CN107964311A - A kind of graphene heat dissipation flame-retardant waterproof coating - Google Patents
A kind of graphene heat dissipation flame-retardant waterproof coating Download PDFInfo
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- CN107964311A CN107964311A CN201711219709.0A CN201711219709A CN107964311A CN 107964311 A CN107964311 A CN 107964311A CN 201711219709 A CN201711219709 A CN 201711219709A CN 107964311 A CN107964311 A CN 107964311A
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- waterproof coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of graphene heat dissipation flame-retardant waterproof coating, it is made of following components and parts by weight：70 80 parts of acrylic emulsion, 58 parts of graphene oxide water solution, 8 10 parts of perlite powder, 69 parts of nano silica powder, 35 parts of titanium dioxide, 0.1 0.5 parts of thickener, 25 parts of aqueous fire retardant, 0.05 0.08 parts of preservative, 0.01 0.03 parts of defoamer, 35 parts of water cross-linking agent, 13 parts of aqueous catalyst, 25 parts of water, 0.1 0.5 parts of filler material.The present invention enhances performance relative to existing water-repellent paint.
Description
Technical field
The invention belongs to building material technical field, and in particular to a kind of graphene heat dissipation flame-retardant waterproof coating.
Background technology
Will be on building surface, the chemical reaction of volatilization or two kinds of components through solvent or moisture forms thin film,
Building surface is set to completely cut off with water, so as to play the role of waterproof, sealing, these thick liquids brushed are known as water-repellent paint,
The waterproof material of in the market has two major classes：First, polyurethane kind water-repellent paint.This kind of material is usually by polyurethane and coal tar
It is made as raw material.The tar gas toxicity that it is volatilized is big, and does not allow easy-clear, also containing toxic；Another kind of is polymer
Cement-base waterproof coating, but existing cement-base waterproof coating is of high cost, water resistance, weatherability, resistant of high or low temperature, resistance to ag(e)ing
Can be poor, various reinforcing agents, filler, macromolecular elastomer are made it be dispersed in colloid by hardly possible, and product easily leaks
Basic reason be exactly loss of properties on aging, non-refractory is not heat-insulated, antirust, service life is not short or bonds showing loosely
As.In some steel structural plant roofs, ship steel deck, metallic bone face, metal platform and various relevant metal Roof waterproofs,
Need water-repellent paint to construct on complex-shaped roofing, the good waterproof layer of overall performance can be formed, have preferable overall
It is structural, and the overall structure performance of existing water-repellent paint is poor, is not suitable for the waterproof of metal steel structure building.
Later, the applicant was in order to overcome above-mentioned technological deficiency, it is proposed that improvement project simultaneously obtains 201310244734.X
Number Chinese invention patent.
The content of the invention
Keep on improving, the applicant experiences dearly, and only product, which is constantly brought forth new ideas, preferably to develop.Whether can make
201310244734.X number the performance of Water-resistant paint for steel structure color steel tile be further enhancedFor this reason, applicant makes
Experiment many times, tests many kinds different component and dosage, has paid creative work, just obtained the present invention.
It is more more preferable in thermal diffusivity, anti-flammability and water proofing property than existing water-repellent paint it is an object of the invention to provide one kind
Graphene heat dissipation flame-retardant waterproof coating.
Used technical solution is：
A kind of graphene heat dissipation flame-retardant waterproof coating, it is made of following components and parts by weight：
Further, the perlite powder is the perlite powder of 200-300 mesh.
In the technical solution of the present invention, the effect of acrylic emulsion also has good in addition to preferable bond properties
Water proofing property；Water cross-linking agent is used cooperatively with aqueous catalyst, can improve the crosslinking of water cross-linking agent and acrylic emulsion
Speed and reactivity worth, so as to further improve water proofing property.
Aqueous fire retardant, for improving the anti-flammability of product, by this product of aqueous fire retardant component formation, is being subject to
During extraneous burning things which may cause a fire disaster attack, flame transmission can be effectively prevented, delayed or terminated, and is haveed the function that fire-retardant.
Graphene oxide water solution except with can solve the problems, such as well metal surface poor adhesive force, improve product
Outside overall tensile strength and elongation at break, additionally it is possible to improve the thermal diffusivity of product entirety, metallic steel can be perfectly suitable for
Structure, in this regard, graphene oxide water solution also has antiseptic property.
Perlite powder, the component are resistant to 800-1000 DEG C of high temperature.
In addition, nano silica powder has hydrophily, and affine other powders such as perlite powder and titanium dioxide,
With polymolecularity；Acrylic emulsion has the function that to combine other each components；Thickener adds the density, thick of product
Degree, and product component such as perlite powder, nano silica powder, titanium dioxide is not precipitated.Water cross-linking agent, it may have connection
Cooperation is used, and for improving the adhesivity of product, and water cross-linking agent has good compatibility in aqueous systems；Along with Shen
Ask someone repeatedly to grope the content for adjusting each component, enable each component whole production of compatible formation well being entirely formulated
Product.
During preparation, first by other each components in addition to graphene oxide water solution, after being mixed evenly, then stirring
Under be slowly added to graphene oxide water solution and be uniformly mixed, you can product is made, it is convenient to prepare.
The present invention should be stored in the interior of aeration-drying, be greater than or equal to 100 DEG C of flawlesses after film forming, avoid solarization
Drench with rain, after coating drives bucket, must be stirred evenly with wooden stick or mixer, prevent precipitation and metachromatism from occurring, this coating waterproof layer
Brushing method mainly is used, brushing every time should not be blocked up, and when the coating is as waterproof layer, its coating thickness is no less than 2mm, applies
During brush, stir evenly and reuse, it is good with the bonding of basal plane to ensure, during curing of coatings, forbid film after hardening
Upper dilatory weight, in order to avoid destroy waterproof layer.
The beneficial effects of the present invention are：
By repeatedly to the Adjustment Tests of existing No. 201310244734.X formula, obtained it is a kind of in thermal diffusivity, it is fire-retardant
Property and water proofing property more preferable graphene heat dissipation flame-retardant waterproof coating.
Embodiment
Technical scheme is further described with reference to embodiment, but is simply enumerated from the numerous experiments of applicant
Section Example, the protection domain of application claims is not limited thereto.
Embodiment 1
The graphene heat dissipation flame-retardant waterproof coating of the present embodiment, it is made of following components and parts by weight：
Embodiment 2
The graphene heat dissipation flame-retardant waterproof coating of the present embodiment, it is made of following components and parts by weight：
Embodiment 3
The graphene heat dissipation flame-retardant waterproof coating of the present embodiment, it is made of following components and parts by weight：
Embodiment 4
The graphene heat dissipation flame-retardant waterproof coating of the present embodiment, it is made of following components and parts by weight：
Embodiment 5
The graphene heat dissipation flame-retardant waterproof coating of the present embodiment, it is made of following components and parts by weight：
Graphene heat dissipation flame-retardant waterproof coating made from each embodiment, carries out it performance detection, and add by more than
201310244734.X number water-repellent paint performance data, obtain following table：
The detection method of graphene heat dissipation flame-retardant waterproof coating made from this each embodiment and No. 201310244734.X
Water-repellent paint detection method it is consistent.
The graphene heat dissipation flame-retardant waterproof coating of the present invention is respectively provided with good property in thermal diffusivity, anti-flammability and water proofing property
Can, comprehensive performance is better than the water-repellent paint of No. 201310244734.X.
And as can be known from the above table, graphene of the invention radiate flame-retardant waterproof coating tensile strength, elongation at break and
In high temperature resistant, the water-repellent paint comprehensively than No. 201310244734.X in each lower limit value has obtained significantly carrying
Height, amplification achieve unexpected technique effect beyond expection！
Claims (2)
- The flame-retardant waterproof coating 1. a kind of graphene radiates, it is characterised in that it is made of following components and parts by weight：
- The flame-retardant waterproof coating 2. graphene according to claim 1 radiates, it is characterised in that the perlite powder is The perlite powder of 200-300 mesh.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711219709.0A CN107964311A (en) | 2017-11-28 | 2017-11-28 | A kind of graphene heat dissipation flame-retardant waterproof coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711219709.0A CN107964311A (en) | 2017-11-28 | 2017-11-28 | A kind of graphene heat dissipation flame-retardant waterproof coating |
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| Publication Number | Publication Date |
|---|---|
| CN107964311A true CN107964311A (en) | 2018-04-27 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711219709.0A Pending CN107964311A (en) | 2017-11-28 | 2017-11-28 | A kind of graphene heat dissipation flame-retardant waterproof coating |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111777900A (en) * | 2020-07-26 | 2020-10-16 | 吴晨伟 | Waterproof coating and preparation method thereof |
| CN113025136A (en) * | 2020-04-10 | 2021-06-25 | 深圳市烯世传奇科技有限公司 | Graphene heat dissipation coating and preparation method and application thereof |
| CN113527966A (en) * | 2021-07-09 | 2021-10-22 | 河北三棵树涂料有限公司 | Water-based polyurea composite modified single-component acrylic acid waterproof coating and preparation method thereof |
| CN113913073A (en) * | 2021-11-05 | 2022-01-11 | 浙江双金粉末涂料有限公司 | Weather-resistant waterproof flame-retardant integrated coating and preparation method thereof |
| CN115073986A (en) * | 2022-08-11 | 2022-09-20 | 马赫 | Elastic waterproof coating and preparation method thereof |
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| CN103275582A (en) * | 2013-06-20 | 2013-09-04 | 厦门力嘉诚防水工程有限公司 | Water-resistant paint for steel structure color steel tile |
| CN105219190A (en) * | 2015-09-30 | 2016-01-06 | 徐州卧牛山新型防水材料有限公司 | A kind of flame retardant type metal Roof waterproof paint and preparation method thereof |
| CN107189664A (en) * | 2017-07-14 | 2017-09-22 | 合肥威斯伏新材料有限公司 | A kind of waterproof coating and preparation method |
| CN107384084A (en) * | 2017-09-06 | 2017-11-24 | 哈尔滨绿科科技有限公司 | A kind of high-strength anti-corrosion water paint and preparation method thereof |
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2017
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| CN103275582A (en) * | 2013-06-20 | 2013-09-04 | 厦门力嘉诚防水工程有限公司 | Water-resistant paint for steel structure color steel tile |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113025136A (en) * | 2020-04-10 | 2021-06-25 | 深圳市烯世传奇科技有限公司 | Graphene heat dissipation coating and preparation method and application thereof |
| CN111777900A (en) * | 2020-07-26 | 2020-10-16 | 吴晨伟 | Waterproof coating and preparation method thereof |
| CN113527966A (en) * | 2021-07-09 | 2021-10-22 | 河北三棵树涂料有限公司 | Water-based polyurea composite modified single-component acrylic acid waterproof coating and preparation method thereof |
| CN113527966B (en) * | 2021-07-09 | 2022-10-28 | 河北三棵树涂料有限公司 | Water-based polyurea composite modified single-component acrylic acid waterproof coating and preparation method thereof |
| CN113913073A (en) * | 2021-11-05 | 2022-01-11 | 浙江双金粉末涂料有限公司 | Weather-resistant waterproof flame-retardant integrated coating and preparation method thereof |
| CN113913073B (en) * | 2021-11-05 | 2022-07-05 | 浙江双金粉末涂料有限公司 | Weather-resistant waterproof flame-retardant integrated coating and preparation method thereof |
| CN115073986A (en) * | 2022-08-11 | 2022-09-20 | 马赫 | Elastic waterproof coating and preparation method thereof |
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Application publication date: 20180427 |
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