CN107964321A - A kind of photo-thermal dual curable type blast coating and preparation method thereof - Google Patents
A kind of photo-thermal dual curable type blast coating and preparation method thereof Download PDFInfo
- Publication number
- CN107964321A CN107964321A CN201710741899.6A CN201710741899A CN107964321A CN 107964321 A CN107964321 A CN 107964321A CN 201710741899 A CN201710741899 A CN 201710741899A CN 107964321 A CN107964321 A CN 107964321A
- Authority
- CN
- China
- Prior art keywords
- photo
- curable type
- dual curable
- coating
- thermal dual
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/02—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber
- B05D7/04—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to macromolecular substances, e.g. rubber to surfaces of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of photo-thermal dual curable type blast coating and preparation method thereof, which is made of following 5 30% light-cured resin of weight percentage, 20 50% thermosetting resins, 16 20% photo polymerization monomers, 2 5% light curing agents, 10 15% latency thermal curing agents, 0 10% diluent, 0 20% function additive.The preparation method of the coating includes：Light-cured resin, photo polymerization monomer, thermosetting resin are uniformly mixed, form mixture；By levelling agent, defoamer, polymerization inhibitor are sequentially added in mixture, then light curing agent, latency thermal curing agents, coupling agent are added, and photo-thermal dual curable type blast coating is made.Coating of the present invention can overcome the disadvantages that the deficiency of photocuring, assign the excellent physics of coating, mechanical performance, can particularly improve the adhesive force and wearability of coating and basement membrane.
Description
Technical field
The present invention relates to brightness enhancement film technical field of coatings, and in particular to a kind of photo-thermal dual curable type blast coating and its
Preparation method.
Background technology
Brightness enhancement film (BEF, Brightness Enhancement Film) is most important light in the module of display backlight source
One of film is learned, light that luminaire sent can be converged to increase display brightness.Its action principle is using on surface
Special prismatic structure, is narrowed through the visual angle of the light of scatter plate to increase the brightness for the light that display user is seen, is saved aobvious
Show device battery apparatus energy, and improve the utilization rate for sending luminous energy.
Blast membrane material generally use UV curing process produces currently on the market, and this technique is exactly a kind of two-way in fact
The liquid glue of plastic material last layer or multilayer after stretching, the structure figure to form brightness enhancement film is rolled by patterned roll.But
Be photocuring depth it is limited, ultraviolet light less than dash area can not cure, be restricted the shape of curing object,
Coating and basement membrane attachment are unstable, and blast coating abrasion performance is poor, seriously reduces the product qualified rate of production.
The Chinese invention patent application that application publication number is CN103555153A (Application No. 201310454630.1) is public
A kind of brightness enhancement film coating composition has been opened, has included each component of following parts by weight：5~80 parts of light-cured resin, photopolymerization list
5~100 parts of body, 1~30 part of photoinitiator, 0~20 part of diluent, 0~10 part of auxiliary agent.What the brightness enhancement film coating composition was formed
Coating is easy to template separation, is conducive to prismatic structure special made by improving and is replicated on the base material with blast coating
Precision；Coating good film-forming property, resistance to ag(e)ing are good；But the coating that the brightness enhancement film coating composition is formed still suffers from coating and basement membrane
Adhere to unstable, the defects of blast coating abrasion performance is poor.
The content of the invention
The present invention provides a kind of photo-thermal dual curable type blast coating being readily produced and preparation method thereof, the coating
It can overcome the disadvantages that the deficiency of photocuring, assigned the excellent physics of coating, mechanical performance, can particularly improve the attached of coating and basement membrane
Put forth effort and wearability.
A kind of photo-thermal dual curable type blast coating, is made of the component of following weight percentage：
It is compound by light-cured resin, thermosetting resin, photo polymerization monomer in the present invention, coordinate light curing agent, latency
Thermal curing agents, each component can interact, mutually collaboration, assign the excellent physics of coating, mechanical performance, particularly consolidate in light
On the basis of changing resin, photo polymerization monomer, light curing agent, thermosetting resin and latency thermal curing agents are added, can be notable
The adhesive force of coating and basement membrane is improved, can also improve the wearability of blast membrane coat.Also, the brightness enhancement film coating preparation goes out to carry
High-light-energy utilization rate, the brightness enhancement film for strengthening light-source brightness.
Coupling agent, levelling agent, defoamer, polymerization inhibitor etc. can be selected in the function additive.
The preferred technical solution of the present invention is used as below：
The photo-thermal dual curable type blast coating, is made of the component of following weight percentage：
In the present invention, using coupling agent, levelling agent, defoamer and polymerization inhibitor as function additive, the function of said components
Auxiliary agent is combined with each other with light-cured resin, thermosetting resin, photo polymerization monomer, light curing agent, latency thermal curing agents, can
The adhesive force of coating and basement membrane is further improved, can also improve the wearability of blast membrane coat, it is more excellent coating can be assigned
Good physics, mechanical performance.
Still more preferably, the photo-thermal dual curable type blast coating, by the component of following weight percentage
Form：
The light-cured resin is aliphatic urethane acrylate (U.S. cyanogen spy EBECRYL8200), aliphatic poly
More than one or both of urethane acrylate (EBECRYL8405), acroleic acid esterification acrylate (741) (including two
Kind).
The preferred cycloaliphatic epoxy resin of the thermosetting resin (such as 711,732), glycidyl ester type epoxy resin are (such as
731st, 672, TDE-85), diglycidyl ether type epoxy resin (such as 680, F-76), glycidyl amine type epoxy resin (such as AG-
One or both of 80) more than (including two kinds).
The photo polymerization monomer is propylene glycol diacrylate (such as TPGDA), and monofunctional epoxy acrylate is (such as
EBECRYL113), polyether acrylate (EBECRYL140, EBECRYL892), bisphenol a diacrylate (such as SR601,
EM2261, BP042, EBECRYL150), adjacent phenyl benzene ethoxyethyl acrylate (such as EM2105, PP-011, AM611), third
Olefin(e) acid isobornyl thiocyanoacetate (such as ODA), ethoxylated neopentylglycol diacrylate (such as EBECRYL 145), trimethylolpropane tris
More than one or both of acrylate (such as TMPTA) (including two kinds).
The light curing agent is the double methyl ethers (such as 651) of benzil, Dialkoxy acetophenones (such as 1173), 2- hydroxyls -2-
Methyl isophthalic acid-phenyl -1- acetone (such as Darocur1173), phosphorous oxide is (such as phenyl double (2,4,6- trimethylbenzoyls)
Irgacure819), alpha-hydroxyalkyl benzophenone (such as 184), α-aminoalkylphenones (such as 907,369), styrax methyl phenyl ethers anisole is (such as
Irgacure651), acyl group phosphorous oxides (such as TP0,819).
The latency thermal curing agents are made of following one or more kinds of mixture of substances：Succinic acid hydrazide ii, oneself
More than one or both of dihydrazi, isophthalic dihydrazide, salicylic acid hydrazides (including two kinds).
The diluent is alcohol ethers solvent, in esters solvent, ketones solvent, aromatic solvent, oil series solvent
One or both of more than (including two kinds).
The coupling agent is made of following one or more kinds of mixture of substances：Aminopropyl triethoxysilane is (such as
KH550), glycidyl ester oxy propyl trimethoxysilane (such as KH560), methacryloxypropyl trimethoxy silane
(such as KH570), vinyltriethoxysilane (such as A151), vinyltriethoxysilane (such as A171), mercapto propyl group trimethoxy
Base silane (such as KH580, KH590), ethylenediaminepropyltriethoxysilane (such as KH792), ethylenediamine hydroxypropyl methyl dimethoxy
Silane (such as KBM602).
The levelling agent is made of following one or more kinds of mixture of substances：Dimethyl silicone polymer, polymethyl-benzene
Radical siloxane.
The polymerization inhibitor is made of following one or more kinds of mixture of substances：Hydroquinone, 1,4-benzoquinone, para hydroxybenzene
Methyl ether, 2- tert-butyl hydroquinone.
The defoamer is made of following one or more kinds of mixture of substances：Aliphatic acid and its metallic soap and esters,
Propane diols, polyoxypropylene ethylene oxide glycerin ether, dimethicone, 2-Ethylhexyl Alcohol.
A kind of preparation method of photo-thermal dual curable type blast coating, comprises the following steps：
1) light-cured resin, photo polymerization monomer, thermosetting resin are uniformly mixed, form mixture；
2) levelling agent, defoamer, polymerization inhibitor are sequentially added in the mixture in step 1), then by light curing agent, latent
Property thermal curing agents, coupling agent add, photo-thermal dual curable type blast coating is made.
A kind of photo-thermal dual curable type brightness enhancement film, including blast film base material and use photo-thermal dual curable type of the present invention increase
Bright coating is coated on the broached-tooth design coating formed on blast film base material.
Blast film base material is specially ethylene glycol terephthalate material.
The photo-thermal dual curable type brightness enhancement film further includes two be arranged on outside blast film base material and broached-tooth design coating
Layer protective film.
A kind of preparation method of photo-thermal dual curable type brightness enhancement film, comprises the following steps：
Using the process units of photo-thermal dual curable type brightness enhancement film, including the cleaning being connected for roll unit, with for roll unit
Unit, the coater unit being connected with cleaning unit, the embossing unit being connected with coater unit, the protective film being connected with embossing unit
Recombiner unit, the rolling unit being connected with protective film recombiner unit；
Blast film base material is placed on on roll unit, coater unit is by photo-thermal dual curable type blast coating of the present invention
Blast film base material is coated on, by embossing unit, broached-tooth design coating is formed, afterwards, passes through protective film recombiner unit compound two
Layer protective film, finally winding are completed, and obtain photo-thermal dual curable type brightness enhancement film.
Sawtooth on the broached-tooth design coating is isosceles triangle.
The embossing unit include sequentially connected patterned roll, UV lamp group, baking oven, the patterned roll include roll body with
And it is arranged on the sawtooth on the roll body.
The protective film recombiner unit includes protective film for volume and protective film for volume.
Compared with prior art, the invention has the advantages that：
1st, the adhesive force of coating and basement membrane is improved；
2nd, the wearability of blast membrane coat is improved；
3rd, the product qualified rate of production is improved.
Brief description of the drawings
Fig. 1 is the structure diagram of photo-thermal dual curable type brightness enhancement film in the present invention；
Fig. 2 is the structure diagram of the process units of photo-thermal dual curable type brightness enhancement film in the present invention.
Embodiment
Embodiment 1
Component is weighed according to table 1 below：
Table 1
Wherein light-cured resin, photo polymerization monomer, thermosetting resin it will be put into dispersing mixer and be uniformly mixed, be formed mixed
Compound；
By levelling agent, defoamer, polymerization inhibitor are sequentially added in said mixture；
Light curing agent, latency thermal curing agents, coupling agent are added in said mixture, photo-thermal dual curable type is made and increases
Bright coating；
Using the process units of photo-thermal dual curable type brightness enhancement film, photo-thermal dual curable type blast coating is coated on increasing
On bright film base material 100, the drying and forming-film after ultraviolet light and heat cure, film, that is, broached-tooth design coating of formation.
Protective film is covered on broached-tooth design coating 200, that is, photo-thermal dual curable type brightness enhancement film of the present invention is made.
Fig. 1 is photo-thermal dual curable type brightness enhancement film proposed by the present invention, including blast film base material 100 and using the present invention
Photo-thermal dual curable type blast coating is coated on the broached-tooth design coating 200 on blast film base material 100.Blast film base material 100
Specially ethylene glycol terephthalate (PET) material.
As shown in Fig. 2, the process units of photo-thermal dual curable type brightness enhancement film, including supply roll unit 1, with connecting for roll unit 1
It is the cleaning unit 2 that connects, the coater unit 3 being connected with cleaning unit 2, the embossing unit 4 being connected with coater unit 3, single with embossing
The protective film recombiner unit 5 of the connection of member 4, the rolling unit 6 being connected with protective film recombiner unit 5, embossing unit 4 include connecting successively
Patterned roll 4.1, UV lamp group 4.2 and the baking oven 4.3 connect, protective film recombiner unit 5 include protective film and are supplied for volume 5.1 and protective film
Volume 5.2.
Brightness enhancement film made from this preparation embodiment has following physico-chemical parameter, as shown in table 2：
Table 2
Embodiment 2
Component is weighed according to following table, as shown in table 3：
Table 3
Wherein light-cured resin, photo polymerization monomer, thermosetting resin it will be put into dispersing mixer and be uniformly mixed, be formed mixed
Compound；
By levelling agent, defoamer, polymerization inhibitor are sequentially added in said mixture；
By light curing agent, latency thermal curing agents.Coupling agent is added in said mixture, and photo-thermal dual curable type is made and increases
Bright coating；
Using the process units of photo-thermal dual curable type brightness enhancement film, photo-thermal dual curable type blast coating is coated on increasing
On bright film base material 100, the drying and forming-film after ultraviolet light and heat cure, film, that is, broached-tooth design coating of formation.
Protective film is covered on broached-tooth design coating 200, that is, photo-thermal dual curable type brightness enhancement film of the present invention is made.
Brightness enhancement film made from this preparation embodiment has following physico-chemical parameter, as shown in table 4：
Table 4
Embodiment 3
Component is weighed according to table 5 below：
Table 5
Wherein light-cured resin, photo polymerization monomer, thermosetting resin it will be put into dispersing mixer and be uniformly mixed, be formed mixed
Compound；
By levelling agent, defoamer, polymerization inhibitor are sequentially added in said mixture；
By light curing agent, latency thermal curing agents.Coupling agent is added in said mixture, and photo-thermal dual curable type is made and increases
Bright coating；
Using the process units of photo-thermal dual curable type brightness enhancement film, photo-thermal dual curable type blast coating is coated on increasing
On bright film base material 100, the drying and forming-film after ultraviolet light and heat cure, film, that is, broached-tooth design coating of formation.
Protective film is covered on broached-tooth design coating 200, that is, photo-thermal dual curable type brightness enhancement film of the present invention is made.
Brightness enhancement film made from this preparation embodiment has following physico-chemical parameter, as shown in table 6：
Table 6
Comparative example 1
Component is weighed according to table 7 below, latency thermal curing agents, the same embodiment of preparation method are not used relative to embodiment 1
1：
Table 7
Brightness enhancement film made from this preparation embodiment has following physico-chemical parameter, as shown in table 8：
Table 8
Comparative example 2
Component is weighed according to table 9 below, latency thermal curing agents and light curing agent, preparation side are not used relative to embodiment 1
Method is the same as embodiment 1：
Table 9
Brightness enhancement film made from this preparation embodiment has following physico-chemical parameter, as shown in table 10：
Table 10
Embodiment 1~3 uses photo-thermal dual curable type blast coating of the present invention, and obtained brightness enhancement film, its performance is more
It is excellent, particularly embodiment 1, its relative to embodiment 2 and 3, performance is more excellent, and particularly damage resistant, pencil hardness refers to
Mark, shows more excellent, illustrates, the photo-thermal dual curable type brightness enhancement film adhesive force and wearability of embodiment 1 are more excellent.
Comparative example 1 does not add latency thermal curing agents, its performance is decreased obviously, particularly scratch-resistant relative to embodiment 1
The index of wound, pencil hardness and adhesion decreases drastically, and illustrates that adhesive force and wearability have dropped, it is seen then that latent
Property thermal curing agents add, to adhesive force and wearability lifting have obvious effect.
Comparative example 2 does not add latency thermal curing agents and light curing agent, its performance is further bright relative to embodiment 1
Aobvious to decline, the index of particularly damage resistant, pencil hardness and adhesion further significantly declines, and illustrates adhesive force and wear-resisting
Property further have dropped, it is seen then that latency thermal curing agents and light curing agent add, and can produce synergy, to attachment
Power and wearability lifting have obvious effect.
Claims (9)
1. a kind of photo-thermal dual curable type blast coating, it is characterised in that be made of the component of following weight percentage：
2. photo-thermal dual curable type blast coating according to claim 1, it is characterised in that contained by following weight percent
The component of amount is formed：
3. photo-thermal dual curable type blast coating according to claim 2, it is characterised in that contained by following weight percent
The component of amount is formed：
4. the photo-thermal dual curable type blast coating according to claim 1,2 or 3, it is characterised in that the light is consolidated
Change resin is aliphatic urethane acrylate, one kind in aliphatic urethane acrylate, acroleic acid esterification acrylate
It is or two or more.
5. the photo-thermal dual curable type blast coating according to claim 1,2 or 3, it is characterised in that the thermosetting
Type resin is cycloaliphatic epoxy resin, glycidyl ester type epoxy resin, diglycidyl ether type epoxy resin, glycidic amine type
It is more than one or both of epoxy resin.
6. the photo-thermal dual curable type blast coating according to claim 1,2 or 3, it is characterised in that the light gathers
Conjunction monomer is propylene glycol diacrylate, monofunctional epoxy acrylate, polyether acrylate, bisphenol a diacrylate, neighbour
Phenyl benzene ethoxyethyl acrylate, isobornyl acrylate, ethoxylated neopentylglycol diacrylate, trihydroxy methyl third
It is more than one or both of alkane triacrylate.
7. the photo-thermal dual curable type blast coating according to claim 1,2 or 3, it is characterised in that the light is consolidated
Agent is that the double methyl ethers of benzil are Dialkoxy acetophenones, 2- hydroxy-2-methyl -1- phenyl -1- acetone, the double (2,4,6- of phenyl
Trimethylbenzoyl) phosphorous oxide, alpha-hydroxyalkyl benzophenone, α-aminoalkylphenones, styrax methyl phenyl ethers anisole, in acyl group phosphorous oxides
It is one or more kinds of.
8. the photo-thermal dual curable type blast coating according to claim 1,2 or 3, it is characterised in that described is latent
Property thermal curing agents for succinic acid hydrazide ii, adipic dihydrazide, isophthalic dihydrazide, one kind in salicylic acid hydrazides or two
More than kind.
9. according to the preparation method of claim 2~8 any one of them photo-thermal dual curable type blast coating, its feature exists
In comprising the following steps：
1) light-cured resin, photo polymerization monomer, thermosetting resin are uniformly mixed, form mixture；
2) levelling agent, defoamer, polymerization inhibitor are sequentially added in the mixture in step 1), then light curing agent, latency is hot
Curing agent, coupling agent add, and photo-thermal dual curable type blast coating is made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710741899.6A CN107964321A (en) | 2017-08-25 | 2017-08-25 | A kind of photo-thermal dual curable type blast coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710741899.6A CN107964321A (en) | 2017-08-25 | 2017-08-25 | A kind of photo-thermal dual curable type blast coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107964321A true CN107964321A (en) | 2018-04-27 |
Family
ID=61997588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710741899.6A Pending CN107964321A (en) | 2017-08-25 | 2017-08-25 | A kind of photo-thermal dual curable type blast coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107964321A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113249003A (en) * | 2021-06-24 | 2021-08-13 | 东莞大宝化工制品有限公司 | Heat and ultraviolet dual-curing varnish and preparation method thereof |
| CN114456684A (en) * | 2022-02-16 | 2022-05-10 | 无锡八禾新材料科技有限公司 | Solvent-free photo-thermal dual-curing anticorrosive paint |
| CN117304772A (en) * | 2023-11-29 | 2023-12-29 | 清华大学深圳国际研究生院 | Hard epoxy composite material for optical fiber insulator and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555153A (en) * | 2013-09-27 | 2014-02-05 | 上海维凯化学品有限公司 | Brightening film paint composition |
| CN104312233A (en) * | 2014-09-28 | 2015-01-28 | 上海维凯光电新材料有限公司 | Scratch-resistant wear-resistant self-repairing brightness-enhancing film coating composition |
| CN104877557A (en) * | 2015-05-12 | 2015-09-02 | 上海乘鹰新材料有限公司 | Self-repairing lustering coating composition with high refraction index |
| US20180201720A1 (en) * | 2015-05-08 | 2018-07-19 | Kcc Corporation | Powder coating latent curing agent, and epoxy powder coating composition containing same |
-
2017
- 2017-08-25 CN CN201710741899.6A patent/CN107964321A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103555153A (en) * | 2013-09-27 | 2014-02-05 | 上海维凯化学品有限公司 | Brightening film paint composition |
| CN104312233A (en) * | 2014-09-28 | 2015-01-28 | 上海维凯光电新材料有限公司 | Scratch-resistant wear-resistant self-repairing brightness-enhancing film coating composition |
| US20180201720A1 (en) * | 2015-05-08 | 2018-07-19 | Kcc Corporation | Powder coating latent curing agent, and epoxy powder coating composition containing same |
| CN104877557A (en) * | 2015-05-12 | 2015-09-02 | 上海乘鹰新材料有限公司 | Self-repairing lustering coating composition with high refraction index |
Non-Patent Citations (2)
| Title |
|---|
| 胡玉明等: "《固化剂》", 30 April 2004, 化学工业出版社 * |
| 袁东芝等: "PET型光学薄膜用涂层及相关技术研究现状", 《化学与黏合》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113249003A (en) * | 2021-06-24 | 2021-08-13 | 东莞大宝化工制品有限公司 | Heat and ultraviolet dual-curing varnish and preparation method thereof |
| CN114456684A (en) * | 2022-02-16 | 2022-05-10 | 无锡八禾新材料科技有限公司 | Solvent-free photo-thermal dual-curing anticorrosive paint |
| CN117304772A (en) * | 2023-11-29 | 2023-12-29 | 清华大学深圳国际研究生院 | Hard epoxy composite material for optical fiber insulator and preparation method thereof |
| CN117304772B (en) * | 2023-11-29 | 2024-02-13 | 清华大学深圳国际研究生院 | Hard epoxy composite material for optical fiber insulator and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107523185A (en) | A kind of photo-thermal dual curable type brightness enhancement film and preparation method thereof | |
| TWI409306B (en) | Hard coating | |
| TWI488910B (en) | Photocurable resin composition, method of fabricating optical film using the same, and optical film including the same | |
| CN102236113B (en) | Ultraviolet-cured hard coating and application thereof | |
| CN104105598B (en) | Laminate for window sheet, window sheet comprising same and display device comprising same | |
| JP5463170B2 (en) | Fine pattern manufacturing method, substrate with fine pattern, light source device including substrate with fine pattern, and image display device | |
| CN107964321A (en) | A kind of photo-thermal dual curable type blast coating and preparation method thereof | |
| JP5168608B2 (en) | Radical polymerizable composition, cured product, and plastic lens | |
| CN106497499B (en) | A kind of UV solidification optical cement | |
| CN106634761B (en) | Ultraviolet light curing composition and preparation method of master mask | |
| US20080057262A1 (en) | Low-Reflection Material | |
| CN104093561A (en) | Direct electric heating system for heating a subsea pipeline | |
| CN102046674B (en) | Resin composition for manufacturing optical component and application thereof | |
| JP5796757B2 (en) | Photopolymerizable resin composition for molding and multilayer molded product | |
| WO2014045856A1 (en) | Laminate and use thereof | |
| CN113512365A (en) | Ultraviolet-curing structural adhesive composition and application thereof | |
| CN104459844B (en) | A kind of optical diffusion and preparation method thereof | |
| KR102321823B1 (en) | Active energy ray-curable resin composition for optical article, cured product and optical sheet | |
| KR20130000288A (en) | Adhesive, manufacturing method of display device using the same | |
| JP4273990B2 (en) | Manufacturing method of transparent composite substrate | |
| JP2012116993A (en) | Active energy ray-curable matting material liquid composition and coated article | |
| JP6365917B1 (en) | Inkjet ink composition | |
| CN107001884B (en) | Optical applications adhesive composition, the preparation method of optical applications adhesive composition and optical applications binder film | |
| KR20190097670A (en) | UV curing type paint composition | |
| JP2019006984A (en) | Active energy ray-curable composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180427 |