CN107984812A - Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it - Google Patents

Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it Download PDF

Info

Publication number
CN107984812A
CN107984812A CN201711473850.3A CN201711473850A CN107984812A CN 107984812 A CN107984812 A CN 107984812A CN 201711473850 A CN201711473850 A CN 201711473850A CN 107984812 A CN107984812 A CN 107984812A
Authority
CN
China
Prior art keywords
fiber
composite fiber
tissue layer
composite
optical fiber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711473850.3A
Other languages
Chinese (zh)
Inventor
王彬
岳清瑞
李�荣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Central Research Institute of Building and Construction Co Ltd MCC Group
Original Assignee
Central Research Institute of Building and Construction Co Ltd MCC Group
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Central Research Institute of Building and Construction Co Ltd MCC Group filed Critical Central Research Institute of Building and Construction Co Ltd MCC Group
Priority to CN201711473850.3A priority Critical patent/CN107984812A/en
Publication of CN107984812A publication Critical patent/CN107984812A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/10Interconnection of layers at least one layer having inter-reactive properties
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of composite fiber tissue layer, include its composite fiber sheet material and composite fiber adhesive tape.Composite fiber tissue layer is formed by optical fiber and fiber mixed weaving, and preparation method includes:Selection, distribution density and the count design of optical fiber and fiber, the braiding of warp-wise laying method, broadwise and fixing means etc.;Composite fiber sheet material includes the composite fiber tissue layer;Composite fiber adhesive tape includes the composite fiber tissue layer, further includes gauze layer and glue-line, preparation method includes:Breadth design, fiber selection, optical fiber selection, the preparation of fleece-laying method, adhesive tape etc., preparation method is easy to operate.Structure design advantages of simple of the present invention, excellent product performance, can long-duration load use, monitoring signals stablize.Production prepares efficient quick, it can be achieved that extensive, industrialized production.The military services such as material, the structure of different area monitoring is can be widely applied for, strong support and technical guarantee are provided for engineering construction construction, maintenance and monitoring etc..

