CN107965748A - A kind of coal oven dithio-gas heat recovery system free of discontinuities - Google Patents

A kind of coal oven dithio-gas heat recovery system free of discontinuities Download PDF

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Publication number
CN107965748A
CN107965748A CN201711405018.XA CN201711405018A CN107965748A CN 107965748 A CN107965748 A CN 107965748A CN 201711405018 A CN201711405018 A CN 201711405018A CN 107965748 A CN107965748 A CN 107965748A
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CN
China
Prior art keywords
heat exchanger
steam
gas
vapor
output terminal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711405018.XA
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Chinese (zh)
Inventor
付立欣
许桂瑛
金基浩
李桦
蒋富
何玉涛
肖丽
任众
李旭东
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Priority to CN201711405018.XA priority Critical patent/CN107965748A/en
Publication of CN107965748A publication Critical patent/CN107965748A/en
Pending legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00Methods of steam generation characterised by form of heating method
    • F22B1/02Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B27/00Arrangements for withdrawal of the distillation gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B43/00Preventing or removing incrustations
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22STEAM GENERATION
    • F22BMETHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B33/00Steam-generation plants, e.g. comprising steam boilers of different types in mutual association
    • F22B33/18Combinations of steam boilers with other apparatus
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coke Industry (AREA)

Abstract

The present invention relates to a kind of coal oven dithio-gas heat recovery system free of discontinuities, including hot precipitator, waste heat boiler, cryogenic heat exchanger, oxygen-eliminating device, sweet-water tank, heating furnace, reducing-and-cooling plant, steam superheater and decompressor;The present invention uses the heat of waste heat heat boiler high efficiente callback coal oven dithio-gas, and the steam for producing multi-parameter is used for high-voltage power user and low-pressure steam user, and realizes that process system steam inside recycles, and reaches energy saving purpose;Meanwhile ensure the operation free of discontinuities of waste heat reclaiming process system and do not influence coke oven safety in production.

Description

A kind of coal oven dithio-gas heat recovery system free of discontinuities
Technical field
The present invention relates to residual heat utilizing technology of coke oven crude gas field, more particularly to a kind of coal oven dithio-gas heat are free of discontinuities Recovery system.
Background technology
Coking process flow is substantially the industrial flow using carbon stream as main body train of thought, therefore solves carbon stream It is energy-saving to be of great significance for optimization coking process flow.Heat expenditure in coke production mainly by it is red it is burnt from 650~750 DEG C of medium temperature waste heats, coke oven flues that 950~1050 DEG C of high-temperature residual heats, the coal oven dithio-gas taken out of in coke oven are taken out of give up 180~250 DEG C of low temperature exhaust heats and four part of furnace body surface heat loss composition that gas is taken out of.Wherein, coal oven dithio-gas is taken out of 650~750 DEG C of medium temperature waste heats account for the 37% of coke oven heat expenditure, this partial heat of high efficiente callback recycles coal chemical enterprise secondary energy sources It is particularly important that utilization, but coal oven dithio-gas component is extremely complex, easily condensation precipitation is attached in heat-exchanger rig and graphite occurs Change effect.At present, waste heat of coke oven crude gas, but recuperation of heat are mainly recycled using Ascension Pipe Gasification cooling device, HYWHR technologies etc. Efficiency is low, product category is single, it is easy generation coke oven coke oven uprising tube leak to coke furnace carbonization chamber phenomena such as, influence coke oven keep the safety in production.
The content of the invention
It is burnt using the high efficiente callback of waste heat heat boiler the present invention provides a kind of coal oven dithio-gas heat recovery system free of discontinuities The heat of stove raw coke oven gas, the steam for producing multi-parameter is used for high-voltage power user and low-pressure steam user, and realizes technique system System steam inside recycles, and reaches energy saving purpose;Meanwhile ensure the operation free of discontinuities of waste heat reclaiming process system and do not influence Jiao Stove is kept the safety in production.
In order to achieve the above object, the present invention is realized using following technical scheme:
A kind of coal oven dithio-gas heat recovery system free of discontinuities, including hot precipitator, waste heat boiler, cryogenic heat exchanger, Oxygen-eliminating device, sweet-water tank, heating furnace, reducing-and-cooling plant, steam superheater and decompressor;The waste heat boiler by drum and Vapor heat exchanger A, the vapor heat exchanger B connected respectively by tedge, down-comer and drum;The raw coke oven gas of hot precipitator is defeated Enter the gas collecting tube of end connection coke oven, the raw coke oven gas output terminal of hot precipitator connects vapor heat exchanger A and steaming in waste heat boiler Vapour heat exchanger B;The demineralized water output terminal of sweet-water tank pumps the demineralized water input terminal of connection oxygen-eliminating device, oxygen-eliminating device by deaerated feedwater Boiler feedwater input terminal pass through boiler feed pump connect cryogenic heat exchanger boiler feedwater output terminal, the boiler of cryogenic heat exchanger Feed water input terminal connection drum;The conduction oil output terminal of the conduction oil input terminal connection heating furnace of cryogenic heat exchanger, low-temperature heat exchange The conduction oil input terminal of the conduction oil output terminal connection heating furnace of device;The saturated vapor output terminal of drum connects pressure and temperature reducing at the same time The saturated vapor input terminal of device and steam superheater, the desuperheating water input terminal connection boiler feedwater pump discharge of reducing-and-cooling plant Pipeline;The low-pressure steam output terminal connection low-pressure steam user of reducing-and-cooling plant;Steam superheater sets coke dry quenching furnace recyclegas Entrance, the high pressure superheated steam output terminal connection high-voltage power user of steam superheater, the high pressure superheated steam of steam superheater Output terminal connects vapor heat exchanger A and vapor heat exchanger B by decompressor.
The vapor heat exchanger A sets raw coke oven gas entry and exit pressure difference monitoring device, vapor heat exchanger A and vapor heat exchanger B it Between raw coke oven gas input channel on set switching valve, set block valve respectively on the tedge of vapor heat exchanger A, down-comer;Raw coke oven gas Entry and exit pressure difference monitoring device and switching valve, block valve interlocked control.
Ash cellar is set below the hot precipitator.
The heating furnace uses heated by gas.
The vapor heat exchanger A, the sewerage output terminal of vapor heat exchanger B connect blowdown by periodical blowdown expander Well.
Compared with prior art, the beneficial effects of the invention are as follows:
1) coal oven dithio-gas is led into waste heat boiler and carries out coal oven dithio-gas heat recovery and utilization, ensure heat-exchange system With coke oven independent operating;It is capable of the heat of high efficiente callback coal oven dithio-gas, produces the steam of many kinds of parameters and realize process system Steam inside recycles, and reaches energy saving purpose;
2) recycling free of discontinuities of coal oven dithio-gas heat is realized, is not required to halt production coke cleaning, steam can be avoided to greatest extent Heat exchange is because of the possibility of coking booster;And steam user can be continuously steam is provided;
3) it is abundant to make use of self-produced 550 DEG C of low-pressure superheated steams to improve steam circulation utilization rate, clearly as heat source is burnt Burnt effect is good, speed is fast, avoids the damage of mechanical decoking exchange heat pipe, while has saved the energy;
4) heat-exchange system and coke oven independent operation, are independent of each other, and can be matched with a variety of production-scale coke ovens;
5) monitor coking situation in heat exchanger tube on-line, realize and automatically switch between vapor heat exchanger A, B;
6) coke dry quenching furnace recyclegas utilization rate is improved;
7) water cycle efficieny is high in system, reduces outer net water supply.
Brief description of the drawings
Fig. 1 is a kind of structure diagram of coal oven dithio-gas heat recovery system free of discontinuities of the present invention.
In figure:1. 2. hot precipitator of coke oven, 3. sweet-water tank, 4. deaerated feedwater pumps 5. oxygen-eliminating device, 6. boiler feedwater Pump 7. cryogenic heat exchanger, 8. tedge, 9. down-comer, 10. periodical blowdown expander, 11. sewage well, 12. ash cellar, 13. waste heat 17. decompressor of boiler 14. reducing-and-cooling plant, 15. steam superheater, 16. heating furnace, 18. vapor heat exchanger A 19. steams 20. drums of vapour heat exchanger B
Embodiment
The embodiment of the present invention is described further below in conjunction with the accompanying drawings:
As shown in Figure 1, a kind of coal oven dithio-gas heat recovery system free of discontinuities of the present invention, including hot precipitator 2, Waste heat boiler 13, cryogenic heat exchanger 7, oxygen-eliminating device 5, sweet-water tank 3, heating furnace 16, reducing-and-cooling plant 14, steam superheater 15 And decompressor 17;The steaming that the waste heat boiler 13 is connected by drum 20 and respectively by tedge 8, down-comer 9 with drum 20 Vapour heat exchanger A 18, vapor heat exchanger B 19;The gas collecting tube of the raw coke oven gas input terminal connection coke oven 1 of hot precipitator 2, high temperature remove Vapor heat exchanger A 18 and vapor heat exchanger B 19 in the raw coke oven gas output terminal connection waste heat boiler 13 of dirt device 2;Sweet-water tank 3 Demineralized water output terminal pass through deaerated feedwater pump 4 connection oxygen-eliminating devices 5 demineralized water input terminals, oxygen-eliminating device 5 boiler feedwater input End connects the boiler feedwater output terminal of cryogenic heat exchanger 7, the boiler feedwater input terminal of cryogenic heat exchanger 7 by boiler feed pump 6 Connect drum 20;The conduction oil output terminal of the conduction oil input terminal connection heating furnace 16 of cryogenic heat exchanger 7, cryogenic heat exchanger 7 Conduction oil output terminal connects the conduction oil input terminal of heating furnace 16;The saturated vapor output terminal of drum 20 connects pressure and temperature reducing at the same time The saturated vapor input terminal of device 14 and steam superheater 15, the desuperheating water input terminal connection boiler feedwater of reducing-and-cooling plant 14 Pump 6 outlet conduits;The low-pressure steam output terminal connection low-pressure steam user of reducing-and-cooling plant 14;Steam superheater 15 sets dry put out Stove recyclegas entrance, the high pressure superheated steam output terminal connection high-voltage power user of steam superheater 15, steam superheater 15 High pressure superheated steam output terminal pass through decompressor 17 and connect vapor heat exchanger A 18 and vapor heat exchanger B 19.
The vapor heat exchanger A 18 sets raw coke oven gas entry and exit pressure difference monitoring device, and vapor heat exchanger A 18 and steam change Set switching valve on raw coke oven gas input channel between hot device B 19, on the tedge 8 of vapor heat exchanger A 18, down-comer 9 respectively If block valve;Raw coke oven gas entry and exit pressure difference monitoring device and switching valve, block valve interlocked control.
The lower section of the hot precipitator 2 sets ash cellar 12.
The heating furnace 16 uses heated by gas.
The vapor heat exchanger A 18, the sewerage output terminal of vapor heat exchanger B 19 are connected by periodical blowdown expander 10 Connect sewage well 11.
A kind of technical process of coal oven dithio-gas high temperature section heat efficient system for reclaiming of the present invention is as follows:
1) 650~750 DEG C of raw coke oven gas from coke oven enter gas collecting tube by the tedge of coke oven 1, enter after flue dust aggregation Hot precipitator 2 carries out dedusting, and the raw coke oven gas after dedusting exchanges heat into waste heat boiler 13, and the lime-ash after dedusting enters ash cellar Outer row after 12;
2) the vapor heat exchanger A 18 that raw coke oven gas enters in waste heat boiler 13 exchanges heat, and keeps raw coke oven gas inlet temperature about For 650 DEG C, 25~40m/s of mean flow rate, 330 DEG C of heat exchanger tube tube wall temperature;After heat exchange low temperature raw coke oven gas enter other workshop sections into Row low-temperature zone heat recovery;
3) at the same time, the temperature after deaerated feedwater pump 4 enters oxygen-eliminating device 5 of the room temperature demineralized water in sweet-water tank 3 reaches 104 DEG C, 104 DEG C of deaerated feedwater enters cryogenic heat exchanger 7 through boiler feed pump 6 all the way, the 300 DEG C of heat conduction produced with heating furnace 16 Temperature reaches 210 DEG C after oil heat exchange;Another way is sent to reducing-and-cooling plant 14 and is used as desuperheating water;
4) after 210 DEG C of boiler feedwater enters drum 20, enter vapor heat exchanger A 18 through down-comer 9, handed over by heat Change, become through tedge 8 to enter in drum 20 after steam water interface and carry out vapor-liquid separation, the high temperature and pressure saturated vapor of generation (10~13MPa of steam pressure, 311~331 DEG C of vapor (steam) temperature) send paramount pressure after being overheated into steam superheater 15 Electric user, be sent into vapor heat exchanger A 18 after being depressurized into decompressor 17, vapor heat exchanger B 19 is burnt, or enter and subtract Warm decompressor 14 is sent to each low-pressure steam user after carrying out desuperheat, decompression;
5) monitor the raw coke oven gas inlet outlet pressure differential of vapor heat exchanger A 18 on-line, automatically switch when pressure difference reaches 1.5KPa To vapor heat exchanger B 19, the steam/water circulating process of vapor heat exchanger B 19 is identical with vapor heat exchanger A 18;At the same time, Take in the high pressure superheated steam of the generation of steam superheater 15 all the way, producing 550 DEG C of low-pressure superheated steams through decompressor 17 leads to Enter in vapor heat exchanger A 18 and start on-line decoking, when stopping when product is clean water of burning that vapor heat exchanger A 18 is discharged is burnt It is burnt;
6) sewerage that waste heat boiler 13 produces in process of production, sewage well 11 is discharged into through periodical blowdown expander 10.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (5)

1. a kind of coal oven dithio-gas heat recovery system free of discontinuities, it is characterised in that including hot precipitator, waste heat boiler, low Warm heat exchanger, oxygen-eliminating device, sweet-water tank, heating furnace, reducing-and-cooling plant, steam superheater and decompressor;The waste heat pot Vapor heat exchanger A, the vapor heat exchanger B that stove is connected by drum and respectively by tedge, down-comer and drum;Hot precipitator Raw coke oven gas input terminal connection coke oven gas collecting tube, hot precipitator raw coke oven gas output terminal connection waste heat boiler in steam change Hot device A and vapor heat exchanger B;The demineralized water that the demineralized water output terminal of sweet-water tank pumps connection oxygen-eliminating device by deaerated feedwater inputs End, the boiler feedwater input terminal of oxygen-eliminating device connect the boiler feedwater output terminal of cryogenic heat exchanger by boiler feed pump, and low temperature changes The boiler feedwater input terminal connection drum of hot device;The conduction oil output of the conduction oil input terminal connection heating furnace of cryogenic heat exchanger End, the conduction oil input terminal of the conduction oil output terminal connection heating furnace of cryogenic heat exchanger;The saturated vapor output terminal of drum is at the same time Connect the saturated vapor input terminal of reducing-and-cooling plant and steam superheater, the desuperheating water input terminal connection pot of reducing-and-cooling plant Stove feed pump outlet conduit;The low-pressure steam output terminal connection low-pressure steam user of reducing-and-cooling plant;Steam superheater sets dry Stove recyclegas entrance is put out, the high pressure superheated steam output terminal of steam superheater connects high-voltage power user, steam superheater High pressure superheated steam output terminal connects vapor heat exchanger A and vapor heat exchanger B by decompressor.
A kind of 2. coal oven dithio-gas heat recovery system free of discontinuities according to claim 1, it is characterised in that the steam Heat exchanger A sets raw coke oven gas entry and exit pressure difference monitoring device, the raw coke oven gas input pipe between vapor heat exchanger A and vapor heat exchanger B Set switching valve on road, block valve is set respectively on the tedge of vapor heat exchanger A, down-comer;Raw coke oven gas entry and exit pressure difference monitoring dress Put and switching valve, block valve interlocked control.
A kind of 3. coal oven dithio-gas heat recovery system free of discontinuities according to claim 1, it is characterised in that the high temperature Ash cellar is set below deduster.
A kind of 4. coal oven dithio-gas heat recovery system free of discontinuities according to claim 1, it is characterised in that the heating Stove uses heated by gas.
A kind of 5. coal oven dithio-gas heat recovery system free of discontinuities according to claim 1, it is characterised in that the steam Heat exchanger A, the sewerage output terminal of vapor heat exchanger B connect sewage well by periodical blowdown expander.
CN201711405018.XA 2017-12-22 2017-12-22 A kind of coal oven dithio-gas heat recovery system free of discontinuities Pending CN107965748A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108590789A (en) * 2018-07-05 2018-09-28 中冶焦耐(大连)工程技术有限公司 A kind of coal oven dithio-gas sensible heat and red burnt sensible heat cogeneration technique and system
CN109611820A (en) * 2018-12-14 2019-04-12 江西庞泰环保股份有限公司 A kind of relieving haperacidity waste heat recovery apparatus and method
CN111187139A (en) * 2020-03-06 2020-05-22 中冶焦耐(大连)工程技术有限公司 Industrial naphthalene oil gas cooling process and system for byproduct steam

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CN103436271A (en) * 2013-08-30 2013-12-11 常州江南电力节能科技有限公司 System for recycling raw gas afterheat of coke oven
CN204079875U (en) * 2014-09-29 2015-01-07 南京竣业过程机械设备有限公司 A kind of new Type Coke Oven raw gas waste-heat recovery device
CN205115368U (en) * 2015-09-30 2016-03-30 上海宝钢节能环保技术有限公司 Coke oven crude gas sensible heat recovery system
CN206232660U (en) * 2016-11-18 2017-06-09 邯郸钢铁集团设计院有限公司 A kind of attemperating unit of coal oven dithio-gas Exposure degree
CN206538377U (en) * 2017-03-14 2017-10-03 中冶华天工程技术有限公司 Coke oven coke oven uprising tube raw coke oven gas waste heat recovery co-generation unit
CN107286961A (en) * 2017-07-21 2017-10-24 中冶焦耐(大连)工程技术有限公司 A kind of coal oven dithio-gas high temperature section heat high efficiente callback device
CN207741061U (en) * 2017-12-22 2018-08-17 中冶焦耐(大连)工程技术有限公司 A kind of coal oven dithio-gas heat recovery system free of discontinuities

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103436271A (en) * 2013-08-30 2013-12-11 常州江南电力节能科技有限公司 System for recycling raw gas afterheat of coke oven
CN204079875U (en) * 2014-09-29 2015-01-07 南京竣业过程机械设备有限公司 A kind of new Type Coke Oven raw gas waste-heat recovery device
CN205115368U (en) * 2015-09-30 2016-03-30 上海宝钢节能环保技术有限公司 Coke oven crude gas sensible heat recovery system
CN206232660U (en) * 2016-11-18 2017-06-09 邯郸钢铁集团设计院有限公司 A kind of attemperating unit of coal oven dithio-gas Exposure degree
CN206538377U (en) * 2017-03-14 2017-10-03 中冶华天工程技术有限公司 Coke oven coke oven uprising tube raw coke oven gas waste heat recovery co-generation unit
CN107286961A (en) * 2017-07-21 2017-10-24 中冶焦耐(大连)工程技术有限公司 A kind of coal oven dithio-gas high temperature section heat high efficiente callback device
CN207741061U (en) * 2017-12-22 2018-08-17 中冶焦耐(大连)工程技术有限公司 A kind of coal oven dithio-gas heat recovery system free of discontinuities

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108590789A (en) * 2018-07-05 2018-09-28 中冶焦耐(大连)工程技术有限公司 A kind of coal oven dithio-gas sensible heat and red burnt sensible heat cogeneration technique and system
CN109611820A (en) * 2018-12-14 2019-04-12 江西庞泰环保股份有限公司 A kind of relieving haperacidity waste heat recovery apparatus and method
CN111187139A (en) * 2020-03-06 2020-05-22 中冶焦耐(大连)工程技术有限公司 Industrial naphthalene oil gas cooling process and system for byproduct steam

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Application publication date: 20180427