CN107163557A - A kind of mosquito-proof cooling slippers and its production technology - Google Patents
A kind of mosquito-proof cooling slippers and its production technology Download PDFInfo
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- CN107163557A CN107163557A CN201710409839.4A CN201710409839A CN107163557A CN 107163557 A CN107163557 A CN 107163557A CN 201710409839 A CN201710409839 A CN 201710409839A CN 107163557 A CN107163557 A CN 107163557A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
- C08L75/08—Polyurethanes from polyethers
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/10—Footwear characterised by the material made of rubber
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B1/00—Footwear characterised by the material
- A43B1/14—Footwear characterised by the material made of plastics
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The present invention relates to a kind of mosquito-proof cooling slippers and its production technology, the cooling slippers are made up of following raw material：16 21 parts of toluene di-isocyanate(TDI), 10 14 parts of polypropylene oxide glycol, 14 parts of catalyst, 7 11 parts of vinyl acetate, 47 parts of cordate telosma, 47 parts of sweet orange, 24 31 parts of neoprene, 25 parts of sulphur, 36 parts of crosslinking agent, 15 parts of foaming agent, 9 13 parts of nano montmorillonite, 38 parts of tetrahydrofuran solution, 25 parts of nano titanium oxide, 25 parts of polyester fiber, appropriate amount of water；The made cooling slippers heat resistance of the present invention is good, and Anti-mosquito disinsectization effect is good, and anti-flammability is strong, ageing-resistant, practical, is worthy to be popularized.
Description
Technical field
Field is manufactured the present invention relates to slippers, and in particular to a kind of mosquito-proof cooling slippers and its production technology.
Background technology
The material for being presently used for manufacturing sandy beach slippers is mainly TPR thermoplastic elastic materials and PVC plastic and EVA trees
Fat synthetic material.Poor, the elastic bad, proportion of TPR material antiskid properties is heavier.PVC plastic proportion is heavier, easy fracture, poor flexibility.
EVA resin synthetic material easily turns yellow, easy fracture, elongation percentage are poor, not water-fast.The present invention proposes a kind of cooling slippers, and this product is fire-retardant
Property good, Anti-mosquito disinsectization, good percentage elongation.
In patent application CN103122099A disclosed in China for obtain a kind of slippers material of sandy beach containing wood chip and its
Preparation method, is raw material by the ethylene-vinyl acetate copolymer of VA contents 28%, wood chip, zinc oxide, talcum powder etc., obtained to drag
Footwear light specific gravity, elasticity it is good, anti-skidding, be difficult tear.It is a kind of for obtaining in patent application CN104544699A disclosed in China
Environmentally friendly massage slipper preparation method, uses silkworm excrement for raw material, after raw material stoving, dedusting removal of impurities, sews shoe body, filling, after inspection
Go out finished product, gained slippers are ventilative, comfortable, health care.
The made slippers of currently available technology although flexible good, light specific gravity, it is anti-skidding the advantages of, but heat resistance is poor, anti-
Mosquito anthelminthic effect is poor.
The content of the invention
For above-mentioned problem, the present invention proposes a kind of mosquito-proof cooling slippers.The made slippers of the present invention compensate for dragging
Footwear heat resistance is poor, the defect of Anti-mosquito disinsectization effect difference, also has the advantages that fire-retardant, ageing-resistant.
In order to realize above-mentioned purpose, the present invention uses following technical scheme：
A kind of mosquito-proof cooling slippers, are made up of following parts by weight raw material：16-21 parts of toluene di-isocyanate(TDI), polycyclic oxygen third
10-14 parts of alkane glycol, 1-4 parts of catalyst, 7-11 parts of vinyl acetate, 4-7 parts of cordate telosma, 4-7 parts of sweet orange, neoprene 24-31
Part, 2-5 parts of sulphur, 3-6 parts of crosslinking agent, 1-5 parts of foaming agent, 9-13 parts of nano montmorillonite, 3-8 parts of tetrahydrofuran solution, nanometer
2-5 parts of titanium dioxide, 2-5 parts of polyester fiber, appropriate amount of water.
It is preferred that, the slippers are made up of following parts by weight raw material：17-21 parts of toluene di-isocyanate(TDI), PPOX
11-14 parts of glycol, 2-4 parts of catalyst, 8-11 parts of vinyl acetate, 5-7 parts of cordate telosma, 5-7 parts of sweet orange, 25-31 parts of neoprene,
3-5 parts of sulphur, 4-6 parts of crosslinking agent, 2-5 parts of foaming agent, 10-13 parts of nano montmorillonite, 4-8 parts of tetrahydrofuran solution, nanometer two
3-5 parts of titanium oxide, 3-5 parts of polyester fiber, appropriate amount of water.
It is preferred that, the mass ratio of toluene di-isocyanate(TDI) and neoprene is more than 2/3.
It is preferred that, cordate telosma is 1 with sweet orange mass ratio:1.
It is preferred that, the slippers, production technology includes following several steps：
(1) toluene di-isocyanate(TDI), polypropylene oxide glycol, catalyst and neoprene are put into autoclave, then
Sulphur is added, under the conditions of 80 DEG C, 2h is reacted, then adds nano montmorillonite and tetrahydrofuran solution, stir, will react
Temperature in the kettle is maintained at 110 DEG C, reaction a period of time；
(2) cordate telosma and sweet orange are put into pot, the decocting for adding ten times of quality is boiled, and original six points are reduced to moisture
One of, soup is taken, soup cryogenic vacuum is concentrated into moisture is reduced to taken soup 1/10th, it is standby；
(3) soup, leftover materials and (1) products therefrom are put into reactor together and are well mixed, be warming up to 80 DEG C, instead
Answer and added after 1h in sole casting machine batch can, constant temperature 30min；
(4) by (3) products therefrom under the conditions of 100-105 DEG C banburying 20min, through double roller refine mould, then made through single screw rod
Grain machine granulation, is ultimately molded onto type, is stripped, produces mosquito-proof cooling slippers.
It is preferred that, sole casting built-in temperature is 55-65 DEG C in step (3).
Using above-mentioned technical scheme, the beneficial effects of the invention are as follows：Toluene di-isocyanate(TDI) and neoprene blending ratio
During more than 2/3, the chlorine that toluene di-isocyanate(TDI) starts to be connected with polarity in the main body as blend, the double bond of macromolecular main chain is former
Son, attracts the active pi-electron in double bond, reduces the activity and respond of double bond, while also reducing α-chlorine atom
Activity, so that blend has good weatherability and heat-resisting foster aging, while chlorine side base makes it have fire-retardant, resistance to be situated between again
The good characteristics such as matter, for producing slippers, improve the weatherability and anti-flammability of slippers；Toluene diisocynate is used as using sulphur
The vulcanizing system of ester and neoprene blend compounds, can make blend compounds combination property improve, and improve the crosslink density of vulcanizate, right
Other performances of vulcanizate do not produce influence；In addition, nano montmorillonite and neoprene carry out intercalation in tetrahydrofuran solution
Reaction prepares composite, and nano montmorillonite is dispersed in neoprene, and that has upset rubber molecular chain to a certain extent has
Sequence is arranged, and making the degree of order of rubber molecule reduces, therefore hinders the crystallization of rubber, for making slippers, improves slippers
Lower temperature resistance, anti-flammability and barrier property；Cordate telosma is irritant, and wherein extractive of volatile oil has efficient mosquito-repelling function,
Coordinate with sweet orange, be 1 in mass ratio:When 1, more preferable repelling effect is shown, adds in slippers making, improves as raw material
The Anti-mosquito disinsectization effect of slippers.
Embodiment is handed over flat
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention,
Technical scheme in the embodiment of the present invention is clearly and completely described.Based on embodiments of the invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belongs to the model that the present invention is protected
Enclose.
Embodiment 1：
A kind of mosquito-proof cooling slippers, are made up of following parts by weight raw material：16 parts of toluene di-isocyanate(TDI), PPOX two
10 parts of alcohol, 1 part of catalyst, 7 parts of vinyl acetate, 4 parts of cordate telosma, 4 parts of sweet orange, 24 parts of neoprene, 2 parts of sulphur, crosslinking agent 3
Part, 1 part of foaming agent, 9 parts of nano montmorillonite, 3 parts of tetrahydrofuran solution, 2 parts of nano titanium oxide, 2 parts of polyester fiber, water are fitted
Amount.
A kind of mosquito-proof cooling slippers, its production technology includes following several steps：
(1) toluene di-isocyanate(TDI), polypropylene oxide glycol, catalyst and neoprene are put into autoclave, then
Sulphur is added, under the conditions of 80 DEG C, 2h is reacted, then adds nano montmorillonite and tetrahydrofuran solution, stir, will react
Temperature in the kettle is maintained at 110 DEG C, reacts 1h；
(2) cordate telosma and sweet orange are put into pot, the decocting for adding ten times of quality is boiled, and original six points are reduced to moisture
One of, soup is taken, soup cryogenic vacuum is concentrated into moisture is reduced to taken soup 1/10th, it is standby；
(3) soup, leftover materials and (1) products therefrom are put into reactor together and are well mixed, be warming up to 80 DEG C, instead
Answer and added after 1h in the sole casting machine batch can that temperature is 55 DEG C, constant temperature 30min；
(4) by (3) products therefrom under the conditions of 100-105 DEG C banburying 20min, through double roller refine mould, then made through single screw rod
Grain machine granulation, is ultimately molded onto type, is stripped, produces mosquito-proof cooling slippers.
Embodiment 2：
A kind of mosquito-proof cooling slippers, are made up of following parts by weight raw material：21 parts of toluene di-isocyanate(TDI), PPOX two
14 parts of alcohol, 4 parts of catalyst, 11 parts of vinyl acetate, 7 parts of cordate telosma, 7 parts of sweet orange, 31 parts of neoprene, 5 parts of sulphur, crosslinking agent 6
Part, 5 parts of foaming agent, 13 parts of nano montmorillonite, 8 parts of tetrahydrofuran solution, 5 parts of nano titanium oxide, 5 parts of polyester fiber, water are fitted
Amount.
A kind of mosquito-proof cooling slippers, its production technology includes following several steps：
(1) toluene di-isocyanate(TDI), polypropylene oxide glycol, catalyst and neoprene are put into autoclave, then
Sulphur is added, under the conditions of 80 DEG C, 2h is reacted, then adds nano montmorillonite and tetrahydrofuran solution, stir, will react
Temperature in the kettle is maintained at 110 DEG C, reacts 1h；
(2) cordate telosma and sweet orange are put into pot, the decocting for adding ten times of quality is boiled, and original six points are reduced to moisture
One of, soup is taken, soup cryogenic vacuum is concentrated into moisture is reduced to taken soup 1/10th, it is standby；
(3) soup, leftover materials and (1) products therefrom are put into reactor together and are well mixed, be warming up to 80 DEG C, instead
Answer and added after 1h in the sole casting machine batch can that temperature is 56 DEG C, constant temperature 30min；
(4) by (3) products therefrom under the conditions of 100-105 DEG C banburying 20min, through double roller refine mould, then made through single screw rod
Grain machine granulation, is ultimately molded onto type, is stripped, produces mosquito-proof cooling slippers.
Embodiment 3：
A kind of mosquito-proof cooling slippers, are made up of following parts by weight raw material：17 parts of toluene di-isocyanate(TDI), PPOX two
11 parts of alcohol, 2 parts of catalyst, 8 parts of vinyl acetate, 5 parts of cordate telosma, 5 parts of sweet orange, 25 parts of neoprene, 3 parts of sulphur, crosslinking agent 4
Part, 2 parts of foaming agent, 10 parts of nano montmorillonite, 4 parts of tetrahydrofuran solution, 3 parts of nano titanium oxide, 3 parts of polyester fiber, water are fitted
Amount.
A kind of mosquito-proof cooling slippers, its production technology includes following several steps：
(1) toluene di-isocyanate(TDI), polypropylene oxide glycol, catalyst and neoprene are put into autoclave, then
Sulphur is added, under the conditions of 80 DEG C, 2h is reacted, then adds nano montmorillonite and tetrahydrofuran solution, stir, will react
Temperature in the kettle is maintained at 110 DEG C, reacts 1h；
(2) cordate telosma and sweet orange are put into pot, the decocting for adding ten times of quality is boiled, and original six points are reduced to moisture
One of, soup is taken, soup cryogenic vacuum is concentrated into moisture is reduced to taken soup 1/10th, it is standby；
(3) soup, leftover materials and (1) products therefrom are put into reactor together and are well mixed, be warming up to 80 DEG C, instead
Answer and added after 1h in the sole casting machine batch can that temperature is 65 DEG C, constant temperature 30min；
(4) by (3) products therefrom under the conditions of 100-105 DEG C banburying 20min, through double roller refine mould, then made through single screw rod
Grain machine granulation, is ultimately molded onto type, is stripped, produces mosquito-proof cooling slippers.
Embodiment 4：
A kind of mosquito-proof cooling slippers, are made up of following parts by weight raw material：18 parts of toluene di-isocyanate(TDI), PPOX two
13 parts of alcohol, 3 parts of catalyst, 9 parts of vinyl acetate, 6 parts of cordate telosma, 6 parts of sweet orange, 26 parts of neoprene, 4 parts of sulphur, crosslinking agent 5
Part, 3 parts of foaming agent, 11 parts of nano montmorillonite, 5 parts of tetrahydrofuran solution, 4 parts of nano titanium oxide, 4 parts of polyester fiber, water are fitted
Amount.
A kind of mosquito-proof cooling slippers, its production technology includes following several steps：
(1) toluene di-isocyanate(TDI), polypropylene oxide glycol, catalyst and neoprene are put into autoclave, then
Sulphur is added, under the conditions of 80 DEG C, 2h is reacted, then adds nano montmorillonite and tetrahydrofuran solution, stir, will react
Temperature in the kettle is maintained at 110 DEG C, reacts 1h；
(2) cordate telosma and sweet orange are put into pot, the decocting for adding ten times of quality is boiled, and original six points are reduced to moisture
One of, soup is taken, soup cryogenic vacuum is concentrated into moisture is reduced to taken soup 1/10th, it is standby；
(3) soup, leftover materials and (1) products therefrom are put into reactor together and are well mixed, be warming up to 80 DEG C, instead
Answer and added after 1h in the sole casting machine batch can that temperature is 58 DEG C, constant temperature 30min；
(4) by (3) products therefrom under the conditions of 100-105 DEG C banburying 20min, through double roller refine mould, then made through single screw rod
Grain machine granulation, is ultimately molded onto type, is stripped, produces mosquito-proof cooling slippers.
Embodiment 5：
A kind of mosquito-proof cooling slippers, are made up of following parts by weight raw material：20 parts of toluene di-isocyanate(TDI), PPOX two
12 parts of alcohol, 3 parts of catalyst, 10 parts of vinyl acetate, 6 parts of cordate telosma, 6 parts of sweet orange, 28 parts of neoprene, 4 parts of sulphur, crosslinking agent 5
Part, 4 parts of foaming agent, 12 parts of nano montmorillonite, 7 parts of tetrahydrofuran solution, 4 parts of nano titanium oxide, 4 parts of polyester fiber, water are fitted
Amount.
A kind of mosquito-proof cooling slippers, its production technology includes following several steps：
(1) toluene di-isocyanate(TDI), polypropylene oxide glycol, catalyst and neoprene are put into autoclave, then
Sulphur is added, under the conditions of 80 DEG C, 2h is reacted, then adds nano montmorillonite and tetrahydrofuran solution, stir, will react
Temperature in the kettle is maintained at 110 DEG C, reacts 1h；
(2) cordate telosma and sweet orange are put into pot, the decocting for adding ten times of quality is boiled, and original six points are reduced to moisture
One of, soup is taken, soup cryogenic vacuum is concentrated into moisture is reduced to taken soup 1/10th, it is standby；
(3) soup, leftover materials and (1) products therefrom are put into reactor together and are well mixed, be warming up to 80 DEG C, instead
Answer and added after 1h in the sole casting machine batch can that temperature is 60 DEG C, constant temperature 30min；
(4) by (3) products therefrom under the conditions of 100-105 DEG C banburying 20min, through double roller refine mould, then made through single screw rod
Grain machine granulation, is ultimately molded onto type, is stripped, produces mosquito-proof cooling slippers.
Product in slippers and market in the embodiment of the present invention is done into performance test, its test result is as follows：
| Tensile strength/MPa | Hardness/degree | Rub integrity degree/% | |
| Embodiment 1 | 17.13 | 16.9 | 80 |
| Embodiment 2 | 18.66 | 17.3 | 82 |
| Embodiment 3 | 17.39 | 16.8 | 81 |
| Embodiment 4 | 16.87 | 17.1 | 79 |
| Embodiment 5 | 17.05 | 17.0 | 81 |
| Reference examples 1 | 7.31 | 21.3 | 65 |
| Reference examples 2 | 8.25 | 22.4 | 71 |
In addition, cordate telosma, lavender, sweet orange, peppermint are combined into contrast, mosquito eradication rate such as following table：
The slippers are compared with slippers common in market as can be seen from the above table, and this product has good stretch resistance
Can, softness is suitable, and crocking resistance is good；Cordate telosma and sweet orange, lavender, peppermint mating reaction, repelling effect are more preferable, its
In, coordinate repelling effect more preferably with sweet orange, be worthy to be popularized.
Above example is only to the technical scheme for illustrating type of the present invention, rather than its limitations；Although implementing with reference to foregoing
Type of the present invention is described in detail example, it will be understood by those within the art that：It still can be to foregoing each
Technical scheme described in embodiment is modified, or carries out equivalent substitution to which part technical characteristic；And these are changed
Or replace, the essence of appropriate technical solution is departed from the spirit and scope of each embodiment technical scheme of type of the present invention.
Claims (6)
1. a kind of mosquito-proof cooling slippers, it is characterised in that be made up of following parts by weight raw material：16-21 parts of toluene di-isocyanate(TDI),
10-14 parts of polypropylene oxide glycol, 1-4 parts of catalyst, 7-11 parts of vinyl acetate, 4-7 parts of cordate telosma, 4-7 parts of sweet orange, neoprene rubber
24-31 parts of glue, 2-5 parts of sulphur, 3-6 parts of crosslinking agent, 1-5 parts of foaming agent, 9-13 parts of nano montmorillonite, tetrahydrofuran solution 3-8
Part, 2-5 parts of nano titanium oxide, 2-5 parts of polyester fiber, appropriate amount of water.
2. mosquito-proof cooling slippers according to claim 1, it is characterised in that be made up of following parts by weight raw material：Toluene two
17-21 parts of isocyanates, 11-14 parts of polypropylene oxide glycol, 2-4 parts of catalyst, 8-11 parts of vinyl acetate, 5-7 parts of cordate telosma,
5-7 parts of sweet orange, 25-31 parts of neoprene, 3-5 parts of sulphur, 4-6 parts of crosslinking agent, 2-5 parts of foaming agent, nano montmorillonite 10-13
Part, 4-8 parts of tetrahydrofuran solution, 3-5 parts of nano titanium oxide, 3-5 parts of polyester fiber, appropriate amount of water.
3. mosquito-proof cooling slippers according to claim 1, it is characterised in that the quality of toluene di-isocyanate(TDI) and neoprene
Than more than 2/3.
4. mosquito-proof cooling slippers according to claim 1, it is characterised in that cordate telosma is 1 with sweet orange mass ratio:1.
5. mosquito-proof cooling slippers according to claim 1, it is characterised in that production technology includes following several steps：
(1) toluene di-isocyanate(TDI), polypropylene oxide glycol, catalyst and neoprene are put into autoclave, then added
Sulphur, under the conditions of 80 DEG C, reacts 2h, then adds nano montmorillonite and tetrahydrofuran solution, stir, by reactor
Temperature is maintained at 110 DEG C, reacts 1h；
(2) cordate telosma and sweet orange are put into pot, the decocting for adding ten times of quality is boiled, original six are reduced to moisture/
One, soup is taken, soup cryogenic vacuum is concentrated into moisture is reduced to taken soup 1/10th, it is standby；
(3) soup, leftover materials and (1) products therefrom are put into reactor together and are well mixed, be warming up to 80 DEG C, react 1h
Add afterwards in sole casting machine batch can, constant temperature 30min；
(4) by (3) products therefrom under the conditions of 100-105 DEG C banburying 20min, through double roller refine mould, then through single screw rod comminutor
Granulation, is ultimately molded onto type, is stripped, produces mosquito-proof cooling slippers.
6. the production technology of mosquito-proof cooling slippers according to claim 5, it is characterised in that sole is poured in the step (3)
It is 55-65 DEG C to cast built-in temperature.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710409839.4A CN107163557A (en) | 2017-06-02 | 2017-06-02 | A kind of mosquito-proof cooling slippers and its production technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710409839.4A CN107163557A (en) | 2017-06-02 | 2017-06-02 | A kind of mosquito-proof cooling slippers and its production technology |
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| CN107163557A true CN107163557A (en) | 2017-09-15 |
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| CN201710409839.4A Pending CN107163557A (en) | 2017-06-02 | 2017-06-02 | A kind of mosquito-proof cooling slippers and its production technology |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233319A (en) * | 2018-09-13 | 2019-01-18 | 温州职业技术学院 | A kind of production technology of slippers |
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| CN105440370A (en) * | 2015-12-14 | 2016-03-30 | 桐乡市亿源鞋业有限公司 | Hard rubber sole material |
| CN105524345A (en) * | 2016-01-20 | 2016-04-27 | 苏州市景荣科技有限公司 | Method for preparing anti-mosquito EVA (Ethylene-Vinyl Acetate copolymer) shoe sole material |
| CN105968781A (en) * | 2016-07-20 | 2016-09-28 | 南京东亚橡塑制品有限公司 | Preparation method of low-hardness and soft slipper material |
| CN105968420A (en) * | 2016-07-20 | 2016-09-28 | 南京东亚橡塑制品有限公司 | Preparation method of biodegradable mosquito-repelling slipper sole material |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109233319A (en) * | 2018-09-13 | 2019-01-18 | 温州职业技术学院 | A kind of production technology of slippers |
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