CN107973475A - Desulfurization wastewater Zero discharging system and method based on waste heat reuse under running on the lower load - Google Patents

Desulfurization wastewater Zero discharging system and method based on waste heat reuse under running on the lower load Download PDF

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Publication number
CN107973475A
CN107973475A CN201711451275.7A CN201711451275A CN107973475A CN 107973475 A CN107973475 A CN 107973475A CN 201711451275 A CN201711451275 A CN 201711451275A CN 107973475 A CN107973475 A CN 107973475A
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desulfurization wastewater
flue
waste water
waste
economizer
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李飞
刘海洋
孟磊
陈海杰
谷小兵
白玉勇
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Datang Environment Industry Group Co Ltd
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Datang Environment Industry Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • B01D53/8625Nitrogen oxides
    • B01D53/8631Processes characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/90Injecting reactants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/10Treatment of water, waste water, or sewage by heating by distillation or evaporation by direct contact with a particulate solid or with a fluid, as a heat transfer medium
    • C02F1/12Spray evaporation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/04Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C02F1/16Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to desulfurization wastewater Zero discharging system and method based on waste heat reuse under a kind of running on the lower load.The desulfurization wastewater Zero discharging system includes economizer gas bypass subsystem and desulfurization wastewater evaporative subsystem.The economizer gas bypass subsystem includes economizer bypass flue, can improve the exhaust gas temperature and denitration efficiency under unit running on the lower load;The desulfurization wastewater evaporative subsystem includes waste pipe, Softening box, enrichment facility, waste water preheater, gas cooler, heating agent water pump, heating agent waterpipe, waste water pump and spray nozzle, concentration decrement, preheating and atomization can be carried out to waste water, lift its evaporation efficiency.The invention further relates to a kind of method for realizing desulfurization wastewater zero-emission under running on the lower load using the above-mentioned desulfurization wastewater Zero discharging system based on waste heat reuse.The present invention has the characteristics that technological process is simple, the zero-emission that thermal flue gas realizes waste water can be efficiently used under unit running on the lower load, while can also improve system denitration efficiency.

Description

Desulfurization wastewater Zero discharging system and method based on waste heat reuse under running on the lower load
Technical field
The present invention relates to desulfurization wastewater Zero discharging system and method based on waste heat reuse under a kind of running on the lower load, specifically For a kind of system and method for evaporating desulfurization wastewater using thermal flue gas under coal-burning power plant's running on the lower load, belong to thermal power generation Energy-saving and emission-reduction field.
Background technology
Low temperature flue evaporation technique is one of technical way for realizing Desulphurization for Coal-fired Power Plant wastewater zero discharge, its principle It is the flue by desulfurization wastewater atomized spray between air preheater and electric precipitator, evaporates waste water using fume waste heat as heat source, Resulting particulate matter etc. is captured with flue gas into electric precipitator.Since space is limited, which must be when shorter The interior evaporation for completing waste water.Recent year coal unit is chronically at underrun state, the boiler when load reduction Exhaust gas temperature also decreases, and causes the thermal energy of air preheater exiting flue gas to be not enough to evaporate waste water in given time, waste water Drop is attached to flue inner wall, and the problems such as may causing fouling, dust stratification, blocking and corrode, electric precipitation can be even influenced when serious The normal operation of device, desulfurization wastewater low temperature flue evaporation technique will be unable to come into operation.Improving exhaust gas temperature becomes reality The key of desulfurization wastewater zero-emission under existing unit running on the lower load.
Another serious problems caused by performing low-load running of machine set are the decline of denitration efficiency, it is however generally that denitrating catalyst Active reaction temperature is 320-420 DEG C, and when flue-gas temperature is too low, efficiency can be greatly reduced in SCR denitration equipment, when serious even It is forced out of service, the discharge of nitrogen oxides will be unable to the requirement for reaching national minimum discharge.Economizer gas bypass technology is Solve the problems, such as one of important method of unit underload denitration, its principle is to set the flue duct bypass in parallel with economizer, from province Flue collector before coal device draws partial fume and directly imports the flue collector after economizer, since flue gas is changed with what is fed water in economizer Heat is lowered, and the temperature of SCR denitration equipment entrance flue gas gets a promotion, it is ensured that the efficiency of SCR denitration equipment.However, by In the raising of flue-gas temperature, this method also results in the increase of boiler exhaust gas heat loss, rationally using the part waste heat to improving Unit capacity usage ratio important in inhibiting.
In conclusion under unit running on the lower load, desulfurization wastewater needs more sufficient thermal energy to realize zero-emission;Save Coal device gas bypass technology also result in the raising of flue-gas temperature while denitration effect is improved, and increase boiler exhaust gas heat waste Lose.If evaporation of the partial heat energy for desulfurization wastewater, can not only realize wastewater zero discharge, unit energy profit can be more improved With rate.
The content of the invention
To solve the above problems, the present invention provides the desulfurization wastewater zero-emission based on waste heat reuse under a kind of running on the lower load System and method.The desulfurization wastewater Zero discharging system is a kind of joint economizer gas bypass subsystem and desulfurization wastewater evaporation The system of subsystem, can efficiently use the zero-emission that unit thermal flue gas realizes waste water under unit running on the lower load.Wherein, save Coal device gas bypass subsystem can lift unit underload denitration efficiency and smoke evacuation heat content;Desulfurization wastewater evaporative subsystem can be to useless Water is pre-processed, concentrates decrement and atomization etc., is reduced its evaporation process to the demand of thermal energy and is realized zero-emission.
The purpose of the present invention is what is be achieved through the following technical solutions:
Desulfurization wastewater Zero discharging system based on waste heat reuse under a kind of running on the lower load, including be sequentially connected by flue Boiler, economizer, SCR denitration equipment, air preheater, electric precipitator and desulfurizing tower, it is characterised in that further include economizer flue gas Bypass subsystem and desulfurization wastewater evaporative subsystem;
Wherein, the economizer gas bypass subsystem includes economizer bypass flue;
The desulfurization wastewater evaporative subsystem is included by the sequentially connected Softening box of waste pipe, enrichment facility, waste water Preheater, waste water pump and spray nozzle;Wherein, the Softening box connects desulfurizing tower, the atomized spray by waste pipe Device is installed in the flue between the air preheater and electric precipitator.
Further, the flue collector before the entrance connection economizer entrance of the economizer bypass flue, junction is equipped with The bypass flue baffle of adjustable aperture, the outlet of the economizer bypass flue connect the flue collector after economizer exit.
Further, gas cooler is installed in the flue between the electric precipitator and desulfurizing tower, the flue gas is cold But device is connected by heating agent waterpipe with waste water preheater, and the waste water preheater is installed between enrichment facility and waste water pump On waste pipe.
Further, the heating agent waterpipe is equipped with heating agent water pump.
Further, the enrichment facility uses principle of reverse osmosis, and desulfurization wastewater is filtered into high-concentration waste water and clear water.
Further, the enrichment facility is additionally provided with fresh water pipeline.
Desulfurization wastewater zero under running on the lower load is realized using the desulfurization wastewater Zero discharging system based on waste heat reuse The method of discharge, comprises the following steps:
Step 1, when unit load reduces, bypass flue baffle is opened, enters economizer by adjusting the control of its aperture The flow of bypass flue flue gas, flue collector of the partial fume after economizer bypass flue enters economizer exit are mixed with main flue gas Close, SCR denitration equipment importation flue-gas temperature is promoted to more than 320 DEG C, SCR denitration device efficiency is promoted to more than 80%; Meanwhile air preheater exit gas temperature accordingly improves 5-20 DEG C, more sufficient heat source is provided for desulfurization wastewater evaporation;
Step 2, desulfurization wastewater enters Softening box, removes desulfurization wastewater hardness ions, hardness is adjusted to below 150ppm (with calcium carbonate), alleviates and prevents waste water from fouling and blocking occurring in enrichment facility;Desulfurization wastewater after softening enters dense Compression apparatus, high-concentration waste water and clear water are filtered into by reverse osmosis membrane, and wherein clear water is reused by fresh water pipeline discharge, High-concentration waste water enters waste water preheater;
Step 3, high temperature heat medium water heat being absorbed into the high-concentration waste water of waste water preheater, temperature improves about 40-60 DEG C, Further reduce the heat demand of its evaporation;Heat medium water after heat release enter gas cooler absorb electric precipitator and desulfurizing tower it Between flue gas waste heat lifting temperature, returned under the action of heating agent water pump waste water preheater continue heat release, circulated with this;
Step 4, enter spray nozzle through waste water pump by the desulfurization wastewater that waste water preheater is discharged, be atomized as average grain The drop that about 30-60 μm of footpath, sprays the flue between air preheater and electric precipitator, and moisture absorption fume waste heat is evaporated, production Raw solid particulate matter is captured with main flue gas into electric precipitator, completes wastewater zero discharge.
Beneficial effects of the present invention are:
1. improving the temperature of flue gas between air preheater and electric precipitator, solves flue-gas temperature deficiency under running on the lower load Caused waste water evaporates incomplete problem, realizes the zero-emission of desulfurization wastewater.
2. being preheated using the waste heat of flue gas between electric precipitator and desulfurizing tower to waste water, removed using air preheater and electricity The waste heat of flue gas is evaporated waste water between dirt device, improves system capacity utilization rate.
3. improve the temperature of SCR denitration equipment importation flue gas, it is ensured that the denitration efficiency of unit in low- load conditions.
4. waste water evaporation increases smoke moisture, be conducive to the reunion of wherein flue dust, reduce the discharge of fine particle.
5. improving air preheater entrance flue gas temperature, it is too low caused to alleviate air preheater cold junction temperature under running on the lower load The problems such as fouling and blocking.
6. the concentration of waste water can generating unit distinguish water, saved water resource.
Brief description of the drawings
Fig. 1 is the structural representation of the desulfurization wastewater Zero discharging system based on waste heat reuse under running on the lower load of the present invention Figure;
Wherein, 1- boilers, 2- economizers, 3-SCR denitration devices, 4- air preheaters, 5- electric precipitators, 6- desulfurizing towers, 7- are soft Change case, 8- enrichment facilities, 9- waste water preheaters, 10- gas coolers, 11- heating agent water pumps, 12- waste water pumps, 13- atomized sprays Device, 14- waste pipes, 15- fresh water pipelines, 16- flue collectors, 17- economizer bypass flues, 18- bypass flue baffles, 19- give Waterpipe, 20- heating agent waterpipes.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to the accompanying drawings and embodiments, it is right The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only to explain the present invention, not For limiting the present invention.
As shown in Figure 1, the desulfurization wastewater Zero discharging system based on waste heat reuse under a kind of running on the lower load, including pass through cigarette The sequentially connected boiler 1 in road, economizer 2, SCR denitration equipment 3, air preheater 4, electric precipitator 5 and desulfurizing tower 6, further include province's coal Device gas bypass subsystem and desulfurization wastewater evaporative subsystem;
Wherein, the economizer gas bypass subsystem includes economizer bypass flue 17;The economizer bypass flue Flue collector 16 before 17 entrance connection 2 entrance of economizer, junction is equipped with the bypass flue baffle 18 of adjustable aperture, described Flue collector 16 behind outlet connection economizer 2 outlet of economizer bypass flue 17.
The desulfurization wastewater evaporative subsystem include by the sequentially connected Softening box 7 of waste pipe 14, enrichment facility 8, Waste water preheater 9, waste water pump 12 and spray nozzle 13;Wherein, the Softening box 7 connects desulfurizing tower 6 by waste pipe 14, The spray nozzle 13 is installed in the flue between the air preheater 4 and electric precipitator 5.The electric precipitator 5 and desulfurization Gas cooler 10 is installed, the gas cooler 10 is preheated by heating agent waterpipe 20 and waste water in the flue between tower 6 Device 9 is connected, and the waste water preheater 9 is installed on the waste pipe 14 between enrichment facility 8 and waste water pump 12.The heat medium water Pipeline 9 is equipped with heating agent water pump 11.
The enrichment facility 8 uses principle of reverse osmosis, and desulfurization wastewater is filtered into high-concentration waste water and clear water.
The enrichment facility 8 is additionally provided with fresh water pipeline 15.
Desulfurization wastewater zero under running on the lower load is realized using the desulfurization wastewater Zero discharging system based on waste heat reuse The method of discharge, comprises the following steps:
Step 1, when unit load reduces, bypass flue baffle 18 is opened, enters province's coal by adjusting the control of its aperture The flow of 17 flue gas of device bypass flue, partial fume through economizer bypass flue 17 enter economizer 2 export after flue collector with Main flue gas mixes, and exchanges heat since the partial fume is introduced into economizer 2 with boiler feedwater, can be by 3 import of SCR denitration equipment Flue-gas temperature is promoted to more than 320 DEG C, by 3 improved efficiency of SCR denitration equipment to more than 80%;Meanwhile 4 exiting flue gas of air preheater Temperature accordingly improves about 5-20 DEG C, and more sufficient heat source is provided for desulfurization wastewater evaporation.
Step 2, desulfurization wastewater enters Softening box 7, removes desulfurization wastewater hardness ions, hardness is adjusted to below 150ppm (with calcium carbonate), alleviates and prevents waste water from fouling and blocking occurring in enrichment facility 8;Desulfurization wastewater after softening enters dense Compression apparatus 8, is filtered into high-concentration waste water and clear water, wherein clear water is discharged sharp again by fresh water pipeline 15 by reverse osmosis membrane With high-concentration waste water enters waste water preheater 9;Due to the reduction of waste water water, it evaporates the heat needed and is reduced.
Step 3, high temperature heat medium water heat is absorbed into the high-concentration waste water of waste water preheater 9, temperature improves about 40-60 DEG C, further reduce its heat demand evaporated;Heat medium water after heat release enters gas cooler 10 and absorbs electric precipitator 5 and take off The waste heat lifting temperature of flue gas, waste water preheater 9 is returned under the action of heating agent water pump 11 and continues heat release, with this between sulphur tower 6 Circulation;
Step 4, by the desulfurization wastewater that waste water preheater 9 is discharged through waste water pump 12 enter spray nozzle 13, be atomized for The drop that about 30-60 μm of average grain diameter, sprays the flue between air preheater 4 and electric precipitator 5, moisture absorption fume waste heat quilt Evaporation, the solid particulate matter of generation are captured with main flue gas into electric precipitator 5, complete wastewater zero discharge.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention, for the skill of this area For art personnel, the invention may be variously modified and varied.Within the spirit and principles of the invention, that is made any repaiies Change, equivalent substitution, improvement etc., should all be included in the protection scope of the present invention.

Claims (7)

1. the desulfurization wastewater Zero discharging system based on waste heat reuse under a kind of running on the lower load, including it is sequentially connected by flue Boiler (1), economizer (2), SCR denitration equipment (3), air preheater (4), electric precipitator (5) and desulfurizing tower (6), it is characterised in that Further include economizer gas bypass subsystem and desulfurization wastewater evaporative subsystem;
Wherein, the economizer gas bypass subsystem includes economizer bypass flue (17);
The desulfurization wastewater evaporative subsystem is included by waste pipe (14) sequentially connected Softening box (7), enrichment facility (8), waste water preheater (9), waste water pump (12) and spray nozzle (13);Wherein, the Softening box (7) passes through waste pipe (14) desulfurizing tower (6) is connected, the spray nozzle (13) is installed on the cigarette between the air preheater (4) and electric precipitator (5) In road.
2. the desulfurization wastewater Zero discharging system based on waste heat reuse, its feature under running on the lower load according to claim 1 It is, the flue collector (16) before entrance connection economizer (2) entrance of the economizer bypass flue (17), junction is equipped with can The bypass flue baffle (18) of aperture is adjusted, behind outlet connection economizer (2) outlet of the economizer bypass flue (17) Flue collector (16).
3. the desulfurization wastewater Zero discharging system based on waste heat reuse, its feature under running on the lower load according to claim 1 It is, gas cooler (10), the flue gas cooling is installed in the flue between the electric precipitator (5) and desulfurizing tower (6) Device (10) is connected by heating agent waterpipe (20) with waste water preheater (9), and the waste water preheater (9) is installed on enrichment facility (8) on the waste pipe (14) between waste water pump (12).
4. the desulfurization wastewater Zero discharging system based on waste heat reuse, its feature under running on the lower load according to claim 3 It is, the heating agent waterpipe (9) is equipped with heating agent water pump (11).
5. the desulfurization wastewater Zero discharging system based on waste heat reuse, its feature under running on the lower load according to claim 1 It is, the enrichment facility (8) uses principle of reverse osmosis, and desulfurization wastewater is filtered into high-concentration waste water and clear water.
6. the desulfurization wastewater Zero discharging system based on waste heat reuse, its feature under running on the lower load according to claim 5 It is, the enrichment facility (8) is additionally provided with fresh water pipeline (15).
7. realize underload using desulfurization wastewater Zero discharging system of claim 1~6 any one of them based on waste heat reuse The method of desulfurization wastewater zero-emission under operating mode, it is characterised in that comprise the following steps:
Step 1, when unit load reduces, bypass flue baffle (18) is opened, enters economizer by adjusting the control of its aperture The flow of bypass flue (17) flue gas, partial fume through economizer bypass flue (17) enter economizer exit after flue collector with Main flue gas mixes, and SCR denitration equipment (3) input gas temperature is promoted to more than 320 DEG C, SCR denitration equipment (3) efficiency is carried Rise to more than 80%;Meanwhile air preheater (4) exit gas temperature accordingly improves 5-20 DEG C, provided more for desulfurization wastewater evaporation Sufficient heat source;
Step 2, desulfurization wastewater enters Softening box (7), removes desulfurization wastewater hardness ions, hardness is adjusted to below 150ppm, Alleviate and prevent waste water from fouling and blocking occurring in enrichment facility;Desulfurization wastewater after softening enters enrichment facility (8), passes through Reverse osmosis membrane is filtered into high-concentration waste water and clear water, and wherein clear water is reused by fresh water pipeline (15) discharge, high concentration Waste water enters waste water preheater (9);
Step 3, high temperature heat medium water heat being absorbed into the high-concentration waste water of waste water preheater (9), temperature improves about 40-60 DEG C, Further reduce the heat demand of its evaporation;Heat medium water after heat release enter gas cooler (10) absorb electric precipitator (5) and The waste heat lifting temperature of flue gas, waste water preheater (9) is returned under the action of heating agent water pump (11) and continues to put between desulfurizing tower (6) Heat, is circulated with this;
Step 4, the desulfurization wastewater discharged by waste water preheater (9) enters spray nozzle (13) through waste water pump (12), is atomized For about 30-60 μm of drop of average grain diameter, the flue between air preheater (4) and electric precipitator (5), moisture absorption flue gas are sprayed Waste heat is evaporated, and the solid particulate matter of generation is captured with main flue gas into electric precipitator (5), completes wastewater zero discharge.
CN201711451275.7A 2017-12-27 2017-12-27 Desulfurization wastewater Zero discharging system and method based on waste heat reuse under running on the lower load Pending CN107973475A (en)

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CN109626691A (en) * 2018-12-28 2019-04-16 大唐环境产业集团股份有限公司 A kind of flexibly adjustable thermal power plant's high-salinity wastewater zero-emission system and method
CN109626691B (en) * 2018-12-28 2023-04-18 大唐环境产业集团股份有限公司 Flexible and adjustable zero discharge system and method for high-salinity wastewater of thermal power plant
CN109455867B (en) * 2018-12-28 2023-04-25 大唐环境产业集团股份有限公司 Flexible and adjustable thermal power plant full-load high-salinity wastewater zero-emission system and method
CN110372142A (en) * 2019-07-10 2019-10-25 中国华电科工集团有限公司 A kind of device using low-grade flue gas processing waste water
CN110748901A (en) * 2019-11-04 2020-02-04 洪新思 High-temperature catalytic sewage treatment device and high-temperature catalytic sewage treatment process
CN111362342A (en) * 2019-11-06 2020-07-03 北京铝能清新环境技术有限公司 Wastewater zero discharge system and method for multi-stage treatment
CN114585430A (en) * 2019-11-15 2022-06-03 普莱克斯技术有限公司 Energy-saving VPSA system using directly-driven high-speed centrifugal compressor

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