Description

Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it
Technical field
The present invention relates to engineering construction technical field, can be widely applied to engineering construction, maintenance and intellectual monitoring, sends out at the same time Wave structure efficiently reinforce, security maintenance with health from monitoring etc. multiple use, more particularly to a kind of composite fiber knit Nitride layer, the composite fiber sheet material and composite fiber adhesive tape for including it.
Background technology
High-performance fiber reinforced resin based composites (FRP) have lightweight, high-strength, corrosion-resistant, flexible design, construction soon The excellent specific properties such as victory, applied to engineering construction field, have the irreplaceable performance advantage of traditional material.Using FRP sheet materials pair Existing building structure carry out rapid reinforcement reparation, greatly save society, financial cost, or by FRP material design be prepared into it is new Structural elements, substitutes the metal materials and conventional building construction etc. such as reinforcing bar, promotes engineering structure to superelevation, superpower, super-span, length Formula spanning development is changed in durable direction, becomes the research hotspot of domestic and foreign scholars' extensive concern.At this stage, FRP is built as new Build material exclusive use, or with the working mechanism of the traditional material such as ground, concrete, steel and its structural elements synergistic effect, Long service performance, safeguard that key mechanism, technology and the delivery receiving acceptances such as reparation etc. wait further investigation and break through, and hinders its big rule Molded Depth enters to promote and apply.
By intellectual monitoring means, by the crackle of FRP material or the generation of structural elements military service process, deformation, structure Damage etc. develops and change progress is timely and effective from monitoring, and has before inside configuration morphs and forms major accident Effect precognition and alarm, the long-term safety of Reliable Design application and structural elements to guiding material, which is on active service, to be of great significance.
In recent years, optical fiber is introduced to receive significant attention applied to engineering construction field as intellectual monitoring means.Usual work Optical fiber is pasted onto by monitoring of structures surface using epoxy resin in journey, but since bare fibre is thin and crisp, it is necessary to monitoring thing surface Tight bond, and need to be laid with even straight.Optical fiber dosage applied to common engineering reality is grown greatly, using length, paste process of constructing The bent wrinkle even brittle failure of naked fibre easily occurs, very big inconvenience is brought to execute-in-place.Certain methods are proposed optical fiber together with fiber The composite material containing optical fiber is prepared into through composite material process planning, is mainly used for the monitorings such as strain and the temperature of multiple material structure, Composite material also plays the role of packaging protection to optical fiber at the same time.But the forming process of optical fiber embedment composite material need to pass through drawing The processing steps such as crowded/winding/priming by vacuum/compression molding, are usually subjected to high temperature and pressure and the effect of certain drafting force, naked fibre pole Brittle failure easily occurs in the process, embedment survival rate is very low.In addition the material gender gap of naked fibre and reinforcing fiber is larger, in composite wood During expecting forming and hardening, naked fibre ambient stress/strain can be caused to concentrate, the heat that composite material solidification process produces in addition is remaining Stress, produces optical fiber measurement data precision different degrees of influence.The more difficult large-scale industrial production of product, technology controlling and process Relatively it is difficult to guarantee with terms of product stability.On the other hand, the addition of optical fiber, destroys the structural homogeneity of composite material in itself, There are harmful effect for mechanical property, endurance quality to multiple material etc..
Therefore, how providing one kind can ensure that fiber-optic monitoring signal stabilization, excellent combination property, engineer application are efficiently fast The problem of victory, intellectual monitoring product applied widely is those skilled in the art's urgent need to resolve.
The content of the invention
In view of this, the present invention provides a kind of composite fiber tissue layer, the composite fiber sheet material and complex light that include it Fine adhesive tape, its preparation method feature, outstanding advantages and solves the problems, such as:
(1) technology of preparing:Using the easy mechanical braid mean of technology, compared to traditional fiber and the composite molding work of fiber Skill, on the one hand effectively prevent traditional fiber and is acted on during composite molding technique through high temperature and pressure and tractive force, easily The problem of causing brittle failure, optical fiber are embedded to the problem of composite material survival rate is low and survival rate is unstable;It effectively prevent because of optical fiber It is larger with undulation degree sex differernce, due to introducing optical fiber during composite material forming and hardening, cause composite material forming and hardening mistake Journey causes stress/strain to be concentrated around optical fiber, thermal residual strain collection is medium influences significantly to ask on optical fiber measurement data precision Topic;It effectively prevent optical fiber and participate in composite material shaping, interference even destroys the structural homogeneity of composite material in itself, so that The problem of causing multiple material mechanical property, endurance quality etc. to produce harmful effect.Comprehensive, this mechanical weaving is from entirety On solve the technical barrier of optical fiber and composite material high efficiency composition, solve the problems, such as that fiber-optic monitoring signal is steady and audible, solve Determine optical fiber and multiple material interdependence and the problem of structural behaviour is not interfere with each other, and greatly solve the extensive of this type product The technical barrier of industrialized production, technology controlling and process and product stability etc..
(2) preparation method, including breadth design, optical fiber select, fiber selects, fleece-laying method determines:According to quilt Size, signal resolution, collection sampling point, length distance, bearing capacity size and the load direction of monitoring object require, durability is wanted Ask, determine present invention design preparation method, including:Selection, the design of fleece-laying mode of breadth size, optical fiber and fiber Deng.The multifunctionality of the present invention is farthest played, design is stronger, better adaptability, while reduces cost.
To achieve these goals, the present invention adopts the following technical scheme that:
A kind of composite fiber tissue layer, the composite fiber tissue layer are formed by optical fiber and fiber mixed weaving.
Preferably, in above-mentioned composite fiber tissue layer, distribution of the optical fiber in the composite fiber tissue layer is close Degree is 1-100 roots/rice wide cut.
Preferably, in above-mentioned composite fiber tissue layer, the fiber is high performance fibre material or general fibre material.
Preferably, in above-mentioned composite fiber tissue layer, the high performance fibre material include carbon fiber, aramid fiber, Basalt fibre or glass fibre.
A kind of composite fiber tissue layer preparation method, specifically includes following steps:
1) suitable optical fiber and fiber are selected, and determines optical fiber and fibrage density;
2) warp-wise tight type parallel laid optical fiber and fiber, wherein optical fiber uniformly disperse sandwiched among the fibers;
3) fiber and optical fiber being laid with to step 2) carry out broadwise braiding with fiber and fix, composite fiber tissue layer density symbol Close the sets requirement of step 1).
Preferably, in the preparation method of above-mentioned composite fiber tissue layer, the composite fiber fabric of the step 3) preparation The breadth scope of layer is 0.5-100cm.
A kind of composite fiber sheet material, includes any of the above-described composite fiber tissue layer.
A kind of composite fiber adhesive tape, comprising any of the above-described composite fiber tissue layer, further includes:It is arranged on described multiple Gauze layer on the downside of closing light fibre tissue layer, and the glue-line on the downside of the gauze layer.
A kind of preparation method of composite fiber adhesive tape, it is characterised in that specifically include following steps:
A. breadth designs;
B. fiber selects;
C. optical fiber selects;
D. fleece-laying method determines;
E. the preparation of composite fiber adhesive tape.
A kind of application of the composite fiber tissue layer, the composite fiber tissue layer are applied to applying for construction project Work, maintenance and intellectual monitoring.
It can be seen via above technical scheme that compared with prior art, a kind of composite fiber tissue layer provided by the invention, Composite fiber sheet material, composite fiber adhesive tape comprising it, structure design advantages of simple, product mechanical property and endurance quality are excellent It is different, can long-duration load use, and monitoring signals stablize.Production prepares efficient quick, it can be achieved that extensive, industrial metaplasia Production.The military services such as material, the structure of different area monitoring is can be widely applied for, is carried for engineering construction construction, maintenance and monitoring etc. Strong support and technical guarantee are supplied.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing There is attached drawing needed in technology description to be briefly described, it should be apparent that, drawings in the following description are only this The embodiment of invention, for those of ordinary skill in the art, without creative efforts, can also basis The attached drawing of offer obtains other attached drawings.
Fig. 1 attached drawings are structure diagram of the invention;
Fig. 2 attached drawings are the weaving manner schematic diagram of the embodiment of the present invention.
In above-mentioned attached drawing:
1 it is composite fiber tissue layer, 2 be gauze layer, 3 be glue-line, 4 be optical fiber, 5 be warp fiber, 6 is weft fiber.
Embodiment
Below in conjunction with the attached drawing in the embodiment of the present invention, the technical solution in the embodiment of the present invention is carried out clear, complete Site preparation describes, it is clear that described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained every other without making creative work Embodiment, belongs to the scope of protection of the invention.
A kind of composite fiber tissue layer provided by the invention, the composite fiber sheet material comprising it, composite fiber adhesive tape, first Can according to the size of different building structure or monitored thing carry out product breadth design, solve high temperature extrusion technique into The problem of breadth is narrow during type, so that it is more to can be widely used in house, bridge, tunnel, roadbed, side slope, underground engineering etc. Construction, maintenance and the intellectual monitoring in field;Such as:Monitoring is safeguarded available for engineering structure small area intellectual monitoring or large area, For example local monitoring in real time is carried out to the crack of small area, or the military service monitoring of the structural material such as relatively narrow muscle material of pair cross-section, And be on active service monitoring, the reinforcing such as greater area of side slope of the component of slightly larger area is safeguarded and monitored;The product that the present invention designs can be real Now extensive, industrialized production, which is that the structural strain in engineering construction monitors, reinforces maintenance, security protection etc., provides technology Support and ensure, have a vast market development space.
Embodiment 1
Relevant attached drawing is referred to, the present invention provides a kind of composite fiber tissue layer 1, composite fiber tissue layer is by light Fibre 4 and fiber mixed weaving form.
In order to further optimize above-mentioned technical proposal, optical fiber 4 gathers signal point according to the size of monitored object, sensor Resolution, collection sampling point and length distance etc. composite factor select suitable optical fiber, and determine optical fiber in composite fiber tissue layer 1 The distribution density of warp-wise, thus can meet different monitoring requirements, design is stronger, better adaptability, while reduces into This.
In order to further optimize above-mentioned technical proposal, distribution density of the optical fiber in composite fiber tissue layer be 1-100 roots/ Rice wide cut.
In order to further optimize above-mentioned technical proposal, the count of composite fiber tissue layer 1 is 150~300g/m2
In order to further optimize above-mentioned technical proposal, fiber is selected from high performance fibre material or common fine according to use demand Tie up material;Wherein when building structure has reinforcing demand, high performance fibre material is selected, such as carbon fiber, aramid fiber, the Black Warrior Rock fiber or glass fibre;High performance fibre material disclosure satisfy that the demand of mechanical property and endurance quality, and can be one Determine to carry the damage deformation of monitored structure in degree, at the same its excellent durability can ensure it is right during long service Optical fiber plays a good protective effect;,, can to reduce cost when not requiring bearing capacity and durability when being only used for monitoring Select general fibre material.
Wherein, conventional high-performance fiber fabric Main Mechanical is as shown in table 1 below.
The conventional high-performance fiber fabric Main Mechanical of table 1
Product Tensile strength (MPa) Elasticity modulus (GPa) Elongation at break (%)
Carbon fibre fabric ≥2500 ≥210 ≥1.3
Glass fabric ≥1500 ≥75 ≥2.0
Basalt fibre fabrics ≥2000 ≥90 ≥2.0
Aramid fabric ≥2000 ≥110 ≥2.0
Embodiment 2
A kind of preparation method of composite fiber tissue layer, specifically includes following steps:
1) suitable optical fiber and fiber are selected according to the demand of engineer application, and determines optical fiber and fibrage density;Such as Fruit has the broadwise of composite fiber tissue layer the requirement of bearing capacity and durability, then fiber used in warp-wise and broadwise selects High-performance fiber, if requirement of the broadwise without bearing capacity and durability to composite fiber tissue layer, warp-wise selection high-performance is fine General fibre may be selected in dimension or general fibre, broadwise;
2) warp-wise tight type parallel laid optical fiber and fiber, wherein optical fiber uniformly disperse sandwiched among the fibers;
3) fiber and optical fiber being laid with to step 2) carry out broadwise braiding with fiber and fix, composite fiber tissue layer density symbol Close the sets requirement of step 1).
In order to further optimize above-mentioned technical proposal, the breadth scope of composite fiber tissue layer prepared by step 3) is 0.5- 100cm。
The Main Mechanical for the composite fiber tissue layer that table 2 is prepared for different fibers with optical fiber shuffling.
2. composite fiber tissue layer Main Mechanical of table
Product Tensile strength (MPa) Elasticity modulus (GPa) Elongation at break (%)
Carbon fiber/fiber textile layer ≥2500 ≥210 ≥1.3
Glass fibre/fiber textile layer ≥1500 ≥75 ≥1.9
Basalt fibre/fiber textile layer ≥2000 ≥90 ≥1.9
Aramid fiber/fiber textile layer ≥2000 ≥110 ≥2.0
General fibre/fiber textile layer ≥200 ≥10 ≥2.2
Ordinary optic fibre ≥600 ≥15 ≥4.0
As shown in Table 2:Composite fiber tissue layer mechanical property:Since optical fiber has relatively large elongation at break, During bearing load, for high-performance fiber tissue layer before being broken, maximum magnitude bears Main Mechanical, very big journey The protection optical fiber of degree is injury-free.
Embodiment 3
A kind of composite fiber sheet material, includes composite fiber tissue layer 1.
Embodiment 4
A kind of composite fiber adhesive tape, comprising composite fiber tissue layer 1, the gauze being arranged on the downside of composite fiber tissue layer 1 Layer 2, the glue-line 3 positioned at the downside of gauze layer 2;Composite fiber tissue layer 1 is formed by optical fiber 4 and 5 warp knit of warp fiber, and is passed through 6 broadwise of weft fiber, which is fixed, forms composite fiber tissue layer 1.
In order to further optimize above-mentioned technical proposal, yarn or braiding cord fabric thread yarn can be selected in weft fiber 6.
In order to further optimize above-mentioned technical proposal, optical fiber 4 gathers signal point according to the size of monitored object, sensor Resolution, collection sampling point and length distance etc. composite factor select suitable optical fiber.Such as monitored object is large scale bridge floor Plate, side slope when reinforcing maintenance and during intellectual monitoring, one side maximum area meets reinforcement criteria, therefore breadth width in design Maximize design;On the other hand, intellectual monitoring light is designed in floorings central axes forced position, side slope significant data gathering line Fibre, comprehensive definite optical fiber 4 are 2-1 roots/rice wide cuts in the distribution density of composite fiber tissue layer 1.
In order to further optimize above-mentioned technical proposal, gauze layer 2 is used to protect composite fiber tissue layer 1, and can control During side impregnation forms glue-line 3 pumping, fracture of wire phenomenon occur for system and reduction composite fiber tissue layer 1, can be effective Play and coordinate the bond effect that composite fiber knits adhesive tape entirety;Gauze layer 2 is 8~12 mesh, in actual production, the hole of gauze layer 2 Gap size is preferably controlled in 10 mesh or so.
In order to further optimize above-mentioned technical proposal:The material of glue-line 3 includes epoxy resin, its epoxy resin have compared with Strong endurance quality, the construction quality of effective guarantee construction monitoring;And the thickness range of glue-line 3 is 0.03~0.05mm, glue The piece of surface covering glass paper of layer 3;On the one hand the setting of glassine paper avoids the adhesion between glue-line 3, protection is played to glue-line 3 Effect;Glassine paper need to be only thrown off when on the other hand using, directly by glue-line 3 and applies surface mount, it is convenient and efficient.
In order to further optimize above-mentioned technical proposal, the count of composite fiber tissue layer 1 is 150~300g/m2
Embodiment 5
In the present embodiment, optical fiber 4 gathers signal resolution, collection sampling point according to the size of monitored object, sensor And the composite factor such as length distance selects suitable optical fiber.Such as when being monitored object as compared with small area section bar or component etc., Comprehensive definite optical fiber 4 is 50 piece/meter wide cuts in the distribution density of composite fiber tissue layer 1, and other parts are with reference to embodiment 4, no Repeat again.
Embodiment 6
In the present embodiment, optical fiber 4 gathers signal resolution, collection sampling point according to the size of monitored object, sensor And the composite factor such as length distance selects suitable optical fiber.Such as monitored object be more small area structure load material rib, When rope, grid etc., comprehensive definite optical fiber 4 is 100 piece/meter wide cuts in the distribution density of composite fiber tissue layer 1, and other parts are joined According to embodiment 4, repeat no more.
Embodiment 7
A kind of preparation method of composite fiber adhesive tape, specifically includes following steps:
A. breadth designs:The breadth for determining composite fiber adhesive tape according to use environment and requirement of engineering designs;
B. fiber selects:High performance fibre material is selected according to the use demand in terms of reinforcing bearing capacity and durability, when It is only used for monitoring, when not requiring composite fiber sheet material bearing capacity and durability, to reduce cost, general fibre material may be selected Material;
C. optical fiber selects:Suitable optical fiber is selected according to the requirement of the environment of actual monitoring and resolution ratio;
D. fleece-laying method determines:According to engineer application to the intensity requirement of composite fiber sheet material and carrying force direction Demand determine optical fiber and fibrage density and weaving manner;Under normal circumstances, fiber is formed with optical fiber warp knit, by common Fiber yarn broadwise fixes and is prepared into composite fiber tissue layer, has both given full play to composite fiber adhesive tape and has unidirectionally had along its length There is excellent bearing capacity, and can be effectively cost-effective;It should be noted that there is the composite fiber of intensity requirement for broadwise Sheet material is, it is necessary to carry out fiber and optical fiber warp knit and weft knitting, and weft knitting needs to select high-performance fiber to meet to the strong of broadwise Degree demand.
E. the preparation of composite fiber adhesive tape:Will according to the count and weaving manner of the step d optical fiber determined and fiber The fiber of step b selections and the optical fiber of step c selections carry out shuffling, prepare the complex light for meeting step a breadth design requirements Fine tissue layer;Gauze layer is fixed on the downside of composite fiber tissue layer, glue-line is adhered on the downside of gauze layer, glue-line can be by multiple The mode of closing light fibre tissue layer impregnation drying is formed.
In order to further optimize above-mentioned technical proposal, the bondline thickness scope in step e is 0.03~0.05mm, and glue The piece of surface covering glass paper of layer.
In order to further optimize above-mentioned technical proposal, further include and lopping envelope is carried out to the composite fiber adhesive tape of cover glass paper Dress.
In order to further optimize above-mentioned technical proposal, the count of composite fiber tissue layer 1 is 150~300g/m2
Embodiment 8
A kind of preparation method of composite fiber adhesive tape, specifically includes following steps:
A. breadth designs:The breadth for determining composite fiber adhesive tape according to use environment and requirement of engineering designs;
B. fiber selects:High-performance carbon fibre is selected according to the use demand in terms of reinforcing bearing capacity and durability;
C. optical fiber selects:Optical fiber is prepared according to the requirement of the environment of actual monitoring and resolution ratio;
D. fleece-laying method determines:According to engineer application to the intensity requirement of composite fiber sheet material and carrying force direction Demand determine optical fiber and high-performance carbon fibre count;
E. the preparation of composite fiber adhesive tape:It will be walked according to the count of the step d optical fiber determined and high-performance carbon fibre The carbon fiber of rapid b selections carries out shuffling with the step c optical fiber prepared, prepares the complex light for meeting step a breadth design requirements Fine tissue layer;Adhere to glue-line on the downside of composite fiber tissue layer, glue-line can be by drying composite fiber tissue layer impregnation Mode is formed.
In order to further optimize above-mentioned technical proposal, distribution density of the optical fiber in composite fiber tissue layer is 20 pieces/meter Wide cut.
In order to further optimize above-mentioned technical proposal, the bondline thickness scope in step e is 0.04mm, and the table of glue-line Face cover glass paper.
In order to further optimize above-mentioned technical proposal, further include and lopping envelope is carried out to the composite fiber adhesive tape of cover glass paper Dress.
In order to further optimize above-mentioned technical proposal, the count of composite fiber tissue layer 1 is 150g/m2
Embodiment 9
In the present embodiment, glass fibre, other portions are selected according to the use demand in terms of reinforcing bearing capacity and durability Divide with reference to embodiment 8, repeat no more.
Embodiment 10
In the present embodiment, basalt fibre is selected according to the use demand in terms of reinforcing bearing capacity and durability, other Partly referring to embodiment 8, repeat no more.
Embodiment 11
In the present embodiment, aramid fiber, other portions are selected according to the use demand in terms of reinforcing bearing capacity and durability Divide with reference to embodiment 8, repeat no more
Embodiment 12
In the present embodiment, according to use demand, it is mainly used for data monitoring, does not have to bearing capacity of the present invention and endurance quality When there are special requirement, general fibre is selected, other parts are repeated no more with reference to embodiment 8.
Embodiment 13
The test of endurance quality and mechanical property is carried out for composite fiber adhesive tape prepared by embodiment 8-12, such as table 3 Shown in table 4.
The endurance quality of 3 composite fiber adhesive tape of table
Product Endurance quality
Carbon fiber/optical fiber adhesive tape >=25 years
Glass fibre/optical fiber adhesive tape >=10 years
Basalt fibre/optical fiber adhesive tape >=20 years
Aramid fiber/optical fiber adhesive tape >=15 years
General fibre/optical fiber adhesive tape >=3 years
The Main Mechanical for the composite fiber adhesive tape that the different fibers of table 4 are prepared with optical fiber shuffling respectively
Product Tensile strength (MPa) Elasticity modulus (GPa) Elongation at break (%)
Carbon fiber/optical fiber adhesive tape ≥2500 ≥210 ≥1.3
Glass fibre/optical fiber adhesive tape ≥1500 ≥75 ≥1.9
Basalt fibre/optical fiber adhesive tape ≥2000 ≥90 ≥1.9
Aramid fiber/optical fiber adhesive tape ≥2000 ≥110 ≥2.0
General fibre/optical fiber adhesive tape ≥200 ≥10 ≥2.2
Table 3 to carbon fiber/optical fiber adhesive tape, glass fibre/optical fiber adhesive tape, basalt fibre/optical fiber adhesive tape, aramid fiber/ Optical fiber adhesive tape and general fibre/optical fiber adhesive tape carry out endurancing, the results showed that:Fiber of the high-performance fiber as base material Composite fiber adhesive tape endurance quality is good, is at least 10 years, and general fibre/optical fiber adhesive tape such as acrylic fiber adhesive tape durability is only high In 3 years, therefore high-performance fiber had good durability as the fiber composite optical fiber adhesive tape of base material.
Table 4 shows:Since optical fiber has relatively large elongation at break, during bearing load, high-performance Fiber composite optical fiber adhesive tape bears the load of maximum magnitude before being broken, and high degree protection optical fiber is injury-free.
Embodiment 14
On the basis of embodiment 8-12, the preparation of step e. composite fiber adhesive tapes is replaced by:Determined according to step d The count of optical fiber and carbon fiber, the aramid fiber that step b is selected carry out shuffling with the step c optical fiber prepared, prepare Meet the composite fiber tissue layer of step a breadth design requirements;Gauze layer is fixed on the downside of composite fiber tissue layer, in gauze layer Downside adheres to glue-line, and glue-line can be formed by way of being dried to composite fiber tissue layer impregnation.
In order to further optimize above-mentioned technical proposal, the pore-size of gauze layer 2 is preferably controlled in 10 mesh;Band gauze layer 2 Different fibers prepare composite fiber adhesive tape product Main Mechanical it is as shown in table 5 below.
Different fiber composite optical fiber adhesive tape product Main Mechanicals of the table 5 with gauze
Product Tensile strength (MPa) Elasticity modulus (GPa) Elongation at break (%)
Carbon fiber/optical fiber adhesive tape ≥2500 ≥210 ≥1.3
Glass fibre/optical fiber adhesive tape ≥1500 ≥75 ≥1.9
Basalt fibre/optical fiber adhesive tape ≥2000 ≥90 ≥1.9
Aramid fiber/optical fiber adhesive tape ≥2000 ≥110 ≥2.0
General fibre/optical fiber adhesive tape ≥200 ≥10 ≥2.2
As shown in Table 5:2 elongation strain rate of gauze layer is larger, and generally higher than 3%, break in fiber composite optical fiber Tape Pull Not yet stress is lost before splitting (2%), therefore composite fiber adhesive tape mechanical property is had little to no effect.
Embodiment 15
According to the composite fiber adhesive tape mentioned by embodiment 4-14, there is provided a kind of construction method of composite fiber adhesive tape, Composite fiber adhesive tape at least one layer is laid on monitored material, component, in structure, for intellectual monitoring;Or composite fiber adhesive tape It is at least one layer of or be laid on point up and down in building structure for two layers, while safeguarded and intellectual monitoring for constructing, reinforcing.
When structure needs reinforcement maintenance, intellectual monitoring in itself, while typical material as the main load of structure, component etc. When being also required to monitoring military service data, can be first laid with the structural bearing capacity material that need to monitor, the surface such as component first one layer it is compound Optical fiber adhesive tape, treats that overall structure is reinforced after the completion of maintenance, one layer of composite fiber adhesive tape is re-layed in ruggedized construction outer surface, not only The purpose of structural strengthening is realized, while the monitoring of health data can be carried out to structural bearing capacity material, component, evaluation is reinforced Effect, improve the offer basic datas such as reinforcement technique, lifting reinforcing level.
The composite fiber adhesive tape that the present invention designs and reinforcing matrices of composite material fiber, and reinforce with the choosing such as performance glue Material is consistent, it is ensured that monitoring adhesive tape and reinforcement material material homogeneity so that and both can quite beautiful match, and not repel mutually, so that It ensure that the superiority of bonding and reinforcement construction quality.In addition the site operation means of composite fiber adhesive tape and multiple material structural strengthening side Method is similar, and the invention product does not propose new demand to construction technology, effectively reduces technical difficulty.
In order to further optimize above-mentioned technical proposal, make when the monitored structure of structural strain monitoring mainly carries one direction When firmly, such as beam, column, pipe, adhesive tape should along its length with structure-bearing direction parallel laid;When monitored structure is mainly held When load power is multidirectional, composite fiber adhesive tape should be laid with along structure length direction in right-angled intersection is double-deck, and it is more to consider structure at this time To the on-line monitoring of stress point, at the same it is maximum sized along structure length direction, it ensure that every optical fiber is not disrupted cutting, protect Demonstrate,prove the normal acquisition of data.
In order to further optimize above-mentioned technical proposal, composite fiber adhesive tape is when in use first according to use environment and work Journey needs to cut composite fiber sheet material, it is ensured that the maximum length direction of composite fiber adhesive tape, then composite fiber adhesive tape Two ends reserve the width of 1~10cm, and optic fibre end is deeply determined along warp-wise, to avoid later stage external coating structure primer And protective materials pollutes optic fibre end, therefore termination need to use protective quartz packaging protection, subsequently directly be connect with facilitating Enter grating sensor.
For further, composite fiber adhesive tape is used cooperatively with reinforcement material:Cloth, plate, grid reinforcement material are such as reinforced, In reinforcement material surface mount composite fiber adhesive tape, monitoring in real time is realized.Such as:, will be compound in landslide, side slope protection Optical fiber adhesive tape is bonded in protection network, protective grille surface, carries out real time data monitoring, realizes disaster prevention.
For further, for the material for the maintenance that needs reinforcement, composite fiber adhesive tape can be straight separately as fiber cloth is reinforced Connect laying to use, be such as used for bridge floor, bridge, column, stake, floor, exterior wall.
For further, in order to avoid causing to damage to optical fiber in composite fiber adhesive tape preparation process, material can be answered in fiber Or the product surface such as section bar is directly taped outside, the data-signal during material military service can be effectively monitored, to material structure Design, preparation, working service etc. basic basis are provided.
For further, in specific practice of construction scheme, first according to design drawing to the position that needs reinforcement, or need The position of data monitoring is wanted, pulls stickup bit line, and monitored thing surface is handled, is beaten using sand-blasting machine or machinery Mill, removes the impurity such as monitoring thing surface laitance, greasy dirt, occurs the portion of peeling, honeycomb, corrosive degradation deformation for monitoring thing surface Position, should reject, to the layer inferior of larger area, surface reconditioning should be first carried out after rejecting.
Secondly, monitored thing surface need to polish flat, and especially surface projection position should polish;Corner location for paste should be fallen Angle handles and is polished into arc-shaped, and with hair-dryer that monitored removing surface is clean and keep drying.
Then, a Rotating fields primer is brushed first on monitored thing surface, to ensure surface mount composite fiber adhesive tape Reinforced or directly paste closely bonding for composite fiber adhesive tape and monitored face;Next road is carried out after curing etc. structure primer Process.
Again, brush leveling glue and carry out that surface is levelling, and for rough surface, more rough situation, surface is again Grinding process, and after applying brush configuration primer, should also brush one layer of leveling glue again, it is levelling to carry out surface;Effect is same as above, and ensures to paste tight Close property.
Finally directly stickup or in fabric reinforcing layer surface mount composite fiber adhesive tape, specifically includes following steps:
(i) adhesive tape is cut;By construction requirement size, composite fiber adhesive tape is cut, it is ensured that composite fiber adhesive tape maximum length Direction;Composite fiber adhesive tape two ends reserve 1-10cm width (according to actual job selection composite fiber adhesive tape type, complex light Fine adhesive tape is laid with breadth), and deeply determine optic fibre end along warp-wise;To avoid later stage external coating structure primer and protective materials Optical fiber end is polluted, at this time end protective quartz packaging protection, subsequently grating sensor is directly accessed to facilitate;
(ii) composite fiber adhesive tape bottom glass paper is peeled off, composite fiber adhesive tape is affixed directly to monitored face;It is laid with When composite fiber adhesive tape should ensure that abundant flattening, must not have fold;With smooth roller in composite fiber tape surface along same side To rolling repeatedly, to ensure that composite fiber adhesive tape is closely pasted with monitoring surface;
(iii) composite fiber tape surface uniformly brushes dipping, bonding application specific architecture glue together;For with long service It is required that, its outermost should also carry out surfacecti proteon processing;Surface preventing material tackles fiber and adhesive is harmless, and should be with glue Stick has reliable adhesion strength and mutually coordinated deformation performance;
(iv) composite fiber adhesive tape end should take corresponding addition thereto when necessary, such as take Interal fixation;Cut out The optic fibre end gone out is answered exposed outside fixed strip;When needing monitoring, end protective case is removed, directly will cover glass under optical fiber adhesive tape Glass film protection sheet is thrown off, and is affixed on grating sensor.
Each embodiment is described by the way of progressive in this specification, what each embodiment stressed be and other The difference of embodiment, between each embodiment identical similar portion mutually referring to.For device disclosed in embodiment For, since it is corresponded to the methods disclosed in the examples, so description is fairly simple, related part is said referring to method part It is bright.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or use the present invention. A variety of modifications to these embodiments will be apparent for those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention The embodiments shown herein is not intended to be limited to, and is to fit to and the principles and novel features disclosed herein phase one The most wide scope caused.

Claims (10)

1. a kind of composite fiber tissue layer, it is characterised in that the composite fiber tissue layer is by optical fiber and fiber mixed weaving Form.
2. composite fiber tissue layer as claimed in claim 1, it is characterised in that the optical fiber is in the composite fiber tissue layer In distribution density be 1-100 roots/rice wide cut.
3. composite fiber tissue layer as claimed in claim 1, it is characterised in that the fiber is high performance fibre material or general Perforating fiber material.
4. composite fiber tissue layer as claimed in claim 3, it is characterised in that it is fine that the high performance fibre material includes carbon Dimension, aramid fiber, basalt fibre or glass fibre.
A kind of 5. composite fiber tissue layer preparation method as described in claim 1-4 is any, it is characterised in that specifically include with Lower step:
1) suitable optical fiber and fiber are selected, and determines optical fiber and fibrage density;
2) warp-wise tight type parallel laid optical fiber and fiber, wherein optical fiber uniformly disperse sandwiched among the fibers;
3) fiber and optical fiber being laid with to step 2) carry out broadwise braiding with fiber and fix, and composite fiber tissue layer density meets step Rapid sets requirement 1).
6. the preparation method of composite fiber tissue layer as claimed in claim 5, it is characterised in that prepared by the step 3) answers The breadth scope of closing light fibre tissue layer is 0.5-100cm.
7. a kind of composite fiber sheet material, it is characterised in that include claim 1-4 any one of them composite fiber tissue layers.
A kind of 8. composite fiber adhesive tape, it is characterised in that comprising claim 1-4 any one of them composite fiber tissue layers, Further include:The gauze layer being arranged on the downside of the composite fiber tissue layer, and the glue-line on the downside of the gauze layer.
9. a kind of preparation method of composite fiber adhesive tape as claimed in claim 8, it is characterised in that specifically include following step Suddenly:
A. breadth designs;
B. fiber selects;
C. optical fiber selects;
D. fleece-laying method determines;
E. the preparation of composite fiber adhesive tape.
A kind of 10. application of composite fiber tissue layer as described in claim 1-4 is any, it is characterised in that the complex light Fine tissue layer is applied to construction, maintenance and the intellectual monitoring of construction project.
CN201711473850.3A 2017-12-29 2017-12-29 Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it Pending CN107984812A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711473850.3A CN107984812A (en) 2017-12-29 2017-12-29 Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711473850.3A CN107984812A (en) 2017-12-29 2017-12-29 Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it

Publications (1)

Publication Number Publication Date
CN107984812A true CN107984812A (en) 2018-05-04

Family

ID=62042211

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711473850.3A Pending CN107984812A (en) 2017-12-29 2017-12-29 Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it

Country Status (1)

Country Link
CN (1) CN107984812A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109870256A (en) * 2019-03-08 2019-06-11 东莞理工学院 A kind of monitoring DOFS-FRP cloth and its monitoring method certainly
CN111057477A (en) * 2019-12-27 2020-04-24 中冶建筑研究总院有限公司 FRP fiber adhesive tape for quick connection and fixed connection method thereof
CN112747780A (en) * 2020-12-24 2021-05-04 上海微波技术研究所(中国电子科技集团公司第五十研究所) Adhesive tape type optical fiber sensor realized based on OTDR optical fiber scheme
CN113584669A (en) * 2021-07-30 2021-11-02 宁波甬强科技有限公司 Photoelectric glass fiber cloth and manufacturing method thereof
US20220064798A1 (en) * 2020-08-31 2022-03-03 Free Form Fibers, Llc Composite tape with lcvd-formed additive material in constituent layer(s)

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2561789A1 (en) * 1984-03-21 1985-09-27 Commissariat Energie Atomique Method for installing optical fibres in an ordered fashion and conductors of optical data obtained by this method
US4772092A (en) * 1984-12-22 1988-09-20 Mbb Gmbh Crack detection arrangement utilizing optical fibres as reinforcement fibres
US5256468A (en) * 1991-03-19 1993-10-26 Page Automated Telecommunications Systems, Inc. Smart skin array woven fiber optic ribbon and arrays and packaging thereof
US20070103928A1 (en) * 2005-11-09 2007-05-10 Keith Goossen Automated process for embedding optical fibers in woven composites
CN101845763A (en) * 2010-04-07 2010-09-29 金文成 Distributed intelligent rope and manufacturing method thereof
CN101984890A (en) * 2010-09-13 2011-03-16 中国纺织工程学会 Curtain with controllable luminous pattern based on optical fibers and preparation method thereof
EP2572871A2 (en) * 2011-09-21 2013-03-27 Siemens Aktiengesellschaft Textile-reinforced fibre compound and method for the non-destructive testing of fibre orientation and layer structure in components made of textile-reinforced compound materials
CN104563522A (en) * 2014-11-25 2015-04-29 中冶建筑研究总院有限公司 Permanent connection method for FRP (Fiber Reinforced Plastic) rebars
CN104764412A (en) * 2014-01-06 2015-07-08 中国计量学院 Two-dimensional strain flexible high-temperature fiber grating sensor based on braiding structure
CN106404065A (en) * 2016-10-09 2017-02-15 山东大学 Composite material packaged optical fiber grating sensor and manufacturing method thereof
CN106633139A (en) * 2016-12-15 2017-05-10 中国航空工业集团公司基础技术研究院 Transparent continuous fiber-reinforced composite material and preparation method thereof
CN107091615A (en) * 2017-06-14 2017-08-25 四川睿铁科技有限责任公司 A kind of intelligent geotextiles monitored suitable for high ferro subgrade deformation with controlling
CN206465547U (en) * 2017-02-16 2017-09-05 浙江华光汽车内饰股份有限公司 Automobile inner decoration facing
CN107246158A (en) * 2017-07-20 2017-10-13 浙江之江工程项目管理有限公司 The construction technology of carbon fiber cloth strengthening technology

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2561789A1 (en) * 1984-03-21 1985-09-27 Commissariat Energie Atomique Method for installing optical fibres in an ordered fashion and conductors of optical data obtained by this method
US4772092A (en) * 1984-12-22 1988-09-20 Mbb Gmbh Crack detection arrangement utilizing optical fibres as reinforcement fibres
US5256468A (en) * 1991-03-19 1993-10-26 Page Automated Telecommunications Systems, Inc. Smart skin array woven fiber optic ribbon and arrays and packaging thereof
US20070103928A1 (en) * 2005-11-09 2007-05-10 Keith Goossen Automated process for embedding optical fibers in woven composites
CN101845763A (en) * 2010-04-07 2010-09-29 金文成 Distributed intelligent rope and manufacturing method thereof
CN101984890A (en) * 2010-09-13 2011-03-16 中国纺织工程学会 Curtain with controllable luminous pattern based on optical fibers and preparation method thereof
EP2572871A2 (en) * 2011-09-21 2013-03-27 Siemens Aktiengesellschaft Textile-reinforced fibre compound and method for the non-destructive testing of fibre orientation and layer structure in components made of textile-reinforced compound materials
CN104764412A (en) * 2014-01-06 2015-07-08 中国计量学院 Two-dimensional strain flexible high-temperature fiber grating sensor based on braiding structure
CN104563522A (en) * 2014-11-25 2015-04-29 中冶建筑研究总院有限公司 Permanent connection method for FRP (Fiber Reinforced Plastic) rebars
CN106404065A (en) * 2016-10-09 2017-02-15 山东大学 Composite material packaged optical fiber grating sensor and manufacturing method thereof
CN106633139A (en) * 2016-12-15 2017-05-10 中国航空工业集团公司基础技术研究院 Transparent continuous fiber-reinforced composite material and preparation method thereof
CN206465547U (en) * 2017-02-16 2017-09-05 浙江华光汽车内饰股份有限公司 Automobile inner decoration facing
CN107091615A (en) * 2017-06-14 2017-08-25 四川睿铁科技有限责任公司 A kind of intelligent geotextiles monitored suitable for high ferro subgrade deformation with controlling
CN107246158A (en) * 2017-07-20 2017-10-13 浙江之江工程项目管理有限公司 The construction technology of carbon fiber cloth strengthening technology

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109870256A (en) * 2019-03-08 2019-06-11 东莞理工学院 A kind of monitoring DOFS-FRP cloth and its monitoring method certainly
CN111057477A (en) * 2019-12-27 2020-04-24 中冶建筑研究总院有限公司 FRP fiber adhesive tape for quick connection and fixed connection method thereof
CN111057477B (en) * 2019-12-27 2024-04-19 中冶建筑研究总院有限公司 FRP fiber tape for quick connection and fixed connection method thereof
US20220064798A1 (en) * 2020-08-31 2022-03-03 Free Form Fibers, Llc Composite tape with lcvd-formed additive material in constituent layer(s)
US11761085B2 (en) * 2020-08-31 2023-09-19 Free Form Fibers, Llc Composite tape with LCVD-formed additive material in constituent layer(s)
CN112747780A (en) * 2020-12-24 2021-05-04 上海微波技术研究所(中国电子科技集团公司第五十研究所) Adhesive tape type optical fiber sensor realized based on OTDR optical fiber scheme
CN113584669A (en) * 2021-07-30 2021-11-02 宁波甬强科技有限公司 Photoelectric glass fiber cloth and manufacturing method thereof

Similar Documents

Publication Publication Date Title
CN107984812A (en) Composite fiber tissue layer, the composite fiber sheet material and composite fiber adhesive tape for including it
AU2017276343B2 (en) Arrangement and Method for Reinforcing Supporting Structures
CN102235095B (en) Preparation method of fiber reinforced polymer sheet
MX341495B (en) Wind turbine rotor blade components and methods of making same.
CN104060765A (en) Steel-continuous-fiber composite bar and preparation method thereof
JP5722714B2 (en) Concrete peeling prevention sheet and concrete peeling prevention method using the same
CN211851012U (en) Shear-resistant reinforcing device for reinforced concrete member
CN104085117A (en) Preparation method of steel fiber composite bar
CN101871267B (en) Composite strengthening technology of aged reinforced concrete beam
JP2002348749A (en) Woven fabric of reinforcing fiber, and concrete structure reinforced with the same
CN207697172U (en) Composite fiber tissue layer, composite fiber sheet material and composite fiber adhesive tape comprising it
CN104563522A (en) Permanent connection method for FRP (Fiber Reinforced Plastic) rebars
JP2015161039A (en) Fiber sheet for earthquake-proof reinforcement
CN105421330B (en) A kind of compound needle thorn cloth warp knit grid and its production method
CN102785371B (en) Method for making composite material lattice sandwich boards by prepreg fiber bundles
JP4667069B2 (en) Carbon fiber sheet
CN104060766A (en) Steel-continuous-fiber composite bar for building
JP2009119607A (en) Method for manufacturing stiffening insert and stiffening insert manufactured by the method
JP2017223093A (en) Method and structure for reinforcing concrete structure
Codispoti et al. Mechanical performanceof naturalfiber-reinforced composites for the strengthening of ancient masonry
CN108547469A (en) A method of utilizing fiber cloth reinforced concrete cylindrical
CN212453756U (en) Basalt stainless steel wire mesh grid for building reinforcement
JP2007245431A (en) Fibre-reinforced laminated material
CN208521038U (en) A kind of optical cable glass fiber tape
CN207499576U (en) A kind of pre-stressed carbon fiber net bracing means of the existing circular rod of substation

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination