CN107954668B - A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault - Google Patents

A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault Download PDF

Info

Publication number
CN107954668B
CN107954668B CN201711097970.8A CN201711097970A CN107954668B CN 107954668 B CN107954668 B CN 107954668B CN 201711097970 A CN201711097970 A CN 201711097970A CN 107954668 B CN107954668 B CN 107954668B
Authority
CN
China
Prior art keywords
inorganic compounding
less
base
cement
injecting paste
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201711097970.8A
Other languages
Chinese (zh)
Other versions
CN107954668A (en
Inventor
郑群
曹海山
张敦喜
王波
李俊斌
张辉
杨张杰
钱统傲
杨永刚
李世辉
徐永良
余大军
王庆牛
王福海
王威
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ANHUI PROVINCE COAL SCIENCE RESEARCH INSTITUTE
Huainan Donghua Ouke Mine Support Equipment Co Ltd
Huainan Mining Group Co Ltd
Original Assignee
ANHUI PROVINCE COAL SCIENCE RESEARCH INSTITUTE
Huainan Donghua Ouke Mine Support Equipment Co Ltd
Huainan Mining Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ANHUI PROVINCE COAL SCIENCE RESEARCH INSTITUTE, Huainan Donghua Ouke Mine Support Equipment Co Ltd, Huainan Mining Group Co Ltd filed Critical ANHUI PROVINCE COAL SCIENCE RESEARCH INSTITUTE
Priority to CN201711097970.8A priority Critical patent/CN107954668B/en
Publication of CN107954668A publication Critical patent/CN107954668A/en
Application granted granted Critical
Publication of CN107954668B publication Critical patent/CN107954668B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

Abstract

The invention discloses a kind of inorganic compounding injecting paste materials for the advanced pre-reinforcement of Coal Face Passing Through Fault.It is uniformly mixed at normal temperature by base-material, flyash and chopped carbon fiber and is obtained, or be uniformly mixed at normal temperature by base-material, portland cement, flyash and chopped carbon fiber and obtained.In use, water and inorganic compounding injecting paste material 0.3~0.4:1 in mass ratio are mixed evenly to get inorganic compounding injection slurry;The presetting period of inorganic compounding injection slurry is greater than 5h, and 28d uniaxial compressive strength is not less than 45MPa, and flexural strength is not less than 7 MPa, and the more conventional PO42.5 cement injection material of Residual Compressive Strength improves 30% or more.Inorganic compounding injecting paste material of the invention mobility, curing time, adhesion strength, the feature of environmental protection, in terms of can meet long drilled holes pre-pouring grout reinforcement process requirement, can effectively improve near Faults coal rock strength, guarantee working face safely and fast pass through tomography.

Description

A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault
Technical field
The invention belongs to Grouting support technology fields, and in particular to a kind of underground fault zone fractured coal and rock pre-reinforcement Inorganic compounding injecting paste material.
Background technique
Tomography is that earth's crust stress is broken, and along plane of fracture two sides, the construction of significant relative displacement occurs for sillar.Tomography Scales etc., big person's across pitch extend up to thousands of kms, can cut through the earth's crust, the title being usually made of many tomographies downwards For fracture belt.
In coal mining production process, biggish tomography generally just takes workaround in the design phase, subtracts as far as possible Influence of the craven fault to production.But for relatively small tomography (within general drop 5m), to avoid " workaround " from bringing Coal resources significant wastage and destruction to continuous production, working face can be forced through small tomography.Working face at present Passing fault mainly takes the passive mode of float in advance vehicle or brake, with it is shortest it is broken top or broken bottom back production distance catch upper disk or The top plate of lower wall takes bracket to drop the techniques such as fast drawing, immediate support top plate less or after tomography exposure at the exposure of tomography It carries out wall rock grouting and carrys out consolidating crack.It encounters larger drop tomography and takes above-mentioned construction technology, often will cause working face wall Wall caving, top plate emit leakage, and Roof is at high cost, and safety is poor, not can guarantee the propulsion of working face continuity, have seriously affected work Face per unit area yield.
The many mine geology complicated conditions in China, fault tectonic is more, and each mine that produces is influenced by tomography in various degree, work Making the quick passing fault technology in face is the significant technology issues for restricting mine safety production and benefit.It is taken off according to face up and down trough The fault parameter and orientation of dew carry out first advance Deep-hole Pre-grouting, in advance reinforcing coal before the advance of the face to tomography Rock stratum maintains the integrality of country rock and improves bearing capacity, normally produces during being guarantee raising Coal Face Passing Through Fault important It is great to guarantee that the safe and efficient production of working face has to leakage cash during passing fault, roof fall, the accidents such as frame of falling are prevented for technical measures Meaning.
Current mining injecting paste material series has inorganic series (including single liquid cement slurry class, cement-sodium silicate class and water glass Glass class) and organic series (including quality plasmoid humor, polyurethanes slurries, Lauxite plasmoid humor etc.).The inorganic general choosing of series It is main material with cement, it is from a wealth of sources, price is low, grouting process and equipment are simple, but the Seed harvest formed is directed to fault zone Rock improvement low strength, field-hardened effect is unobvious, and there are security risks;Organic series are mainly chemical material, can be infused Property it is good, fastening strength is high, but haves the defects that gel time is short, price is high, the feature of environmental protection is poor, be not suitable for remote slip casting, And for the engineering big for Coal Face Passing Through Fault this plasmoid humor demand, engineering cost is prohibitively expensive.
Domestic common research of the slip casting in terms of grouting parameter is more deep, at grouting theory, laboratory test and scene Using all comparative maturities, current Shallow hole grouting problem is preferably resolved, but is infused in advance at a distance in Coal Face Passing Through Fault superdeep holes Slurry aspect lacks corresponding research (preferred, grouting process design including injecting paste material etc.), largely limits common note Application of the pulp material in slip casting field.
Summary of the invention
For above-mentioned existing common inorganic injecting paste material set strength is low and curing time is short, organic injecting paste material is at high cost With the problem of feature of environmental protection difference, the present invention provides a kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault.
A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault is by base-material, flyash and chopped carbon Fiber is uniformly mixed obtained siccative at normal temperature, and the siccative is inorganic compounding injecting paste material;Wherein: the matter of base-material and flyash Amount is than being 2~4.5:1, and base-material and flyash are component A, the mass ratio of chopped carbon fiber and component A is 0.0007~ 0.0013:1;
In use, water and siccative 0.3~0.4:1 in mass ratio are mixed evenly to get inorganic compounding injection slurry;
The technical characteristic parameter of the inorganic compounding injection slurry is as follows:
Presetting period is greater than 5h;28d uniaxial compressive strength is not less than 45MPa, and flexural strength is not less than 6MPa;Remaining resistance to compression The more conventional PO42.5 cement injection material of intensity improves 30% or more.
A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault is by base-material, portland cement, powder Coal ash and chopped carbon fiber are uniformly mixed obtained siccative at normal temperature, and the siccative is inorganic compounding injecting paste material;Wherein: base The mass values range of material, portland cement and flyash is 3:1:1~8:1:1, and base-material, portland cement and flyash are Component A, chopped carbon fiber additive amount and component A mass ratio are 0.0007~0.0013:1;
In use, water and siccative 0.3~0.4:1 in mass ratio are mixed evenly to get inorganic compounding injection slurry;
The technical characteristic parameter of the inorganic compounding injection slurry is as follows:
Presetting period is greater than 5h;28d uniaxial compressive strength is not less than 45MPa, and flexural strength is not less than 6MPa;Remaining resistance to compression The more conventional PO42.5 cement injection material of intensity improves 30% or more.
The technical solution further limited is as follows:
The base-material is by 0.4~0.9 part of ordinary portland cement, 0.01~0.1 part of wollastonite powder, sulphate aluminium cement 0.01 ~0.1 part, 0.01~0.1 part of slag powders, 0.005~0.01 part of water-reducing agent, 0.005~0.01 part of plastic expansion agent be uniformly mixed It is made.
The portland cement strength grade is not less than 42.5, and initial set is not less than 45min, and final set is not more than 390min, than Surface area is not less than 300m2/kg;
4~6mm of length of the chopped carbon fiber, 7 μm of filament diameter, intensity 4900 MPa, modulus 240GPa, elongation percentage Not less than 2.1%;
0.4~0.6%, 45 μm of square hole screen over-sizes of the second class powered coal ash water content are not more than 25%.
In use, adding water while stirring into the siccative, continuous stirring 15~20 minutes is connected, i.e. acquisition inorganic compounding is infused Slurries.
Compared with prior art, the beneficial effects of the present invention are embodied in following aspect:
1. inorganic compounding injecting paste material of the invention is in mobility, curing time, adhesion strength, the feature of environmental protection, safety etc. Aspect can meet long drilled holes pre-pouring grout reinforcement process requirement, can effectively improve near Faults coal rock strength, guarantee working face Safely and fast pass through tomography.
2. inorganic compounding injecting paste material of the invention is nontoxic, tasteless, pollution-free, non-corrosive, fire-retardant.
It is that the 30% of ordinary cement grout material amount of water is left 3. inorganic compounding injecting paste material stirring water requirement of the invention is few The right side and for 24 hours bleeding rate are 0, and engineer application economy is strong.
4. inorganic compounding injecting paste material of the invention does not generate high temperature in solidification process, slip casting is safe and reliable.
5. inorganic compounding injecting paste material 28d uniaxial compressive strength of the invention is not less than 45MPa, flexural strength is not less than 7 MPa;The more conventional PO42.5 cement injection material of Residual Compressive Strength improves 30% or more;The caking property of inorganic reinforcing material and coal body It is good, it solves the wall caving occurred during coal mining, roof fall phenomenon, keeps production more safe and reliable.
6. presetting period of inorganic compounding injecting paste material of the invention is long to be greater than > 5h, good fluidity, permeability be strong;Big pressure Achievable remote (> 150m) Deep-hole Pre-grouting, realizes the advance reinforcement to crushed zone or tomography under the conditions of power, big flow.
7. inorganic compounding injecting paste material of the invention is gone into the well in ground mixing pack, finished product, Site is directly applied, behaviour Make simple, easily popularization.
Detailed description of the invention
Fig. 1 is the wet feeding 28d uniaxial compressive strength stress-of the inorganic compounding injecting paste material briquette marking condition obtained of embodiment 1 Strain curve;
Fig. 2 is that anti-reckon the actual amount after a discount of the wet feeding 28d of inorganic compounding injecting paste material briquette marking condition obtained of embodiment 1 tests displacement-load Curve;
Fig. 3 is the wet feeding 28d uniaxial compressive strength stress-of the inorganic compounding injecting paste material briquette marking condition obtained of embodiment 2 Strain curve;
Fig. 4 is that anti-reckon the actual amount after a discount of the wet feeding 28d of inorganic compounding injecting paste material briquette marking condition obtained of embodiment 2 tests displacement-load Curve.
Specific embodiment
With reference to the accompanying drawing, the present invention is further described by embodiment.
Following embodiments are raw materials used and technical parameter is as follows:
Portland cement is PO42.5 portland cement: Chaohu conch cement Co., Ltd (strength grade 42.5, Fineness requirement tails over for 80 μm of square hole screens must not exceed 10%, and the presetting period is no earlier than 45min, and final setting time is earlier than 10h);
Wollastonite powder: Changxing Chen Ming Chemical Co., Ltd. (dioxide-containing silica 49%, moisture content≤0.3%, partial size D97 (μ M)≤10, thermal expansion coefficient 6.5*10-6);
Slag powders: (content of grade S95, the inorganic matters such as calcium activated, silicon, aluminium are greater than for Hebei Yan Xi mineral products processing factory 30%);
Water-reducing agent: (5 ~ 35 DEG C of construction temperature, additive amount is generally the 1.0 of cementitious material for Jinan mountain and sea Chemical Co., Ltd. ~ 1.5%, mixing time is not less than 5min);
Plastic expansion agent: (ash content 0.11%, (50 μm of sieve pore) fineness tail over for Guangzhou Wei Pu chemical analysis Technology Co., Ltd. Object 0.16%, purity 98%, 3h free wxpansion degree 0.08%, for 24 hours free wxpansion degree 0.12%);
Sulphate aluminium cement: (relative density is in 2.87 ~ 2.92 g/cm for Lingshou County Yuan Tong Mineral Products Trade Co., Ltd3It Between, 30 ~ 50min of presetting period, 40 ~ 90min of final setting time, the low < 15% of overall porosity);
PO52.5 portland cement: (strength grade 52.5, initial set is not less than for Chaohu conch cement Co., Ltd 45min, final set are not more than 390min, and portland cement specific surface area is not less than 300m2/ kg);
Second class powered coal ash: (water content 0.5% or so, 45 μm of square hole screen over-sizes are not more than for Lingshou County perseverance stone ore product processing factory 25%);
Chopped carbon fiber: Yancheng Feng Yang special fibre Machinery Co., Ltd. (4 ~ 6mm of length, 7 μm of filament diameter, intensity 4900 MPa, modulus 240GPa, elongation percentage 2.1%).
Embodiment 1
Prepare inorganic compounding injecting paste material specific steps are as follows:
1) under room temperature, dry base-material 1600g, flyash 400g and chopped carbon fiber 2g, base-material: fine coal are weighed respectively Ash: chopped carbon fiber=4:1:0.005;Base-material is by 1200 g of PO42.5 portland cement, 128 g of wollastonite powder, aluminium sulfate water 128 g of mud, 120 g of slag powders, 11.2 g of water-reducing agent and 12.8 g of plastic expansion agent, which are uniformly mixed, to be made, PO42.5 silicate cement Mud: wollastonite powder: sulphate aluminium cement: slag powders: water-reducing agent: plastic expansion agent==75:8:8:7.5:0.7:0.8.
2) weighed each raw material is successively poured into stirring container, is stirred evenly.
3) water 630g is weighed by ratio of mud 0.315:1, is slowly added to above-mentioned stirring container, while waterside is added to stir;After adding Continue that 15min is sufficiently stirred, obtains inorganic compounding injection slurry.
4) according to GB/T 17671-1999 Test method for strength of hydraulic cement mortar (ISO method) and GB/T 50107-2010 coagulation The slurries stirred evenly are poured into two groups of crush test molds (every group of three test blocks) and two by native ruggedness test evaluation criteria respectively The anti-folding experiment mould (every group of three test blocks) of group, (temperature is 3 °C of 20 scholar, relative humidity 60-80%) carries out at the standard conditions Maintenance.
5) after die-filling maintenance 7d, by one group of resistance to compression and one group of anti-folding mold demoulding, can obtain resistance to compression (7.07 × 7.07 × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.On pressure experiment machine to standard specimen into The anti-folding of row 7d and compression strength detection.
6) after die-filling maintenance 28d, by second group of resistance to compression and second group of anti-folding mold demoulding, resistance to compression (7.07 × 7.07 can be obtained × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.To standard specimen on pressure experiment machine Carry out the anti-folding of 28d and compression strength detection.
After tested, reference block presetting period 5.5h made from the inorganic compounding injecting paste material of the present embodiment;It marks wet under condition It supports 7d and 28d uniaxial compressive strength mean value and is divided into 42MPa and 58MPa, see Fig. 1, residual strength 20MPa or so;Mark wet under condition support 7d and 28d flexural strength mean value is respectively 4.08MPa and 7.84MPa, sees Fig. 2.
Embodiment 2
Prepare inorganic compounding injecting paste material specific steps are as follows:
1) under room temperature, dry base-material 1500g, flyash 500g and chopped carbon fiber 2g, base-material: fine coal are weighed respectively Ash: chopped carbon fiber=3:1:0.004;Base-material is by 1125 g of PO42.5 portland cement, 120 g of wollastonite powder, aluminium sulfate water 120 g of mud, 112.5 g of slag powders, 10.5 g of water-reducing agent and 12.0 g of plastic expansion agent, which are uniformly mixed, to be made, PO42.5 silicate Cement: wollastonite powder: sulphate aluminium cement: slag powders: water-reducing agent: plastic expansion agent==75:8:8:7.5:0.7:0.8.
2) weighed each raw material is successively poured into stirring container, is stirred evenly.
3) water 620g is weighed by ratio of mud 0.31:1, is slowly added to above-mentioned stirring container, while waterside is added to stir;It adds subsequent It is continuous that 15min is sufficiently stirred, obtain inorganic compounding injection slurry.
4) according to GB/T 17671-1999 Test method for strength of hydraulic cement mortar (ISO method) and GB/T 50107-2010 coagulation The slurries stirred evenly are poured into two groups of crush test molds (every group of three test blocks) and two by native ruggedness test evaluation criteria respectively The anti-folding experiment mould (every group of three test blocks) of group, (temperature is 3 °C of 20 scholar, relative humidity 60-80%) carries out at the standard conditions Maintenance.
5) after die-filling maintenance 7d, by one group of resistance to compression and one group of anti-folding mold demoulding, can obtain resistance to compression (7.07 × 7.07 × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.On pressure experiment machine to standard specimen into The anti-folding of row 7d and compression strength detection.
6) after die-filling maintenance 28d, by second group of resistance to compression and second group of anti-folding mold demoulding, resistance to compression (7.07 × 7.07 can be obtained × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.To standard specimen on pressure experiment machine Carry out the anti-folding of 28d and compression strength detection.
After tested, reference block made from the inorganic compounding injecting paste material of the present embodiment, presetting period 5.5h;It marks wet under condition It supports 7d and 28d uniaxial compressive strength mean value and is divided into 34MPa and 54MPa, residual strength 20MPa or so;Mark wet feeding 7d and 28d under condition Flexural strength mean value is respectively 5.08MPa and 6.67MPa.
Embodiment 3
Prepare inorganic compounding injecting paste material specific steps are as follows:
1) under room temperature, dry base-material 1400g, PO52.5 cement 300g, flyash 300g and chopped carbon fiber are weighed respectively Tie up 2g, base-material: PO52.5 cement: flyash: chopped carbon fiber=7:1.5:1.5:0.01;Base-material is by PO42.5 portland cement 1050 g, 112 g of wollastonite powder, sulphate aluminium cement 112g, 11.2 g of 105 g of slag powders, water-reducing agent 9.8g and plastic expansion agent It is uniformly mixed and is made, PO42.5 portland cement: wollastonite powder: sulphate aluminium cement: slag powders: water-reducing agent: plastic expansion agent== 75:8:8:7.5:0.7:0.8。
2) weighed each raw material is successively poured into stirring container, is stirred evenly.
3) water 620g is weighed by ratio of mud 0.31:1, is slowly added to above-mentioned stirring container, while waterside is added to stir;It adds subsequent It is continuous that 15min is sufficiently stirred, obtain inorganic compounding injection slurry.
4) according to GB/T 17671-1999 Test method for strength of hydraulic cement mortar (ISO method) and GB/T 50107-2010 coagulation The slurries stirred evenly are poured into two groups of crush test molds (every group of three test blocks) and two by native ruggedness test evaluation criteria respectively The anti-folding experiment mould (every group of three test blocks) of group, (temperature is 3 °C of 20 scholar, relative humidity 60-80%) carries out at the standard conditions Maintenance.
5) after die-filling maintenance 7d, by one group of resistance to compression and one group of anti-folding mold demoulding, can obtain resistance to compression (7.07 × 7.07 × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.On pressure experiment machine to standard specimen into The anti-folding of row 7d and compression strength detection.
6) after die-filling maintenance 28d, by second group of resistance to compression and second group of anti-folding mold demoulding, resistance to compression (7.07 × 7.07 can be obtained × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.To standard specimen on pressure experiment machine Carry out the anti-folding of 28d and compression strength detection.
After tested, reference block made from the inorganic compounding injecting paste material of the present embodiment, presetting period 5.5h are marked wet under condition Supporting 7d and 28d uniaxial compressive strength mean value is respectively 36MPa and 51MPa, sees Fig. 3, residual strength 20MPa or so;It marks wet under condition Supporting 7d and 28d flexural strength mean value is respectively 3.71MPa and 6.51MPa, sees Fig. 4.
Embodiment 4
Prepare inorganic compounding injecting paste material specific steps are as follows:
1) under room temperature, dry base-material 1200g, PO52.5 cement 400g, flyash 400g and chopped carbon fiber are weighed respectively Tie up 2g, base-material: PO52.5 cement: flyash: chopped carbon fiber=3:1:1:0.005;Base-material is by PO42.5 portland cement 900 G, 96 g of wollastonite powder, sulphate aluminium cement 96g, 90 g of slag powders, water-reducing agent 8.4g and 9.6 g of plastic expansion agent are uniformly mixed system , PO42.5 portland cement: wollastonite powder: sulphate aluminium cement: slag powders: water-reducing agent: plastic expansion agent==75:8:8:7.5: 0.7:0.8。
2) weighed each raw material is successively poured into stirring container, is stirred evenly.
3) water 630g is weighed by ratio of mud 0.315:1, is slowly added to above-mentioned stirring container, while waterside is added to stir;After adding Continue that 15min is sufficiently stirred, obtains inorganic compounding injection slurry.
4) according to GB/T 17671-1999 Test method for strength of hydraulic cement mortar (ISO method) and GB/T 50107-2010 coagulation The slurries stirred evenly are poured into two groups of crush test molds (every group of three test blocks) and two by native ruggedness test evaluation criteria respectively The anti-folding experiment mould (every group of three test blocks) of group, (temperature is 3 °C of 20 scholar, relative humidity 60-80%) carries out at the standard conditions Maintenance.
5) after die-filling maintenance 7d, by one group of resistance to compression and one group of anti-folding mold demoulding, can obtain resistance to compression (7.07 × 7.07 × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.On pressure experiment machine to standard specimen into The anti-folding of row 7d and compression strength detection.
6) after die-filling maintenance 28d, by second group of resistance to compression and second group of anti-folding mold demoulding, resistance to compression (7.07 × 7.07 can be obtained × 7.07cm square) and the anti-standard specimen for rolling over (4 × 4 × 16cm) strength test.To standard specimen on pressure experiment machine Carry out the anti-folding of 28d and compression strength detection.
After tested, reference block made from the inorganic compounding injecting paste material of the present embodiment, presetting period 5.5h;It marks wet under condition Supporting 7d and 28d uniaxial compressive strength mean value is respectively 39MPa and 48MPa, residual strength 20MPa or so;Mark condition under wet feeding 7d and 28d flexural strength mean value is respectively 4.89MPa and 6.2MPa.
Above embodiments are not intended to limit the invention, done within the spirit and principles of the present invention any to repair Change, equivalent replacement and improvement etc., should all be included in the protection scope of the present invention.

Claims (2)

1. a kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault, it is characterised in that: by base-material, fine coal Ash and chopped carbon fiber are uniformly mixed obtained siccative at normal temperature, and the siccative is inorganic compounding injecting paste material;Wherein: base-material with The mass ratio of flyash is 2~4.5:1, and base-material and flyash are component A, and the mass ratio of chopped carbon fiber and component A is 0.0007~0.0013:1;
The base-material by 0.4~0.9 part of ordinary portland cement, 0.01~0.1 part of wollastonite powder, sulphate aluminium cement 0.01~ 0.1 part, 0.01~0.1 part of slag powders, 0.005~0.01 part of water-reducing agent, 0.005~0.01 part of plastic expansion agent uniformly mixed system At;
The ordinary portland cement strength grade is not less than 42.5, and initial set is not less than 45min, and final set is not more than 390min, than Surface area is not less than 300m2/kg;
4 ~ 6mm of length of the chopped carbon fiber, 7 μm of filament diameter, intensity 4900 MPa, modulus 240GPa, elongation percentage is not small In 2.1%;
0.4~0.6%, 45 μm of square hole screen over-sizes of the flyash water content are not more than 25%;
In use, water and siccative 0.3~0.4:1 in mass ratio are mixed evenly, add water in Xiang Suoshu siccative while stirring, even Continuous stirring 15~20 minutes to get inorganic compounding injection slurry;
The technical characteristic parameter of the inorganic compounding injection slurry is as follows:
Presetting period is greater than 5h;28d uniaxial compressive strength is not less than 45MPa, and flexural strength is not less than 7 MPa;Remaining pressure resistance It spends more conventional PO42.5 cement injection material and improves 30% or more.
2. a kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault, it is characterised in that: by base-material, silicic acid Salt cement, flyash and chopped carbon fiber are uniformly mixed obtained siccative at normal temperature, and the siccative is inorganic compounding injecting paste material; Wherein: the mass values range of base-material, portland cement and flyash be 3:1:1~8:1:1, and base-material, portland cement and Flyash is component A, and chopped carbon fiber additive amount and component A mass ratio are 0.0007~0.0013:1;
The base-material by 0.4~0.9 part of ordinary portland cement, 0.01~0.1 part of wollastonite powder, sulphate aluminium cement 0.01~ 0.1 part, 0.01~0.1 part of slag powders, 0.005~0.01 part of water-reducing agent, 0.005~0.01 part of plastic expansion agent uniformly mixed system At;
The ordinary portland cement strength grade is not less than 42.5, and initial set is not less than 45min, and final set is not more than 390min, than Surface area is not less than 300m2/kg;
4 ~ 6mm of length of the chopped carbon fiber, 7 μm of filament diameter, intensity 4900 MPa, modulus 240GPa, elongation percentage is not small In 2.1%;
0.4~0.6%, 45 μm of square hole screen over-sizes of the flyash water content are not more than 25%;
In use, water and siccative 0.3~0.4:1 in mass ratio are mixed evenly, add water in Xiang Suoshu siccative while stirring, even Continuous stirring 15~20 minutes to get inorganic compounding injection slurry;
The technical characteristic parameter of the inorganic compounding injection slurry is as follows:
Presetting period is greater than 5h;28d uniaxial compressive strength is not less than 45MPa, and flexural strength is not less than 6MPa;Residual Compressive Strength More conventional PO42.5 cement injection material improves 30% or more.
CN201711097970.8A 2017-11-09 2017-11-09 A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault Active CN107954668B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711097970.8A CN107954668B (en) 2017-11-09 2017-11-09 A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711097970.8A CN107954668B (en) 2017-11-09 2017-11-09 A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault

Publications (2)

Publication Number Publication Date
CN107954668A CN107954668A (en) 2018-04-24
CN107954668B true CN107954668B (en) 2019-10-22

Family

ID=61964374

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711097970.8A Active CN107954668B (en) 2017-11-09 2017-11-09 A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault

Country Status (1)

Country Link
CN (1) CN107954668B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110818368A (en) * 2019-10-24 2020-02-21 山西澳华工矿山支护科技有限公司 Super-strong mineral inorganic reinforcing material with good permeability and preparation method thereof

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109356583A (en) * 2018-12-10 2019-02-19 大同煤矿集团有限责任公司 A kind of coal-mining method under complex geological condition
CN111810197B (en) * 2019-08-27 2022-04-08 淮南矿业(集团)有限责任公司 Pre-grouting reinforcement method for fault structural zone of working face
CN112343605B (en) * 2020-11-05 2022-09-27 西南科技大学 Rock burst prevention tunnel excavation supporting method based on reduced-scale modified pressure arch
CN114180895A (en) * 2021-10-18 2022-03-15 安徽华耀科力工程科技有限公司 Production process of inorganic composite grouting material
CN115108790A (en) * 2022-06-06 2022-09-27 安徽华耀科力工程科技有限公司 Mineral inorganic filling reinforcing material and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105236863B (en) * 2015-09-16 2017-07-04 长安大学 A kind of intumescent flowing cement base road surface grouting reinforcing material high and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110818368A (en) * 2019-10-24 2020-02-21 山西澳华工矿山支护科技有限公司 Super-strong mineral inorganic reinforcing material with good permeability and preparation method thereof

Also Published As

Publication number Publication date
CN107954668A (en) 2018-04-24

Similar Documents

Publication Publication Date Title
CN107954668B (en) A kind of inorganic compounding injecting paste material for the advanced pre-reinforcement of Coal Face Passing Through Fault
Deng et al. Experimental characterization of the influence of solid components on the rheological and mechanical properties of cemented paste backfill
Zhang et al. Development of cement-based self-stress composite grouting material for reinforcing rock mass and engineering application
Li et al. Experimental study on shear property and rheological characteristic of superfine cement grouts with nano-SiO2 addition
Xu et al. Coupled effect of curing temperature and age on compressive behavior, microstructure and ultrasonic properties of cemented tailings backfill
Zhang et al. Experimental study on properties of a new type of grouting material for the reinforcement of fractured seam floor
CN103739254B (en) A kind of strength grade underground anti-seepage anti-crack concrete being not more than C50 and preparation method thereof
Tian et al. Experimental study on the properties of concrete mixed with iron ore tailings
CN104692720B (en) A kind of copper tailing is non-burning brick and preparation method thereof
CN111268990B (en) Basalt fiber reinforced phosphogypsum-based composite material and preparation method thereof
CN108203281A (en) A kind of microdilatancy injecting paste material and preparation method thereof
CN104386987A (en) Modified asphalt emulsion and modified cement composite grouting material and preparation method thereof
Yao et al. Experimental study on dynamic mechanical properties of coal gangue concrete
CN111892362A (en) Building mortar and preparation method thereof
CN101633836B (en) Quick-setting early strength cement slurry for ground pregrouting reinforcement
Hou et al. Experimental study on seepage-stress coupling failure characteristics and fracture fractal characteristics of cemented gangue-fly ash backfill with defects
Yin et al. Experimental study on gangue backfilling materials improved by soda residue and field measurement of surface subsidence
Gao et al. Effect of curing temperature on the mechanical properties and pore structure of cemented backfill materials with waste rock-tailings
Lyu et al. Strength modeling and experimental study of coal pillar-artificial dam combination after wetting cycles
CN108863291B (en) Grouting material preparation method
POLAT et al. The Effects of Water/Cement Ratio and Cement Dosage Variables on the Performance of Shotcrete: Compressive Strength and Drying Shrinkage Perspective
CN105503100B (en) A kind of road and bridge engineering reinforcing high performance grouting material and preparation method thereof
CN114315273A (en) Sandstone bone material system concrete and preparation method and application thereof
CN103396078B (en) A kind of Phosphogypsum base polymer and preparation method thereof
Yu Preparation and structure analysis of aluminum oxide/water glass/polyurethane composite grouting material for mining

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant