can reduce the viscosity of gelling precursor using water as solvent, avoid using caused by organic matter solvent Problem of environmental pollution, and drying process is simple, belongs to environmentally friendly technique, is adapted to industrialized production.
Brief description of the drawings
Fig. 1 present invention process flow charts.
Fig. 2 present device schematic diagrames.
Embodiment
The present invention provides a kind of water-based 3D printing forming method, and concrete technology method is as shown in Figure 1, comprise the following steps：
S1. using water as carrier, the powder body material that addition can form suspension with water is made into powder suspension, and the suspension is consolidated Phase volume fraction is 20~65%, and organic monomer is added into powder suspension, it is spare to obtain slurry A；
S2. preparing can be spare with the substance B of organic monomer generation gelling reaction in step S1；
S3. it is product mix spare in step S1 and step S2 is uniform, obtain mixture C；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. 3D printing head mixture C being delivered in 3D printing equipment, and given in 3D printing equipment and can accelerate organic list The condition of body polymerization, 3D printing head is controlled by computer, and layer upon layer is molded, and finally obtains the base substrate of required shape；
S6. the obtained base substrates of step S5 are dried, obtain high intensity base substrate, then dumping and sintered, obtain final products.
Wherein, it is that the powder body material of low-density and water are made into low viscosity, high solid volume fraction, mobility in step S1 Good powder suspension（According to actual conditions addition dispersant can be selected to improve solid concentration）, and simultaneous selection is suitable Organic monomer is added to component units gelling system in powder suspension, or the suitable organic monomer of selection and crosslinking agent add Polynary gel rubber system is formed into powder suspension；Substance B selects initiator or photocuring according to gel rubber system in step S2 Agent；It is also to be determined according to gel rubber system that can accelerate the condition that organic monomer polymerize in step S4.
For the above method, the water-based 3D printing former of the present invention may be designed to as shown in Fig. 2, including slurry tank 1, storage Batch can 2, mixing tank 3 and 3D printing equipment 4, slurry tank 1, storage tank 2 are connected with mixing tank 3 respectively, and mixing tank 3 is set with 3D printing First 41 connection of 3D printing in standby 4；
Agitating device 11 is equipped with slurry tank 1, discharge outlet is equipped with metering device 12, and 2 discharge outlet of storage tank is equipped with metering and fills 21 are put, agitating device 31 is equipped with mixing tank 3.
The water-based 3D printing former operation principle of the present invention is as follows：It can occur the slurry A prepared and with organic monomer The substance B of gelling reaction is individually positioned in slurry tank 1 and storage tank 2, if necessary to add initiator and catalyst at the same time, is stored up Batch can 2 at least needs to prepare 2 separately storage initiator and catalyst, then mixes, can also be directly being starched with slurry respectively Catalyst is first added in material, slurry, which fills the working status that the agitating device 11 in 1 is kept stirring, prevents slurry A from depositing, it is necessary to beat When print, three-dimensional modeling data is imported into 3D printing equipment 4, the material in slurry tank 1 and storage tank 2 is respectively by passing through meter Amount device 12 and metering device 21 prepare be delivered in mixing tank 3 in proportion, and the agitating device 31 in mixing tank 3 keeps work shape Mixture C, is delivered in the 3D printing head of 3D printing equipment 4 by state after mixing, and 3D printing equipment 4 is according to threedimensional model number Factually injection prints, need in print procedure to give temperature or ultraviolet light that 4 interior energy of 3D printing equipment accelerates organic monomer polymerization or Laser beam or focused microwave, obtain base substrate be dried again, dumping, sintering, finally obtain product.
Wherein, due to slurry A good fluidities, gravity is passed through（Such as under the control of valve）It can complete to convey, mix Close, without ambient pressure, it is contemplated that some situations need to accelerate the efficiency of 3D printing, can also be acted on by pressure（Such as note Penetrate or pump）To accelerate material conveying, mixing.The present invention realizes that the equipment for the condition for accelerating organic monomer polymerization can be heating dress Put, light irradiation apparatus or microwave tube etc., it can be on the print platform of 3D printing equipment to apply object.Specific device and structure Those skilled in the art can select and design according to actual conditions.
The present invention is further illustrated with reference to specific embodiment.Following embodiments are only illustrative examples, not structure Into inappropriate limitation of the present invention, the multitude of different ways that the present invention can be limited and covered by the content of the invention is implemented.It is unless special Do not mentionlet alone bright, the present invention reagent, compound and the equipment that use is the art conventional reagent, compound and equipment.
Embodiment 1
The present embodiment provides a kind of water-based 3D printing forming method, using Al2O3Original washing powder body is raw material, and energy is given in print procedure Accelerate the temperature of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 50wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 1wt%, dispersant PAA-NH4 is 4wt%, catalyst tetramethyl second two Amine（TMEDA）It is 0.1~1wt% for 5wt%, defrother, adds the Al that volume ratio is 55%2O3Original washing powder body, after ball grinding stirring Suspension slurry A to low viscosity, high solid volume fraction is spare；
S2. the initiator ammonium persulfate solution that configuration concentration is 1% is spare as substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the temperature that organic monomer can be accelerated to polymerize is given in print procedure, is specifically maintained under 150 DEG C of atmosphere and implements to beat Print so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
Originally it is embodied as ensureing to be molded soon during 3D printing（Each layer will not produce deformation during layer upon layer）, improve cure speed Rate and green strength, optimize the proportioning of slurry A, suitably（It is too high to cause impurity excessive on the contrary）Improve the weight of monomer addition Percentage is measured, and implements printing under 150 DEG C of atmosphere.
The base substrate green strength that the present embodiment is prepared reaches 41MPa, and relative density more than 96% is sintered in normal temperature air.
Embodiment 2
The present embodiment provides a kind of water-based 3D printing forming method, using Al2O3Original washing powder body is raw material, and energy is given in print procedure Accelerate the temperature of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 45t%, Crosslinking agent methylene-bisacrylamide（MBAM）For 0.5wt%, dispersant PAA-NH4 is 3wt%, tetramethylethylenediamine（TMEDA） It is 0.1~1wt%% for 4wt%, defrother, is controlled solution ph 9 or so by ammonium hydroxide, it is 55% to add volume ratio Al2O3Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
S2. the initiator ammonium persulfate solution that configuration concentration is 1% is spare as substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the temperature that organic monomer can be accelerated to polymerize is given in print procedure, is specifically maintained under 150 DEG C of atmosphere and implements to beat Print so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 34MPa, and relative density more than 95% is sintered in normal temperature air.
Embodiment 3
The present embodiment provides a kind of water-based 3D printing forming method, using Al2O3Original washing powder body is raw material, and energy is given in print procedure Accelerate the temperature of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 55wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 1.5wt%, dispersant PAA-NH4 is 5wt%, tetramethylethylenediamine （TMEDA）It is 0.1~1wt%% for 6wt%, defrother, is controlled solution ph 9 or so by ammonium hydroxide, adding volume ratio is 55% Al2O3Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
The initiator ammonium persulfate solution that S2 configuration concentrations are 1% is spare as substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the temperature that organic monomer can be accelerated to polymerize is given in print procedure, is specifically maintained under 150 DEG C of atmosphere and implements to beat Print so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 36MPa, and relative density more than 97% is sintered in normal temperature air.
Embodiment 4
The present embodiment is substantially the same manner as Example 1, and difference is, Al in step S12O3The volume fraction of original washing powder body is 65%。
The present embodiment the present embodiment changes Al2O3Original washing powder body volume fraction, the base substrate green strength being prepared reach 39MPa, relative density more than 97% is sintered in normal temperature air.
Embodiment 5
The present embodiment is substantially the same manner as Example 1, and difference is, Al in step S12O3The volume fraction of original washing powder body is 20%。
The present embodiment the present embodiment changes Al2O3Original washing powder body volume fraction, the base substrate green strength being prepared reach 32MPa, relative density more than 95% is sintered in normal temperature air.
Embodiment 6
The present embodiment provides a kind of water-based 3D printing forming method, using ZrO2Original washing powder body is raw material, and energy is given in print procedure Accelerate the ultraviolet light or laser beam of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 50wt%, additive ethyl acetate（EA）For 8wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 1wt%, dispersant PAA- NH4 is 4wt%, defrother is 0.1~1wt%%, is controlled solution ph 9 or so by ammonium hydroxide, adds volume ratio as 50% ZrO2Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
S2. a certain amount of light curing agent that can trigger gelling reaction is configured（Light curing agent 819）, it is spare to obtain substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the ultraviolet light or laser beam that organic monomer can be accelerated to polymerize are given in print procedure, specifically in wavelength 365~405 Printed under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
Originally it is embodied as ensureing to be molded soon during 3D printing（Each layer will not produce deformation during layer upon layer）, improve cure speed Rate and green strength, optimize the proportioning of slurry A, suitably（It is too high to cause impurity excessive on the contrary）Improve the weight of monomer addition Percentage is measured, and with the addition of additive ethyl acetate（EA）, implement printing under ultraviolet light or laser beam atmosphere.
The base substrate green strength that the present embodiment is prepared reaches 20MPa, and relative density more than 96% is sintered in normal temperature air.
Embodiment 7
The present embodiment provides a kind of water-based 3D printing forming method, using ZrO2Original washing powder body is raw material, and energy is given in print procedure Accelerate the ultraviolet light or laser beam of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 45wt%, additive ethyl acetate（EA）For 7wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 0.5wt%, dispersant PAA-NH4 is 3wt%, defrother is 0.1~1wt%%, is controlled solution ph 9 or so by ammonium hydroxide, adding volume ratio is 50% ZrO2Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
S2. a certain amount of light curing agent that can trigger gelling reaction is configured（Light curing agent 819）, it is spare to obtain substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the ultraviolet light or laser beam that organic monomer can be accelerated to polymerize are given in print procedure, specifically in wavelength 365~405 Printed under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 15MPa, and relative density more than 95% is sintered in normal temperature air.
Embodiment 8
The present embodiment provides a kind of water-based 3D printing forming method, using ZrO2Original washing powder body is raw material, and energy is given in print procedure Accelerate the ultraviolet light or laser beam of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 55wt%, additive ethyl acetate（EA）For 9wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 2wt%, dispersant PAA- NH4 is 5wt%, defrother is 0.1~1wt%%, is controlled solution ph 9 or so by ammonium hydroxide, adds volume ratio as 50% ZrO2Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
S2. a certain amount of light curing agent that can trigger gelling reaction is configured（Light curing agent 819）, it is spare to obtain substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the ultraviolet light or laser beam that organic monomer can be accelerated to polymerize are given in print procedure, specifically in wavelength 365~405 Printed under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 17MPa, and relative density more than 96% is sintered in normal temperature air.
Embodiment 9
The present embodiment is substantially the same manner as Example 6, and difference is, ZrO described in step S12The volume fraction of original washing powder body is 65%。
The present embodiment changes ZrO2Original washing powder body volume fraction, the base substrate green strength being prepared reach 19MPA, sintering Relative density is obtained afterwards reaches more than 97%.
Embodiment 10
The present embodiment is substantially the same manner as Example 6, and difference is, ZrO described in step S12The volume fraction of original washing powder body is 20%。
The present embodiment changes ZrO2Original washing powder body volume fraction, the base substrate green strength being prepared reach 95MPA, sintering Relative density is obtained afterwards reaches more than 95%.
Embodiment 11
The present embodiment provides a kind of water-based 3D printing forming method, using Si3N4Original washing powder body is raw material, and energy is given in print procedure Accelerate the focused microwave of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 50wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 1wt%, dispersant PAA-NH4 is 4wt%, catalyst tetramethyl second two Amine（TMEDA）It is 0.1~1wt%% for 3wt%, defrother, solution ph is controlled 9 or so by ammonium hydroxide, adds volume ratio For 45% Si3N4Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
S2. the initiator ammonium persulfate solution that configuration concentration is 1% is spare as substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the focused microwave that organic monomer can be accelerated to polymerize is given in print procedure, is specifically maintained at focused microwave（By setting Put microwave tube）Implement printing under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base of required shape Body；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
Originally it is embodied as ensureing to be molded soon during 3D printing（Each layer will not produce deformation during layer upon layer）, improve cure speed Rate and green strength, optimize the proportioning of slurry A, suitably（It is too high to cause impurity excessive on the contrary）Improve the weight of monomer addition Percentage is measured, and implements printing under focused microwave atmosphere.
Focused microwave is produced by microwave tube in the present embodiment, and design parameter is according to 600 watts~800 watts progress phases of micro-wave oven The adjustment answered.
The base substrate green strength that the present embodiment is prepared reaches 43MPa, and relative density more than 98% is sintered in normal temperature air.
Embodiment 12
The present embodiment provides a kind of water-based 3D printing forming method, using Si3N4Original washing powder body is raw material, and energy is given in print procedure Accelerate the focused microwave of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 45wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 0.5wt%, dispersant PAA-NH4 is 3wt%, catalyst tetramethyl second Diamines（TMEDA）It is 0.1~1wt%% for 2wt%, defrother, solution ph is controlled 9 or so by ammonium hydroxide, adds volume Than the Si for 45%3N4Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
S2. the initiator ammonium persulfate solution that configuration concentration is 1% is spare as substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the focused microwave that organic monomer can be accelerated to polymerize is given in print procedure, is specifically maintained at focused microwave（By setting Put microwave tube）Implement printing under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base of required shape Body；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 37MPa, and relative density more than 97% is sintered in normal temperature air.
Embodiment 13
The present embodiment provides a kind of water-based 3D printing forming method, using Si3N4Original washing powder body is raw material, and energy is given in print procedure Accelerate the focused microwave of organic monomer polymerization, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 55wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 1.5wt%, dispersant PAA-NH4 is 5wt%, catalyst tetramethyl second Diamines（TMEDA）It is 0.1~1wt%% for 4wt%, defrother, solution ph is controlled 9 or so by ammonium hydroxide, adds volume Than the Si for 45%3N4Original washing powder body, it is spare to obtain low viscosity, the suspension slurry A of high solid volume fraction after ball grinding stirring；
S2. the initiator ammonium persulfate solution that configuration concentration is 1% is spare as substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the focused microwave that organic monomer can be accelerated to polymerize is given in print procedure, is specifically maintained at focused microwave（By setting Put microwave tube）Implement printing under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base of required shape Body；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 39MPa, and relative density more than 98% is sintered in normal temperature air.
Embodiment 14
The present embodiment is substantially the same manner as Example 11, and difference is, Si described in step S13N4Original washing powder volume fraction is 65%。
The present embodiment changes Si3N4Original washing powder volume fraction, the base substrate green strength being prepared reach 41MPa, normal temperature air Middle sintering relative density more than 98%.
Embodiment 15
The present embodiment is substantially the same manner as Example 11, and difference is, Si described in step S13N4Original washing powder volume fraction is 20%。
The present embodiment changes Si3N4Original washing powder volume fraction, the base substrate green strength being prepared reach 35MPa, normal temperature air Middle sintering relative density more than 97%.
Embodiment 16
The present embodiment provides a kind of water-based 3D printing forming method, submicron metal nano silver powder is used as raw material, is printed During give can accelerate organic monomer polymerize ultraviolet light or laser beam, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 50wt%, additive ethyl acetate（EA）For 8wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 1wt%, defrother 0.1 ~1wt%%, adds the nano silver powder that volume ratio is 50%, obtain after ball grinding stirring low viscosity, high solid volume fraction it is outstanding Buoyant slurry A is spare；
S2. a certain amount of light curing agent that can trigger gelling reaction is configured（Light curing agent 819）, it is spare to obtain substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the ultraviolet light or laser beam that organic monomer can be accelerated to polymerize are given in print procedure, specifically in wavelength 365~405 Printed under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
Originally it is embodied as ensureing to be molded soon during 3D printing（Each layer will not produce deformation during layer upon layer）, improve cure speed Rate and green strength, optimize the proportioning of slurry A, suitably（It is too high to cause impurity excessive on the contrary）Improve the weight of monomer addition Percentage is measured, and with the addition of additive ethyl acetate（EA）, implement printing under ultraviolet light or laser beam atmosphere.
The base substrate green strength that the present embodiment is prepared reaches 24MPa, and relative density more than 98% is sintered in normal temperature air.
Embodiment 17
The present embodiment provides a kind of water-based 3D printing forming method, submicron metal nano silver powder is used as raw material, is printed During give can accelerate organic monomer polymerize ultraviolet light or laser beam, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 45wt%, additive ethyl acetate（EA）For 7wt%, crosslinking agent methylene-bisacrylamide（MBAM）It is for 0.5wt%, defrother 0.1~1wt%%, adds the nano silver powder that volume ratio is 50%, low viscosity, high solid volume fraction is obtained after ball grinding stirring Suspension slurry A it is spare；
S2. a certain amount of light curing agent that can trigger gelling reaction is configured（Light curing agent 819）, it is spare to obtain substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the ultraviolet light or laser beam that organic monomer can be accelerated to polymerize are given in print procedure, specifically in wavelength 365~405 Printed under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 18MPa, and relative density more than 97% is sintered in normal temperature air.
Embodiment 18
The present embodiment provides a kind of water-based 3D printing forming method, submicron metal nano silver powder is used as raw material, is printed During give can accelerate organic monomer polymerize ultraviolet light or laser beam, comprise the following steps：
S1. using water as carrier, it is monomer N, N- methylene bisacrylamide acyl to add mass ratio into deionized water（DMAA）For 55wt%, additive ethyl acetate（EA）For 9wt%, crosslinking agent methylene-bisacrylamide（MBAM）For 2wt%, defrother 0.1 ~1wt%%, adds the nano silver powder that volume ratio is 65%, obtain after ball grinding stirring low viscosity, high solid volume fraction it is outstanding Buoyant slurry A is spare；
S2. a certain amount of light curing agent that can trigger gelling reaction is configured（Light curing agent 819）, it is spare to obtain substance B；
S3. the A material prepared by step S1 are placed in Fig. 2 in slurry tank 1, and are stirred.B material prepared by step S2 are placed in Fig. 2 In storage tank 2；
S4. data modeling：The part model of required planform is designed using 3D sculpting software, part model is divided Layer slicing treatment, synusia thickness is 0.05~0.2mm, obtains the three-dimensional modeling data of part, and import in 3D printing equipment；
S5. A material and B material are passed through metering in mass ratio 90~100 by equipment respectively by setting proportioning:2 are delivered to mixing tank in Fig. 2 Agitated to obtain mixture C in 3, then mixture C is delivered in the printhead in 3D printing equipment, according to three-dimensional modeling data Printed, the ultraviolet light or laser beam that organic monomer can be accelerated to polymerize are given in print procedure, specifically in wavelength 365~405 Printed under atmosphere so that mixture C cures rapidly, layer upon layer shaping, finally obtains the base substrate of required shape；
S6. the base substrate that step S5 is obtained is placed into 24~72h in room temperature, is then dried in vacuo at 60 DEG C, obtains high intensity base Body, then in the case where flowing atmospheric condition, keeps the temperature 3h at 600 DEG C by high intensity base substrate and carries out dumping processing, then be placed on vacuum bar Under part, temperature is to sinter 2h at 1000~1300 DEG C, obtains final products.
The base substrate green strength that the present embodiment is prepared reaches 21MPa, and relative density more than 98% is sintered in normal temperature air.
Embodiment 19
The present embodiment is substantially the same manner as Example 16, and difference is, the volume fraction of nano silver powder described in step S1 For 65%.
The present embodiment changes nano silver powder volume fraction, and the base substrate green strength being prepared reaches 23MPA, sintering Relative density is obtained afterwards reaches more than 98%.
Embodiment 20
The present embodiment is substantially the same manner as Example 16, and difference is, the volume fraction of nano silver powder described in step S1 For 20%.
The present embodiment changes nano silver powder volume fraction, and the base substrate green strength being prepared reaches 16MPA, sintering Relative density is obtained afterwards reaches more than 97%.

Claims (10)

  1. A kind of 1. water-based 3D printing base substrate method, it is characterised in that comprise the following steps：
    S1. using water as carrier, the powder body material that addition can form suspension with water is made into powder suspension, the powder suspension Solid volume fraction be 20~65%, and organic monomer is added into powder suspension, it is spare to obtain slurry A；
    S2. preparing can be spare with the substance B of step S1 organic monomers generation gelling reaction；
    S3. substance B in slurry A in step S1 and step S2 is uniformly mixed, obtains mixture C；
    S4. mixture C is delivered to 3D printing head and gives the condition that organic monomer can be accelerated to polymerize, according to three-dimensional modeling data Printed, layer upon layer shaping, finally obtain the base substrate of required shape.
  2. 2. water-based 3D printing base substrate method according to claim 1, it is characterised in that powder body material described in step S1 is pottery Porcelain powder or submicron metal.
  3. 3. water-based 3D printing base substrate method according to claim 1, it is characterised in that slurry A described in step S1 includes handing over Join agent.
  4. 4. water-based 3D printing base substrate method according to claim 1, it is characterised in that slurry A is further included described in step S1 Dispersant, defrother, levelling agent, additive, the one or more of catalyst.
  5. 5. water-based 3D printing base substrate method according to claim 1, it is characterised in that substance B described in step S2 is initiation Agent or curing agent.
  6. 6. water-based 3D printing base substrate method according to claim 5, it is characterised in that curing agent is consolidated for light described in step S2 Agent.
  7. 7. water-based 3D printing base substrate method according to claim 1, it is characterised in that organic list can be accelerated described in step S4 The condition of body polymerization is ultraviolet light or laser beam.
  8. 8. water-based 3D printing base substrate method according to claim 1, it is characterised in that organic list can be accelerated described in step S4 The condition of body polymerization is temperature.
  9. 9. water-based 3D printing base substrate method according to claim 1, it is characterised in that organic list can be accelerated described in step S4 The condition of body polymerization is focused microwave.
  10. 10. a kind of water-based 3D printing forming method, it is characterised in that comprise the following steps：By claim 1~9 any one The base substrate that the water-based 3D printing base substrate method is prepared is dried, and obtains high intensity base substrate, then dumping and sinters, obtains To final products.
CN201711413232.XA 2017-12-24 2017-12-24 A kind of water-based 3D printing base substrate method and its forming method Pending CN107986763A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711413232.XA CN107986763A (en) 2017-12-24 2017-12-24 A kind of water-based 3D printing base substrate method and its forming method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711413232.XA CN107986763A (en) 2017-12-24 2017-12-24 A kind of water-based 3D printing base substrate method and its forming method

Publications (1)

Publication Number Publication Date
CN107986763A true CN107986763A (en) 2018-05-04

Family

ID=62041613

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711413232.XA Pending CN107986763A (en) 2017-12-24 2017-12-24 A kind of water-based 3D printing base substrate method and its forming method

Country Status (1)

Country Link
CN (1) CN107986763A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116751054A (en) * 2023-06-21 2023-09-15 上海应用技术大学 Zirconia ceramic slurry, preparation method, application and zirconia ceramic

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003068511A (en) * 2001-08-22 2003-03-07 Sumitomo Metal Mining Co Ltd Composition for resin bond type magnet and method for manufacturing resin bond type magnet using the same
CN103801696A (en) * 2014-02-11 2014-05-21 北京科技大学 Method for preparing powder metallurgy complex shape part by using 3D printing mold
CN103801697A (en) * 2014-02-11 2014-05-21 北京科技大学 Method for forming mould-free gel with metal sizing agents through 3D printing
CN103980397A (en) * 2014-04-30 2014-08-13 中国科学院化学研究所 3D printing composition, preparation and application methods and product thereof
CN104628936A (en) * 2015-02-25 2015-05-20 湖北工业大学 Method for preparing high-strength double-network hydrogel stent by virtue of 3D printing
CN104841935A (en) * 2015-05-19 2015-08-19 北京科技大学 3D (three-dimensional) mixed slurry printing device and 3D mixed slurry printing forming method
CN105057665A (en) * 2015-08-17 2015-11-18 王海英 Three-dimensional part printing method
CN106938332A (en) * 2017-04-26 2017-07-11 北京科技大学 A kind of method that 3D gels printing prepares neodymium iron boron magnetic body
CN106965291A (en) * 2017-04-07 2017-07-21 南京先临三维科技有限公司 A kind of gel injection-moulding 3D printing preparation method of gradient ceramic

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003068511A (en) * 2001-08-22 2003-03-07 Sumitomo Metal Mining Co Ltd Composition for resin bond type magnet and method for manufacturing resin bond type magnet using the same
CN103801696A (en) * 2014-02-11 2014-05-21 北京科技大学 Method for preparing powder metallurgy complex shape part by using 3D printing mold
CN103801697A (en) * 2014-02-11 2014-05-21 北京科技大学 Method for forming mould-free gel with metal sizing agents through 3D printing
CN103980397A (en) * 2014-04-30 2014-08-13 中国科学院化学研究所 3D printing composition, preparation and application methods and product thereof
CN104628936A (en) * 2015-02-25 2015-05-20 湖北工业大学 Method for preparing high-strength double-network hydrogel stent by virtue of 3D printing
CN104841935A (en) * 2015-05-19 2015-08-19 北京科技大学 3D (three-dimensional) mixed slurry printing device and 3D mixed slurry printing forming method
CN105057665A (en) * 2015-08-17 2015-11-18 王海英 Three-dimensional part printing method
CN106965291A (en) * 2017-04-07 2017-07-21 南京先临三维科技有限公司 A kind of gel injection-moulding 3D printing preparation method of gradient ceramic
CN106938332A (en) * 2017-04-26 2017-07-11 北京科技大学 A kind of method that 3D gels printing prepares neodymium iron boron magnetic body

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116751054A (en) * 2023-06-21 2023-09-15 上海应用技术大学 Zirconia ceramic slurry, preparation method, application and zirconia ceramic

Similar Documents

Publication Publication Date Title
CN108017378A (en) A kind of water-based alumina base 3D printing base substrate method and its forming method
CN104493952B (en) The gel injection-moulding 3D printing preparation method of gradient ceramic
CN107963892A (en) A kind of ink silicon-nitride-based ceramic powder 3D printing base substrate method and its forming method
CN106965291A (en) A kind of gel injection-moulding 3D printing preparation method of gradient ceramic
CN108101519A (en) A kind of ceramic-mould preparation method for the shaping of parts with complex structures directional solidification
CN102500748B (en) Method for preparing aluminum silicon carbide composite material
CN106541129A (en) A kind of preparation method of particles reiforced metal-base composition
CN110078513B (en) Method for preparing silicon carbide complex device through extrusion 3D printing
CN101733402B (en) Gel injection molding method for high-gravity alloy
CN108033802A (en) Fiber reinforced ceramic profiled piece forming method based on gel injection-moulding 3D printing
CN104496480A (en) Silicon carbide ceramic preform, aluminum-based silicon carbide ceramic material, and preparation method of silicon carbide ceramic preform
CN108516730A (en) A kind of composition, preparation and its application for spraying 3D printing based on binder
CN110483008A (en) A kind of slurry and its ceramic product preparation method for photocuring 3D printing ceramics
CN107540352A (en) The preparation and application of 3D printing aluminum oxide toughening ceramic slurry
CN105016751A (en) Method for preparing zircon refractory material by using particle size distribution combined with gel injection molding process
CN110511002A (en) The method that DLP 3D printing technique prepares ZTA ceramic component
CN100560536C (en) The method of water-soluble epoxy resin in situ solidification for preparing ceramic blank
CN108017394A (en) A kind of water-based nitridation silicon substrate 3D printing base substrate method and its forming method
CN109678478A (en) A kind of light, high-intensitive and lower thermal conductivity anorthite porous ceramic film material and preparation method thereof
CN105128128A (en) Mold-free material forming method and device
CN107986763A (en) A kind of water-based 3D printing base substrate method and its forming method
CN107973875A (en) A kind of ink 3D printing base substrate method and its forming method
CN101745968A (en) Gel injection molding and forming technology of specific zircon brick
CN108044110A (en) A kind of ink WC base cemented carbides 3D printing green body method and its forming method
CN107963886A (en) A kind of water-based titanium dioxide zirconium base 3D printing base substrate method and its forming method

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180504

RJ01 Rejection of invention patent application after publication