CN107955229A - A kind of cushion of functional form sole - Google Patents
A kind of cushion of functional form sole Download PDFInfo
- Publication number
- CN107955229A CN107955229A CN201711421323.8A CN201711421323A CN107955229A CN 107955229 A CN107955229 A CN 107955229A CN 201711421323 A CN201711421323 A CN 201711421323A CN 107955229 A CN107955229 A CN 107955229A
- Authority
- CN
- China
- Prior art keywords
- cushion
- functional form
- sole
- vinegar
- polyisoprene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
- A43B13/18—Resilient soles
- A43B13/187—Resiliency achieved by the features of the material, e.g. foam, non liquid materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/002—Methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/18—Spheres
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The present invention provides a kind of cushion of functional form sole, includes the component of following parts by weight：Polyisoprene 85 105, cyclohexyl thio maleimide 9 15, tetraalkylthiuram disulfide 6 11, Isosorbide-5-Nitrae diaminobutane 8 17, polyacrylamide 16 25, Properties of Polystyrene Nano Particles 23 29, acid fiber by polylactic 31 45, silicic acid second vinegar 8 15, kaolin 11 23.Coordinated by the synergistic of each component of the present invention, the damping property of sole and the comfort of dress is greatly improved, made shoe body moulded simpler, beautiful, easily meet public demand.
Description
Technical field
The present invention relates to a kind of component of shoes, specifically refers to a kind of cushion of functional form sole, it can be extensive
Among the sport footwears such as basketball shoes, running shoe, climbing boot, tennis shoes, commercial Men's Shoes, women's shoes.
Background technology
Footwear are an important components of people's dress, and the general part of the force of footwear is sole, so the structure of sole
Make and directly influence the performances of footwear in itself.
The original structure of sole is that a piece of glue bottom is sole, but because sole is thicker, so general weight is not light, in order to
Weight is reduced, the structure of boring upper surface open occurs, centre there are some soles of thick stick lattice as supporting point.It is such
Although sole alleviates, but also do not have assist function and obvious damping effect, does not meet ergonomic designs' requirement.Because of people
Each walking, whole body Bones and joints is undergone one-shot, the impact bigger that people is subject in running or jump, almost
There is the pressure for being three times in own body weight, can thus easily cause injury, especially waist-leg portion, foot, be damaged bigger.With
The growth at age, the damping of Bones and joints itself, lubricating function weaken, and are allowed to the impact bigger being subject to, and cause waist-leg to be ached
Bitterly, other sensitive parts such as brain, internal organ also comes to harm.
Currently on the market there are some products, sole to be only made of the foaming body of individual layer, such product possess it is light, compared with
Good elasticity, it mainly adds thicker elastic foam in sole, but this foaming body using when can seem partially thick,
So that the ratio of sole does not live, it is unfavorable for walking or moves.For this reason, a kind of sole for possessing excellent damping performance is existing to overcome
The deficiency of product is very important.
The content of the invention
In view of this, the present invention provides a kind of cushion of functional form sole, to overcome weight present in existing product
Greatly, the problems such as antiskid, shock-absorbing effect is poor.
The technical scheme is that：A kind of cushion of functional form sole, it is characterised in that including following parts by weight
Component：Polyisoprene 85-105, cyclohexyl thio maleimide 9-15, tetraalkylthiuram disulfide 6-11,1,
4- diaminobutanes 8-17, polyacrylamide 16-25, Properties of Polystyrene Nano Particles 23-29, acid fiber by polylactic 31-45,
Silicic acid second vinegar 8-15, kaolin 11-23.
Further, the cushion of the functional form sole includes the component of following parts by weight：Polyisoprene 95-
100th, cyclohexyl thio maleimide 11-14, tetraalkylthiuram disulfide 8-10, Isosorbide-5-Nitrae-diaminobutane 11-15,
Polyacrylamide 19-22, Properties of Polystyrene Nano Particles 26-28, acid fiber by polylactic 34-43, silicic acid second vinegar 10-13, kaolinite
Native 15-20.
Further, the cushion of the functional form sole includes the component of following parts by weight：Polyisoprene
98th, cyclohexyl thio maleimide 12, tetraalkylthiuram disulfide 9, Isosorbide-5-Nitrae-diaminobutane 13, polyacrylamide
21st, Properties of Polystyrene Nano Particles 27, acid fiber by polylactic 38, silicic acid second vinegar 11, kaolin 17.
Further, the tensile strength that the cushion of the functional form sole is measured according to JIS K6251 for 25MPa with
On, elongation at break is more than 150%, and 100% tensile stress is 15-22MPa.
Particularly, the present invention can be prepared by any prior art.
Preferably, preparation method of the invention is：According to the proportioning of each component of the present invention, by polyisoprene, curing
Tetraalkyl thiuram, polyacrylamide, Properties of Polystyrene Nano Particles, acid fiber by polylactic, silicic acid second vinegar, kaolin are mediated with pressurization
Machine is kneaded, and the rotating speed for controlling pressure kneader is 50rpm, and mixing time is set to until the maximum temperature of mixture reaches
Time untill 120 DEG C.After cooling, cyclohexyl thio maleimide, Isosorbide-5-Nitrae-diaminourea are added in obtained mixture
Butane, is kneaded using mixing mill, and the cushioning layer material of the functional form sole of the present invention is prepared.
The complex role of cyclohexyl thio maleimide according to the present invention and Isosorbide-5-Nitrae-diaminobutane, using poly- different
Pentadiene is as main component, and other formula components are also general component, but by suitably controlling formula components
Species, combination and content, being also capable of providing reduces manufacture cost and the extremely excellent padded coaming of impact resistance.By of the invention each
The synergistic of component coordinates, and the damping property of sole and the comfort of dress is greatly improved, and makes shoe body moulded simpler, beautiful,
Easily meet public demand.
Embodiment
The technical solution in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example is only part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this area is common
Technical staff's all other embodiments obtained without making creative work, belong to the model that the present invention protects
Enclose.
Embodiment 1
A kind of cushion of functional form sole, it is characterised in that include the component of following parts by weight：Polyisoprene 85, ring
It is the thio maleimide 9 of hexyl, tetraalkylthiuram disulfide 6, Isosorbide-5-Nitrae-diaminobutane 8, polyacrylamide 16, poly-
Styrene nanoparticle 23, acid fiber by polylactic 31, silicic acid second vinegar 8, kaolin 11.
Embodiment 2
A kind of cushion of functional form sole, it is characterised in that include the component of following parts by weight：Polyisoprene 105,
Cyclohexyl thio maleimide 15, tetraalkylthiuram disulfide 11, Isosorbide-5-Nitrae-diaminobutane 17, polyacrylamide
25th, Properties of Polystyrene Nano Particles 29, acid fiber by polylactic 45, silicic acid second vinegar 15, kaolin 23.
Embodiment 3
A kind of cushion of functional form sole, includes the component of following parts by weight：Polyisoprene 100, cyclohexyl thio horse
Come acid imide 14, tetraalkylthiuram disulfide 10, Isosorbide-5-Nitrae-diaminobutane 15, polyacrylamide 22, polystyrene to receive
Meter Wei Qiu 28, acid fiber by polylactic 43, silicic acid second vinegar 13, kaolin 20.
Embodiment 4
A kind of cushion of functional form sole, includes the component of following parts by weight：Polyisoprene 95, cyclohexyl thio horse
Come acid imide 11, tetraalkylthiuram disulfide 8, Isosorbide-5-Nitrae-diaminobutane 11, polyacrylamide 19, polystyrene to receive
Meter Wei Qiu 26, acid fiber by polylactic 34, silicic acid second vinegar 10, kaolin 15.
Embodiment 5
A kind of cushion of functional form sole, includes the component of following parts by weight：Polyisoprene 98, cyclohexyl thio horse
Come acid imide 12, tetraalkylthiuram disulfide 9, Isosorbide-5-Nitrae-diaminobutane 13, polyacrylamide 21, polystyrene to receive
Meter Wei Qiu 27, acid fiber by polylactic 38, silicic acid second vinegar 11, kaolin 17.
Comparative example 1
A kind of cushion of functional form sole, includes the component of following parts by weight：Polyisoprene 98, cyclohexyl thio horse
Come acid imide 12, tetraalkylthiuram disulfide 9, polyacrylamide 21, Properties of Polystyrene Nano Particles 27, acid fiber by polylactic
38th, silicic acid second vinegar 11, kaolin 17.
Comparative example 2
A kind of cushion of functional form sole, includes the component of following parts by weight：Polyisoprene 98, curing tetraalkyl
Thiuram 9, Isosorbide-5-Nitrae-diaminobutane 13, polyacrylamide 21, Properties of Polystyrene Nano Particles 27, acid fiber by polylactic 38,
Silicic acid second vinegar 11, kaolin 17.
Comparative example 3
A kind of cushion of functional form sole, includes the component of following parts by weight：Polyisoprene 98, cyclohexyl thio horse
Come acid imide 12, tetraalkylthiuram disulfide 9, Isosorbide-5-Nitrae-diaminobutane 13, polyacrylamide 21, silicic acid second vinegar
11st, kaolin 17.
Performance test
According to following methods production by the component proportion of embodiment 1-5 and comparative example 1-3, finished product is prepared.Specific method is such as
Under：According to the proportioning of each component of the present invention, by polyisoprene, tetraalkylthiuram disulfide, polyacrylamide, polystyrene
Nanoparticle, acid fiber by polylactic, silicic acid second vinegar, kaolin are kneaded with pressure kneader, control the rotating speed of pressure kneader
For 50rpm, mixing time is set to the time untill the maximum temperature of mixture reaches 120 DEG C.After cooling, what is obtained
Cyclohexyl thio maleimide, Isosorbide-5-Nitrae-diaminobutane are added in mixture, is kneaded, is prepared using mixing mill
The cushion of the functional form sole of the present invention.
No. 3 type test films of dumbbell shaped are die cut from sheet products formed according to JIS K6251, the sheet products formed is basis
JIS K6250 are fabricated to the products formed of the thickness of 2mm.Stretched the test film in a manner of 500mm/ minutes, measure tensile strength,
Elongation at break, 100% tensile stress.In addition, according to JIS K6253, with A type scleroscope hardness tests machine measure sheet into
The hardness of type product.These experiments all carry out at a temperature of 25 DEG C, and the experimental results are shown inthe following table.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical solution, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.It is noted that the technical characteristic not being described in detail in the present invention, can be by appointing
One prior art is realized.
Claims (4)
1. a kind of cushion of functional form sole, it is characterised in that include the component of following parts by weight：Polyisoprene 85-
105th, cyclohexyl thio maleimide 9-15, tetraalkylthiuram disulfide 6-11, Isosorbide-5-Nitrae-diaminobutane 8-17, poly-
Acrylamide 16-25, Properties of Polystyrene Nano Particles 23-29, acid fiber by polylactic 31-45, silicic acid second vinegar 8-15, kaolin
11-23。
2. the cushion of functional form sole according to claim 1, it is characterised in that include the group of following parts by weight
Point：Polyisoprene 95-100, cyclohexyl thio maleimide 11-14, tetraalkylthiuram disulfide 8-10, Isosorbide-5-Nitrae-
Diaminobutane 11-15, polyacrylamide 19-22, Properties of Polystyrene Nano Particles 26-28, acid fiber by polylactic 34-43, silicon
Sour second vinegar 10-13, kaolin 15-20.
3. the cushion of functional form sole according to claim 1, it is characterised in that include the group of following parts by weight
Point：Polyisoprene 98, cyclohexyl thio maleimide 12, tetraalkylthiuram disulfide 9, Isosorbide-5-Nitrae-diaminobutane
13rd, polyacrylamide 21, Properties of Polystyrene Nano Particles 27, acid fiber by polylactic 38, silicic acid second vinegar 11, kaolin 17.
4. according to the cushion of claim 1-3 any one of them functional form soles, it is characterised in that according to JIS K6251
The tensile strength of measure is more than 25MPa, and elongation at break is more than 150%, and 100% tensile stress is 15-22MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711421323.8A CN107955229A (en) | 2017-12-25 | 2017-12-25 | A kind of cushion of functional form sole |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711421323.8A CN107955229A (en) | 2017-12-25 | 2017-12-25 | A kind of cushion of functional form sole |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107955229A true CN107955229A (en) | 2018-04-24 |
Family
ID=61956333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711421323.8A Withdrawn CN107955229A (en) | 2017-12-25 | 2017-12-25 | A kind of cushion of functional form sole |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107955229A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3732271A (en) * | 1970-07-30 | 1973-05-08 | Monsanto Co | N-(thio)diamides |
| US3847879A (en) * | 1970-07-30 | 1974-11-12 | Monsanto Co | N-(thio)diamides |
| US3855192A (en) * | 1971-06-07 | 1974-12-17 | Monsanto Chemicals | Inhibiting premature vulcanization of w-type polychloroprene rubber with n-hydrocarbyl-thioimides |
| CN103570982A (en) * | 2013-10-18 | 2014-02-12 | 青岛科技大学 | Composite rubber material of high-elasticity damping sole, and preparation method thereof |
| CN105348575A (en) * | 2015-11-26 | 2016-02-24 | 王威淞 | Formula of insulating cable jacket encapsulation |
-
2017
- 2017-12-25 CN CN201711421323.8A patent/CN107955229A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3732271A (en) * | 1970-07-30 | 1973-05-08 | Monsanto Co | N-(thio)diamides |
| US3847879A (en) * | 1970-07-30 | 1974-11-12 | Monsanto Co | N-(thio)diamides |
| US3855192A (en) * | 1971-06-07 | 1974-12-17 | Monsanto Chemicals | Inhibiting premature vulcanization of w-type polychloroprene rubber with n-hydrocarbyl-thioimides |
| CN103570982A (en) * | 2013-10-18 | 2014-02-12 | 青岛科技大学 | Composite rubber material of high-elasticity damping sole, and preparation method thereof |
| CN105348575A (en) * | 2015-11-26 | 2016-02-24 | 王威淞 | Formula of insulating cable jacket encapsulation |
Non-Patent Citations (1)
| Title |
|---|
| 于清溪: "《橡胶原材料手册》", 31 January 1996, 化学工业出版社 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180424 |
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| WW01 | Invention patent application withdrawn after publication |